FeCo nanoparticles coated with (Fe,Co)3O4 (magnetite doped with cobalt) were synthesized by the proteic sol-gel chemical route. The synthesized materials were characterized by Thermogravimetry (TG), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), vibrating-sample magnetometer (VSM) and Mössbauer spectroscopy (MS). The results show that the increase in temperature and the choice of the correct air/N2 flow directly influence on the final physical-chemical properties of the nanocomposite. The SEM and TEM images confirmed that a thin layer of oxide was formed on the alloy, indicating that it was obtained a self-assembled FeCo-(Fe,Co)3O4 nanocomposites. In addition, the VSM results show that a possible exchange-spring coupling in magnetic FeCo-(Fe,Co)3O4 nanoparticles occurred with high saturation magnetization from FeCo alloy and high coercivity from (Fe,Co)3O4. The rotary oven allows the uniform contact of the powder with the atmosphere of synthesis during the different oxidation-reduction steps, generating more homogeneous particles.

Neste trabalho é apresentada uma avaliação sobre a assinatura geoquímica dos principais elementos maiores em rochas lateríticas que ocorrem nos municípios de Granja, Martinópole e Parazinho, no Noroeste do Estado do Ceará. Geologicamente, a área está localizada no Domínio Médio Coreaú, caracterizada pelo Complexo Granja, representando o embasamento da região, composto por gnaisses, granulitos e migmatitos e por sequências supracrustais compostas pelos quartzitos e filitos do Grupo Martinópole e Ubajara, além de sedimentos cenozoicos da Formação Barreiras. Lateritas são normalmente encontradas em climas úmidos (sazonais ou não), porém a condição climática atual da região é considerada semiárida. Sendo assim, o mais provável é que o processo que levou à geração desses mantos seja decorrente de condições climáticas mais antigas e diferenciadas da atual. As lateritas encontram-se associadas aos gnaisses, quartzitos e filitos. O processo de laterização predominante é o enriquecimento em metais, principalmente o ferro. Os teores de ferro variam de 34,69 a 77,85% nas zonas laterizadas; essa tendência ferruginosa é mais evidente nos gnaisses, em que os valores de enriquecimento chegam a resultados acima de 75%. Os teores de Al crescem aproximadamente de 6 a 7% na rocha em processo de alteração. Dados isotópicos Sm-Nd mostram que os valores das razões obtidas nas lateritas são similares aos protólitos, podendo ser utlizados na definição de lateritas autóctones ou alóctones, além de confirmar relativa imobilidade do Sm e do Nd no processo de laterização.

In this paper an evaluation is made over the geochemistry signature of major elements in lateritic rocks on the counties of Granja, Martinópole and Parazinho, Northwest of Ceará State. Geologically, the area is located in Médio Coreaú Domain, characterized by the Granja Complex, which is the geological basement of the region, composed by gneiss, granulites and migmatites, and supracrustal sequences formed by quartizites and phyllites of Martinópole and Ubajara Group, and also cenozoic sediments of Barreiras Formation. Laterites are normally found in humid weather (seasonal or not), so it is more likely that the generation process of this lateritic beds were under ancient climatic conditions, totally different from the present. The laterites are associated with gneiss, quartzites and phyllites. The prevailing laterization process is the metal enrichment, especially iron. Iron content varies from 34.69 to 77.85% in the altered rock samples; this trend being more evident in gneiss, in which iron enrichment exceeds 75%. Al content increases 6 to 7% in altered rocks. Sm-Nd data showed that the ratios obtained in these laterites are similar to the protoliths and can be used to define autochthonous from allocththounus laterites and also confirm Sm and Nd mobility in the laterization process.

This work evaluated the catalytic activity of TiO2 synthesized by the Pechini method. with varying molar ratios of 2:1, 3:1 and 4:1 of citric acid/metallic cations, in the photocatalytic degradation of methyl red dye in aqueous solution. The samples were characterized by X-ray diffraction, phase quantification by Rietveld structure refinement, and textural analysis by nitrogen adsorption, and their photocatalytic performance was bench- tested. The results indicated that the 3:1 and 4:1 samples contained two phases, with 84.4 and 89% of anatase phase and 15.6 and 11% of rutile phase, respectively. The 2:1 sample contained only anatase phase. The total discoloration of methyl red dye in 24 hours confirmed the high photocatalytic efficiency of the 2:1 sample, which was ascribed to the formation of monophasic anatase.

