ABSTRACT Most Brazilian municipalities do not have regulated areas for solid waste disposal in civil construction. Usually, residues are disposed of vacant lots and dumps, posing risks to the population health and the environment. Soils are the primary means for the disposal or recycling of waste, highlighting the importance of well-characterized soils and their respective landscape. This study aimed to establish a land suitability system for solid residues in civil construction and apply such information in a case study in Southeastern Brazil. An unprecedented digital soil map with a resolution of 30 m was created using the random forest classifier algorithm and soil field prospection information. A guide listing favorable soil-landscape attributes that most prevent soil erosion, water bodies or water table contamination was elaborated and discussed. Thus, such information was linked through a suitability system to classify areas with potential for receiving waste on a daily volume basis as follows: large size: >500 m³ day-1, medium size: >100 m³ day-1 and <300 m³ day-1, and small size <100 m³ day-1. Topography and soil depth were the most limiting factors of the areas in the case study. The proposed attributes as criteria for the suitability system complement the current state legislation. A total of 236 ha closer to the urban perimeter connected by roads in good condition were classified as suitable for managing medium- and small-scale daily volume, whose destination might reduce transportation and installation costs in the study area. Usually dumps environment wellcharacterized well characterized landscape Brazil 3 soillandscape erosion discussed Thus follows 500 >50 day1, day1 day 1, 1 100 >10 day- 300 <30 <10 day1. 1. legislation 23 smallscale scale area 50 >5 10 >1 <3 <1 2 5 > <

ABSTRACT Peach rootstock and scion cultivars are selected in breeding programs considering resistance to pests and diseases, salt tolerance, drought tolerance, and vigor. However, rootstock tolerance to aluminum (Al), which is markedly present in tropical and subtropical soils of the world, is not considered. Thus, it is essential to define potential markers that can contribute to the selection of Al-resistant or Al-tolerant peach rootstocks. The objective of this study was to identify Al-tolerant peach tree rootstock cultivars and clonal selections using physiological and oxidative stress variables. A completely randomized experimental design was used in a 13 (rootstock cultivars and clonal selections) × 2 (with and without Al) factorial arrangement, with three replications. Nursery peach trees of own-rooted ‘BRS Mandinho’ (without rootstock) and nursery trees of ‘BRS Mandinho’ grafted on different rootstock cultivars and clonal selections were grown in a hydroponic system, consisting of two treatments, with and without 100 mg L-1 of Al. Dry biomass, photosynthetic variables, pigment concentration, hydrogen peroxide content, membrane lipid peroxidation, and activity of the antioxidant enzymes were evaluated. The total dry matter production of the own-rooted ‘BRS Mandinho’ trees and the SS-CHI-09-39 and SS-CHI-09-40 selections is affected by the Al presence, representing a decline of 35.4, 37.2, and 24.4 %, respectively, compared to the treatment with Al. The highest total dry matter production in Al presence was observed for the ‘Sharpe’ rootstock. ‘Capdeboscq’, DB-SEN-09-23, FB-ESM-09-43, JB-ESM-09-13, JAH-MAC-09-77, SAS-SAU-09-71, and VEH-GRA-09-55 rootstock selections are tolerant to Al. The use of physiological and biochemical variables shows potential for the selection of clonal rootstocks tolerant or resistant to Al. diseases vigor However Al, , (Al) world considered Thus Alresistant Altolerant 1 arrangement replications ownrooted own rooted BRS Mandinho system treatments 10 L1 L L- biomass concentration content peroxidation evaluated SSCHI0939 SSCHI SS CHI 09 39 SS-CHI-09-3 SSCHI0940 40 SS-CHI-09-4 354 35 4 35.4 372 37 37.2 244 24 24. % respectively ‘Sharpe Sharpe ‘Capdeboscq, Capdeboscq ‘Capdeboscq ‘Capdeboscq’ DBSEN0923, DBSEN0923 DBSEN DB SEN 23, 23 DB-SEN-09-23 FBESM0943, FBESM0943 FBESM FB ESM 43, 43 FB-ESM-09-43 JBESM0913, JBESM0913 JBESM JB 13, JB-ESM-09-13 JAHMAC0977, JAHMAC0977 JAHMAC JAH MAC 77, 77 JAH-MAC-09-77 SASSAU0971, SASSAU0971 SASSAU SAS SAU 71, 71 SAS-SAU-09-71 VEHGRA0955 VEHGRA VEH GRA 55 VEH-GRA-09-5 (Al SSCHI093 0 3 SS-CHI-09- SSCHI094 35. 37. DBSEN092 DB-SEN-09-2 FBESM094 FB-ESM-09-4 JBESM091 JB-ESM-09-1 JAHMAC097 7 JAH-MAC-09-7 SASSAU097 SAS-SAU-09-7 VEHGRA095 5 VEH-GRA-09- SSCHI09 SS-CHI-09 DBSEN09 DB-SEN-09- FBESM09 FB-ESM-09- JBESM09 JB-ESM-09- JAHMAC09 JAH-MAC-09- SASSAU09 SAS-SAU-09- VEHGRA09 VEH-GRA-09 SSCHI0 SS-CHI-0 DBSEN0 DB-SEN-09 FBESM0 FB-ESM-09 JBESM0 JB-ESM-09 JAHMAC0 JAH-MAC-09 SASSAU0 SAS-SAU-09 VEHGRA0 VEH-GRA-0 SS-CHI- DB-SEN-0 FB-ESM-0 JB-ESM-0 JAH-MAC-0 SAS-SAU-0 VEH-GRA- SS-CHI DB-SEN- FB-ESM- JB-ESM- JAH-MAC- SAS-SAU- VEH-GRA DB-SEN FB-ESM JB-ESM JAH-MAC SAS-SAU

