ABSTRACT Soil is an important carbon repository in terrestrial ecosystems, serving a fundamental role in the intricate cycling of this elemental component. Wetlands are crucial components of the global carbon cycle, playing a significant role in carbon sequestration due to their remarkable productivity and unique sedimentary structures. Our study focuses on the wetlands east of Marajó island, recognized as the largest fluvial-marine plain in South America. In this study, we applied a methodological framework to optimize SOC content prediction in the wetlands of Marajó island using readily available environmental covariates. We collected and analyzed 81 soil samples from the most representative geoenvironments on the island at a layer of 0.00-0.20 m. Our database included vegetation indices, morphometric maps, and covariates based on distance from water bodies and archaeological sites. We tested five machine learning algorithms - Cubist, Linear Model, Random Forest, K Nearest Neighbor, and Support Vector Machine - to obtain the best prediction performance. Cubist model demonstrated the highest performance for training (R2 = 0.483) and testing (R2 = 0.505) datasets, making it the optimal choice for SOC prediction in the topsoil. The most important covariates selected by Cubist using recursive feature elimination were digital elevation model, topographic heterogeneity index, vertical distance between the summit and base of the slope, and Euclidean distance from water bodies. Geoenvironments characterized by dense alluvial rainforest with palms on Plinthosols and Gleysols, mangroves with Gleysols, and coastal muddy plains exhibited the highest SOC content in the topsoil. ecosystems component cycle structures fluvialmarine fluvial marine America 8 0.000.20 000020 0.00 0.20 0 00 20 0.00-0.2 m indices maps sites Model Forest Neighbor R2 R (R 0.483 0483 483 0.505 0505 505 datasets topsoil index slope Gleysols 000 0.000.2 00002 0.0 020 0.2 2 0.00-0. 0.48 048 48 0.50 050 50 0.000. 0000 0. 02 0.00-0 0.4 04 4 0.5 05 5 0.000 0.00-

ABSTRACT Serra da Saudade Formation corresponds to the upper part of the stratigraphic column of the Bambuí Group. Few studies have addressed the soil properties and pedogenesis of the pelitic rocks rich in potassium minerals of this formation. This study analyzed siltstone-derived soils, some of which are glauconitic (green siltstone; “verdete”), to understand the role of the main pedogenetic factors and processes in the landscape of the Central-West region of the Minas Gerais State, covered by Cerrado vegetation. Nine soil profiles were described, and their morphological, physical, chemical and mineralogical properties were analyzed. Soils were classified as Neossolos Litólicos (P1, P3, P6, P8 and P9), Cambissolos Háplicos (P2 and P5), Argissolo Vermelho-Amarelo (P4) and Argissolo Acinzentado (P7). The main active pedogenetic processes identified in the study area are melanization, goethization, argiluviation and elutriation. These are essentially controlled by the nature of the parent material and position of the soil in the relief. Soils are typically shallow, dystrophic, highly Al-saturated and contain essentially quartz and micas in the coarse fractions (sand and silt) and illite/glauconite and kaolinite in the clay fraction. In soil environments with siltstone and green siltstone under “dry forests”, the soil water pH was higher and high levels of exchangeable calcium and magnesium, a eutrophic character and high-activity clay were observed. Barium, chromium, lead and zinc contents were high in all studied soils. Green siltstone-derived soils have peculiar physical and chemical properties, divergent from those developed from other glauconitic rocks on the Earth surface. However, greenish tones in horizons are common in all these soils. Group formation siltstonederived derived verdete, verdete , “verdete”) CentralWest Central West State vegetation described morphological P1, P1 P (P1 P3 P6 P9, P9 P9) P2 (P P5, P5 P5) VermelhoAmarelo Vermelho Amarelo P4 (P4 P7. P7 . (P7) melanization goethization elutriation relief shallow dystrophic Alsaturated Al saturated sand silt illiteglauconite illite glauconite fraction dry forests, forests forests” magnesium highactivity activity observed Barium chromium surface However “verdete” (P7 “verdete

