This contribution presents a characterization of Barremian evaporite facies of the Neuquén Basin (western Argentina) in order to discuss accumulation processes and depositional conditions. The evaporite accumulation is related to a proto-Pacific transgression that followed an Early Barremian widespread desiccation event. These evaporites are known as the Upper Troncoso Member of the Huitrín Formation. They constitute a research topic of great importance, both from the theoretical point of view (stratigraphy, origin, palaeoclimate), as well as from the knowledge of non-renewable natural resources (celestine - barite, anhydrite - gypsum, rock salt, potassium salts and hydrocarbons). The Neuquén Basin is considered an ensialic backarc basin associated with the easterly oriented subduction along the proto-Pacific margin of Gondwana (Figs. 1, 4). A generalised extensional stress regime due to steep subduction angle occurred in the magmatic arc and in the backarc settings, although regional thermal subsidence was punctuated by several episodes of structural inversion. Thus, the Upper Troncoso evaporites represent an unique example of accumulation in a marginal marine basin linked to the active continental margin of western Gondwana (Figs. 3, 4). The Lower Cretaceous deposits of the Huitrín Formation crop out almost continuously for more than 500 km along a north-south oriented belt (Fig. 5), from the latitude of the Aconcagua Mountain (Mendoza Province) up to the vicinity of the city of Zapala (Neuquén Province). Owing to the highest solubility and hygroscopic characteristics of the sediments, combined with the strong tectonic disturbation of the Huitrín Formation, the methodology for the study of the evaporites was largely based on subsurface information (geophysical well-log responses, cutting and cores) taken from oil and potassium salt exploration drill holes. In particular, electric logs allowed to identify electrofacies, and -based on the interpretation of cross-plots- to infer the mineralogy of the evaporites. Together with lithological descriptions of cutting and cores, representative samples of the rocks were studied in thin sections and by X-ray diffractometry. In the latter both whole-rock composition and <2μm clay mineral composition were defined. Lithological sections were elaborated, adjusted and correlated on the basis of this compositional information, and the areal distribution of evaporite salts was represented in a regional map. Geological correlations of the sedimentological record allowed define the geometry of evaporite facies in order to identify the main sedimentary environments. The regional study also involved the quantification of thickness variations in the deposits as well as the changes in evaporite mineralogy. The marine brine associated with the Troncoso evaporites followed successive processes of concentration and dilution. As a result, different salts were accumulated. In this study, these compositional changes are represented by the definition of several evaporite facies (Fig. 6). At the base of the Upper Troncoso Member the Facies Anhidrita was formed (Figs. 7, 8). This unit was covered by a thick salt succession composed of three facies: the lower Facies Salina Concentradora (Figs. 7, 9), the middle Facies de Sales Amargas (Figs. 10, 11), and the upper Facies Salina Terminal (Figs. 12, 13). During Facies Anhidrita deposition (Figs. 7, 8), the evaporite basin reached its maximum expansion (Fig. 14). An extensive salt pan formed from perennial or free brine, in the depocentral sector of the basin. Besides, a sabkha setting subjected to periodic events of flooding and concentration of the brines characterized the marginal areas of the basin. In this marginal belt, sulphate and carbonate microbial mats and siliciclastic muds were accumulated. In the central sectors of the basin, the anhydrite facies is characterized by microcrystalline films (sheets) composed of anhydrite-calcite pairs (Fig. 8), indicating a pelagic sedimentation under an almost stillness environment. A lateral transition from this central sector up to the coastal and supratidal sabkha sectors is recorded by regional correlation. In the lower part of the Facies Salina Concentradora, halite with a crystalline cumulus texture occurs (Figs. 7, 9). It was precipitated from a relatively depth brine and passes upwards to halite with a chevron texture indicating a progressive shallowing of the brine. The stratigraphic record of this facies shows cycles of primary clean halite - recycled halite - anhydrite sheets that repetitively occur. The Facies de Sales Amargas starts with sylvite daughter crystals in halite fluid inclusions, followed by a few crystals of sylvite, passing upwards to two thick beds of sylvinite (Fig. 10). This facies reaches a maximum thickness of 25 meters and represents the evaporite deposits of the Upper Troncoso Member with the smallest areal distribution (Fig. 14). However, they cover a (preserved) area of 3,000 km². These deposits are dominated by sylvinite (sylvite plus halite), which appears as anhedral to subhedral reddish, yellowish and whitish crystal aggregates (Fig. 11). The presence of hematite as fine solid dispersions, suggests that sylvite would result from lixiviation of magnesium chloride from a primary red carnallite. The Facies Salina Terminal represents the dilution of the evaporite basin (Fig. 12). Three successive evaporite cycles are recognized and they are interpreted as the result of flash floods that supplied rainwater from emerged areas. The mix of these waters with the perennial brines in the depocenter allowed precipitation of an anhydrite bed followed by a rhythmic laminated succession of halite with chevron texture alternating with anhydrite. At this time, fine-grained siliciclastics would have been supplied to the evaporite basin through flash floods from emerged areas, as well as from pyroclastic activity in the magmatic arc. This terrigenous