Abstract This study investigated the effect of dolomitic lime incorporation on the microstructure and mechanical properties of metakaolin-based geopolymers activated by alkaline solution. Five geopolymer mixtures were prepared with the addition of 0.0%, 2.5%, 5.0%, 7.5%, and 10.0% dolomitic lime. The microstructure of the geopolymers was evaluated by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction analyses (XRD). The compressive strength of the mixtures ranged between 53.2 and 63.0 MPa after 28 days of ambient curing. SEM/EDS analyses showed that the main phases formed were the N-A-S-H gel together with the C-A-S-H and N-M-A-S-H gels in the mixtures with dolomitic lime. In summary, the results showed that the incorporation of dolomitic lime can significantly improve the microstructure and properties of geopolymers. metakaolinbased metakaolin based solution 00 0 0.0% 25 2 5 2.5% 50 5.0% 75 7 7.5% 100 10 10.0 SEM, SEM , (SEM) energydispersive energy dispersive Xray X ray EDS, EDS (EDS) XRD. XRD . (XRD) 532 53 53. 630 63 63. curing SEMEDS NASH N A S H CASH C NMASH M summary 0.0 2.5 5.0 7.5 1 10. (SEM (EDS (XRD 6 0. 2. 5. 7.

Resumo Este estudo investigou o efeito da incorporação de cal dolomítica na microestrutura e nas propriedades mecânicas de geopolímeros à base de metacaulim ativados por solução alcalina. Foram preparadas cinco misturas de geopolímeros com adição de 0,0%, 2,5%, 5,0%, 7,5% e 10,0% de cal dolomítica. A microestrutura dos geopolímeros foi avaliada por microscopia eletrônica de varredura (MEV), espectroscopia de energia dispersiva de raios X (EDS) e análises de difração de raios X (DRX). A resistência à compressão das misturas variou entre 53,2 e 63,0 MPa após 28 dias de cura ambiente. As análises SEM/EDS mostraram que as principais fases formadas foram o gel N-A-S-H juntamente com os géis C-A-S-H e N-M-A-S-H nas misturas com cal dolomítica. Em resumo, os resultados mostraram que a incorporação de cal dolomítica pode melhorar significativamente a microestrutura e as propriedades dos geopolímeros. alcalina 00 0 0,0% 25 2 5 2,5% 50 5,0% 75 7 7,5 100 10 10,0 MEV, MEV , (MEV) EDS (EDS DRX. DRX . (DRX) 532 53 53, 630 63 63, ambiente SEMEDS SEM NASH N S H CASH C NMASH M resumo 0,0 2,5 5,0 7, 1 10, (MEV (DRX 6 0, 2, 5,

The recycle and utilization of expired drugs is a challenge for many countries at present. The employment of expired drugs as green corrosion inhibitors is expected to address both drug recycling and corrosion prevention issues, with significant economic and environmental value. Herein, the individually and combination corrosion inhibition performance of expired amoxicillin (AMC) and penicillin V potassium tablets (PVP) for lowcarbon steel in 20% acetic acid solution containing 600 mg L-1 chloride ion are evaluated by electrochemistry and weight loss method. Both the AMC and PVP present the mixed-type corrosion inhibitors mainly affect the cathode process when used individually. The optimum inhibition efficiency is 61.22% (AMC) and 79.21% (PVP), which all appear in 5.0 × 10-3 mol L-1. The AMC and PVP are adsorbed on the steel surface by mixed physisorption and chemisorption, which are consistent with the Langmuir adsorption isotherm. The corrosion inhibition rate drops sharply when AMC and PVP are combined use with a close mole ratio. But a small amount of PVP significantly enhance the corrosion inhibition effect of AMC, the corrosion inhibition rate from 61.22 to 79.72%. The corrosion inhibition rate of AMC and PVP combination inhibitor decreased with the increase of temperature. issues value Herein (AMC (PVP 20 60 L1 L 1 L- method mixedtype type 6122 61 22 7921 79 21 79.21 PVP, , 50 5 0 5. 103 10 3 10- L1. 1. chemisorption isotherm ratio 61.2 7972 72 79.72% temperature 2 6 612 792 7 79.2 61. 797 79.72 79. 79.7