ABSTRACT: Arsenic (As) is a naturally occurring chemical element considered toxic and carcinogenic by health and environmental protection agencies. Studies of As adsorption/desorption behavior in soils are important to predictions of As’ potential mobility in natural systems. The aim of this study was to assess the adsorption of As(V) in soils from Minas Gerais, Brazil, and determine its immobilization rate in order to identify soils with characteristics more favorable to its deployment as an As geochemical barrier. The adsorption experiment was performed using different As concentrations and the data pertaining to the maximum adsorption capacity of As(V) (MACAs) were determined by Langmuir and Freundlich isoterms. The Oxisols, due to their more oxidic mineralogy, especially more gibbsitic, and clayey texture, showed the highest MACAs, followed by Ultisols, Inceptisols, and Entisols. In terms of the desorption of As the Inceptisols were the soils that showed the most As desorption. Both As desorption and mobility was lower in the more oxidic and clayey soils. In all soils, the total amount of As was desorbed in due course, but the As release ratio tended to decrease with the passage of time. In general, soils with higher MACAs did not necessarily show less As desorption. For use as a geochemical barrier, as important as a high adsorption capacity of As by the soil is a low As desorption rate. The increase in As mobility may increase the risks of contaminating the supplies of water. To be a good As geochemical barrier the soil has to be a clayey Oxisol, with relatively high amounts of Fe and Al oxides, especially gibbsite.

Abstract Vertisols presenting kaolinite codominance or prevalence were already reported in several countries worldwide. However, the literature has few studies focused on investigating the influence of this clay mineral in soil geotechnical behavior. This study aimed to carry out the characterization of Vertisols in Bahia State, Brazil, to understand the influence of physical, chemical, and mineralogical properties on their geotechnical behavior, as these soils have high natural fertility and have been used for agricultural activity, but with great risk due to their physical and geotechnical properties. Six Vertisols were selected, three located in Juazeiro County (Semiarid region) and the other three in Recôncavo region. Geotechnical characterization of selected soils was carried out in their respective diagnostic horizons by determining properties such as granulometric curve, Atterberg limits, clay activity, linear expansion coefficient, compaction capacity, cohesion (c), and internal friction angle (ϕ) of saturated soils. Soil expansion potential was associated with expansive clay contents and clay content in each soil sample. The best soil compaction efficiency was observed for kaolinitic Vertisol, which presented greater void ratio reduction and higher density due to moisture increase. In addition, c increased as kaolinite content also increased and decreased as clay content increased in soils presenting similar mineralogy. On the other hand, ϕ was influenced mainly by granulometry since higher sand and gravel levels enabled higher ϕ, regardless of clay type.

ABSTRACT: A set of attributes endows the soils with distinctive characteristics and astute understanding is required in order to formulate suitable strategies for soil management. The aim of this study was to physically, chemically and mineralogically characterize samples of the main soil classes in Minas Gerais, Brazil, determine the point of zero salt effect (PZSE) and the point of zero charge (PZC), and ascertain the correlation between these factors and soil attributes. The soils evaluated presented different textural classes ranging from loamy sand (Entisol) to very clayey (some Oxisols and Ultisols). The soils differed substantially in terms of fertility, presenting a range from dystrophic (low fertility, base saturation < 50 %) to eutrophic character (fertility, base saturation ≥ 50 %), even within the same soil class, such as the Oxisols, which suggests the concurrence of the parent material. Highly weathered soils are predominant in Minas Gerais and these soils are composed predominantly of kaolinite, gibbsite, goethite and hematite. Traces of hydroxy-Al interlayered vermiculite and illite were also found in the Oxisols, Ultisols and Inceptisols. A correlation between the PZSE and the PZC in the A horizon was observed. A high degree of correlation was observed between the PZC and the exchangeable aluminum and the ratio of iron obtained by ammonium oxalate and dithionite-citrate (Feo/Fed) in both the A and B horizons of soil classes. The results obtained reinforce the importance of knowledge of soil attributes to the adoption of practices such as the management of phosphate fertilization in clayey soils and liming in soils rich in aluminum.

