Abstract CuCrO2 was synthesized by solution combustion synthesis (SCS) and applied as a heterogeneous catalyst to produce soybean biodiesel. The combustion reaction was carried out using urea as a fuel, and copper (II) and chromium (III) nitrates as precursors. After the powders’ obtention, these were calcined and functionalized in an acidic medium. The powders were characterized by thermogravimetry (TG), X-ray diffraction (XRD), scanning electron microscopy (SEM), and infrared spectroscopy (IR) techniques. The TG curve revealed that the formation of the CuCrO2 in the combustion reaction remained stable up to 1000 °C. The XRD results confirmed the formation of the CuCrO2 compound. The SEM images showed that the crystallinity of the samples increased after the calcination process. The IR spectra showed the presence of delafossite characteristic bands. After the transesterification reaction, biodiesel was obtained with a yield of around 80%. Thus, catalysts based on delafossite synthesized through the combustion method and functionalized showed to be promising for the transesterification reaction of vegetable oils. CuCrO SCS (SCS fuel II (II III (III precursors obtention medium TG, , (TG) Xray X ray XRD, (XRD) SEM, (SEM) (IR techniques 100 C °C compound process bands 80 80% Thus oils (TG (XRD (SEM 10 8 1