In this work, the crystalline structure, chemical composition, size, and morphology of core@shell nanoparticles based on Zn-Mn ferrite nanocrystals were investigated. These materials have been proposed as promising candidates for multifunctional applications in biomedicine, catalysis, environmental remediation, among others. Those properties were probed by using several experimental techniques such as Synchrotron X-Ray Diffraction, Energy-Dispersive X-ray Spectroscopy, Transmission Electron Microscopy and Selected Area Electron Diffraction. Results show that all synthesized nanoparticles present a single crystalline spinel phase without the appearance of undesirable byproducts. The nanoparticles present a non-stoichiometric Zn-Mn ferrite core, due to a Fe enrichment and a Zn loss with respect to the synthesis medium. The surface treatment of the nanoparticles induces a greater iron enrichment, which occurs at the nanoparticles surface without changing the crystalline structure. Finally, modifications in lattice parameters and strain suggest a contribution of the Mn2+ cations, mainly related to their easy oxidation in the synthesis route, which increases the structural vacancies of Mn-richer ferrites.

A dynamical freezing, which is the analogous of a glass transition, is observed at large concentrations in aqueous dispersions of maghemite nanoparticles. We study experimentally the structure and the dynamical properties of two dense ferroglass-formers in two very distinct states of interparticle interaction, either strongly repulsive or attractive. The static structure of the magnetic colloidal dispersions is probed by means of Small Angle X-ray Scattering both in and without the presence of an external magnetic field. Translational dynamics of the repulsive glassformer are investigated by X ray Photon Correlation Spectroscopy. Slow dynamics and aging properties, which both become anisotropic under an applied field, are here investigated.

We present here the experimental determination of the dispersion relation of surface waves of a ferrofluid submitted to a steady vertical magnetic field. The results are compared to a linear theory where all the magnetic characteristics of the fluid have been taken into account. The knowledge of the dispersion equation is then used to analyse the capillary-wave resistance, that is the drag force associated to the emission of waves by a moving disturbance at a free fluid surface. It undergoes a transition from zero to a finite value as the speed of the disturbance reaches a certain critical value. The effect of viscosity is explored, and a magnetic fluid is shown to allow controlling the critical speeds. Contrary to the theoretical model, however, the measured wave resistance reveals a non monotonic speed dependence after the threshold.

We study ionic magnetic colloidal dispersions, which are constituted of g-Fe2O3 nanoparticles dispersed in water, and stabilized with electrostatic interparticle repulsion. The phase diagram PV versus F (P: osmotic pressure, V: particle volume, F: particle volume fraction) is explored, especially in the range of high P and high F. The osmotic pressure P of the colloidal dispersion is known either by a measurement either because it is imposed during the sample preparation by osmotic compression. The structure of the colloidal dispersion is determined from Small Angle Neutron Scattering (SANS). Two regimes can be distinguished. At high pressure, fluid and solid phases can exist. Their structure is governed by strong electrostatic repulsion, the range of which is here evaluated. At low pressure, gas, liquid and glassy solids can exist. Their structure results from a sticky hard sphere potential.