ABSTRACT Ferrimagnetic Fe-oxides are important soil components, which are present in most of the agricultural soils of Brazil. Distinction, origin, and assessment of the influence of these minerals on magnetism and geochemistry is a challenge for mineralogists. This study aimed to characterize mineralogically Fe-rich Rhodic Oxisols ( Latossolos Vermelhos ) originating from several mafic rocks in Brazil, and assess the implications on their magnetic and geochemical properties. We present results on magnetic measurements, chemical dissolutions, X-ray diffractometry, Rietveld refinement, Raman, and Mössbauer spectroscopies of Fe-rich Rhodic Oxisols originating from several mafic rocks. They show that magnetite is inherited from the parent material, and its oxidation leads to the formation of maghemite. In the coarse fractions (sand and silt), magnetite and maghemite coexist and are interstratified with hematite, confirmed by Raman spectroscopy. This limited the distinction between magnetite and maghemite by Mössbauer spectroscopy. Maghemite represents the only ferrimagnetic Fe oxide in the clay fraction. The influence of both ferrimagnetic minerals, magnetite and maghemite, on magnetic susceptibility and total content of trace elements is determined by the pedogenic development, even among highly weathered soils. In general, the coarse fractions contribute with most of the total trace element contents, while the clay fraction contributes to trace elements availability and magnetic susceptibility of soils.

RESUMO Os solos da região semi-árida de Minas Gerais possuem pequena profundidade; consistência dura, muito dura ou mesmo extremamente dura quando seca e muito plástica e muito pegajosa quando úmida; estrutura colunar ou em blocos angulares e fendilhamento significativo ao longo do perfil no período seco, entretanto eles não foram profundamente estudados até agora. Assim, o objetivo deste estudo foi detalhar a gênese dos Luvissolos da Depressão Semi-árida do Vale do Jequitinhonha (MG), a partir de atributos morfológicos, físicos, químicos, micromorfológicos e mineralógicos, e suas relações. A ausência de cutãs de iluviação na análise micromorfológica em laboratório foi consistente com a fraca e pouca cerosidade observada no topo do horizonte B de apenas um dos quatro perfis de solo estudados durante os trabalhos de campo. Considerando a ocorrência de argilominerais 2:1 expansíveis, os quais podem facilmente modificar tal feição pedológica, cautela é recomendada com relação à interpretação da gênese do solo. Desta maneira, a perda lateral de argila dos horizontes superficiais é enfatizada como o principal processo de formação dos Luvissolos estudados. A capacidade de troca de cátions desses solos revelou valores diferencialmente mais baixos para Luvissolos em regiões semi-áridas brasileiras.

ABSTRACT Soils of the semi-arid region of Minas Gerais have small depth; hard, very hard or even extremely hard consistency when dry and very plastic and very sticky when moist; columnar or angular blocky structure and significant cracking along the profile in the dry period, however they have not been deeply studied yet. Thus, the aim of this study was to detail the genesis of Luvisols in the Semi-arid Depression of the Jequitinhonha Valley (MG), incompassing morphological, physical, chemical, micromorphological and mineralogical attributes, and their relationships. The lack of illuviation coatings in the micromorphological analysis is in line with the expressionless and unclear clay skins observed in the top of the B horizon in only one out of the four soil profiles during the field work. Considering the occurrence of expandable 2:1 clay minerals, which can easily modify such pedological feature, caution is recommended in relation to soil genesis interpretation. The lateral loss of the clay fraction from the superficial horizons is highlighted as the main formation process of the Luvisols studied. The cation exchange capacity of these soils revealed remarkable lower values for the Luvisols in semi-arid Brazilian regions.

ABSTRACT: Fe-rich Oxisols on mafic rocks in Brazil generally have high magnetic susceptibility with high contents of some trace elements. These are taxonomically similar soils; however, differences in magnetic and geochemical properties may affect agricultural or environmental usability and subsequent management. This study investigated the pedogenesis of Fe-rich Oxisols from various parent materials and evaluated the lithogenetic influence on magnetic susceptibility and trace elements contents. Soil samples were collected from Bw horizons in 13 Rhodic Oxisols and a Typic Oxisol developed from several parent materials in Minas Gerais State, Brazil. Soils were analyzed by X-ray diffractometry (XRD) and magnetometry. Soil chemical analyses consisted of sulfuric and total (tri-acid) digestions and selective Fe oxides dissolutions and statistical correlations were determined. Fe-rich Oxisols presented a typical mineralogical composition of highly weathered soils with structural stability. The results confirm the difficulty to identify accurately magnetic minerals in different grain sizes using XRD. However, coarse fractions still exert dominant influence on the magnetic properties of the Fe-rich Rhodic Oxisols. In addition, coarse fractions probably contribute to the enrichment of superparamagnetic particles for the clay fraction. Although highly weathered, Fe-rich Oxisols may have their geochemical attributes still controlled by the parent material, where trace elements seem to be correlated with the magnetic minerals in the coarse fractions. Thus, the natural replacement of some trace elements from soil-solution equilibrium reactions during plant development could be more effective in soils with higher magnetic particles concentrations in the coarse fractions.