The selective separation of precious metals from complex aqueous solutions is important in protecting the environment, aquatic ecosystems, water resources and recycling resources. In this study, cysteine-containing polymeric nanoparticles were synthesized using the molecular imprinting (MIP) technique with the mini-emulsion polymerization method. The basis of the polymer design is inspired by affinity of silver to cysteine in biological systems. The synthesized silver ion imprinted (Ag+-IIP) poly(hydroxyethylmethacrylate-N -methacryloyl-L-cysteine) poly(HEMA-MAC) nanoparticles were characterized by elemental analysis, zeta sizer, Fourier transform infrared (FTIR) spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM). The effects of pH, ionic strength and interaction time on adsorption of Ag+ ions were investigated. In experimental studies, the highest adsorption amount (196.9 mg g1 nanoparticle) was reached in a short period of 40 min at pH 5.0 and 150 mg L-1 concentration. Selectivity studies of synthesized Ag+-IIP nanoparticles against silver (Ag+) ions were carried out in the presence of lithium (Li+), barium (Ba2+), mercury (Hg2+) and cadmium (Cd2+) ions. Experimental results indicate that nanoparticles adsorb Ag+ ions with high selectivity. Ag+-IIP nanoparticles have 3.7, 3.1, 2.4, and 2.6 times more selective or higher affinity for Ag+ ions compared to Li+, Ba2+, Hg2+ and Cd2+ ions, respectively, compared to Ag+-non-imprinted (NIP) nanoparticles. environment ecosystems study cysteinecontaining containing MIP (MIP miniemulsion mini emulsion method systems Ag+IIP AgIIP IIP Ag (Ag+-IIP polyhydroxyethylmethacrylateN poly hydroxyethylmethacrylate N methacryloylLcysteine methacryloyl L -methacryloyl-L-cysteine polyHEMAMAC HEMA MAC poly(HEMA-MAC analysis sizer FTIR (FTIR spectroscopy AFM, AFM , (AFM) SEM. SEM . (SEM) investigated 196.9 1969 196 9 (196. g nanoparticle 4 50 5 0 5. 15 L1 1 L- concentration (Ag+ Li Li+ (Li+) Ba2 Ba Ba2+ (Ba2+) Hg2 Hg (Hg2+ Cd2 Cd (Cd2+ selectivity 37 3 7 3.7 31 3.1 24 2 2.4 26 6 2. respectively Ag+nonimprinted Agnonimprinted non NIP (NIP (AFM (SEM 196. 19 (196 (Ag (Li+ (Ba2+ (Hg2 (Cd2 3. nonimprinted (19 (Li (Ba2 (Hg (Cd (1 (Ba (

Sensor calibration for dissolved gas is a critical and necessary step to ensure consistent sensor response over time and under different conditions. In this work, we describe a 3D printed device that facilitates the calibration of gas sensors. The device effectively maintained gas concentration in the solution for at least 2 h. Analytical curves were constructed in the pH range of 2 to 12, yielding determination coefficients surpassing 0.98. The chosen method proved suitable for the calibration of the sensors. Furthermore, using accurate and reliable reference sensors contributed to obtaining precise and trustworthy measurements. conditions work D h 12 098 0 98 0.98 Furthermore measurements 1 09 9 0.9 0.

Alzheimer’s disease (AD) is a neurodegenerative disorder characterized by extracellular accumulation of amyloid-β (Aβ) peptides in the brain. This study demonstrates the direct association of the disposable pipette extraction (DPX) with tandem mass spectrometry (MS/MS) for the analysis of Aβ peptides in cerebrospinal fluid (CSF) samples. Different parameters were optimized in order to improve detectability in the MS/MS including mobile phase percentage of ammonium hydroxide, mobile phase flow rate and acquisition mode. Also, this method used an electrospray ionization (ESI) low-flow probe and direct infusion of an organic solution in the MS/MS. The DPX-MS/MS method showed adequate linearity for determining Aβ peptides in CSF-linearity ranged from 0.1 to 1.5 ng mL 1. The coefficients of determination were higher than 0.99; the precision coefficient of variation (CV) ranged from 0.3 to 12.7%; and the accuracy relative standard deviation (RSD) ranged from -13.6 to 13.2%. Alzheimers Alzheimer s AD (AD amyloidβ amyloid β (Aβ brain DPX (DPX MSMS MS (MS/MS CSF (CSF samples hydroxide mode Also ESI (ESI lowflow low DPXMS/MS DPXMSMS CSFlinearity 01 0 1 0. 15 5 0.99 099 99 CV (CV 03 3 12.7% 127 12 7 RSD (RSD 13.6 136 13 6 -13. 132 2 13.2% DPXMS 0.9 09 9 12.7 13. -13 13.2 12. -1 -