ABSTRACT Increasing the use of nitrogen (N) fertilizers will be necessary to enhance grain and pasture yields to satisfy the growing world demand for food. Organic amendments, such as farm dairy effluents (FDE), are an alternative to traditional synthetic fertilizers. However, part of the applied N could be lost as ammonia (NH3) volatilization or nitrous oxide (N2O) emission, decreasing N availability to plants. Nitrification inhibitors, such as dicyandiamide (DCD), suppress the microbial process of nitrification, decreasing soil nitrate concentration and, therefore, N2O emission. Reducing N2O losses from agricultural soils is a key subject for sustainable production. This research aimed to quantify the effect of DCD addition to the FDE on the emissions of N2O and the volatilization of NH3 from the soil. A field trial was carried out in which NH3 volatilization and N2O emission were measured over 49 days after applying FDE, FDE with DCD (DCD), and control (C, without N added) treatments. The amount of N applied as FDE was 120 kg of N ha-1. Accumulated N2O emission during the 49 days after the application was 526, 237, and 174 g N2O-N ha-1 from the soil in the FDE, DCD, and C treatments, respectively. No significant differences were observed in accumulated NH3 volatilization. Pasture yield was higher in DCD treatment, followed by C and FDE. Under low temperatures and high soil moisture conditions, adding DCD to the FDE could be considered an effective alternative to increase pasture yields, decrease N2O emissions, and maintain NH3 volatilization, reducing total N losses to the atmosphere by about 14 %. Adding DCD to the FDE is a promising alternative for the more efficient N use of farm dairy effluents as fertilizer to mitigate N losses, tending to reduce N losses as N2O emissions. More studies are necessary to verify the result of using FDE + DCD under different soils and climates. (N food amendments , (FDE) However NH (NH3 NO O (N2O plants inhibitors (DCD) nitrification therefore production 4 C, (C added treatments 12 ha1. ha1 ha 1. 1 526 237 17 N2ON NON ha- respectively treatment conditions % climates (FDE (NH (DCD 52 23 ON 5 2

