The present work carried out an extensive and deepened study regarding the physico-chemical characteristics of two Si-MCM-41-type supports, synthesized employing two distinct silica precursors, tetraethyl orthosilicate (TEOS) and rice husk ash (RHS), with the dispersion of nickel on the surface of the catalytic support. The direct influence of the active phase dispersion was analyzed, making a relationship with the formation of coke and with its performance on methane dry reform (DRM). The catalysts were prepared with 5, 10, and 20% (m/m) of Ni by wet impregnation method (with excess solvent), calcined at 800 ºC for 6 h, and characterized by the techniques of scanning electron microscopy and energy dispersive spectroscopy (SEM/ EDS), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET)/Barret-Joyer-Halenda (BJH), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), temperature-programmed ammonia desorption (TPD-NH3), and H2-temperature-programmed reduction (TPR). The DRM experiments were carried out at 800 °C for 24 h with a 1:1 CH4:CO2 molar ratio. Analyzes of gaseous products were performed in gas chromatography (GC) and the coke produced was estimated by temperature-programmed oxidation (TPO). The best reaction results were obtained for catalysts with 20% nickel, which were selective and stable within 24 h of reaction. Comparing the TEOS and RHS catalysts for 20% Ni, the DRM results were very similar. The catalysts on RHS support demonstrated a significant low formation of coke, which can be considered negligible in a 24 h reaction. physicochemical physico chemical SiMCM41type SiMCMtype Si MCM 41 type supports precursors (TEOS RHS, , (RHS) analyzed DRM. . (DRM) 5 10 20 m/m mm m (m/m solvent, solvent solvent) 80 SEM/ SEM (SEM EDS, EDS EDS) TEM, TEM (TEM) BrunauerEmmettTeller Brunauer Emmett Teller BET/BarretJoyerHalenda BETBarretJoyerHalenda BET /Barret Joyer Halenda Barret BJH, BJH (BJH) Xray X ray XRD, XRD (XRD) FTIR, FTIR (FTIR) temperatureprogrammed temperature programmed TPDNH3, TPDNH3 TPDNH TPD NH3 NH (TPD-NH3) H2temperatureprogrammed Htemperatureprogrammed H2 H TPR. TPR (TPR) C 2 11 1 1: CH4CO2 CHCO CH4 CO2 CH CO CH4:CO ratio GC (GC TPO. TPO (TPO) similar SiMCM 4 (RHS (DRM 8 (TEM BarretJoyerHalenda (BJH (XRD (FTIR (TPD-NH3 (TPR CH4CO (TPO (TPD-NH

Abstract This research evaluated the use of industrial ash from eucalyptus chips in the biosorption of sodium dipyrone with the subsequent, study of its potential in Portland cement matrix. The biosorbent was characterized by the point of zero charge and the surface area. For comparison, before and after the biosorption process, scanning electron microscopy, energy dispersive x-ray spectroscopy, and Fourier transform infrared spectrometry were performed. Regarding the study of the potential of industrial ash after biosorption (AAB), it was characterized by analyzing specific mass, moisture, loss on fire, and X-ray fluorescence, as well as by X-ray diffraction, modified Chapelle, pozzolanic activity index with lime, and performance index with cement, compressive strength, and tensile strength by diametral compression. The biosorption tests were carried out in batch, it being possible to observe that at 298.15 K, 130 rpm, without pH adjustment approximately 93% of commercial dipyrone was removed. The pseudo-second-order kinetic model fitted better with the experimental data and the process was characterized as exothermic and spontaneous. The chemical composition of ash and AAB showed a predominance of CaO followed by MgO, without the presence of an amorphous halo. In the study of the filer effect, using cement pastes, both materials showed favorable results. Thus, it is concluded that the industrial ash studied has the potential to be applied as an alternative material in the removal of sodium dipyrone and for the replacement of cement in the composition of cement matrices, due to the filer effect they presented. subsequent matrix area comparison microscopy xray x ray spectroscopy performed AAB, , (AAB) mass moisture fire Xray X fluorescence diffraction Chapelle lime compression batch 29815 298 15 298.1 K 13 rpm 93 removed pseudosecondorder pseudo second order spontaneous MgO halo pastes results Thus matrices presented (AAB 2981 29 1 298. 9 2