ABSTRACT Although the physical environment of the Atlantic Forest realm is well known, studies on the soil-landform relationships are fundamental to improve the management of soil resources to facilitate sustainable development. The purpose of this study was to evaluate a representative topossequence on the “Mares de Morros” landscape of deeply weathered regolith on leucocratic granite rocks and demi-orange convex slopes. The soils varied along the topossequence according to drainage and were classified as Acrudox, Pseudogleysol, and Epiaquent. The clay fraction was composed by kaolinite, in association with gibbsite, goethite, hematite, and traces of vermiculite and hydroxy-Al interlayered vermiculite (HIV). The kaolinite crystallinity index obtained by different methods showed high structural disorder throughout the sequence, indicating that long-term pre-weathering has produced a homogenous regolith with little differences in terms of mineralogy, despite the changes in drainage. On the other hand, micromorphological features showed a complete change from the typical, well-developed microaggregate structure of upland, well-drained soils, to a massive, poorly developed structure downslope, consistent with the morphological description. Changes in microstructure development and micropedological features occurred both vertically and laterally along the topossequence and indicate that mineralogy alone cannot account for the microaggregate structure of kaolinitic Latossolos (Oxisols) well-drained with low Fe contents. Soils from the “Mares de Morros” landscape of the Alegre river basin on leucocratic granitic rocks highlight an inheritance of a deep pre-weathered regolith, showing subtle chemical and mineralogical changes, but marked morphological and physical differences along the topossequence, basically controlled by soil drainage in the past or present.

ABSTRACT Despite the considerable amount of information on the mineralogical characteristics of pedogenic Fe oxides in Brazilian soils, there are few studies on Fe-rich soils developed from mafic rocks with taxonomic identities at lower categorical levels. This study evaluated the mineralogical characteristics of pedogenic Fe oxides in B horizons (Bw) of Fe-rich Oxisols developed from several mafic rocks in the state of Minas Gerais, Brazil. The Bw horizons were sampled at a 0.8-1.0 m depth in 13 Ferric and Perferric Rhodic Oxisols along with a Mesoferric Typic Oxisol originating from basalt, gabbro, tuffite, amphibolite and itabirite in Minas Gerais. The selected soils have taxonomic identities up to the fourth categorical level of the Brazilian System of Soil Classification. In the laboratory, the following analyses were made: a) powder X ray diffraction (XRD) of the clay fraction before and after selective concentration of Fe oxides by silicate alkaline dissolution (5 mol L-1 NaOH); b) selective chemical dissolution of the clay fraction by citrate-bicarbonate-dithionite (CBD), acid ammonium oxalate (AAO), and sulfuric acid (H2SO4 1.8 mol L-1); c) quantitative estimation of minerals in the clay fraction through allocation of phases from the XRD patterns, magnetic susceptibility of the clay fraction, and quantification of elements after sulfuric acid digestion (H2SO4 1:1) of the air-dried fine earth and treatment of the clay fraction with CBD; and d) estimation of the mean crystal size (MCS), specific surface area (SSA), and isomorphic Al-substitution (IS) of hematite, goethite, and maghemite from the XRD patterns obtained from concentrates of Fe oxides. The results showed that estimation of Fe content of maghemite by selective dissolution with 1.8 mol L-1 H2SO4 may not be accurate enough to realistically reflect the maghemite contents in the soil sample. The Al content extracted may also be influenced by other minerals that are sources of this element. Hematite crystals were predominantly placoid in shape in all Rhodic Oxisols and had smaller SSA compared to goethite, which showed both isodimensional and asymmetric habit. Higher crystallinity of maghemite and the IS values generally lower than those of hematite and goethite suggest that in well-drained soils derived from mafic rocks, the IS phenomenon in maghemites seems to result from pedogenetic advancement after its formation from magnetite oxidation.