O presente experimento objetivou testar o uso de antioxidantes na conservação de rabanetes minimamente processados. Os rabanetes minimamente processados foram submersos nos tratamentos por 3 minutos (ácido ascórbico ou ácido cítrico) e armazenados a 5ºC (±1ºC) e 90% (±5%) UR durante 10 dias. O tratamento com ácido ascórbico gerou a maior taxa respiratória nas 4 primeiras horas após o processamento e durante o armazenamento. O teor de sólidos solúveis totais (SST) foi significativamente maior no tratamento com ácido cítrico. Quanto ao teor de ácido ascórbico, para os tratamentos com ácido ascórbico houve um aumento significativo no 2º dia. Os valores de luminosidade (L*) apresentaram redução durante o armazenamento. Os tratamentos com ácido cítrico provocaram uma forte coloração vermelha nas raízes minimamente processadas. Nenhum dos tratamentos evitou o escurecimento das raízes de rabanete minimamente processadas.

The objective of this study was to evaluate the efficiency of antioxidants in the cold storage of fresh cut radishes. The shredded roots were submerged in the respective treatments during 3 min (ascorbic acid or citric acid) and stored at 5ºC and 90% RH during 10 days. The radish treated with ascorbic acid showed the higher respiratory rate in the first 4 h after the processing during the storage. The content of total soluble solids (TSS) was significantly higher in the treatment with citric acid. There was an increase in the content of ascorbic acid after two day of storage in the treatments with this antioxidant. The values of lightness (L*) were decreasing along the storage. Citric acid treatments caused strongly red coloration in the minimally processed roots. None of the treatments avoided the browning of the shredded radishes during the cold storage.

A cidade de Nova Olinda, sul do Estado do Ceará, é abastecida através de quatro poços tubulares profundos que captam num aqüífero confinado, composto, basicamente, por arenito. Na área também afloram calcita e gipsita, que são explotadas por mineradoras instaladas dentro da bacia hidrográfica, onde estão três dos quatro poços. Desde 2006, as tubulações de abastecimento de água estão sendo obstruídas por um precipitado folhear, causando prejuízos. Neste trabalho foi feita uma investigação, usando análises químicas, físico-químicas e de raios X e o índice de saturação de calcita (ISC), para estudar as possíveis causas dos precipitados, identificados, basicamente como calcita. As concentrações de cálcio e os ISCs indicaram que o tratamento da água aplicado na desinfecção aumenta a tendência da precipitação de calcita devido o cálcio contido nos produtos químicos usados.

The township of Nova Olinda, south of Ceará, is supplied with waters from four deep wells exploiting a confined sandstone aquifer. Calcite and gypsum rock outcrop and are being exploited commercially in the watershed where three of the wells are located. Since 2006, public supply pipelines are damaged due to a sheet-like precipitation causing frequent obstruction of the pipes. In this investigation we used chemical analyses, physical chemistry, X-ray analyses and determination of the calcite saturation index - CSI for studying possible causes for the deposits identified, basically, as calcite. Calcium concentrations and CSIs indicate that the water disinfection process adopted increases the tendency of calcite precipitation due to calcium contained in the chemicals used.

The study of fossils has made considerable progress over the last years as a result of the use of new experimental techniques. This paper describes the chemical composition of a fossilized fish of the Cretaceous period, from a 100 million-year-old, material originated from the Araripe Basin (northeastern Brazil). The chemical composition of the fossilized fish was analyzed by means of X-ray powder diffraction and Fourier transform infrared spectroscopy (FT-IR). The spectroscopic study has proven that the main substances found in the fossilized fish are CaCO3 and Ca5(PO4)3(OH). A tentative mechanism to explain the fossilization process is also given.

Coprolites are fossilized faeces that constitute an important source of palaeobiological informations. This paper describes the characterization of some coprolite materials originated from the Romualdo Member of the Santana Formation (Araripe Basin, south of Ceará State in Brazil) by means of two techniques: X-ray powder diffraction and Fourier transform infrared spectroscopy (FT-IR). This characterization allowed us to determine the main composition of the coprolites, of the nodulus (where the coprolites were extracted) and of the sediment (where the nodulus was found) suggesting that the material was produced by a carnivorous fish of the Lower Cretaceous.

The aqueous material found in the fruits of Bixa Orellana L. was collected, dried, and characterized using several experimental techniques, namely phytochemical analysis in order to identify the biologically active constituents, Fourier transform infrared (FT-IR) spectroscopy for vibrational analysis, and X-ray powder diffraction in order to identify the presence of crystalline phases in the sample. The results showed that the aqueous material possesses high concentrations of hydrolyzable tannin. This result justifies the anti-inflammatory activity of this substance reported in other studies.

