This study describes titanium and zirconium incorporations into a FAU zeolite and subsequent modification with nickel hexacyanoferrate.The obtained materials (ZTiNiH and ZZrNiH) were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), X-ray Dispersive Energy Spectroscopy (EDS), Porosity and Surface Area and Cyclic Voltammetry (CV). The cyclic voltammograms of the modified ZTiNiH and ZZrNiH carbon paste electrodes in the proportions graphite-modifier (20% m/m) indicate sensitivity to isoniazid (IZN). The modified ZTiNiH carbon paste electrode displayed a linear analytical curve response from 4.0× 10–5 to 7.0× 10–4 mol L−1 and a limit of detection of 4.9×10-5 mol L-1, while the modified ZZrNiH electrode presented a linear analytical curve response from 1.0×10-5 a 3.0×10-4 mol L-1 and a limit of detection of 2.0×10-5 mol L-1. The amperometric sensitivity was 47.59 mA/mol L-1 and 20.55 mA/mol L-1 for ZTiNiH and ZZrNiH respectively. After catalytic IZN electro-oxidation, a study concerning the main IZN interferents was performed and its recovery from a synthetic urine sample was assessed. The obtained ZTiNiH and ZZrNiH materials are noteworthy for their good limit of detection and recovery eficiency when applied to real samples, thus comprising potential candidates for the development of electrochemical sensors aiming at IZN detection. hexacyanoferrateThe hexacyanoferrate FTIR, FTIR , (FTIR) SEM, SEM (SEM) Xray X ray EDS, EDS (EDS) CV. CV . (CV) graphitemodifier graphite modifier 20% 20 (20 m/m mm m IZN. (IZN) 40 4 0 4.0 105 10 5 10– 70 7 7.0 104 L1 L 1 L− 4.9×105 49105 4.9×10 9 4.9×10- L1, 1, 1.0×105 10105 1.0×10 1.0×10- 3.0×104 30104 3.0×10 3 3.0×10- L- 2.0×105 20105 2.0×10 2 2.0×10- L1. 1. 4759 47 59 47.5 mAmol mA 2055 55 20.5 respectively electrooxidation, electrooxidation electro oxidation, oxidation electro-oxidation assessed samples (FTIR (SEM (EDS (CV (2 (IZN 4. 7. 4910 4.9×1 1010 1.0×1 3010 3.0×1 2010 2.0×1 475 47. 205 20. ( 491 4.9× 101 1.0× 301 3.0× 201 2.0× 49 4.9 1.0 30 3.0 2.0 3. 2.

Abstract A thermosetting epoxy polymer composed of diglycidyl ether of bisphenol A and triethylenetetramine (DGEBA/TETA) was modified by incorporating flexographic photopolymer plate residues (rubber microparticles). The photopolymer plate residues were processed in two ways: (a) by grinding and performing particle size classification (where the resulting samples were denoted PP) and (b) by polyester layer separation and grinding the elastomeric fraction by cryogenic grinding (where the resulting samples were denoted ER). Both residual particles were incorporated into the epoxy at concentrations of 2.5, 5 and 7.5 wt%. The main results indicate that PP was not efficient as a modifier of the epoxy system. A reduction in mechanical properties (maximum tensile strength and deformation) was observed in the samples produced with PP in different concentrations. But, when the ER is incorporated, an increase in tensile property and in the deformation capacity, as well as impact resistance was observed in samples produced with ER. Scanning electron microscopy analysis showed a greater presence of voids in formulations produced with PP, which corroborates the decrease in the tensile strength of these samples. DGEBA/TETA DGEBATETA DGEBA TETA (DGEBA/TETA rubber microparticles. microparticles . microparticles) ways (a where b (b ER) 25 2 2.5 75 7 7. wt wt% system maximum But capacity 2.