Resumo O objetivo deste estudo foi avaliar um método de síntese verde de nanopartículas de ferro (Fe(NPs)) utilizando o extrato das folhas de Eucalyptus grandis, visando reduzir a geração de resíduos e diminuir o uso de insumos químicos convencionais, como o Borohidreto de sódio (NaBH4), sem comprometer a atividade catalítica. Diversas proporções volumétricas do extrato vegetal e de agente redutor NaBH4 foram testadas para compreender como essa variação afetaria as características morfológicas, estruturais e o poder catalítico do material. Nas análises realizadas, observou-se uma redução na cristalinidade das Fe(NPs) para proporções acima de 25% do extrato. No entanto, o tamanho das partículas permaneceu estável entre as diferentes sínteses, destacando-se o fato de que os íons de ferro apresentaram melhor dispersão em proporções de 40% e 50% do extrato. Em relação à estabilização, foram identificadas bandas características de compostos fenólicos, álcoois e ácidos carboxílicos, evidenciando a atuação do extrato no revestimento dos núcleos metálicos. Para avaliar o desempenho catalítico, foram conduzidos estudos de redução catalítica do contaminante 4-nitrofenol a 4-aminofenol, utilizando as Fe(NPs) como catalisadores. Os resultados revelaram conversões acima de 80% para as Fe(NPs) sintetizadas com proporções volumétricas de até 40% do extrato vegetal, indicando que a substituição do agente químico não afetou significativamente a atividade catalítica do biocatalisador. Por fim, os testes ecotoxicológicos realizados com Lemna minor e artemia salina demonstraram uma redução significativa na toxicidade do contaminante 4-nitrofenol, além de comprovar a biocompatibilidade das Fe(NPs) obtidas. FeNPs Fe NPs (Fe(NPs) grandis convencionais NaBH4, NaBH , (NaBH4) morfológicas material realizadas observouse observou se Fe(NPs 25 entanto sínteses destacandose destacando 40 50 estabilização fenólicos carboxílicos metálicos 4nitrofenol nitrofenol 4 4aminofenol, 4aminofenol aminofenol aminofenol, 4-aminofenol catalisadores 80 biocatalisador fim 4nitrofenol, nitrofenol, obtidas (Fe(NPs (NaBH4 2 5 8 (NaBH

Abstract This study assessed a green synthesis method for iron nanoparticles (Fe(NPs)), using Eucalyptus grandis leaf extract, to reduce waste generation and diminish the use of conventional chemical inputs, such as Sodium Borohydride (NaBH4), without significant losses in catalytic activity. Various volumetric ratios of plant extract and NaBH4 were tested to understand how this variation would affect the morphological, structural, and catalytic power of the material. In the conducted analyses, a reduction in the crystallinity of Fe(NPs) was observed for proportions above 25% of the extract. However, the particle size remained stable among different syntheses, with iron ions showing improved dispersion for proportions of 40% and 50% of the extract. Regarding stabilization, characteristic bands of aromatic compounds, alcohols, ethers and carboxylic acids were identified, indicating the extract's involvement in coating the metallic cores. To assess the catalytic performance, studies were conducted on the catalytic reduction of the contaminant 4-nitrophenol to 4-aminophenol, using Fe(NPs) as catalysts. The results revealed conversions above 80% for Fe(NPs) synthesized with volumetric proportions of up to 40% of the plant extract, suggesting that substituting the chemical agent did not significantly affect the catalytic activity of the biocatalyst. Finally, ecotoxicological tests performed with Lemna minor and artemia salina demonstrated a significant reduction in the toxicity of the contaminant 4-nitrophenol, as well as the biocompatibility of the obtained Fe(NPs). FeNPs, FeNPs Fe NPs , (Fe(NPs)) inputs NaBH4, NaBH (NaBH4) morphological structural material analyses Fe(NPs 25 However syntheses 40 50 stabilization compounds alcohols identified extracts s cores performance 4nitrophenol nitrophenol 4 4aminophenol, 4aminophenol aminophenol aminophenol, 4-aminophenol catalysts 80 biocatalyst Finally 4nitrophenol, nitrophenol, FeNPs. . (Fe(NPs) (NaBH4 2 5 8 (Fe(NPs (NaBH