ABSTRACT Land-use changes from native pastures to forest plantations in humid temperate areas have raised concerns about their potential impact on the environment. This study aimed to assess the effects of such changes on soil water properties, focusing on the impact of the forest species planted and their relationship with changes in soil C content. Specifically, we aimed to identify the development of surficial soil hydrophobicity and changes in soil water holding capacity. A long-term forest experiment with variable planting densities (816, 1111, and 2066 trees ha-1) of Eucalyptus grandis Hill ex Maiden and Pinus taeda L. was established in 2004 on native pasture vegetation. Undisturbed soil samples (0.00-0.03 m soil layer) were extracted from the experiment and surrounding pastures and soil water repellency was determined by the water drop penetration time (WDPT) method at three soil matric potential levels (SMP). Bootstrapping was used to test if the sample size was sufficient to obtain robust results. Replacing native pastures with forest plantations significantly increased surficial soil hydrophobicity, which was more pronounced under Eucalyptus grandis than under Pinus taeda. Soil water repellency increased with decreasing SMP, particularly in land-uses that generated higher initial hydrophobicity. Additionally, the soils under forest cover had less water retention capacity than those under pastures at each SMP, with larger differences when the soil was dried to more negative SMP. More research is necessary to determine if soil alterations from converting native pastures to forest plantations in temperate climates will lead to a significant decrease in soil water holding capacity and an increase in hydrophobicity at deeper depths. Landuse Land use environment properties content Specifically longterm long term 816, 816 (816 1111 206 ha1 ha 1 ha-1 L 200 vegetation 0.000.03 000003 0.00 0.03 0 00 03 (0.00-0.0 layer WDPT (WDPT SMP . (SMP) results landuses land uses Additionally depths 81 (81 111 20 ha- 000 0.000.0 00000 0.0 003 (0.00-0. (SMP 8 (8 11 2 0.000. 0000 0. (0.00-0 ( 0.000 (0.00- (0.00 (0.0 (0. (0

ABSTRACT Few Brazilian rural landowners are aware of the technology available to survey the subsoil of terrains earmarked for aquaculture operations. This study evaluated subsoils of Monte Alegre (area 1) and Montenegro 3 (area 2) aquaculture zones in the geographic region of Bragança (Amazon region, northern Brazil), and the adequacy of these areas for aquaculture. Ground Penetrating Radar, electrical conductivity measurements, and sedimentological analyses were applied to evaluate the subsoil of fish farms. Apparent conductivity values recorded by the Electromagnetic Induction (EMI) in area 1 indicated possible presence of clayey soils. Excavation analysis and sedimentological samples (sand) from this site confirmed the inadequacy of the terrain. The EMI tool in area 2 indicated possible presence of clayey soils. Geophysical and sedimentological results from the site confirmed its suitability. These geophysical tools are recommended for evaluating prospective aquaculture sites, given their capacity to provide reliable data on the subsoil characteristics , which is essential to guarantee the success and sustainability of aquaculture operations. operations Amazon Brazil, Brazil Brazil) Radar measurements farms (EMI soils sand (sand terrain suitability sites

ABSTRACT One of the challenges in the peach palm production system is the interpretation of leaf analyses and the adaptation of fertilization recommendations. Tools that enhance fertilizer use efficiency are therefore needed. This study aimed to establish norms for evaluating the nutrient status of peach palms using the Diagnosis and Recommendation Integrated System (DRIS) and to determine the adequate number of palm heart samples necessary for a more accurate assessment of productivity. Production, leaf nutrient content, and soil fertility data were collected from 102 commercial stands of peach palm in the Ribeira Valley, state of São Paulo, Brazil, between 2015 and 2020. Adequate number of individual samples (palm hearts) to be collected per stand for productivity assessment was estimated. DRIS norms were established by dividing the database into high-yield (reference population) and low-yield subpopulations, using average productivity as a criterion. By assuming an acceptable error of 5 to 10 % for the assessment of peach palm productivity, taking into account total palm heart weight and/or the weight of cylinders, respectively, 16 plants per stand should be sampled. DRIS was not sensitive enough to diagnose differences in the probability of positive response to fertilization; however, the P, K, Ca, Mg, S, B, Fe, Cu, Mn and Zn contents were positively correlated with the respective nutrient indices. recommendations needed (DRIS Production content Valley Paulo Brazil 201 2020 hearts estimated highyield high yield reference population lowyield low subpopulations criterion 1 andor or cylinders respectively sampled however P K Ca Mg S B Fe Cu indices 20 202 2

ABSTRACT Increasing soybean yield in the MATOPIBA region can be attributed to fertility management, which is crucial to achieving maximum agronomic efficiency. Therefore, the proper management begins with the assessment of plant nutrition. This study aimed to evaluate soybean nutritional status in western Bahia using the Diagnosis and Recommendation Integrated System (DRIS). Database comprised 153 samples from commercial fields located in the research area. To carry out the evaluation using the DRIS method, the database contained information on nutritional levels and leaf productivity of the sampled areas. Database was divided into high-productivity populations (reference population) and low-productivity populations, based on the inflection point value of the cumulative cubic function of yield. The DRIS method allowed for evaluating the potential response to fertilization; however, this method was inefficient in recommending fertilizer doses in both subpopulations. For the sufficiency levels proposed by DRIS, the nutrients N, K, Ca, Mg and S had their maximum and minimum limits reduced, while Cu, Fe and Zn had their ranges of sufficiency expanded, when compared with ranges proposed by other authors. In addition, Zn and Mn were more limiting due to lack for the high-yield subpopulation, and P and Mn for the low-yield subpopulation. The most limiting nutrients due to excess were P and Zn for the high-yield, while K and S were limiting for the low yield subpopulation. efficiency Therefore nutrition DRIS. . (DRIS) 15 area areas highproductivity high reference population lowproductivity fertilization however subpopulations N Ca reduced Cu expanded authors addition highyield subpopulation lowyield highyield, yield, (DRIS 1

