Abstract The current study proposes to investigate the diversity and phylogeny of trypanosomes parasitizing wild birds from the Brazilian Atlantic Forest. Cytological examination was carried out by light microscopy of blood smears and positive birds were selected for amplification of the 18S rDNA sequence through PCR. The resulting amplicons were subjected to purification, cloning, and sequencing analysis. Phylogenetic reconstruction was conducted, including all avian trypanosomes representative’s lineages. A total of ten bird samples from species of Turdus flavipes (N=1/12), T. albicollis (N=1/8), Tachyphonus coronatus (N=6/121), Thamnophilus caerulescens (N=1/22) and Synallaxis spixi (N=1/8) were positive for Trypanosoma spp. In the six specimens of T. coronatus, five distinct lineages of Trypanosoma spp. 18S-rRNA were observed in ninety sequences obtained, and using the strategy of cloning independent PCR, it was possible to observe that two of them were related to T. avium (JB01/JB02), and three were closed related to T. bennetti (JB03/ JB04/JB05). Addionaly, all fifteen sequences obtained from T. caerulescens/ S. spixi/T. flavipes/T. albicollis were identical. The present research is the first study to access molecular diversity and polyparasitism by avian trypanosomes in Brazil. The current research exhibits the wide genetic variability in avian trypanosomes and its non-specific relationship with its avian hosts. Forest S PCR purification analysis conducted representatives representative s N=1/12, N112 N N=1/12 , 1 12 (N=1/12) T N=1/8, N18 N=1/8 8 N=6/121, N6121 N=6/121 6 121 (N=6/121) N=1/22 N122 22 (N=1/22 (N=1/8 spp 18SrRNA SrRNA rRNA JB01/JB02, JB01JB02 JBJB JB01/JB02 JB01 JB02 JB (JB01/JB02) JB03/ JB03 (JB03 JB04/JB05. JB04JB05 JB04/JB05 . JB04 JB05 JB04/JB05) Addionaly spixiT spixi/T flavipesT flavipes/T identical Brazil nonspecific non specific hosts N11 N=1/1 (N=1/12 N1 N=1/ N612 N=6/12 (N=6/121 N=1/2 N12 2 (N=1/2 (N=1/ JB01JB0 JB01/JB0 JB0 (JB01/JB02 (JB0 JB04JB0 JB04/JB0 (N=1/1 N=1 N61 N=6/1 (N=6/12 (N=1 JB01JB JB01/JB (JB01/JB0 (JB JB04JB JB04/JB N= N6 N=6/ (N=6/1 (N= (JB01/JB N=6 (N=6/ (N (N=6

Currently, the overheating detection of electric system components is performed using thermal imaging devices, which depend on on-site regulation parameters, require skilled operators and suitable weather conditions. The development and application of innovative technologies to monitor hotspots has highlighted the use of sensors based on thermosensitive materials. In this study, a temperature sensor with thermochromic coating was developed. Thermochromic sensors covered with a varnish layer and nano-titanium oxide, in addition to thermochromic paint, were produced. A 23 experimental design was established to assess the performance of thermochromic sensors under artificial weathering conditions. Color measurements of the coatings were performed using the CIELAB method. Fourier-transform infrared (FTIR), UV-Vis (Ultraviolet-Visible), (thermogravimetric TGA, and Differential Scanning Calorimetry (DSC) analyses were performed on the sensors exposed to photodegradation to detect changes in the thermochromic coatings. The sensors exposed to thermodegradation, and salt spray weathering showed ΔE (total color difference) values below 1.50 points in the presence of TiO2. In comparison, the sensors exposed to photodegradation showed ΔE values above 10 points, and UV-Vis analysis revealed changes in the chemical structure of the coatings. These results demonstrate that the varnish layer and TiO2 can help minimize the degradation effects of temperature, light, and salinity. Currently devices onsite site parameters conditions materials study developed nanotitanium nano titanium oxide paint produced 2 method Fouriertransform Fourier transform FTIR, FTIR , (FTIR) UVVis UV Vis UltravioletVisible, UltravioletVisible Ultraviolet Visible (Ultraviolet-Visible) thermogravimetric TGA DSC (DSC thermodegradation total difference 150 1 50 1.5 TiO comparison light salinity (FTIR (Ultraviolet-Visible 15 5 1.