ABSTRACT The aim of this study was to evaluate the effect of controlled atmosphere storage on quality of native and cultivated yerba mate produced in Arvorezinha (RS) and São Mateus do Sul (PR) after 0, 3, 6 and 12 months of storage under ambient conditions, low oxygen (1.0 kPa) and high carbon dioxide (3.0 kPa) partial pressures. Total chlorophyll concentration reduced over the storage period regardless of the atmosphere condition, form of cultivation and production region. Total carotenoids, regardless of the form and place of cultivation, decreased until three months of storage under 1.0 kPa O2. Although, the O2 reduction to 1.0 kPa maintains greener color and higher chlorophyll concentration after 12 months of storage. High carbon dioxide partial pressures (3.0 kPa) in the storage chamber increases the polyphenol concentration until six months of storage. The raw material originated from São Mateus do Sul (PR) has higher chlorophyll concentration and greener color, resulting in greater storage potential.

ABSTRACT The objective of this work was to evaluate the effect of extremely low-oxygen storage on the aerobic, anaerobic metabolism and overall quality maintenance of ‘Royal Gala’ and ‘Galaxy’ apples stored at two temperatures. For ‘Royal Gala’ apples, four treatments were evaluated in a two-factor scheme (2 × 2), with two storage conditions: [1] 1.2 kPa O2 + 2 kPa CO2; [2] 0.8 kPa O2 + 1.6 kPa CO2; and two temperatures (1.0 and 1.5 °C). For ‘Galaxy’ apples, the experiment was conducted in a two-factor (3 × 2) scheme with three storage conditions: [1] 1.2 kPa O2 + 2 kPa CO2; [2] 0.8 kPa O2 + 1.6 kPa CO2; [3] 0.4 kPa O2 + 1.2 kPa CO2, and two temperatures (1.0 and 1.5 °C). The ‘Royal Gala’ apples stored under 0.8 kPa O2 + 1.6 kPa CO2 at 1.5 °C had higher flesh firmness, healthy fruit and soluble solids along with lower incidence of flesh breakdown and mealiness. The ‘Galaxy’ apples stored under 0.4 kPa O2 + 1.2 kPa CO2, at temperature of 1.5 °C had lower 1-carboxylic acid-1-aminocyclopropane (ACC) oxidase enzyme activity, ethylene production, occurrence of mealiness, when compared to 1.0 °C. The storage of these two cultivars at 1.5 °C with extremely low O2 partial pressures is possible. The possibility to increase the storage temperature from 1 °C, which is traditionally used for these mutants, to 1.5 °C allows to keep better quality with the advantage of energy saving.