ABSTRACT From 1913 onwards, the global situation changed from a scenario of nitrogen (N) scarcity to an abundance of ammonia (NH3) produced synthetically via the Haber-Bosch process. Several N compounds have been synthesized since then, with urea becoming the main source of N, accounting for 55 % of current N consumption. However, N efficiency in agroecosystems is low and, normally, N recovery in cultivated plants is less than 50 %. This occurs because a large amount of reactive N is lost to the environment, inducing various forms of pollution, threatening human and environmental health, in addition to causing a negative economic impact on the farmer. The main processes responsible for low N efficiency are NH3 volatilization, leaching, and N denitrification. Considering global NH3 volatilization losses of 14 %, it can be assumed that up to 8.6 million Mg of urea are lost every year in the form of NH3. For each ton of NH3 produced, 1.9 to 3.8 Mg of CO2 is emitted into the atmosphere. Therefore, increasing N use efficiency (NUE) without compromising yield is a necessity and a challenge for crop improvement programs and current management systems, in addition to reducing greenhouse gas emissions. In this context, enhanced efficiency fertilizers (EEFs), which contain technologies that minimize the potential for nutrient losses compared to conventional sources, are an alternative to increasing the efficiency of nitrogen fertilization. Currently, EEFs are classified into three categories: stabilized, slow-release, and controlled-release. This study aims to understand the technologies used to produce EEFs and the factors that govern their availability to plants. This review covers the following topics: the discovery of N, N dynamics in the soil-atmosphere system, N assimilation in plants, strategies to increase NUE in agrosystems, NH3 synthesis, NH3 volatilization losses, N fertilizer technologies, the importance of characterization of EEFs, conventional nitrate or ammonium-based fertilizers to reduce gaseous losses of NH3 and future prospects for the use of N fertilizers in agriculture. 191 onwards (N NH (NH3 HaberBosch Haber Bosch process then 5 consumption However normally environment pollution health farmer leaching denitrification 1 86 8 6 8. 19 9 1. 38 3 3. CO atmosphere Therefore (NUE systems emissions context , (EEFs) sources fertilization Currently categories stabilized slowrelease, slowrelease slow release, release slow-release controlledrelease. controlledrelease controlled release. controlled-release topics soilatmosphere soil system agrosystems synthesis ammoniumbased ammonium based agriculture (NH (EEFs

ABSTRACT Agriculture intensification in Southern Brazil’s subtropical regions combined with the frequent occurrence of erosive rainfall has rendered the area a global water erosion hotspot. In this scenario, understanding and regulating erosion processes at the river catchment scale is critical for mitigating soil and water resource degradation. Traditional methods for tracing sediment sources are expensive and time-consuming and justify the development of alternative approaches. Therefore, in this study, we employed diffuse reflectance spectroscopy analyses in the ultraviolet-visible (UV-VIS), near-infrared (NIR), and mid-infrared (MIR) ranges, combined with multivariate models and spectral pre-processing techniques to estimate sediment source contributions in a homogeneous subtropical catchment (Conceição River, 804 km²). Soil samples (n = 181) were collected to characterize the four potential sediment sources, including: cropland (n = 78), stream bank (n = 36), unpaved road (n = 40) and pasture (n = 27). Moreover, 44 sediment samples were collected, including suspended sediment (n = 8), fine sediment deposited on the riverbed (n = 15), and suspended sediment samples collected in the water column during storm events (n = 21). Vector machine (SVM) model outperformed the others, with better accuracy and reliability. While UV-VIS spectra proved less effective due to soil homogeneity across the catchment, NIR and MIR spectra provided valuable information for discriminating sediment sources. Furthermore, reducing the number of potential sources (from four to three or two) improved model predictions, especially when distinguishing between surface sources (cropland and pasture) and subsurface sources (unpaved roads and stream banks). The study’s findings shed light on the power of efficient and cost-effective alternative methods for assessing sediment sources, which are vital for promoting effective erosion control and sustainable land management in similar regions. Brazils Brazil s hotspot scenario degradation timeconsuming time consuming approaches Therefore study ultravioletvisible ultraviolet visible UVVIS, UVVIS UV VIS , (UV-VIS) nearinfrared near infrared NIR, (NIR) midinfrared mid (MIR ranges preprocessing pre processing Conceição River 80 km². km² km . km²) n 181 78, 78 78) 36, 36 36) 40 27. 27 27) Moreover 4 8, 8 8) 15, 15 15) 21. 21 21) SVM (SVM others reliability Furthermore from two predictions banks. banks banks) studys costeffective cost (UV-VIS (NIR 18 7 3 2 1