Connectors used in electrical power distribution systems should allow the passage of electricity continuously and without interruption. However, this does not always occur due to failure caused by improper assembly and/or corrosion of the materials employed, which reflects the quality of service. Notable among the new detection technologies that have been studied to facilitate the identification of defects is the use of thermochromic materials, which allow the easy identification of "hot spots", without the need for specialized equipment and personnel. In this context, in this study, the performance of a thermochromic liquid crystal was evaluated with the aim of developing a temperature sensor for connectors used in electrical power distribution networks. For the evaluation of the performance, thermal and ultraviolet radiation degradation tests were conducted, as well as analysis using spectroscopic (FTIR, FTIR-HATR, UV-Vis, 1H NMR) and thermal (DSC, PLM) techniques. The results indicated that the liquid crystal and the associated components showed no degradation under the test conditions, as well as a good color stability was observed, verifying the viability of the use of these materials for the construction of a temperature sensor. A field test was performed with the devices and was effective for the suggested application.

The influence of alternating electric field (AC) in the structure and dynamics of giant unilamellar vesicles (GUVs) comprised of 1,2-dilauroyl-sn-glycero-3-phosphatidylcholine (DLPC) is reported. The investigations were conducted by using optical fluorescence microscopy as the method of analysis. The lipid membrane of the DLPC GUVs at the fluid phase can be deformed and they migrate towards the electrodes under AC electric field. Nevertheless, membrane disruption or vesicle fusion was never noticed. The addition of concentrated glucose solution influences the osmotic pressure of the system leading to the formation of filaments at the outer region of the GUVs. These long flexible cylinders do not retract spontaneously. However, the application of AC electric field (20 V/mm, 20 Hz) enables the filaments to be retracted back to the GUVs membrane at a calculated speed of 0.18 µm.s-1

O objetivo deste trabalho foi estudar a adsorção de micronutrientes em humina e verificar a capacidade de liberação desses elementos em água. O primeiro passo foi determinar a capacidade de adsorção da humina para alguns micronutrientes essenciais para as plantas e determinar alguns parâmetros cinéticos. A ordem de adsorção foi Zn < Ni < Co < Mn < Mo < Cu < Fe, sendo que Zn apresentou valores máximos de ca. 2,5 mg g-1 e Fe valores de ca. 0,5 mg g-1, para os sistemas contendo 1 g de humina. O ferro apresentou maiores percentuais de liberação (ca. 100%) e Co apresentou percentuais mais baixos (0,14%). Infere-se a partir dos resultados que o uso de humina enriquecida com micronutrientes pode ser uma alternativa promissora para a fertilização de solos agrícolas, com o benefício adicional de incorporar a matéria orgânica presente na forma de substâncias húmicas no solo e melhorar a produtividade agrícola.

The objective of this work was to investigate the adsorption of micronutrients in humin and to verify the ability to release these elements in water. The first step was to determine the adsorption capacity of humin for several essential plant micronutrients and check the kinetic parameters. The order of adsorption was Zn < Ni < Co < Mn < Mo < Cu < Fe, whereas Zn showed maximum values of ca. 2.5 mg g-1 and Fe values of ca. 0.5 mg g-1 for systems containing 1 g of humin. Iron presented higher percentages of release (ca. 100%) and Co the lowest percentages (0.14%). The findings suggested that the use of humin enriched with micronutrients can be a promising alternative for the fertilization of agricultural soils, with the additional benefit of incorporating organic matter present in the form of humic substances into the soil and improving the agricultural productivity.

In this paper we describe the preparation poly (L-lactide) (PLA) nanocapsules as a drug delivery system for the local anesthetic benzocaine. The characterization and in vitro release properties of the system were investigated. The characterization results showed a polydispersity index of 0.14, an average diameter of 190.1± 3 nm, zeta potential of -38.5 mV and an entrapment efficiency of 73%. The release profile of Benzocaine loaded in PLA nanocapsules showed a significant different behavior than that of the pure anesthetic in solution. This study is important to characterize a drug release system using benzocaine for application in pain treatment.