The use of materials such as organofunctionalized silica for application in solid phase extraction (SPE) allows the preconcentration of several ions, including Pt, and subsequent detection. This work aims to synthesize and characterize an organofunctionalized silica (Sil-TMSDT) with the silylant N’(trimethoxysilyl)propylethylenetriamine and its application as a solid phase in the preconcentration Pt4+ ions in aqueous media, using detection by flame atomization atomic absorption spectroscopy (FAAS). The Fourier-transform infrared spectroscopy (FTIR) spectra and scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS) confirmed the aminofunctionalization of the silica. For the adsorption process, a preconcentration mini-column with 200 mg of Sil-TMSDT, a solution of 0.485 mg L−1 of K2[PtCl6] at pH 10 and HNO3 0.5 mol L−1 as eluent were used, obtaining an enrichment factor of 15-fold with retention efficiency higher than 99%. The Pt4+ ion determined by FAAS showed a linear response between 0.02 and 0.40 mg L−1; a linear coefficient where R = 0.9981; a 16-fold preconcentration factor; a limit of quantification (LOQ) and limit of detection (LOD) of 0.045 and 0.014 mg L−1, respectively. The proposal system showed analytical applicability to determining Pt4+ ion in an aqueous medium and could be used to detect traces of this potentially toxic metal in biological fluids such as urine and blood. SPE (SPE Pt SilTMSDT Sil TMSDT (Sil-TMSDT Ntrimethoxysilylpropylethylenetriamine N trimethoxysilyl propylethylenetriamine Pt4 media FAAS. . (FAAS) Fouriertransform Fourier transform FTIR (FTIR SEM (SEM energydispersive energy dispersive EDS (EDS process minicolumn mini column 20 SilTMSDT, TMSDT, Sil-TMSDT 0485 0 485 0.48 L1 L 1 L− K2PtCl6 KPtCl K2 PtCl6 K PtCl K2[PtCl6 HNO 05 5 0. 15fold fold 15 99 99% 002 02 0.0 040 40 0.4 0.9981 09981 9981 16fold 16 LOQ (LOQ LOD (LOD 0045 045 0.04 0014 014 0.01 respectively blood (FAAS 2 048 48 K2PtCl K2[PtCl 9 00 04 4 0.998 0998 998 004 001 01 0.99 099 0.9 09

ABSTRACT Moringa oleifera Lam. is an arboreal forest species of great economic potential, adapted to the climatic conditions of the Brazilian semi-arid region, whose multiplication is mainly by seeds. Rapid viability and vigor tests help in the choice of lots. Thus, the objective of this study was to assess the efficiency of the pH of exudate and primary root protrusion tests in the evaluation of viability and vigor, respectively. Two seed lots were initially evaluated for moisture content, germination, first count, germination speed index, seedling length, seedling dry mass and electrical conductivity. For the pH of exudate test, phenolphthalein (1%) and sodium carbonate (2 and 4 g L-1) solutions were prepared, with three soaking periods (1, 3 and 5 h) and three temperatures (25, 30 and 35 °C). Exudate solution in strong to light pink color indicated viable seeds, whereas very light pink color to colorless indicated non-viable seeds. The primary root protrusion test was performed under 25, 30 and 35 °C, evaluating the primary root protrusion of at least 2 mm, every 12 h until 196 h. The experimental design was completely randomized, with four replicates. pH of exudate test with 1 h of soaking at 25 or 30 °C with 2 g L-1 sodium carbonate solution was promising, but further studies are needed before it is indicated as routine use for the species. Primary root protrusion test is efficient and can be conducted at 35 °C with evaluation after 48 h. Lam potential semiarid semi arid region seeds Thus respectively content count index length conductivity 1% (1% ( L1 L prepared 1, (1 (25 °C. C . °C) nonviable non mm 19 randomized replicates L- promising