RESUMO Apesar de sua importância, estudos sobre solos de manguezais são escassos, principalmente quanto a pedogênese. O objetivo deste trabalho foi estudar a gênese de alguns solos de manguezais da cidade de Ilhéus (nordeste brasileiro), através de sua caracterização físico-química, morfológica e mineralógica. Todos os solos apresentaram textura arenosa, o que está relacionado ao seu material de origem (depósitos arenosos Quaternários). A ação das marés condiciona o hidromorfismo e leva os solos a apresentar predomínio de coloração cinza-escura e conteúdo elevado de matéria orgânica (processo de paludização). Ainda, valores elevados de condutividade elétrica (CE) e dominância de Na+ no extrato da pasta saturada (processos de salinização e solodização, respectivamente). Em contraste aos demais, o perfil M3, com vegetação de aninga (Montrichardia linifera), uma planta não exclusiva de manguezais, mostrou cromas mais elevados devido à menor influência do efeito das marés. Os valores de pH e a relação SO4=/Cl- indicam a presença de materiais sulfídricos e consequentemente a ocorrência do processo de sulfidização. O fracionamento da matéria orgânica do solo evidenciou a humina como a fração com maiores valores, provavelmente devido ao efeito das marés, removendo as frações mais solúveis. Como em solos de manguezais do sudeste brasileiro, a difratometria de raios-X identificou caulinita, mica e minerais expansíveis 2:1 na fração argila.

ABSTRACT Despite its importance, studies of mangrove soils are scarce, especially from a pedological perspective. The objective of this work was to study the genesis of soils in a mangrove environment in northeastern Brazil (Ilhéus, Bahia) through a morphological, physical, chemical and mineralogical characterization. All soils presented a sandy texture, which is related to the parent material (Quaternary sand deposits). The tidal flooding and resulting hydromorphic conditions is responsible for dominance of dark grey colors, and high organic matter contents (paludization process). As well as the high values of electrical conductivity (EC) and dominance of Na+ in the saturation extract (salinization and solodization processes, respectively). Contrastingly, the M3 profile, with aninga (Montrichardia linifera) vegetation, a non-exclusive mangrove plant, showed colors with high chromas due to a lesser influence of tidal flooding. The pH values and the SO4=/Cl- ratios indicated the presence of sulfidic material and, thus, the occurrence of the sulfidization process. The soil organic matter fractionation evidenced the humin as the fraction with the highest content, probably because of removal of most soluble fractions due to tidal action. Similar to mangrove soils from southeast Brazil, the XRD analysis identified kaolinite, mica and expandable 2:1 minerals in the clay fraction.

ABSTRACT Given the increase in crop yields and the expansion of agriculture in low fertility soils, deficiency of micronutrients, such as iron, in plants grown in tropical soils has been observed. The aim of this study was to evaluate Fe availability and Fe uptake by corn (Zea mays L.) plants in 13 different soils, at two depths. Iron was extracted by Mehlich-1, Mehlich-3, and CaCl2 (Fe-CC) and was fractionated in forms related to low (Feo) and high (Fed) crystallinity pedogenic oxyhydroxides, and organic matter (Fep) using ammonium oxalate, dithionite-citrate, and sodium pyrophosphate, respectively. In order to relate Fe availability to soil properties and plant growth, an experiment was carried out in a semi-hydroponic system in which part of the roots developed in a nutrient solution (without Fe) and part in the soil (the only source of Fe). Forty-five days after seeding, we quantified shoot dry matter and leaf Fe concentration and content. Fed levels were high, from 5 to 132 g kg-1, and Feo and Fe-CC levels were low, indicating the predominance of Fe as crystalline oxyhydroxides and a low content of Fe readily available to plants. The extraction solutions showed significant correlations with various soil properties, many common to both, indicating that they act similarly. The correlation between the Mehlich-1 and Mehlich-3 extraction solutions was highly significant. However, these two extraction methods were inefficient in predicting Fe availability to plants. There was a positive correlation between dry matter and Fe levels in plant shoots, even within the ranges considered adequate in the soil and in the plant. Dry matter production and leaf Fe concentration and content were positively correlated with Fep concentration, indicating that the Fe fraction related to soil organic matter most contributes to Fe availability to plants.