ABSTRACT Potassium (K) vertical mobility in soils has often been overestimated and used as a rationale for recommending the broadcast application of this nutrient in fertility management programs, especially in soils with low cation exchange capacity (CEC). This study aimed to evaluate the vertical distribution of K in two land uses: areas with natural vegetation and crop fields managed under no-tillage (NT) fertilized with K. For this purpose, 49 soil profiles from the Brazilian subtropical state of Rio Grande do Sul were sampled, comprising 45 profiles from areas under NT management and four profiles from sites with natural vegetation. Soil samples were collected in 19 very thin layers: 1 cm layer in the first 10 cm, 2.5 cm layer from 10 to 25 cm, and 5 cm layer from 25 to 40 cm. Sampling sites were then grouped according to their CEC, categorized as < 7.5, 7.6-15.0, and 15.1-30.0 cmolc dm-3. Both crop fields and natural fields exhibit a similar vertical gradient model, characterized by a strong accumulation of K in the soil within the uppermost centimeters. This gradient is notably enhanced by the addition of K fertilizers, leading to a substantial portion of K becoming inaccessible to the root system. The optimal level of available K for the topsoil soils was found within an average range of 4 to 12.5 cm of soil depth. Consequently, K fertilization resulted in two main outcomes: (i) an excess of K in the upper soil layers, which increases the potential for K loss through surface erosion and runoff, and (ii) a limited migration of K towards the deeper soil layers until reaching the root growth zone. There is an urgent need to: (a) reaffirm the official recommendations of public agencies that the replacement of K exported by crops should be carried out in the furrow, along the sowing line, and as deep as possible; and (b) reconsider the diagnostic soil layer for assessing the status of K availability in soils under NT management. (K programs CEC. CEC . (CEC) uses notillage no tillage (NT purpose sampled 2 2. 75 7 7.5 7.615.0, 76150 7.6 15.0, 6 15 0 7.6-15.0 15.130.0 151300 15.1 30.0 30 15.1-30. dm3. dm3 dm 3. 3 dm-3 model centimeters fertilizers system 125 12 12. depth Consequently outcomes i (i runoff ii (ii zone (a furrow line possible b (b (CEC 7. 615 7.615.0 7615 76 150 15.0 7.6-15. 130 15.130. 15130 151 15. 300 30. 15.1-30 dm- 61 7.615. 761 7.6-15 13 15.130 1513 15.1-3 7.615 7.6-1 15.13 15.1- 7.61 7.6-