Nanocomposites of GO/γ-Fe2O3 were used for magnetic dispersive solid-phase microextraction (m-d-μ-SPE) of six pesticides from river water samples, followed by the determination using high performance liquid chromatography-diode array detection. The synthesis of the nanocomposites is described and characterized using Fourier transform-infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. A central composite design was used to optimize the extraction time, sample solution pH, and adsorbent amount. The solvent type and volume for desorption and the effect of the ionic strength for adsorption were also investigated. The optimum adsorption conditions were achieved at 84 min of extraction time, pH 5.4, 115 mg of absorbent, and 1% (m/v) of NaCl, while the desorption solvent selected was 1.0 mL of methanol-acetic acid (9:1, v/v). The limits of detection ranged from 0.1 to 0.9 μg L-1, and a good precision was achieved with relative standard deviation (RSD) lower than 7.6% (n = 10). The accuracy of the method was accessed by recovery tests ranging from 82 to 117% (n = 3, RSD < 8%). GO/γFe2O3 GOγFe2O3 GOγFeO GO/γ Fe2O3 GO γ Fe O GO/γ-Fe2O solidphase solid phase mdμSPE m d μ SPE (m-d-μ-SPE samples chromatographydiode chromatography diode transforminfrared transform infrared spectroscopy Xray X ray diffraction microscopy time amount investigated 8 54 5 4 5.4 11 absorbent 1 m/v mv v (m/v NaCl 10 0 1. methanolacetic methanol acetic 91, 91 9 1, (9:1 v/v. vv v/v . v/v) 01 0. 09 L1, L1 L L-1 (RSD 76 7 6 7.6 n 10. 10) 117 3 8%. 8% 8%) γFe2O3 γFe GO/γFe2O GOγFe GOγFe2O GOγ FeO Fe2O 5. (9: L- 7. γFeO γFe2O (9 (

In the present study a spectrophotometric method for Cr(VI) determination in organic fertilizers, especially those from tanning industry residues, is proposed. Conditions for chromium extraction, extract clean-up and analytical characteristics of the method were established. The method is based on the complexation of Cr(VI) with 1,5-diphenylcarbazide (DPC) in acid medium (pH 2.0). A mixture of NaOH and Na2CO3 solution at 0.125 and 0.07 mol L–1 (pH 12), respectively, and heating at 90 °C for 60 min were the best conditions for chromium extraction. Florisil and activated charcoal were tested for clean-up of the extract, with activated charcoal being effective. Under the established conditions, the calibration linear range is up to 2500 μg L–1 Cr(VI), the results obtained are in agreement with the value of a certified reference material (CRM041), precision is better than 5% for five consecutive determinations of a solution at 1000 μg L–1 of Cr(VI) and the limit of quantification is 1.62 μg g–1. In can be concluded that the method is robust, accurate and precise, and can be easily applied for the determination of Cr(VI) in routine analysis, since it complies with legislation of most countries regarding the maximum allowed concentration of 2 μg g–1 of Cr(VI). CrVI Cr VI Cr(VI fertilizers residues proposed extraction cleanup clean 1,5diphenylcarbazide 15diphenylcarbazide diphenylcarbazide 1,5 1 5 DPC (DPC pH 2.0. 20 2.0 . 0 2.0) NaCO Na CO Na2CO 0125 125 0.12 007 07 0.0 L1 L L– 12, 12 , 12) respectively 9 C 6 effective 250 CrVI, CRM041, CRM041 CRM (CRM041) 100 162 62 1.6 g1 g robust precise analysis g– CrVI. 5diphenylcarbazide 15 1, 2. 012 0.1 00 0. 25 CRM04 (CRM041 10 16 1. 01 CRM0 (CRM04 (CRM0 (CRM

ABSTRACT: This study assessed the efficacy of magnesium sulfate and ketamine hydrochloride in reducing the demand for propofol, remifentanil, and postoperative rescue analgesia in cats undergoing elective ovariohysterectomy. Thirty cats were premedicated with acepromazine (0.05 mg/kg) and morphine (0.3 mg/kg) intramuscularly and induced to unconsciousness with propofol for orotracheal intubation. The continuous infusion (CI) of propofol and remifentanil were started and animals and were randomly allocated into three groups: the magnesium sulfate group (MG) received one bolus (50 mg/kg) and CI (80 mg/kg/h) of magnesium sulfate; the ketamine group (KG) received bolus (0.5 mg/kg) and CI (1.8 mg/kg/h) of ketamine hydrochloride; the control group (CG) received bolus and CI of 0.9% saline solution. Cardiovascular and respiratory functions, extubation time, and rescue postoperative scores were assessed and data were described with a significance level of 95% (P < 0.05). The infusion period of treatments was 21.5 ± 3.4 and 21.0 ± 2.4 minutes in the KG and MG, respectively (P = 0.194). The infusion rates of remifentanil (P = 0.336) and propofol (P = 0.716) were similar between groups. Analysis of the postoperative pain scales revealed no significant intergroup differences in rescue frequency, rescue score, and time to the first rescue analgesia. In conclusion, the proposed protocols were safe and effective, yet it is noteworthy that both magnesium sulfate and ketamine failed to demonstrate significant additional postoperative analgesic or adjuvant anesthetic effects. ABSTRACT ovariohysterectomy 0.05 005 0 05 (0.0 mg/kg mgkg mg kg 0.3 03 3 (0. intubation (CI groups MG (MG 50 (5 80 (8 mg/kg/h mgkgh h (KG 0.5 5 1.8 18 1 8 (1. CG (CG 09 9 0.9 solution functions 95 P 0.05. . 0.05) 215 21 21. 34 4 3. 210 24 2 2. 0.194. 0194 0.194 194 0.194) 0.336 0336 336 0.716 0716 716 frequency score conclusion effective effects 0.0 00 0. (0 ( 1. (1 019 0.19 19 0.33 033 33 0.71 071 71 01 0.1 0.7 07 7