Resumen: El yacimiento de litio del Salar de Atacama fue la primera explotación vía salmuera en Sudamérica. Previamente, las comunidades atacameñas desarrollaron diversas prácticas culturales en torno a este bien común, las cuales fueron interrumpidas tras la instalación de esta minería no metálica durante las décadas de 1980 y 1990. Para comprender esta transformación territorial, este artículo analiza la vinculación de las comunidades locales con el ecosistema del Salar de Atacama antes de su intervención, el proceso de instalación de la minería de litio y su relación inicial con los pueblos atacameños, proponiendo una periodización que abarca desde 1962 a 1998, la cual comprende el hallazgo del yacimiento, su exploración, construcción de minas y su primera fase de producción. Teóricamente, el fenómeno es interpretado a través de los conceptos de bienes comunes y extractivismo. En términos metodológicos, se trata de una investigación cualitativa, basada en la revisión de archivos de prensa, etnografía y fuentes secundarias. Concluimos que en esta primera etapa la metanarrativa de progreso y desarrollo de la minería no se materializó, a la vez que las comunidades debieron enfrentar las primeras consecuencias socioambientales de una explotación que se constituyó sobre un despojo.

Abstract: The Salar de Atacama lithium deposit was South America's first brine mining site. The arrival of non-metallic mining in the 1980s and 1990s interrupted the diverse cultural practices that the Atacameño communities had previously established around this shared asset. This article aims to understand this territorial transformation by analyzing the ties between the local communities and the Salar de Atacama ecosystem prior to the arrival of lithium mining, the installation process and the industry’s early relationship with the Atacameño people. It proposes a periodization that spans from 1962 to 1998 and includes the discovery of the deposit, exploration, mine construction and the initial production phase. Theoretically, the phenomenon is interpreted through the concepts of commons and extractivism. In methodological terms, a review of press archives, ethnography and secondary sources form the basis for this qualitative research. We conclude that the meta-narrative of progress and development through mining did not materialize in this initial stage. However, the communities did have to face the first socio-environmental consequences of mining based on dispossession.

A new fluorophore containing 2,1,3-benzothiadiazole unit with alkylated tetrazole terminal groups as electron donors connected through a π-conjugated system of the type (D-π-A-π-D) was synthesized using the Sonogashira coupling reaction with good yields. The genotoxicity of the two intermediate compounds and the final product was evaluated in vitro in consideration of the potential application of the new compound in the chemical production of photovoltaic paints. The new fluorophore did not show significant biological effects in the cell viability test and the comet assay when compared with the intermediate compounds that were obtained synthetically despite the ability to interact with deoxyribonucleic acid (DNA) as demonstrated in circular dichroism assays. Thus, the compound does not show toxic or genotoxic activity, and therefore, it can be applied as a pigment in photovoltaic paint.

