ABSTRACT: Polyanilines have many applications in Aerospace, especially in their doped form. Studies on their synthesis in a pilot scale can contribute to obtain products with desirable characteristics for such applications. The present study reports the chemical oxidative synthesis of polyaniline in pilot scale and different reaction times in order to determine if there are variations in the polyaniline structure, morphology and conductivity due to these synthesis conditions. It is very common to analyze these data for polymers obtained through bench scale. However, several parameters change the properties of final material in major scales, such as thermal, mechanic and diffusive variables. Therefore, the reaction time is the only variable into the 9 syntheses carried out, and polyaniline is obtained in a doped form, being dedoped with ammonium hydroxide and redoped with dodecylbenzenesulphonic acid. The doped and redoped samples were characterized by their molecular structure, thermal behavior, crystallinity and morphology. The electrical conductivity of redoped samples was determined. Some differences in the structure and morphology of doped and dedoped forms, identifying the doping structures, were reported. This paper aims to present the relationship between changes on structure and morphology of doped and undoped polyaniline obtained by the mentioned experiments. Furthermore, some addicts on conductivity are carried out. It was possible to contribute in order to obtain a more conductive polyaniline in pilot scale.

ABSTRACT: This paper presents a preliminary study of the Radar Cross Section (RCS) reduction on the fighter aircraft. First, it was studied the RCS of the aircraft from computational simulations based on prior knowledge of vulnerable areas of this aircraft to radar threats. Subsequently, the possible applications of Radar Absorbing Materials (RAM) on the surface of the aircraft were evaluated, in order to reduce its RCS. The absorber material used in the simulations was denominated FC70, which has good attenuation in the range of 10 to 12 GHz. The study of this reduction was accomplished by applying RAM in four different scenarios at the frequency of 11.1 GHz, where the material is more sensitive. The RCS simulations of the fighter aircraft and its RCS reduction by RAM application were carried out with the support of the software "Computer Simulation Technology" (CST), version 2012. Such technology makes it possible to simulate the application with an absorber material layer on the surface of the aircraft. For the study of the RCS reduction on the fighter aircraft, it was first necessary to develop a detailed 3D model of the fighter aircraft, and it was developed with the software "Computer Aided Three-Dimensional Interactive Application" (CATIA). In conclusion, it is impossible to make much progress attempting to retrofit stealth onto a conventional aircraft because if the shape is wrong, no amount of absorbing material treatments will reduce the RCS.

The complex dielectric permittivity (ε) and magnetic permeability (µ) of Radar Absorbing Materials (RAM) based on magnetic particles (MnZn ferrite particles) embedded in a dielectric matrix (silicon rubber) have been studied in the frequency range of 2 to 18 GHz. The relative permeability and permittivity of MnZn ferrite-silicon composites for various mass fractions are measured by the transmission/reflection method using a vector network analyzer. The concentration dependence of permittivity and permeability on the evaluated frequency range is analyzed. In a general way, the results show ε' parameter presenting more significant variation among the evaluated parameters (ε", µ", µ'). The comparison of dielectric and magnetic loss tangents (ε"/ε' and µ"/µ', respectively) shows more clearly the variation of both parameters (ε and µ) according to the frequency. It is also observed that higher MnZn ferrite content fractions favor both dielectric and magnetic loss tangents.

Abstract: The complex dielectric permittivity (e) and magnetic permeability (m) of Radar Absorbing Materials (RAM) based on metallic magnetic particles (carbonyl iron particles) embedded in a dielectric matrix (silicon rubber) have been studied in the frequency range of 2 to 18 GHz. The relative permeability and permittivity of carbonyl iron-silicon composites for various mass fractions are measured by the transmission/reflection method using a vector network analyzer. The concentration dependence of permittivity and permeability on the frequency is analyzed. In a general way, the results show that e´ parameter shows a more significant variation among the evaluated parameters (e", m", m'). The comparison of dielectric and magnetic loss tangents (e"/e" and m"/m', respectively) shows more clearly the variation of both parameters (e and m) according to the frequency. It is also observed that higher carbonyl iron content fractions favor both dielectric and magnetic loss tangents.