ABSTRACT The Gala cultivars represent about 65% of the Brazilian apple production, however, it has a short harvest period, making necessary to use technologies that anticipate or delay fruit maturation. A widely used technology is the preharvest application of growth regulators. The objective of this investigation was to evaluate the effect of preharvest application of naphthalene acetic acid (NAA) combined with aminoethoxyvinylglycine (AVG) and 2-chloroethylphosphonic acid (Ethephon), on the quality of ‘Brookfield’ apple at harvest and after eight months controlledatmosphere (CA)(1.2 kPa O2 and 2.0 kPa CO2) storage followed by seven days of shelf life at 20 °C. The treatments were: [1] Control: application of water only; [2] NAA (40 g.ha-1); [3] NAA (40 g·ha-1) plus Ethephon (2.0 L·ha-1 24% of active ingredient), and [4] NAA (40 g·ha-1) plus AVG (0.83 kg.ha-1 15% of active ingredient). At harvest, fruit treated with NAA presented a higher level of starch degradation, ethylene production and respiration rate. Fruit treated with NAA plus AVG maintained better quality after eight months under CA storage plus seven days of shelf life, due to higher healthy fruit amount and higher flesh firmness, but this combination reduced the red skin color index. Additionally, NAA plus Ethephon may be an alternative to maintain the quality of ‘Brookfield’ apple during storage in comparison to the application of NAA isolated.

ABSTRACT The aim of this study was to evaluate the effect of storing ‘Royal Gala’ apple under extremely low oxygen partial pressures on their anaerobic metabolism, ethylene production and fruit quality after 9 months of storage plus 7 days of shelf life at 20 °C. The storage conditions tested were: 1.2 kPa O2 + 2.0 kPa CO2; 0.7 kPa O2 + 1.5 kPa CO2; 0.5 kPa O2 + 1.2 kPa CO2; 0.4 kPa O2 +1.2 kPa CO2 and 0.25 kPa O2 + 0.0 kPa CO2. The fruit storage temperature was 1.0 °C (± 0.1). Fruit stored at 0.4 kPa O2 + 1.2 kPa CO2 maintained higher flesh firmness and a higher percentage of healthy fruit. The fruit stored under the 0.25 kPa O2 + 0.0 kPa CO2 condition had lower flesh firmness as well as a reduced percentage of healthy fruit and a high production of anaerobic metabolism compounds, such as ethanol and ethyl acetate, which may have caused fruit quality loss. The storage of ‘Royal Gala’ apple under 0.4 kPa O2 + 1.2 kPa CO2 is a technique that can be commercially applied to keep a better fruit quality after a 9 months storage period.

RESUMO A podridão parda do pessegueiro, causada pelo fungo Monilinia fructicola, é a principal doença da cultura, causando danos significativos tanto em pré-colheita como pós-colheita. O estudo objetivou avaliar a aplicação pré-colheita de fungicidas, no controle da podridão parda e verificar o papel da infecção latente e contaminação externa na incidência da doença em pós-colheita. Foi conduzido um experimento nos anos de 2014 e 2015 para avaliar o desempenho de seis ingredientes ativos em pré-colheita (captana, iprodiona, iminoctadina, tebuconazol, difenoconazol e azoxistrobina) no controle da podridão parda e o efeito sobre infecções latentes. Um segundo experimento objetivou monitorar a infecção latente durante o crescimento e maturação dos frutos, correlacionando-a com a incidência da doença em pós-colheita. Os dados formam submetidos a análise de variância (Anova) e as médias agrupadas pelo teste de Scott-Knott (p < 0,05) com o software estatístico Sisvar. Os produtos iprodione, tebuconazol e difenoconazol foram os mais eficientes no controle da podridão parda a campo, enquanto o iminoctadine possui maior eficiência em pós-colheita, agindo inclusive sobre as infecções latentes. A incidência de infecções latentes tanto na fase de crescimento quanto maturação tem correlação positiva com a podridão parda em pós-colheita. A maior incidência da doença após o armazenamento foi em decorrência da manifestação de infecções latentes. O eficiente controle químico no campo, durante toda a fase de crescimento e maturação dos frutos é uma importante estratégia para o controle pós-colheita, inclusive após o armazenamento refrigerado e durante a vida de prateleira sob 20 oC.