Objetivo: Analisar variações anatômicas relacionadas ao bloqueio do plexo celíaco por meio da simulação por tomografia computadorizada e avaliar a possibilidade de transfixação de órgãos pelo método transcrural. Materiais e Métodos: Cento e oito imagens de tomografias computadorizadas transaxiais abdominais foram analisadas. As relações aorto-vertebral, tronco celíaco (TCe)-vertebral, TCe-aórtica e celíaco-aorto-vertebral foram registradas. Em cada imagem foram dispostas duas trajetórias de agulhas, a 9 cm e a 4,5 cm à esquerda e à direita da linha média. Os órgãos vitais transfixados e associações relacionadas ao gênero foram registrados. Resultados: Aorto-vertebral - 45,37% esquerda e 54,62% central; TCe-vertebral - T12, 36,11%; T12-L1, 32,4%; L1, 27,77%; T11-T12, 2,77%; TCe-aórtica - 53,7% esquerda e 46,3% central; celíaco-aorto-vertebral - L-l, 22,22%; M-m, 23,15%; L-m, 31,48%; M-l, 23,15%. Em nenhum dos critérios analisados houve correspondência no lado direito e nem associação significativa entre os gêneros. Conclusão: O bloqueio do plexo celíaco não deve ser padronizado, em razão das amplas variações anatômicas abdominais e das características próprias de cada acesso, sendo necessário o registro de imagem prévio ao procedimento para cada paciente, visando diminuir riscos de lesão. Registros sobre a variação anatômica quanto ao gênero, relacionados ao bloqueio do plexo celíaco, devem ser aprofundados.

Objective: To analyze anatomical variations associated with celiac plexus complex by means of computed tomography simulation, assessing the risk for organ injury as the transcrural technique is utilized. Materials and Methods: One hundred eight transaxial computed tomography images of abdomen were analyzed. The aortic-vertebral, celiac trunk (CeT)-vertebral, CeT-aortic and celiac-aortic-vertebral topographical relationships were recorded. Two needle insertion pathways were drawn on each of the images, at right and left, 9 cm and 4.5 cm away from the midline. Transfixed vital organs and gender-related associations were recorded. Results: Aortic-vertebral - 45.37% at left and 54.62% in the middle; CeT-vertebral - T12, 36.11%; T12-L1, 32.4%; L1, 27.77%; T11-T12, 2.77%; CeT-aortic - 53.7% at left and 46.3% in the middle; celiac-aortic-vertebral - L-l, 22.22%; M-m, 23.15%; L-m, 31.48%; M-l, 23.15%. Neither correspondence on the right side nor significant gender-related associations were observed. Conclusion: Considering the wide range of abdominal anatomical variations and the characteristics of needle insertion pathways, celiac plexus block should not be standardized. Imaging should be performed prior to the procedure in order to reduce the risks for injuries or for negative outcomes to patients. Gender-related anatomical variations involved in celiac plexus block should be more deeply investigated, since few studies have addressed the subject.

A ideia do "fim da história", subentendida no capítulo final da Fenomenologia do espírito, serviu de base para o início de uma discussão, feita a partir das posições assumidas por Alexandre Kojève nos seus cursos sobre Hegel em Paris, na década de 1930, e em sua publicação no final dos anos 1940 (com reedição em 1968), voltou à baila com o artigo de Francis Fukuyama, de 1989, sobre o "fim da história", no qual ele comemorava o fim do "socialismo real" e a hegemonia mundial completa dos Estados Unidos da América. Passada a euforia sobre a "nova ordem mundial", inclusive em virtude de sucessivas crises econômicas, é interessante recolocar a questão sobre as condições sob as quais são aceitáveis conceitos associados a esse tema, especialmente o substantivo "pós-história" e o adjetivo "pós-histórico". A tese a ser defendida nesse artigo é a de que o campo da estética é um âmbito em que esses conceitos são defensáveis. Como exemplos de reflexões estéticas frutíferas que deles se valem, são consideradas a noção de "arte pós-histórica", de Arthur Danto, e os desdobramentos estéticos do conceito de "pós-história", tal como sustentado por Vilém Flusser.

The idea of the "end of history", posited in the final chapter of Hegel’s Phenomenology of Mind, grounded the beginning of a discussion unleashed by the position assumed by Alexandre Kojève in his courses on Hegel in Paris, in the 1930s, and by their publication at the end of the 1940s (being reedited in 1968). This point of view reappeared with Francis Fukuyama’s article on the "end of history", published in 1989, in which he commemorated the end of the "real socialism" and the rise of The United States of America’s complete world hegemony. Now that the euphoria about the "new world order" subsided, also in virtue of successive major economic crisis, it is interesting to turn back to the question of the conditions under which concepts associated to that theme, especially the noun "post-history" and the adjective "post-historical" are acceptable. My point in this article is that aesthetics is a field in which these concepts are defensible. As examples of fruitful aesthetic reflections that take advantage of these concepts, I point out the notion of "post-historical art", by Arthur Danto, and the aesthetic unfoldings of the "post-history" issue, just as sustained by Vilém Flusser.