Na unidade geomorfológica dos Tabuleiros Costeiros dominam os solos com horizontes coesos, e alguns deles têm a presença de horizontes cimentados comumente do tipo fragipã. Esses horizontes interferem na dinâmica da água, no crescimento de raízes e, consequentemente, na nutrição mineral de plantas. O objetivo deste trabalho foi avaliar, por meio da dissolução seletiva, a participação de formas de Fe, Si e, ou, Al na coesão e, ou, cimentação de fragipãs e horizontes coesos em Argissolos e Espodossolos da região dos Tabuleiros Costeiros do sul da Bahia e norte do Espírito Santo. Para isso, foram realizadas extrações seletivas de Fe, Si e Al por ditionito-citrato-bicarbonato de sódio (DCB) e oxalato ácido de amônio. Os maiores teores de Fe, Si e, principalmente, Al extraídos por oxalato de amônio nos fragipãs sugerem que, na gênese desses horizontes, formas de baixa cristalinidade desses elementos agem como cimentantes químicos. As dissoluções seletivas não evidenciaram a participação de formas de alta ou baixa cristalinidade de Fe, Si e, ou, Al na gênese dos horiozontes coesos em solos dos Tabuleiros Costeiros. Os Argissolos Amarelos apresentaram goethitas com alta substituição isomórfica de Fe por Al, condizente com o ambiente de forte intemperização, não redutivo e pH ácido onde esses solos se encontram nos Tabuleiros Costeiros. A substituição isomórfica de Fe por Al nos óxidos de Fe cristalinos apresentaram relação com o grau de cristalinidade e teor de Fe obtido na primeira extração com o DCB.

In the geomorphological unit of the Coastal Tablelands of Brazil there is a predominance of cohesive soil horizons and some with the presence of cemented horizons, commonly of the fragipan type. These horizons interfere with water dynamics, root growth, and, consequently, mineral nutrition of plants. The objective of this study was to use selective dissolution to evaluate the participation of forms of Fe, Si, or Al, or their combination, in the cohesion or cementation or both of fragipans and cohesive horizons in Ultisols and Spodosols in the Coastal Tablelands region of southern Bahia and northern Espírito Santo. We made selective extractions of Fe, Al, and Si by sodium citrate-bicarbonate-dithionite (CBD) and acid ammonium oxalate. The higher levels of Fe and Si, and especially Al, extracted by ammonium oxalate in the fragipans suggest that, in the genesis of these horizons, low crystalline forms of these elements act as chemical cementing agents. The selective dissolutions did not show the participation of high or low crystalline forms of Fe, Si, or Al, or their combination, in the genesis of the cohesive horizons in the soils of the Coastal Tablelands. The Yellow Ultisols have goethites with high isomorphic substitution of Fe for Al, matching the strong weathering, non-reductive, and acid pH environment where these soil are found in the Coastal Tablelands. The isomorphic substitution of Fe for Al in the crystalline iron oxides was related to the degree of crystallinity and Fe concentration obtained in the first extraction with the CBD.

Os Latossolos apresentam, de modo geral, baixos teores de P disponível; no entanto, a influência do material de origem parece ser decisiva na definição do estoque e da forma de P predominante nesses solos. O objetivo deste trabalho foi avaliar a disponibilidade de P, pelos extratores Mehlich-1 (M-1) e Resina de Troca Iônica (RTI), em amostras de horizontes B de Latossolos Férricos e Perférricos desenvolvidos a partir de diferentes materiais de origem. Para tanto, além da caracterização física e química dos solos, foram realizadas 10 extrações sequenciais com os extratores M-1 e RTI em amostras de horizonte B coletadas entre 0,8 e 1,0 m de profundidade. Os teores totais de Ca, P, Fe, Al e Ti foram determinados após digestão com os ácidos nítrico, fluorídrico e perclórico. Os efeitos das extrações sequenciais de P sobre os óxidos de Fe também foram avaliados a partir das análises com ditionito-citrato-bicarbonato e oxalato ácido de amônio. A maior semelhança observada entre os teores de P acumulado após as extrações sequenciais com M-1 e RTI nos solos desenvolvidos de tufito é indicativo da predominância de P-Ca. Os maiores teores de P extraídos pela RTI após uma única extração relevam sua maior eficiência na remoção de P em solos bastante intemperizados como os Latossolos estudados e, ainda, ressalta a elevada sensibilidade do extrator M-1 em solos altamente tamponados. Além disso, uma única extração com o extrator M-1 ou RTI não é suficiente para estimar o fator quantidade de P lábil nesses solos.