ABSTRACT The peach brown rot, caused by Monilinia fructicola, is the main disease of the crop, causing significant losses during preharvest and postharvest. This study aimed to evaluate the performance of preharvest fungicide application on brown rot control and verify the role of latent infection and external contamination in postharvest disease. An experiment was carried out in the years 2014 and 2015 in order to evaluate the performance of six active ingredients (captan, iprodione, iminoctadine, tebuconazole, difenoconazole and azoxystrobin) during preharvest on brown rot control and the effect on latent infection. A second experiment was carried out to monitor the latent infection during growth and ripening of the fruit and in order to correlate it with the postharvest disease incidence. The data were submitted to analysis of variance (Anova) and the means were grouped by the Scott-Knott test (p < 0.05), using statistical software Sisvar. The active ingredients iprodione, tebuconazole and difenoconazole were the most efficient in controlling brown rot on the field, while iminoctadine has higher efficiency during postharvest control, acting on latent infections. The incidence of latent infections during fruit growth and ripening has a positive correlation with brown rot incidence at postharvest. The highest disease incidence after storage is due to the latent infections manifestation. Effective chemical control in the field, throughout the growing and ripening of fruit, is an important approach to postharvest brown rot control, even after cold storage and during shelf life at 20 °C.

RESUMO O objetivo do trabalho foi avaliar o efeito da aplicação de etanol e duas doses de óxido nítrico na manutenção da qualidade de maçãs ‘Galaxy’ durante o armazenamento em atmosfera controlada (AC). Tratamentos utilizados: [1] 1,2 kPa O2 + 2,0 kPa CO2; [2] AC + aplicação de 20 µL L-1 de óxido nítrico; [3] AC + aplicação de 40 µL L-1 de óxido nítrico; [4] AC + aplicação de 1 mL de etanol kg-1 de fruto. Os frutos foram mantidos em AC durante oito meses e sete dias a 20º C. Frutos tratados com etanol apresentaram maior produção de etileno, menor firmeza, elevada degenerescência, polpa farinácea e produção de acetaldeído. Já, os frutos tratados com 40 µL L-1 de óxido nítrico, apresentaram menor produção de etileno, taxa respiratória e atividade da enzima ACC (1-aminociclopropano-1-carboxílico) oxidase. Maçãs tradadas com 20 µL L-1 de óxido nítrico apresentaram aumento na produção de etileno e respiração, etileno e CO2 interno, e produzem mais etanol. A aplicação de etanol e óxido nítrico, não apresentam benefícios na manutenção da qualidade dos frutos após o armazenamento em AC devido a menor firmeza de polpa, maior ocorrência de polpa farinácea, degenerescência de polpa e incidência de podridões nos frutos.

ABSTRACT The aim of this work was to evaluate the effect of ethanol and two nitric oxide dose applications on the maintenance of the post-storage quality of ‘Galaxy’ apple during storage under controlled atmosphere (CA). Treatments evaluated were: [1] 1.2 kPa O2 + 2.0 kPa CO2; [2] CA + 20 µL L-1 of nitric oxide, [3] CA + 40 µL L-1 of nitric oxide; [4] CA + 1 ml of ethanol kg-1 fruit. Fruits received treatments before storage and were kept under CA during eight months and seven days of storage at 20 °C. Fruits had been kept on CA for eight months and seven days at 20° C. Fruits treated with ethanol showed higher ethylene production, low flesh firmness, high flesh breakdown, mealiness and acetaldehyde production. Fruits treated with 40 µL L-1 nitric oxide showed lower ethylene production, respiration rate and ACC oxidase ( (1-aminocyclopropane-1-carboxylic acid) oxidase enzyme activity. Apples treated with 20 uL L-1 nitric oxide showed higher ethylene production, respiration rate, internal ethylene concentration CO2 and ethanol concentration. Ethanol and nitric oxide application before storage have no benefits in maintaining fruit quality after storage under CA due to lower flesh firmness, higher mealiness incidence, flesh breakdown and decay incidence.