Cellulose acetate polymeric membranes had been prepared by a procedure of two steps, combining the method of phase inversion and the technique of hydrolysis-deposition. The first step was the preparation of the membrane, and together was organomodified with tetraethylortosilicate and 3-aminopropyltrietoxysilane. Parameters that exert influence in the complexation of the metallic ion, as pH, time of complexation, metal concentration, had been studied in laboratory using tests of metal removal. The membranes had presented resistance mechanics and reactivity to cations, being able to be an alternative for the removal, daily pay-concentration or in the study of the lability of metals complexed.

In this work commercial filters papers were organomodified with tetraethylorthosilicate (TEOS) and 3-aminopropyltriethoxysilane (3-APTS), aiming at the development of a new analytical procedure for in-situ speciation of labile and inert metal species in aquatic systems. Parameters that exert influence on the metal lability such as pH, chelating time, concentration and characteristics of the organic matter were studied in the laboratory using tests for metal recuperation. The results showed slower kinetics for Cu ion than for Ni, Mn and Cd in the absence of aquatic humic substances (AHS). The relative lability observed for complexed metals in aquatic humic substances using organomodified filter papers was Cu>>Cd>Ni>Mn. The pH values, structural characteristics and concentration of AHS exert strong influence on the lability of the metals. The results obtained showed that the utilization of organomodified filter papers can be an interesting and promising alternative for in situ characterization of metal lability in aquatic systems.

Foi investigada a relação entre as propriedades dielétricas (constante dielétrica, épsilon'; fator de perda, épsilon"; energia de ativação, Ea) e a proporção de resina epóxi (OG) para endurecedor em polímeros termorrígidos de resina epóxi (OG). A amplitude do pico de épsilon" decresce com o aumento da porcentagem em massa de OG até aproximadamente 73% e aumenta levemente para maiores % OG. A temperatura da posição do pico de épsilon""aumenta com o aumento da % OG, alcançando valores máximos para formulações no intervalo de 67 a 73%, e então, decresce acentuadamente para maiores % OG. A energia de ativação obtida por relaxação dielétrica aumentou com a % OG até aproximadamente 70%. Um aumento adicional na % OG até 83% reduz a Ea. As curvas das propriedades mecânicas de módulo de tensão e resistência à fratura como função da % em massa de OG apresentaram um comportamento similar.

The relationship between the dielectric properties (dielectric constant, epsilon', and loss factor, epsilon"; activation energy, Ea) and the ratio of epoxy resin (OG) to hardener of the epoxy resin thermosetting polymers was investigated. The amplitude of the epsilon" peak decreases with increasing OG content until about 73 wt.% and slightly increases at higher OG content. The temperature of the position of the epsilon" peak increases with the increasing of OG content, reaching maximum values for compositions in the range of 67 and 73 wt.%, and then it decreases sharply at higher OG content. The activation energy obtained from dielectric relaxation increased with increasing wt.% OG up to around 70 wt.%. Further increase in concentration of OG up to 83 wt.% reduced Ea. The curves of tensile modulus and fracture toughness mechanical properties as a function of OG content presented a similar behavior.

Octakis (hydridodimethylsiloxy) octasilsesquioxane was hydrosilated with allyl chloride using Spiers catalyst (H2PtCl6). This reaction was monitored using FT-IR spectroscopy. The synthesized product was characterized by 13C, 29Si NMR (MAS), SEM, FT-IR, Thermogravimetric techniques. The three propyl groups alpha, beta, gamma, (to the terminal silicon atom), associated of an allyl chloride, were clearly seen in the 13C NMR (alpha-CH2 at 31.8; beta-CH2 at 37.7; gamma-CH2 at 50.1 ppm). In addition, the 29Si NMR spectrum of the final product, exhibits three Q signals for Q type silicon attributed to Q² (-90.1) Q³ (-100.2) and Q4 (-111.3ppm). The presence of allyl chloride substitutes in octameric cube confers a relative porosity and thermal stability to the material.