Recent biochemical and pharmacological studies have led to the characterization of different fatty acid amides as a new family of biologically active lipids. Here, we describe the synthesis of new amides from C16:0, 18:0, 18:1 and 18:1, OH fatty acids (FFA) families with cyclic and acyclic amines and demonstrate for the first time that these compounds produce citotoxic effects. Application of this method to the synthesis of fatty acid amides was performed using the esters aminolysis as a key step and various carboxylic amides were prepared in good yield from fatty acid methyl esters (FAMEs).

A degeneração maligna das lesões da doença de Paget é rara (cerca de 1% dos casos), sendo de mau prognóstico apesar do tratamento. Relatamos o caso de um paciente de 82 anos de idade, portador de doença de Paget há vários anos, em que se identificaram, nos exames de imagem, características de degeneração maligna no calcâneo, com anatomopatológico evidenciando degeneração sarcomatosa do osso.

Neoplastic degeneration in Paget's disease is a rare complication (approximately 1% of cases) and, despite the treatment, presents a poor prognosis. The authors report a case of a male, 82-year-old patient with long standing Paget's disease who presented imaging findings of malignant degeneration in the calcaneus histopathologically diagnosed as sarcomatous degeneration.

De acordo com a teoria da linguagem do jovem Benjamin, a tarefa primordial da linguagem não é a comunicação de Conteúdos, mas expressar a si própria como uma "essência espiritual", da qual também o gênero humano toma parte. Essa concepção, de acordo com a qual a linguagem seria um médium para a significação de algo fora dela leva necessariamente a uma diminuição de sua potência originária e é, portanto, chamada por Benjamin burguesa (bürgerlich). Os nomes da linguagem humana são resquícios de um estado arcaico, no qual as coisas ainda não eram mudas e tinham sua própria linguagem. Benjamin sugere também que todas as artes rememoram a linguagem originária das coisas, na medida em que fazem os objetos "falarem" em forma de sons, cores, formas etc. Essa relação entre arte como resquício da "linguagem das coisas" e a possível reconciliação do gênero humano consigo próprio e com a natureza foram desenvolvidas por Theodor Adorno em vários de seus escritos, especialmente na Teoria Estética, onde a obra de arte é concebida, em última análise, como permeada de "linguagem" no seu significado mais amplo, não no sentido "burguês".

According to the theory of language of the young Benjamin, the primary task of language isn't the communication of contents, but to express itself as a "spiritual essence" in which also men take part. That conception according to which language would be a medium to signification of something outside it leads to a necessary decrease of its original strength and is thus denominated by Benjamin bürgerlich. The names of human language are remainders of an archaic state, in which things weren't yet mute and had their own language. Benjamin suggests also that all the arts remind the original language of things, as they make objects "speak" in form of sounds, colors, shapes etc. That relationship between arts as reminders of the "language of things" and the possible reconciliation of mankind with itself and with nature has been developed by Theodor Adorno in several of his writings, specially in the Aesthetic Theory, where the artwork is ultimately conceived as a construct pervaded by "language" in the widest meaning - not in the "bourgeois" sense.

