ABSTRACT Phosphorous is a limiting nutrient in sugarcane cultivated in Argisols in the Northeast of Brazil, and understanding its availability in the soil, as well as determining sufficiency ranges in the plants is essential when recommending levels of phosphorus fertiliser. The aim of this study was to: (i) Define classes for interpreting P availability in Argisols of the Northeast using the Mehlich-1 and Anion Exchange Resin (AER) extractors; (ii) Evaluate P extraction by the same extractors; and (iii) Correlate the P content of the soil with the P content of the plants, and establish sufficiency ranges in the plants. Three field trials were carried out in a sandy (PVAd1), medium (PAdx) and clayey (PVAd2) Argisol, applying the following amounts of P: 0, 40, 80, 120, 160 and 200 kg ha-1 P2O5. The AER extracted more P than did Mehlich-1 from each of the soils. The P content of the classes for interpreting P availability determined by the AER were higher than those determined by Mehlich-1. AER was the best extractor to represent P availability in the Argisol with the clayey texture (PVAd2), and Mehlich-1 in the Argisol with the sandy texture (PVAd1). The ranges of P sufficiency in the leaves of the sugarcane varied between soils, with values of 0.66-0.73 g kg-1 in PVAd1, 0.59-0.69 g kg-1 in PVAd2 and 0.34-0.47 g kg-1 in PAdx. As such, the texture of Argisols cultivated with sugarcane in the Northeast of Brazil should be a criterion for choosing the P extractor used in assessing its availability. fertiliser i (i Mehlich1 Mehlich 1 Mehlich- (AER extractors ii (ii iii (iii PVAd1 PVAd , (PVAd1) PAdx (PAdx (PVAd2 0 40 80 120 16 20 ha1 ha ha- P2O5 PO O soils Mehlich1. 1. PVAd2, PVAd1. . 0.660.73 066073 0.66 0.73 66 73 0.66-0.7 kg1 kg- 0.590.69 059069 0.59 0.69 59 69 0.59-0.6 0.340.47 034047 0.34 0.47 34 47 0.34-0.4 such (PVAd1 (PVAd 4 8 12 2 P2O 660 0.660.7 06607 066 0.6 073 0.7 6 7 0.66-0. 590 0.590.6 05906 059 0.5 069 5 0.59-0. 340 0.340.4 03404 034 0.3 047 0.4 3 0.34-0. 0.660. 0660 06 0. 07 0.66-0 0.590. 0590 05 0.59-0 0.340. 0340 03 04 0.34-0 0.660 0.66- 0.590 0.59- 0.340 0.34-

ABSTRACT. Phosphorus (P) is one of the most important elements used in fertilizing soils in tropical regions due to the low efficiency of phosphate fertilization. This work aimed to fractionate inorganic P (Pi) in tropical soils of different mineralogical compositions and to relate these fractions with their respective phosphate buffer capacity (PBC) indicators. The soils were characterized physically, chemically and mineralogically. Additionally, we evaluated the P concentration that remained in solution of soil after equilibrium was met; this was termed P remaining (P-rem). In general, the Pi fractions of soils did not correlate with the PBC indicators. The P-H2O fraction showed a negative correlation with the P-Al fraction. Ferric minerals did not influence P fixation. P-rem showed a strong correlation with the maximum P adsorption capacity, adsorption energy, and the amorphous and crystalline forms of Fe. The minerals of aluminum contributed the most to P fixation. P-rem was the best estimator of PBC. The soils with high, moderate and low rates of P fixation showed high amounts of the fractions P-Al, P-Ca, and P-Fe, respectively. The results showed that P fixation was influenced by the fractions of P in the soil, suggesting that the efficiency of phosphate fertilizers in tropical soils depends on the mineralogy of the clay fraction within those soils.