Studies conducted in the field of education have, in many cases, highlighted the little insertion of teaching and learning theories in Natural Sciences classes, in Higher Education. We developed this study to analyze how Chemistry professors take ownership of a historical case to explain the concepts they develop in their classes. To do so, we analyzed this record of undergraduate classes, at times when professors related pedagogical link-making to the future field of work of the students, using the “Thalidomide case.” We realized that, by showing the importance of studies involving chirality and related concepts, the students’ attention to the content seems to have increased significantly, which expands the possibilities of construction of meaning. Thus, we argue that the pedagogical link-making can significantly contribute to students’ knowledge. cases classes Education so linkmaking link making students Thalidomide case. meaning Thus knowledge

In this work, scanning electrochemical microscopy (SECM) was employed to study the corrosion behavior of anodized AZ31B magnesium alloy exposed to simulated body fluid. SECM measurements were carried out in surface generation/tip collection mode. The hydrogen evolution flux caused during corrosion of the magnesium alloy was oxidized at the ultra-microelectrode (UME). Thus, this experimental procedure allowed evaluating the effect of the anodic protection in this alloy from the SECM analysis of Z- approximation curves, cyclic voltammograms and topographic maps. The results evidence differences in the local electrochemical response of magnesium alloy in the anodized and pristine conditions. The main sites of H2 evolution were verified in the magnesium alloy without anodizing at short exposure times.

The aim of the present work was to investigate the effect of the treatment time on the surface chemistry and corrosion behavior of cerium-based chemical conversion coatings on the AZ91D magnesium alloy. The conversion coating was prepared by the immersion technique from a bath consisting of 0.05 mol.L-1 Ce(NO3)3.6H2O and 0.254 mol.L-1 H2O2 (30 wt.%) for times ranging from 20 s to 120 s. The surface chemistry was examined by X-ray photoelectron spectroscopy (XPS). The corrosion behavior was assessed by electrochemical impedance spectroscopy and potentiodynamic polarization. XPS analysis detected the presence of cerium oxides (Ce2O3 and CeO2) and cerium/magnesium hydroxides. The best corrosion behavior was observed for the treatment conducted for 60 s. The results are discussed with respect to coating morphology and composition.