ABSTRACT Currently in Brazil, large grain cultivation projects on Plinthosols are a reality, however, there is little or no knowledge of the real mechanism of formation of the plinthite feature, in addition to what is reported in the literature as being a product of oxidation-reduction processes of iron element. This study evaluates iron redoximorphic features and investigates their chemical and mineralogical composition in two profiles of Plinthosols from the Araguaia River plain (P1 and P2). The study strengthens the understanding of the pedogenetic processes involved in the formation of mottles and plinthite. In this sense, it assesses whether the formation mechanisms corroborate the literature. Soil features were sampled in the upper right and left position at the initial plinthic horizon, upper right and left position at the main plinthic horizon, and lower right position at the base horizon of the plinthite zone in the profile. Separated samples comprising the soil matrix, mottles, and plinthite under natural moisture conditions were ground into powder form for chemical determinations by X-ray fluorescence (XRF), sulfuric acid attack (H2SO4), sodium dithionite-citrate-bicarbonate (DCB), and ammonium acid oxalate; and mineralogical determinations by X-ray diffraction. Iron contents in all determined forms were always higher in the plinthite feature, intermediate in the mottle feature, and lower in the soil matrix feature. Most of the Fe in all redoximorphic features is included in the structure of primary minerals and their derivatives (vermiculite, illite, and VHEs). Only part of the iron present (about 35.40 % in P1 and 41.98 % in P2) is detected in the form of oxides such as goethite and hematite, which could be formed in redox processes. The mottle and plinthite features under study are not the product of the classic process of segregation, mobilization, and accumulation of iron as a consequence of redox processes. These features were formed or emerged as a result of a relatively slow and constant weathering process of their source material, which is gradually decomposed in an aqueous medium, releasing most of its components. These components include iron and more mobile elements such as bases and silicon, which leave the system through drainage water, and of which a small part may eventually recombine to form new less complex minerals such as kaolinite and oxides. Brazil reality however feature oxidationreduction oxidation reduction element P (P P2. P2 . sense profile Xray X ray XRF, XRF , (XRF) H2SO4, H2SO4 HSO H SO (H2SO4) dithionitecitratebicarbonate dithionite citrate bicarbonate DCB, DCB (DCB) oxalate diffraction vermiculite, vermiculite (vermiculite illite VHEs. VHEs VHEs) about 3540 35 40 35.4 4198 41 98 41.9 hematite segregation mobilization material medium silicon water (XRF H2SO (H2SO4 (DCB 354 3 4 35. 419 9 41. (H2SO

ABSTRACT Regosols (Neossolos) are soils with use limitations mainly related to effective depth, abundant presence of rock and saprolite fragments, and frequently high slope gradients; besides that, they represent a new agricultural frontier for grain production in southern Brazil. This study evaluated soil saturated hydraulic conductivity (Ksat) and water retention and availability in Regosols and saprolites derived from volcanic rocks in southern Brazil and the relationship of these variables with porosity in saprolithic horizons characterized by mineralogical weathering. The study was carried out on eight profiles derived from basic and acidic volcanic rocks of the Serra Geral Formation. We evaluated soil morphology, granulometry, porosity, bulk density (BD), Ksat, water retention, electronic/ optical microscopy and chemical composition of parent materials, and soil mineralogy. Soil Ksat ranged from 0.0 to 6.40 cm h-1 in the evaluated horizons, without significant difference between the A and Cr horizons. Seven soil profiles showed BD equal to or less than 1.28 Mg m-3 for the Cr samples. Total porosity in the Cr horizons was above 0.5 m3 m-3 and not significantly different from A horizons. In five of the eight soil profiles, one or more Cr horizons presented greater available water than A horizons. Electronic and optical microscopy evidenced abundant cracks and mineralogical weathering in the rock samples. X-rays diffraction data also indicated advanced degree of weathering of Cr horizons, evidencing abundant formation of pores in the saprolite. and justifying the high-water retention in Regosols profiles in southern Brazil. Neossolos (Neossolos depth fragments gradients that (Ksat Formation morphology granulometry BD, , (BD) electronic materials mineralogy 00 0 0. 640 6 40 6.4 h1 h 1 h- 128 28 1.2 m 3 m- samples 05 5 Xrays X rays highwater (BD 64 4 6. 12 2 1.

ABSTRACT Application of pig manure (PM) in agriculture can influence the amount and composition of soil organic matter (SOM). This study evaluated the changes in contents and stock of C in chemical fractions of SOM and the chemical and spectroscopic composition of humic substances (HS) in a Typic Hapludult (Argissolo Vermelho-Amarelo) after ten years of PM application. Experimental area received 90 and 180 kg ha-1 of N in the form of pig slurry (PS90 and PS180) and pig deep litter (DL90 and DL180), in addition to the control, without application (SA). Soil samples were prepared, and the chemical fractioning of SOM, elemental analysis, and Fourier Transform Infrared Spectroscopy of HS were performed. Applications of PM favored the accumulation of C in soil (up to 53 %), and PS180 increased humic acids (HA) (up to 185 %), while applications of DL favored the increase of hydrophilic substances extracted with HCl and humin (HU) (up to 10 times and 60 %, respectively). Applications of PS180 and DL180 promoted an increase in the aromatic and carboxylic character of the HS, increasing cationic exchange capacity. Therefore, PM applications, especially with DL, contribute positively to C fixation in the soil and the chemical composition of organic material. (PM SOM. . (SOM) (HS Argissolo VermelhoAmarelo Vermelho Amarelo Vermelho-Amarelo 9 18 ha1 ha 1 ha- PS90 PS (PS9 DL90 (DL9 DL180, , DL180) control SA. SA (SA) prepared analysis performed up 5 % %) PS18 HA (HA HU (HU 6 respectively. respectively respectively) DL18 capacity Therefore material (SOM PS9 (PS DL9 (DL (SA PS1 DL1