Nanocrystalline powder of tripotassium sodium sulfate (K3Na(SO4)2 - KNS) was successfully obtained by mechanical alloying a mixture of potassium sulfate (K2SO4) and sodium sulfate (Na2SO4) with a proportion of 3:1 in a planetary mill. X ray powder diffraction (XRPD) was used to characterize this material. Powders produced with high milling times: 15, 30, 45 and 60 hours, have shown a single phase. For 60 hours of milling time, the powder was formed with very small grains (60 nm in average). We also prepared several samples with low milling times: 30, 60, 120, 150 and 180 minutes. The results for this series show that 120 minutes of milling is enough to produce a single crystalline phase of KNS. Therefore, we showed that a nanocrystalline powder of tripotassium sodium sulfate is easily obtained by mechanical alloying and that the grain size can be controlled by the amount of milling time.

Fe10Ag90 granular alloys have been prepared using a sol-gel process, sintered at 300 °C and annealed at temperatures between 400 °C and 700 °C. The mean size of the iron particles, obtained from X-ray diffraction, is 30.0 ± 0.7 nm. Due to the existence of a distribution of particle sizes in these samples, both blocked (BL) and superparamagnetic (SPM) particles are present simultaneously, as confirmed by magnetization measurements at room temperature. AC susceptibility measurements as a function of temperature reveal a magnetic phase transition at about 770 °C, indicating the presence of particles exhibiting bulk behavior, in the samples annealed above 550 °C. The presence of these particles has been attributed to an atomic diffusion process between the grains, forming bulk-like multiple-domain Fe particles having Curie temperatures near that of bulk alpha-Fe phase (T C = 770 °C).

Potassium dihydrogen phosphate presents a ferroelectric phase below 122 K and a paraelectric phase for T > 122 K. X-ray scattering measurements were performed in order to verify the mechanism of the phase transition from point group C2v19 to C2v¹19 at 119 K induced by DC electric field; in other words, a change of the local site symmetries of the phosphate group occurs from C2 site in the C2v19 point group to Cs in the C2v¹19 point group. This phenomenon was shown by analyzing the behavior of the integrated intensity of the (800), (080), (1600), (0160), (400) and (040) reflections. The curve fitting of these reflections showed the occurrence of a rotation of the phosphate group around the [010] crystallographic direction during the phase transition. This study confirms the observation of this metastable phase obtained by Raman spectroscopy.

Reagente novo destinado ao teste de hemaglutinação indireta, THAI IAL, foi padronizado, utilizando hemácias de ganso, como suporte inerte, para o diagnóstico de campo da tripanosomíase americana. O objetivo foi o de substituir o reagente liofilizado ou congelado de THAI produzido rotineiramente, empregando hemácias humanas, no Instituto Adolfo Lutz (São Paulo, Brasil). O reagente padronizado apresentou longa estabilidade em suspensão líquida, e foi avaliado em 137 amostras de soros de pacientes chagásicos e não chagásicos, em THAL IAl. O desempenho diagnóstico deste teste foi semelhante ao de THAI utilizando hemácias humanas e ao de THAl de procedência comercial. A sensibilidade foi 1,00, especificidade 0,98, valores de preditivo positivo 0,96, e negativo 1,00. As diferentes partidas de reagente sucessivamente produzidas demonstraram ser reprodutíveis em método de controle de qualidade. O novo reagente é mais econômico que o anterior, de fácil preparo e aplicável aos estudos soroepidemiológicos.

A new reagent was designed to the indirect hemagglutination test (IHAT IAL), utilizing goose red blood cells as inert matrix and standardized for the field diagnosis of American trypanosomiasis. The objective was to substitute the tyophilized or frozen reagent of IHAT produced routinely using human erythrocytes in the Adolfo Lutz Institute (São Paulo/Brazil). The standardized reagent presented a long stability in liquid suspension, and was evaluated in 137 serum samples from patient with and without Chagas disease, by IHAT ILA. The diagnostic performance of this lest was similar to the IHAT utilizing human erythrocytes and to that of a commercial IHA Tkit. The sensitivity was 1.00, specificity 0.98, predictive value of positive 0.96 and of negative 1.00. Different batches of reagent successively produced proved to be reproducible in a quality control method. The new reagent is more economic than the former reagent, it can be produced easily and may be applicable to the seroepidemiologic studies.