RESUMO: Objetivou-se avaliar a eficácia do sulfato de magnésio e cetamina em reduzir o requerimento de propofol, remifentanil e o resgate analgésico pós-operatório de gatas submetidas à ovariohisterectomia eletiva. Trinta gatas foram pré-medicadas com acepromazina (0,05 mg/kg) e morfina (0,3 mg/kg), intramuscular, e induzidas a inconsciência com propofol para intubação orotraqueal. As infusões contínuas (IC) de propofol e remifentanil foram iniciadas e os animais foram aleatoriamente alocados em três grupos: grupo sulfato de magnésio (MG) que recebeu bolus (50 mg/kg) e IC (80 mg/kg) de sulfato de magnésio; grupo cetamina (KG) que recebeu bolus (0,5 mg/kg) e IC (1,8 mg/kg/h) de cetamina; grupo controle (CG) que recebeu bolus e IC de solução salina 0,9%. As funções cardiovasculares e respiratórias, o tempo de extubação e a pontuação de resgate pós-operatório foram registrados e descritos com nível de significância de 95% (P < 0.05). O tempo de infusão dos tratamentos foi de 21,5 ± 3,4 e 21,0 ± 2,4 minutos no KG e MG, respectivamente (P = 0.194). As taxas de infusões de remifentanil (P = 0.336) e propofol (P = 0.716) foram similares entre grupos. Na análise de dor pós-operatória as escalas não demonstraram diferenças entre grupos quanto a número de resgates, pontuação de resgate ou tempo para o primeiro resgate. Em conclusão, os protocolos propostos foram seguros e efetivos. Contudo, o sulfato de magnésio e cetamina não demonstraram analgesia pós-operatória adicional ou efeitos adjuvantes anestésicos significativos. RESUMO Objetivouse Objetivou se pósoperatório pós operatório eletiva prémedicadas pré medicadas 0,05 005 0 05 (0,0 mg/kg mgkg mg kg 0,3 03 3 (0, mg/kg, , intramuscular orotraqueal (IC MG (MG 50 (5 80 (8 (KG 0,5 5 1,8 18 1 8 (1, mg/kg/h mgkgh h CG (CG 09 9 0,9% respiratórias 95 P 0.05. 0.05 . 0.05) 215 21 21, 34 4 3, 210 24 2 2, 0.194. 0194 0.194 194 0.194) 0.336 0336 336 0.716 0716 716 pósoperatória operatória resgates conclusão efetivos Contudo significativos 0,0 00 0, (0 ( 1, (1 0,9 0.0 019 0.19 19 0.33 033 33 0.71 071 71 0. 01 0.1 0.3 0.7 07 7

Abstract: The starting point of this paper is the well-known crisis of politics and, in particular, the attacks on the principle of political representation. It would seem, then, that the solution lies in a re-politicisation of our communities and a greater presence of political participation. Why is the recovery of political participation utopian at the present? Beyond the non-existence of channels, the question remains open as to when it is possible to dedicate time to such participation. Indeed, present-day life does not seem to leave time for almost anything. Rosa explains the phenomenon of social acceleration, but devotes little time to the political repercussions beyond the consideration of another paradox, as we shall see, regarding the role of the state in acceleration. In this study, we shall attempt, after setting out Rosa's theses, to draw some conclusions with regard to present political participation.