ABSTRACT Soil is an important carbon repository in terrestrial ecosystems, serving a fundamental role in the intricate cycling of this elemental component. Wetlands are crucial components of the global carbon cycle, playing a significant role in carbon sequestration due to their remarkable productivity and unique sedimentary structures. Our study focuses on the wetlands east of Marajó island, recognized as the largest fluvial-marine plain in South America. In this study, we applied a methodological framework to optimize SOC content prediction in the wetlands of Marajó island using readily available environmental covariates. We collected and analyzed 81 soil samples from the most representative geoenvironments on the island at a layer of 0.00-0.20 m. Our database included vegetation indices, morphometric maps, and covariates based on distance from water bodies and archaeological sites. We tested five machine learning algorithms - Cubist, Linear Model, Random Forest, K Nearest Neighbor, and Support Vector Machine - to obtain the best prediction performance. Cubist model demonstrated the highest performance for training (R2 = 0.483) and testing (R2 = 0.505) datasets, making it the optimal choice for SOC prediction in the topsoil. The most important covariates selected by Cubist using recursive feature elimination were digital elevation model, topographic heterogeneity index, vertical distance between the summit and base of the slope, and Euclidean distance from water bodies. Geoenvironments characterized by dense alluvial rainforest with palms on Plinthosols and Gleysols, mangroves with Gleysols, and coastal muddy plains exhibited the highest SOC content in the topsoil. ecosystems component cycle structures fluvialmarine fluvial marine America 8 0.000.20 000020 0.00 0.20 0 00 20 0.00-0.2 m indices maps sites Model Forest Neighbor R2 R (R 0.483 0483 483 0.505 0505 505 datasets topsoil index slope Gleysols 000 0.000.2 00002 0.0 020 0.2 2 0.00-0. 0.48 048 48 0.50 050 50 0.000. 0000 0. 02 0.00-0 0.4 04 4 0.5 05 5 0.000 0.00-

ABSTRACT The accessibility of soil P reserves by plants on highly weathered Brazilian soils remains unclear. In this study, we assessed the contribution of soil P fractions to P uptake by soybean plants in two no-till Oxisols (Latossolos), with low and high initial content of available P. The recommended P rates (viz., 153 and 50 kg ha-1 yr-1 in the low-P and high-P soil, respectively) were applied in the form of triple superphosphate (TSP) or Bayovar rock phosphate (BRP) plus a treatment without fertilizer. Yields of winter cereals and soybean on the studied soils were examined over a period of three years. Soil samples were collected in the 0.00-0.10 m soil layer and subjected to sequential chemical fractionation of P. In the last crop season, the P content of soybean shoot biomass was determined. Soil P fractions and P content of soybean shoots were subjected to path analysis. The addition BRP in the low-P soil resulted in a winter cereal yield of 2.0 Mg ha-1 lower than TSP. In the scenario of high P, it is possible to maintain high crop yields even without phosphate fertilization for three consecutive years. Path analyses demonstrated the addition of P using either TSP or BRP boosted the contribution of the more labile inorganic P fractions. The addition of BRP should be avoided in P-deficient soils. The addition TSP or BRP reduces the pressure of plants to use soil P reserves. Therefore, the soil P legacy should be considered in fertilization recommendations for high-P soils in NT. unclear study notill no till Latossolos, Latossolos , (Latossolos) viz., viz (viz. 15 5 ha1 ha 1 ha- yr1 yr yr- lowP highP respectively (TSP (BRP fertilizer years 0.000.10 000010 0.00 0.10 0 00 10 0.00-0.1 season determined analysis 20 2 2. Pdeficient deficient Therefore NT (Latossolos viz. (viz 000 0.000.1 00001 0.0 010 0.1 0.00-0. 0.000. 0000 0. 01 0.00-0 0.000 0.00-