material was preferentially accumulated during the dilution of the evaporite brine. The peripheral sectors of the basin are represented by salty mudflat sediments or siliciclastic sabkha deposits, which are interpreted to represent the development of wet salt mudflats in coastal areas and relatively drier mudflats in the more proximal (continental) margins of the basin. Syn-depositional to slightly post-depositional changes occurred in both the central and marginal settings, where underground brines produced precipitation of inter-crystalline passive cement in clean halite, and dissolution - reprecipitation of halite in the chaotic mud salt (Fig. 9c). Early diagenetic processes also involved neoformation of evaporitic minerals (anhydrite by dehydration of gypsum and autigenous sylvite from carnallite). By hyperhalmyrolysis, smectite in fine-grained siliciclastic deposits was transformed in mixed layer clay minerals, namely chlorite and illite. Under the global Cretaceous greenhouse context, the Neuquén Basin supported a dry and windy climate. The magmatic arc would have acted as a topographic barrier to the open proto-Pacific Ocean, and the basin behaved as a partially isolated hydrographically depression below sea level at that time (Fig. 4). Therefore, the evaporites of the upper Troncoso Member are linked to a restricted marine environment; this is an inland hypersaline shallow sea. High temperatures generated strong evaporation rates, which exceeded water supply (runoff, ground water discharge and atmospheric precipitations). These conditions increased salt concentration and caused the precipitation of salts according to their degree of solubility (Fig. 16). Moreover, the continuous evaporation would have created an imbalance in sea level currently stimulating continuous income, although limited, of sea water into the basin (Fig. 17a). In turn, the arc produced partial to total reflux retention in the basin, allowing brine concentration over time (Fig. 17a). A larger positive accommodation space towards the western sector of the depression favoured the connection between the proto-Pacific Ocean with the backarc Neuquén Basin during Facies Anhidrita and Facies Salina Concentradora (Fig.18). In the Facies Sales Amargas and in the Facies Salina Terminal, the evaporitic basin was assimilable to a hydrologically closed basin, with continental recharge of recycled marginal evaporites (Fig. 17b). This contribution identifies and characterizes a group of evapofacies in Barremian evaporites of the Neuquén Basin that allows to answer some questions on the origin, the depositional system, the controls and the evolution of the evaporitic record.
El Miembro Troncoso Superior es una unidad evaporítica que forma parte de la Formación Huitrín de edad Barremiana (Cretácico temprano) en la Cuenca Neuquina. El objetivo de este trabajo es presentar un estudio paleoambiental, evolutivo y controles que se dieron en el evento evaporítico huitriniano. El estudio de material e información de sondeos exploratorios de hidrocarburos y de potasio, permitió realizar columnas litológicas, delinear la distribución areal de las sales evaporíticas en el subsuelo y, por medio de correlaciones geológicas, identificar sectores de adelgazamiento y engrosamientos, e inferir la paleotopografía deposicional. La descripción y caracterización petrográfica y por difracción de rayos X permitieron determinar la mineralogía y textura de las unidades litológicas presentes en las evaporitas, lo cual, permitió definir distintas evapofacies o unidades informales. Un horizonte anhidrítico de amplio desarrollo territorial, identificado como Facies Anhidrita se presenta en la base base de la unidad en subsuelo y afloramiento, al cual suprayace un espeso paquete de haluros (halita, silvinita), cuyo registro sedimentario se encuentra hoy solo en el subsuelo de la Cuenca Neuquina. Dentro de este último, se han diferenciado tres facies: la Facies Salina Concentradora en la base, donde la salmuera marina se fue concentrando en sales amargas, que dejó un espeso banco de silvinita intercalado en el tercio superior, referido como Facies de Sales Amargas, la cual constituyó la mayor restricción de la salmuera libre. Culmina la secuencia salina con la dilución de la salmuera, que expandió el área deposicional, y permitió la precipitación de nuevas sales (halita), etapa que se denomina aquí como Facies Salina Terminal. La cuenca evaporítica se vincula a un ambiente marino marginal, separado del Océano proto-Pacífico, por un arco magmático que actuó como una barrera topográfica con el mar abierto, y que permitió el influjo de agua de mar continuo, aunque limitado y, a su vez, habría contribuido con una retención parcial a total del reflujo en la cuenca. Esta condición hidrológica abierta al agua de mar, se habría dado durante la Facies Anhidrita y la Facies Salina Concentradora, cerrándose durante la Facies de Sales Amargas y la Facies Salina Terminal. El espacio de acomodación sedimentaria, mayor en el sector occidental de la cuenca, habría acompañado la vinculación con el ambiente marino proto-Pacífico. El clima habría sido árido y ventoso, en un contexto greenhouse del Cretácico Inferior. La posición de la cuenca a sotavento del arco magmático, habría contribuido con vientos desecantes provenientes del oeste. La depositación de sales en la cubeta con salmuera perenne o libre, siguió un proceso de concentración y dilución evapoquímica. En la faja periférica, que estuvo sujeta a contracciones e inundaciones periódicas de gran escala, se desarrollaron facies de sabkha con matas microbianas bentónicas durante la Facies Anhidrita, mientras que en las facies con haluros, se habrían dado depósitos de barreal salino o de sabkha silicoclástico. Cambios sindeposicionales o ligeramente posdeposicionales, se habrían dado tanto en el ambiente depocentral, como periférico, donde la salmuera subterránea continuó activa modificando los sedimentos.