Resumen: El punto de partida del presente trabajo es la consabida crisis de lo político y en especial los ataques al principio de representación política. Pareciera entonces que la solución pasa por una repolitización de nuestras comunidades y una mayor presencia de la participación política. Ahora bien, ¿por qué resulta utópica en el momento presente la recuperación de la participación en lo político? Más allá de la inexistencia de cauces, queda abierta la pregunta de cuándo es posible dedicar tiempo a tal participación. En efecto, la vida presente no parece dejar espacio temporal para casi nada. Rosa explica el fenómeno de la aceleración social, aunque apenas dedica tiempo a las repercusiones políticas más allá de la consideración de otra paradoja, como veremos, con respecto al papel del Estado en la aceleración. En este estudio, vamos a intentar, después de exponer las tesis de Rosa, sacar algunas conclusiones con respecto a la participación política presente.

Resumo: O ponto de partida deste documento é a conhecida crise da política e, em particular, os ataques ao princípio da representação política. Parece, pois, que a solução reside numa re-politização das nossas comunidades e numa maior presença de participação política. Mas porque é que a recuperação da participação política é utópica no momento actual? Para além da inexistência de canais, a questão permanece em aberto quanto a quando é possível dedicar tempo a essa participação. De facto, a vida actual parece não deixar tempo para quase nada. Rosa explica o fenómeno da aceleração social, mas dedica pouco tempo às repercussões políticas para além da consideração de outro paradoxo, como veremos, no que diz respeito ao papel do Estado na aceleração. Neste estudo, tentaremos, depois de apresentar as teses de Rosa, tirar algumas conclusões no que diz respeito à participação política actual.

Abstract This work evaluated the influence of impregnation of boron compounds, in three concentrations, on Pinus sp. veneers, and its effect on the properties of plywood. The experiment was carried out in a completely randomized design, in a 3 × 3 + 1 factorial scheme, with three boron compounds (boric acid, borax, and disodium octaborate tetrahydrate) and three solution concentrations (1%, 3%, and 5%) plus the control. The panels were produced with three or five veneers, depending on the test, impregnated by dipping in boron compound solutions for 15 min and bonded with urea-formaldehyde adhesive. The apparent density, water absorption, thickness expansion, hygroscopicity, resistance to static bending (parallel and perpendicular to the grain) and shear strength were evaluted. All tests were carried out following the European Committee for Standardization, and the results were compared to the Brazilian Association of Mechanically Processed Wood requirements. Based on the results, it is recommended to use boric acid at a concentration of 1% or 3% or the other compounds tested at a concentration of 1%. sp veneers plywood design scheme borax tetrahydrate 1%, (1% 5% 5 control test ureaformaldehyde urea formaldehyde adhesive density absorption expansion hygroscopicity parallel grain evaluted Standardization requirements (1 (

Resumo Objetivou-se avaliar a influência da impregnação de compostos de boro, em três concentrações, em lâminas de Pinus sp., e seu efeito nas propriedades de compensados. O experimento foi realizado em delineamento inteiramente casualizado, em esquema fatorial 3 × 3 + 1, sendo três compostos de boro (ácido bórico, bórax e octaborato dissódico tetrahidratado) e três concentrações (1%, 3% e 5%) mais o controle. Os painéis foram produzidos com três ou cinco lâminas, encolados com uréia-formaldeído, com as lâminas impregnadas por imersão nas soluções de compostos de boro por 15 min. Foram avaliadas a densidade aparente, absorção de água, expansão de espessura, higroscopicidade, resistência à flexão estática (paralela e perpendicular à grã) e resistência ao cisalhamento. Todos os testes foram realizados de acordo com o Comitê Europeu de Padronização. Para o controle de qualidade, os resultados foram comparados com as exigências da Associação Brasileira de Madeira Processada Mecanicamente. Com base nos resultados, recomenda-se usar ácido bórico na concentração de 1% ou 3% ou os demais compostos testados na concentração de 1%. Objetivouse Objetivou se sp sp. compensados casualizado 1 tetrahidratado 1%, (1% 5% 5 uréiaformaldeído, uréiaformaldeído uréia formaldeído, formaldeído uréia-formaldeído min aparente água espessura higroscopicidade paralela grã cisalhamento Padronização qualidade Mecanicamente recomendase recomenda (1 (

Summary: Soil solution (SS) constitutes the volume from which plant roots extract dissolved nutrients. Despite its importance, the impact of its composition due to the application of organic amendments has been relatively little studied. The objective of this research was to study the impact of humic acids (HA) and chitosan (Cs) on the concentration of minerals in the SS, as well as their effect on the yield of the cabbage crop (Brassica oleracea L.). Under greenhouse conditions with calcareous soil, two doses of HA were applied (200 and 500 kg ha-1), as well as 50 and 150 kg ha-1 of Cs in a targeted manner. From the SS, 22 samples were taken non-destructively from the root zone once a week. The results of mineral content in the soil solution and mineral content on the biomass did not present significant differences, however, it was noted that the Cs50 treatment stimulated 41% higher plant biomass than the control (P ≤ 0.5, Tukey). It is concluded that Cs and HA do not significantly impact the ionic content of the SS or the mineral content of the biomass, although they do stimulate the yield.

