Abstract Virtually all metals used industrially undergo a solidification process during their production. Depending on the material and its manufacturing process, its physical/mechanical properties are affected to a greater or lesser extent by the microstructure and microsegregation obtained during the phase change. Aluminum casting alloys are good examples of products where this microstructure is vital for obtaining the desired properties. A sequence of experiments to analyze the upward vertical unidirectional solidification with transient heat transfer conditions in Al-Si-Cu ternary alloys was developed in the present work. The experimental results obtained were compared with classical microsegregation models. Discrepancies related to their use for ternary alloys were raised. Since the calculated results by these models do not take into account the influence of one alloying element on the solubility of the other element, disparities were founded between experimental and numerical results. A microsegregation model was proposed based on the solubility limits of the Si in the alloy as a function of the Cu concentration present in the liquid. The model, combined with the concepts of classical microsegregation theory, allows a realistic description of the microsegregation phenomenon. The model showed an excellent agreement between microsegregation profiles of solute experimentally measured and calculated.

Abstract The solidification control is of extreme importance, because it strongly affects the final casting quality sanity. The structure obtained is generally not homogeneous and gives rise to great variations in composition, with position at small and large scales, which is known as segregation. An understanding of the way segregation occurs in continuous casting is of great importance for steels and in designing post-casting processes. As-cast structures are responsible the reduction in both scale and extension of segregation, because mass transport is dependent on the time required to diffuse a solute over a characteristic distance, e.g., the dendrite spacing that the characterizes the solidification structure. In this work, the effect of pouring temperature in steel slabs on the continuous casting processes are systematically investigated. Relationships between pouring temperature (PT) and center macrosegregation was qualitatively examined. Photomicrographs of specimen taken from transverse sections of steel slabs, shows that macrosegregation is strongly affected by pouring temperature (PT). For solute of carbon, phosphorus and sulfur, has been shown that the pouring temperature (PT) has a significant role on the resulting macrosegregation profiles, while that the elements as such silicon, manganese and aluminum, the said thermal parameter seems not able to affect its macrosegregation profiles. This is due to the fact that the solutes with lower partition coefficients favors segregation during the continuous casting process. It is shown for considered steels, the pouring temperature (PT) influences the position of the columnar to equiaxed transition (CET). Experimental results show that the end of the columnar region is abbreviated when lower pouring temperatures is used in continuous casting process. One can observe that as the pouring temperature (PT) increase in continuous casting process, the secondary dendritic arm spacing (λ2) increase, i.e., the dendritic morphology became coarsen.

Abstract Hypoperitectic Cu − 20 wt.% Sn alloy was solidified under different cooling rates and solidification growths using directional solidification system. The effects of cooling rate and solidification growth on the microsegregation profiles and tertiary dendritic arm spacing (λ3) were experimentally investigated along the casting. A mathematical model known as phase-field was applied to simulate microstructure and microsegregation during solidification in system Cu-Sn liquid. In this paper the applicability of the phase-field model to the solidification problem in a real alloy system was systematically explored. Microsegregation profiles and realistic dendritic structures were obtained using the phase-field model. The results calculated by phase-field model show various solidification features consistent with our experiment. The calculated tertiary dendritic arm spacing (λ3) and microsegregation profiles were compared with experimental values from directional solidification system. Since the calculated microsegregation profiles using the equilibrium partition coefficient (keq) can yielded discrepancies from the experimental results, an effective partition coefficient (kef) as a function of solidification growth, is proposed in phase-field model, showing a good agreement with the experimental data for any case examined.

The microstructure and mechanical properties of cast materials are strongly dependent on the thermal history during solidification process. The global casting industry has faced major challenges, i.e., customers increasingly demand completely finished cast parts as well as complexity of casting alloys are rising. Therefore, the previous knowledge the solidification conditions effects on the as-cast ingot microstructure and mechanical properties resulting is very useful in the casting industry in order to improve the casting quality. In this present paper, the thermal parameters effects on the microstructure, microhardness and microsegregation of a Cu- 20 wt.% Sn alloy under transient heat flow conditions were experimentally investigated. The experimental observations indicate that the tertiary dendritic arm spacing (λ3), microsegregation and microhardness are affected by the thermal parameters (solidification speed and cooling rate). Solidification speed (SS) associated with increasing cooling rate (RC) are found to contribute to the decreasing tertiary dendritic arm spacing (λ3). However, cooling rates from 11.36 °C/s to 0.65 °C/s were not found to affect significantly the microhardness along the ingot length. The solute concentration (Sn) in solid region were calculated by Scheil and Clyne-Kurz equation, and used in the predictions of microsegregation profiles. The results calculated by equations, have shown deviations from the experimental data. It is well known that it is very difficult to calculate these concentration profiles using the equilibrium partition coefficient, since frequently castings solidify under non-equilibrium conditions and the solidification process is known as non-equilibrium solidification. For this reason, effect of solidification speed (SS) was considered into equations through effective partition coefficient (kef) that has been determined for the range of solidification speed experimentally examined between 0.19 and 0.89 mm/s. However, results calculated by Scheil and Clyne-Kurz equation using the effective partition coefficient (kef), yielded discrepancies from the experimental results. Because of its deviations between calculated and experimental data, an experimental equation with effective partition coefficient (kef), is considered in present work, showing an excellent agreement with the experimental data.

Ternary Al-9.0wt%Si-4.0wt%Cu alloy was solidified in a vertical directional solidification system under unsteady-state heat flow conditions. The resulting dendritic morphology and microsegregation were investigated. A more detailed analysis was dedicated to the microsegregation phenomena where a multielement interaction was observed. The solidification parameters such as: solidification speed (VL) and cooling rate ( T ˙) were determined from the cooling curves obtained during the solidification process. The thermal variables effect on the dendritic morphology is presented. The measurements of tertiary dendrite arm spacing (λ3) and microsegregation were performed for different positions along the casting. The experimental curves for microsegregation were obtained for Si and Cu from the center of dendritic tertiary arm to the next nearest tertiary arm. The solidification speed (VL) influence is "built into" the effective partition coefficient (Kef_Cu and Kef_Si) that has been determined for the range of VL and microsegregation curves are calculated by Scheil's equation for comparison with experimental data. Good agreements of the Scheil's equation with experimental data on microsegregation curves of the Si and Cuwere obtained when effective partition coefficient (Kef_Cu and Kef_Si) is taken into consideration. The multielement interaction effect on the Si microsegregation is investigated. Experimental results show that, Cu-rich dendrites were accompanied by minute amounts of Si. The concentration profiles obtained experimentally point to a strong negative correlation between Si and VL on ternary Al-9.0wt%Si-4.0wt%Cu alloy.