In powder metallurgy the addition of alloying elements is a widely used alternative to increase the service life of mechanical components. However, they have an associated cost. One less exploited process is surface enrichment (or surface alloying), whose same result is obtained on the surface, but at a much lower cost. Self-lubricating composites are especially complex to be enriched, precisely because they have to avoid the deposition of alloying elements over the lubricant stocks. This paper reports the characterization and tribological properties of self-lubricating composites enriched with molybdenum or nickel. Sintered samples were produced for comparative purposes. Wear resistance, friction coefficient and wear rate were analyzed for the evaluation of tribological properties. The results showed that the enrichment process did not cover the lubricant stocks. In addition, the Mo-enriched samples presented the best tribological results, with a 250 % increase in scuffing resistance in relation the sintered sample, and lower wear rate.

Abstract To modify the surface structure of AISI 1005 steel and its properties without any dimensional loss, different plasma surface treatments were performed at low temperatures (500 ºC) in this study. The samples were subjected to single plasma treatments including: nitriding (N5% and N3%), carburizing (CE) and ferritic nitrocarburizing (NC) and to duplex treatments of nitriding followed by carburizing (N5%+CE and N3%+CE) and ferritic nitrocarburizing followed by carburizing (NC+CE). The gas mixture used for these treatments was varied as follows: nitriding (5%N2+95%H2 and 3%N2+97%H2), carburizing (5%CH4+95%H2) and ferritic nitrocarburizing (5%N2+1.5%CH4+93.5%H2). A microstructural characterization of the samples was carried out using optical and scanning electron microscopy in addition to XRD analysis. Microhardness testing was also performed. The XRD analysis showed a stabilization of the outermost cementite layer for all of the carburizing treatments. The results show that a greater hardness increase was achieved for the nitriding treatment as well as a more regular compound layer. However, a greater depth of hardening was obtained in samples with NC+CE and N5%+CE, which extended to the hardened depth to 800 µm.