Resumen: La solución del suelo (SS) constituye el volumen de donde las raíces de las plantas extraen los nutrientes disueltos. A pesar de su importancia, el impacto de su composición por la aplicación de enmiendas orgánicas se encuentra relativamente poco estudiado. El objetivo de esta investigación fue estudiar el impacto de los ácidos húmicos (AH) y quitosán (Cs) sobre la concentración de los minerales en la SS, así como su efecto en el rendimiento del cultivo de col (Brassica oleracea L.). En condiciones de invernadero con suelo calcáreo se aplicaron dos dosis de AH (200 y 500 kg ha-1), así como 50 y 150 kg ha-1 de Cs de forma dirigida. De la SS se tomaron 22 muestras en forma no destructiva de la zona de la raíz una vez por semana. Los resultados del contenido mineral en la solución del suelo y del contenido mineral en la biomasa no presentaron diferencias significativas, no obstante, se apreció que el tratamiento Cs50 estimuló 41% la biomasa vegetal superior al testigo (P ≤ 0.5, Tukey). Se concluye que el Cs y AH no impactan significativamente el contenido iónico de la SS ni el contenido mineral de la biomasa, aunque si estimulan el rendimiento.

Abstract Purpose: To adapt and validate in Sonora the scale to measure Attitudes towards Transgender People in University Students (EATU), which measures the inclusion of trans people in Higher Education Institutions (HEIS). Methodological design: Quantitative, cross-sectional and non-experimental study. 860 participants were selected among three HEIS, with non-probabilistic and intentional sampling. A 4-point Likert-type scale survey was applied that evaluates transinclusive attitudes. Reliability was obtained with Cronbach's alpha and McDonald's omega. For validity, the sample was randomly divided into two; In subsample 1, an Exploratory Factor Analysis (EFA) was carried out and in subsample 2, the model resulting from the EFA was tested using a Structural Equation Model (SEM). Results: The EFA yielded a final solution EATU of 32 items grouped into 3 dimensions called sensitivity, coexistence and cisexist stigma, with values that demonstrate validity and reliability. The SEM generated a model with indices of fitness in a final solution of 17 items and 3 correlated dimensions with acceptable coefficients. Research limitations: The measurement of transinclusion attitudes in a society where it has been documented that such construct is barely being developing, and the failure to collect demographic data on the sample about their religious beliefs. Findings: A measurement instrument on transinclusive attitudes for key social actors interested in promoting the inclusion of trans people, their human rights and substantive equality.

Resumen Objetivo: Adaptar y validar en el contexto sonorense la Escala para medir Actitudes hacia las Personas Transgénero en Estudiantes Universitarios (EATU) que mide la inclusión de personas trans en Instituciones de Educación Superior (IES). Diseño metodológico: Es un estudio cuantitativo, transversal y no experimental. De tres IES, participaron 860 personas seleccionadas con muestreo no probabilístico e intencional. Se aplicó una escala tipo Likert de 4 puntos que evalúa actitudes transincluyentes. La fiabilidad se obtuvo con alfa de Cronbach y omega de McDonald. Para la validez la muestra se dividió al azar en dos; en la submuestra 1 se llevó a cabo un Análisis Factorial Exploratorio (AFE) y en la submuestra 2 se probó el modelo resultante del AFE mediante un Modelo de Ecuaciones Estructurales (MEE). Resultados: El AFE arrojó una solución final de la EATU de 32 ítems agrupados en 3 dimensiones denominadas sensibilidad, convivencia y estigma cisexista, con valores de fiabilidad superiores a .90 y de cargas factoriales superiores a .36. El MEE generó un modelo con índices de bondad de ajuste en una solución final de 17 ítems y 3 dimensiones correlacionadas con coeficientes superiores a .46. Limitaciones de la investigación: La medición de actitudes de transinclusión en una sociedad donde se ha documentado que tal constructo está en desarrollo y el no recabar datos demográficos en la muestra sobre sus creencias religiosas. Hallazgos: Un instrumento de medida sobre actitudes transincluyentes para actores sociales clave interesados en la promoción de la inclusión de las personas trans, sus derechos humanos y la igualdad sustantiva.