Resumo Introdução A reabilitação oral de pacientes com atrofia óssea maxilar representa um grande desafio por estes pacientes apresentarem comprometimento da qualidade de vida, dificuldades alimentares, complicações nutricionais, dificuldades sociais e emocionais. Propostas de reabilitações de maxilas mutiladas e/ou atróficas com próteses totais fixas implantossuportadas, utilizando implantes zigomáticos, foram relatadas. Objetivo O objetivo deste estudo foi avaliar o grau de satisfação dos pacientes reabilitados com implantes zigomáticos e convencionais, em função de carga imediata com prótese do tipo protocolo através de um estudo retrospectivo, por meio de questionário respondido pelos pacientes. Material e método Foram incluídos dezenove pacientes, tratados na clínica do Instituto Latino Americano de Pesquisa e Ensino Odontológico (ILAPEO) em Curitiba, PR (Brasil), entre dezembro de 2005 e junho de 2010. Os pacientes foram reabilitados com 41 implantes zigomáticos e 73 implantes convencionais, todos do tipo cone Morse. As próteses, tipo híbridas, foram instaladas em carga imediata. Resultado O índice de satisfação encontrado foi de 100%. Conclusão Pode-se concluir que esta técnica de reabilitação restabelece fatores primordiais ao ser humano como mastigação, fonética e estética. Os pacientes relataram satisfação com o resultado do tratamento, conseguindo desenvolver atividades sociais dentro da normalidade, elevando sua autoestima.

Abstract Introduction Rehabilitation of patients with atrophic maxilla is challenging. Atrophic maxilla patients present compromised quality of life, impaired function, deficient nutrition, social and emotional difficulties. The rehabilitation of atrophic maxilla by zygomatic fixtures has been previously proposed. Objective This retrospective study evaluated the degree of satisfaction of patients rehabilitated by immediately loaded conventional and zygomatic fixtures supporting full-arch fixed dental prosthesis. A satisfaction questionnaire was used for patient assessment. Material and method Nineteen patients treated at the Latin American Institute for Dental Research and Education (ILAPEO) between December 2005 and June 2010 were evaluated. Patients were rehabilitated with 41 zygomatic implants and 73 conventional implants under immediate load. Result All assessed patients were completely satisfied with the provided rehabilitation. Conclusion It can be concluded that rehabilitation with zygomatic fixtures is capable of restoring function, phonetics, and esthetic for patients with atrophic maxilla. The patients were satisfied with the treatment outcomes and showed increased self-esteem after the rehabilitation.

RESUMO: O objetivo deste trabalho foi avaliar a interação entre estádios de maturação e temperatura de armazenamento na qualidade de frutos de amora-preta ‘Guarani’ armazenados em atmosfera controlada (AC). O experimento foi conduzido em esquema fatorial (2x2), avaliando-se dois estádios de maturação (E1: cor vermelha e E2: cor preta dos frutos) e duas temperaturas (1°C e 5°C). Os frutos foram armazenados em AC (10.0kPa O2+15.0Pa CO2) e 98±1% de umidade relativa. Os resultados mostraram que o componente principal 1 (PC I) e o componente principal 2 (PC II) responderam por 92,84% de variação das variáveis analisadas. Conclui-se que a colheita não deve ser realizada em estádio de maturação antecipado, pois a amora-preta ‘Guarani’ não desenvolve todas as características de qualidade para o consumidor. A amora-preta ‘Guarani’ deve ser armazenada na temperatura de 1°C. Os estádios de maturação apresentam maior importância na variação dos parâmetros de qualidade quando comparados a temperaturas de armazenamento.

ABSTRACT: The aim of this research was to evaluate the interaction between maturity stages and temperature on fruit quality of ‘Guarani’ blackberries stored under controlled atmosphere (CA). The experiment was conducted in a factorial scheme (2x2), evaluating two ripening stages (E1: red-color and E2: black-color of fruits) and two temperatures (1°C and 5°C). The fruit were stored in CA (10.0kPa O2+15.0kPa CO2) and 98±1% of relative humidity (RH). Results showed that the principal component 1 (PC I) and principal component 2 (PC II) corresponded to 92.84% of the overall variation of the evaluated variables. Harvest should not be performed in the early maturity stage, because ‘Guarani’ blackberries do not develop all quality of consumer. ‘Guarani’ blackberries must be stored at 1°C. The maturity stage showed the major importance in the overall variability of quality parameters when compared to storage temperature.

