Abstract Despite the AISI 304 stainless steel has high corrosion/oxidation resistance, its tribological properties are poor, being one of the barriers for use in severe wear applications. Thus, there is a wide field for studying technologies that aim to increase the surface hardness and wear resistance of this material. In this work, hardness and wear resistance for AISI 304 stainless steel submitted to the thermochemical treatment by low temperature plasma carburizing (LTPC) in a fixed gas mixture composition of 93% H2 and 7% CH4 are presented. Through the evaluation of the carburizing layers, it was possible to observe a substantial improvement in tribological properties after all temperature and time of treatment. This improvement is directly related to the increase of the process variables; among them temperature has a stronger influence on the wear resistance obtained using LTPC process.

The aim of this work was to study the micro-abrasive wear resistance of an API 5L X-70 microalloyed steel plasma nitrided under different conditions of time and temperature. Pulsed DC plasma nitriding experiments were performed under a treatment atmosphere of 10%N2 + 90%H2, at temperatures of 410, 440 and 470 °C and for nitriding times of 1, 3 and 5h. The results show that plasma nitriding performed at 440 °C and 1h led to the formation of a compound layer constituted mainly of ε-Fe2-3N nitride and a diffusion zone with large needle-like nitride, offering the highest wear resistance. The amount of γ’- Fe4N phase was found to increase with the plasma nitriding time, decreasing the wear resistance of the material.

Depth sensing indentation is a powerful experimental technique for determining mechanical properties of materials. In this work a computational routine was developed based on Oliver-Pharr method for measuring a more precise values of elastic modulus using a Fischerscope H100 depth sensing indentation apparatus, with a Vickers indenter. This computational routine aims also to measure Vickers hardness, as the equipment does not have software for this purpose. From indentation data it was possible to determine initial unloading stiffness, contact depth, projected contact area, reduced modulus, elastic modulus and Vickers hardness of materials. The validity of the routine was verified analyzing two coatings and nine bulk specimens with different elastic-plastic behaviors. It was verified that the elastic moduli determined through the software of the equipment resulted in great discrepancies when low loads were applied. A good estimate of the elastic moduli of the tested materials is given by the developed routine. For several testing loads, the diagonals determined by means of analytical procedure were compared with the same diagonals measured by image analysis. A good estimate of the Vickers hardness of the above-mentioned materials is given by the developed routine using different testing loads.