Resumen (Objetivo) El estudio tuvo como objetivo examinar bajo la mirada de la teoría APOE (acción, proceso, objeto y esquema), la producción de estudiantes de educación secundaria al aboradar 11 ítems relacionados con la función exponencial. (Metodología) El enfoque fue de corte cualitativo, a través del análisis de contenido. La muestra fue de 15 estudiantes (entre 15 a 18 años), nominados de manera no probabilística con interés de obtener la mayor cantidad de información. Para el diseño del instrumento intencionado desde la teoría, se construyó una descomposición genética hipotética del concepto de función exponencial como objeto cognitivo de acuerdo con las estructuras (acción, proceso, objeto y esquema) y mecanismos mentales (interiorización, coordinación, encapsulación, desencapsulación, reversión), para interpretar la construcción mental que realizan los estudiantes sobre la función en estudio, con base en su desarrollo histórico epistemológico, la presentación en textos escolares y la experiencia del investigador. (Resultados) En el nivel de resultados se evidenció que 13 estudiantes muestran una concepción acción de la función estudiada y 2 estudiantes que llegaron a construir el concepto como proceso. (Conclusiones) Se concluye que los estudiantes construyen el concepto de función exponencial como acción, es decir, todo lo relacionado con procesos repetitivos y mecánicos con potencias, cálculo de imágenes, representación gráfica, solución de ecuaciones exponenciales, incluso algunos estudiantes dan respuesta a los ítems sin realizar explícitamente todos los pasos requeridos en la resolución. Dichos resultados evidencian ausencia de un proceso mental de la función exponencial y por consecuencia la encapsulación de él en el objeto función exponencial.

Resumo (Objetivo) O objetivo do estudo foi examinar, soba perspectiva da teoria APOE (ação, processo, objeto e esquema), a produção de alunos do ensino médio ao lidarem com 11 itens relacionados à função exponencial. (Metodologia) A abordagem foi qualitativa, por meio de análise de conteúdo. A amostra consistiu em 15 alunos (com idades entre 15 e 18 anos), nomeados em uma base não probabilística com o objetivo de obter o máximo de informações possível. Para a elaboração do instrumento baseado na teoria, foi construída uma decomposição genética hipotética do conceito de função exponencial como objeto cognitivo, de acordo com as estruturas (ação, processo, objeto e esquema) e os mecanismos mentais (internalização, coordenação, encapsulamento, desencapsulamento, reversão), a fim de interpretar a construção mental feita pelos alunos sobre a função em estudo, com base no seu desenvolvimento epistemológico histórico, na apresentação em textos escolares e na experiência do pesquisador. (Resultados) Em nível de resultados, ficou evidente que 13 alunos apresentam uma concepção de ação da função estudada e 2 alunos que conseguiram construir o conceito como um processo. (Conclusões) Conclui-se que os alunos constroemo conceito de função exponencial como uma ação, ou seja, tudo o que está relacionado a processos repetitivos e mecânicos com potências, cálculo de imagens, representação gráfica, solução de equações exponenciais, inclusive alguns alunos dão respostas aos itens sem realizar explicitamente todos os passos exigidos na resolução. Esses resultados mostram a ausência de um processo mental da função exponencial e, consequentemente, o encapsulamento dele no objeto da função exponencial.

Abstract (Objective) The objective of this study was to examine, in the light of the APOS theory (action, process, object, and schema), the results produced by secondary school students when addressing 11 items related to the exponential function. (Methodology) The approach was qualitative, using content analysis. The sample consisted of 15 students between 15 and 18 years old, chosen in a non-probabilistic way to obtain the greatest amount of information. Based upon the theory, an instrument was designed which consisted of a hypothetical genetic decomposition of the concept of exponential function as a cognitive object, according to structures (action, process, object and schema) and mental mechanisms (interiorization, coordination, encapsulation, decapsulation, and investment), to interpret the mental construct that students create about the function being studied, based on its historical epistemological development, its presentation in school textbooks and the experience of the researcher. (Results) At the level of results, it was found that 13 students showed an action conception of the function being studied and 2 students built the concept at the process level. (Conclusion) Students most often built the concept of an exponential function at the action level, that is, everything related to repetitive and mechanical processes with powers, image calculation, graphic representation, solution of exponential equations; some students even responded to the items without explicitly performing all the steps required for their resolution. These results demonstrated the absence of a mental process related to the exponential function and its consequent encapsulation into an exponential function object.