RESUMO O estudo das associações lineares existentes entre caracteres é fundamental para a seleção ou quantificação indireta de caracteres de interesse. Assim, o objetivo deste trabalho foi avaliar as relações lineares entre caracteres de frutos de maçã das cultivares ‘Royal Gala’ e ‘Fuji’, na colheita e após armazenamento refrigerado. Foram avaliados 120 frutos de ‘Royal Gala’ e 120 frutos de ‘Fuji’ na colheita e 120 frutos de ‘Royal Gala’ e 111 frutos de ‘Fuji’ após armazenamento refrigerado. Foram mensurados os caracteres morfológicos/produtivos (massa, diâmetro longitudinal e diâmetros transversais maior e menor) e os caracteres de qualidade (firmeza de polpa, sólidos solúveis totais, acidez titulável, teor de suco, produção de etileno e respiração). Em cada cultivar (‘Royal Gala’ e ‘Fuji’) e momento de avaliação (na colheita ou após armazenamento refrigerado), foram calculados os coeficientes de correlação linear de Pearson entre os pares de caracteres e a correlação canônica entre os grupos de caracteres morfológicos/produtivos e de qualidade. Na colheita, os frutos com maior massa apresentaram menor firmeza de polpa e maior teor de sólidos solúveis totais, independentemente da cultivar. Após o armazenamento refrigerado, os frutos com maior massa apresentaram maior teor de sólidos solúveis totais e menor respiração, independentemente da cultivar, e maior teor de suco na cultivar ‘Fuji’.

ABSTRACT The study of linear associations between traits is critical for the selection or the indirect quantification of the interest traits. Thus, the objective of this research was to evaluate the linear relationships among traits of apple fruits, in ‘Royal Gala’ and ‘Fuji’ cultivars, at harvest and after cold storage. In this investigation, 120 fruits of ‘Royal Gala’ and 120 fruits of ‘Fuji’ at harvest and 120 fruits of ‘Royal Gala’ and 111 fruits of ‘Fuji’ after cold storage were evaluated. Morphological/productive (mass, longitudinal diameter, major and minor transverse diameters) and quality traits (firmness, total soluble solids, titratable acidity, juice content, ethylene production and respiration) were measured. In each cultivar (‘Royal Gala’ and ‘Fuji’) and time of evaluation (at harvest or after cold storage), the Pearson’s linear correlation coefficients among the pairs of traits and the canonical correlation among the groups of morphological/productive and of quality traits were calculated. At harvest, the apple fruits with higher mass had lower firmness and higher total soluble solids, regardless of the cultivar. After cold storage, the apple fruits with higher mass had higher total soluble solids and lower respiration, regardless of the cultivar, and higher juice content in the ‘Fuji’ cultivar.