De acordo com a teoria da linguagem do jovem Benjamin, a tarefa primordial da linguagem não é a comunicação de Conteúdos, mas expressar a si própria como uma "essência espiritual", da qual também o gênero humano toma parte. Essa concepção, de acordo com a qual a linguagem seria um médium para a significação de algo fora dela leva necessariamente a uma diminuição de sua potência originária e é, portanto, chamada por Benjamin burguesa (bürgerlich). Os nomes da linguagem humana são resquícios de um estado arcaico, no qual as coisas ainda não eram mudas e tinham sua própria linguagem. Benjamin sugere também que todas as artes rememoram a linguagem originária das coisas, na medida em que fazem os objetos "falarem" em forma de sons, cores, formas etc. Essa relação entre arte como resquício da "linguagem das coisas" e a possível reconciliação do gênero humano consigo próprio e com a natureza foram desenvolvidas por Theodor Adorno em vários de seus escritos, especialmente na Teoria Estética, onde a obra de arte é concebida, em última análise, como permeada de "linguagem" no seu significado mais amplo, não no sentido "burguês".

According to the theory of language of the young Benjamin, the primary task of language isn't the communication of contents, but to express itself as a "spiritual essence" in which also men take part. That conception according to which language would be a medium to signification of something outside it leads to a necessary decrease of its original strength and is thus denominated by Benjamin bürgerlich. The names of human language are remainders of an archaic state, in which things weren't yet mute and had their own language. Benjamin suggests also that all the arts remind the original language of things, as they make objects "speak" in form of sounds, colors, shapes etc. That relationship between arts as reminders of the "language of things" and the possible reconciliation of mankind with itself and with nature has been developed by Theodor Adorno in several of his writings, specially in the Aesthetic Theory, where the artwork is ultimately conceived as a construct pervaded by "language" in the widest meaning - not in the "bourgeois" sense.

Este artigo tem como objetivo mostrar a relação entre a concepção, de Adorno, da "Teoria da semiformação" e sua sugestão (juntamente com Horkheimer), na Dialética do esclarecimento, de que a indústria cultural usurpa dos indivíduos a capacidade de "esquematizar", isto é - de acordo com o ponto de vista kantiano na Crítica da razão pura -, referir sua percepção sensível a conceitos fundamentais. Já que no capítulo da Dialética do esclarecimento sobre a indústria cultural os autores não desenvolvem essa idéia, tento encontrar um desenvolvimento dela na parte intitulada "Elementos do anti-semitismo", particularmente na seção sobre a "falsa projeção". É possível mostrar, então, que a mesma concepção de semiformação, que na Dialética do esclarecimento liga a teoria sobre o anti-semitismo com a crítica à indústria cultural, poder ser considerada um conceito aplicado às questões educacionais.

This paper aims at showing the relationship between "Theory of semi-erudition" by Adorno and his (and Horkheimer's) suggestion found in the Dialectic of enlightenment, that the culture industry removes the individual capacity to "schematize", that is - according to Kant's point of view in the Critique of pure reason - to refer their sensible perception to fundamental concepts. Since in the Dialectic of enlightenment, in the chapter on the culture industry, the authors do not develop this idea, I try to find a development of it in the part entitled "Elements of anti-Semitism", particularly in the section on the "false projection". It is then possible to show that the same conception of "semi-erudition", which, in the Dialectic of enlightenment, links the theory on anti-Semitism to the critique to the culture industry, may be considered as a concept applied to educational issues.

Habermas relê Adorno e Horkheimer à luz do seu próprio modelo, isto é, do "paradigma lingüístico" que substitui a práxis transformadora pela argumentação. Assim, Habermas não percebe que, em Adorno, a competência comunicativa subordina-se a algo essencialmente diferente, a um impulso emancipatório. As características deste a priori transcendental racionalmente mediado devem ser buscadas não na Dialética do esclarecimento, mas em Minima moralia.

Habermas "re-reads" Adorno and Horkheimer from his own perspective, that is, from the point of view of the "linguistic paradigm", which substitutes the transforming práxis for argumentation. Hence, Habermas can not see that Adorno's competence in communication is subordinated to something essentially different, to an impulse towards emancipation. The characteristics of this rationally mediated transcendental a priori must be searched not in Dialectics of enlightenment but in Minima moralia.