In general, Latosols have low levels of available P, however, the influence of the parent material seems to be decisive in defining the pool and predominant form of P in these soils. This study evaluated P availability by extraction with Mehlich-1 (M-1) and Ion Exchange Resin (IER), from samples of B horizons of Ferric and Perferric Latosols developed from different parent materials. To this end, in addition to the physical and chemical characterization of soils, 10 sequential extractions were performed with M-1 and IER from samples of B horizons (depth between 0.8 and 1.0 m). Total contents of Ca, P, Fe, Al, and Ti were determined after digestion with nitric, hydrofluoric and perchloric acids. The effects of sequential P extractions on Fe oxides were also evaluated from the analyses of dithionite-citrate-bicarbonate and ammonium acid oxalate. The high similarity between contents of P accumulated after sequential extractions with M-1 and IER in soils developed on tuffite indicated a predominance of P-Ca. Higher contents of P after a single IER extraction show greater efficiency in P removal from highly weathered soils, as from the Latosols studied here. The P contents also show the high sensitivity of extractant M-1 in highly buffered soils. Furthermore, a single extraction with extractant M-1 or IER is not sufficient to estimate the amount of labile P in these soils.

O conhecimento etnopedológico tem fornecido informações importantes sobre o modo de vida das populações rurais a respeito de suas tradições ancestrais, como a arte de elaborar peças artesanais a partir do barro advindo de solos com características próprias a esse uso. O objetivo deste trabalho foi avaliar física, química e mineralogicamente Planossolos e Gleissolos explorados para a produção de artefatos de cerâmica artesanal em Minas Gerais. Nos barreiros, foram coletados dois perfis de Planossolos (P1 e P2) e um Gleissolo (P3) usados como matéria-prima na produção artesanal de cerâmica. Foram realizadas análises físicas e químicas, limites de liquidez (LL) e plasticidade (LP), índice de plasticidade (IP) e de atividade coloidal (IA), além da mineralogia da fração argila. Os horizontes selecionados pelos ceramistas para a fabricação de cerâmica artesanal (BA, Btg e BCg, do P1; Btg1 e Btg2, do P2; e C2g e C3g, do P3) apresentaram os maiores teores de argila e silte, IP e IA, importantes para a qualidade final da cerâmica. O horizonte Cg do perfil P1 possui potencial de ser utilizado para a produção artesanal, em virtude do seu IP, superior aos dos horizontes normalmente usados, além dos teores de argila, silte e areia fina e suas características mineralógicas. A proporção ideal das frações areia, silte e argila e a porcentagem de matéria orgânica na definição de um bom material para cerâmica são difíceis de estabelecer e variam principalmente em razão de aspectos quantitativos e qualitativos da argila nos solos.

Ethnopedological knowledge has provided important information about the way of life of rural people and their traditions, like the craft of making pieces of pottery from suitable soils. The objective of this study was to evaluate the physical, chemical, and mineralogical properties of Planosols and Gleysols used in the production of handcrafted pottery artifacts in the State of Minas Gerais, Brazil. In the clay pits, two profiles of Planosol soil (P1 and P2) and one of Gleysol soil (P3) used as raw material in the production of handcrafted pottery were collected. Physical and chemical properties, liquidity limits (LL), plasticity limits (LP), plasticity index (PI), and colloidal activity (IA) were analyzed, as well as clay mineralogy. The horizons selected by potters to manufacture handcrafted pottery (BA, Btg, and BCg for P1; Btg1 and Btg2 for P2; and C2g and C3g for P3) showed higher clay and silt, IP, and IA contents, important for the final quality of the pottery. The Cg horizon of the P1 profile has potential for craft production due to its IP, which is greater than the horizons normally used, as well as its clay, silt, and fine sand contents, and mineralogical characteristics. The ideal proportion of sand, silt, and clay and the percentage of organic matter are difficult to establish in defining good material for pottery; they vary mainly as a result of the type and proportion of clay found in the soils.