ABSTRACT The aim of this work was to compare the storage potential of ‘Guarani’ and ‘Tupy’ blackberries in controlled atmosphere (CA) and thereafter to determinate the best CA storage conditions for ‘Tupy’ blackberries. Two experiments were carried out. In the first one, ‘Guarani’ and ‘Tupy’ blackberries were stored in CA condition (10 kPa O2 + 15 kPa CO2). We found that ‘Tupy’ blackberry has the best storage potential. Therefore, in the second experiment, several CA conditions were evaluated for ‘Tupy’ blackberries storage, as follows: [1] cold storage (CS): 20.9 kPa O2 + 0.04 kPa CO2; [2] CA with 10 kPa O2 + 15 kPa CO2; [3] CA with 5 kPa O2 + 15 kPa CO2; [4] CA with 10 kPa O2 + 10 kPa CO2. All treatments were stored at 1 °C and 98% (± 1) of relative humidity. The ‘Tupy’ blackberry, despite showing a significant decrease in ascorbic acid content, presented a higher storage potential than ‘Guarani’ blackberry, if stored at recommended CA condition for other cultivars. ‘Tupy’ blackberry stored at 5 kPa O2 + 15 kPa CO2 showed higher ascorbic acid content, soluble solids and titratable acidity as compared to the other storage conditions. In CA with 10 kPa O2 + 15 kPa CO2, the juice was lighter (high L), but differed significantly only from those fruit of CS. The best CA condition for ‘Tupy’ blackberries storage is 5 kPa O2 with 15 kPa CO2.

ABSTRACT Yerba mate shows social and economic importance for the Southern Latin American countries due to its easy production and large market range. However, there is a problem to harvest the yerba mate at the correct period and to store it until processing and marketing. Thus, the aim of this paper was to evaluate the interaction among the storage in controlled atmosphere, effect of cultivation form and shelf life period on yerba mate quality after long-term controlled atmosphere storage. The experiment was conducted in a factorial arrangement (3 controlled atmosphere conditions × 2 cultivation forms × 4 weeks of shelf life). Native yerba mate, stored under controlled atmosphere, showed higher chlorophyll concentration as compared to the cultivated one. Carotenoid concentration increased up to the third week of shelf life and thereafter remained constant, if the yerba mate was stored under ambient conditions. Oxygen partial pressure lowering allows long-term yerba mate storage, keeping its quality during four shelf life weeks at 20 °C. Controlled atmosphere is an efficient technique for yerba mate quality keeping during long-term storage and shelf life, allowing the harvest of the raw material at the correct period and the maintenance of its quality until processing and marketing. The cultivation form has a significant effect on the storage and shelf life potential of yerba mate stored under controlled atmosphere.

RESUMO: O objetivo deste estudo foi avaliar o efeito da aplicação de boro em pré-colheita sobre a qualidade físico química de maçã 'Galaxy', após a colheita e armazenamento em atmosfera controlada, durante 8 meses mais sete dias de vida de prateleira a 20°C. O experimento foi composto por dois tratamentos aplicados a campo: [1] controle (frutos sem aplicação de boro) e [2] aplicação foliar de boro (quatro aplicações de 1,5kg ha-1). Após a colheita, a aplicação de boro promoveu maior produção de etileno, taxa respiratória e reduziu a firmeza de polpa em relação aos frutos sem boro. Resultado similar foi obtido após oito meses de armazenamento mais sete dias de vida. A aplicação pré-colheita de boro torna possível antecipar a colheita pelo fato de que acelera o metabolismo dos frutos, mas os frutos tem menor potencial de armazenamento, pois apresentam alta produção de etileno, taxa respiratória, incidência de podridões, polpa farinácea e redução da porcentagem de frutos sadios e firmeza de polpa após o armazenamento em AC.

ABSTRACT: The aim of this research was to evaluate the effect of preharvest boron application on the physical and chemical quality of 'Galaxy' apples after harvest and in controlled atmosphere storage during eight months, plus seven days of shelf life at 20°C. The experiment was performed with two treatments applied on the field: [1] Control (fruit without boron application) and [2] Foliar application of boron (four applications of 1.5kg ha-1). Findings showed that the boron application promoted a higher ethylene production and respiratory rate and it application also reduced the flesh firmness in relation to the fruits without it. A similar result was obtained after eight months of storage plus seven days of shelf life. The preharvest application of boron makes it possible to harvest apples earlier due to the fact that it accelerates the fruit metabolism. However, the fruits end up presenting a lower storage potential as a result of the higher ethylene production, respiration rate, decay incidence, mealiness and a reduction of the healthy fruit percentage and flesh firmness after CA storage.