Résumé Par la méthode historique-comparative, cet article aborde les impacts, sur les États-Unis, l’Allemagne et le Brésil, des quatre crises économiques internationales survenues jusqu’en 2019, en se concentrant principalement sur leurs effets sur le régime politique et le post-2008. Les pays sélectionnés ont eu des expériences autoritaires distinctes, anciennes ou actuelles. Je conceptualise l’État de manière tridimensionnelle : régime politique, appareil décisionnel et structure de domination politique appuyée sur des coalitions. J’argumente que les conjonctures internationales critiques ont tendance à avoir un impact sur cette tridimensionalité, facilitant l’observation de ses variations et continuités. Je formule et corrobore trois hypothèses sur ces crises : elles ont tendance à augmenter ou diminuer les niveaux de démocratie ou d’autocratie des régimes ou à les changer ; la réponse autocratisante dépend d’une relation de forces pro-entreprises, subordonnant les travailleurs ; l’engagement démocratique des acteurs s’oppose à l’autocratisation. La contribution à la littérature réside dans la manière d’aborder les processus d’autocratisation et de démocratisation, ici étudiés à travers les impacts des crises économiques internationales sur les États. Les conjonctures critiques éclairent les composants clés de la mutabilité du Léviathan. On examine le régime politique par la politique économique des relations entre l’État, les marchés et les classes sociales, et non exclusivement par les variables politico-institutionnelles. On analyse les mécanismes d’intersection de la sphère et des acteurs politico-institutionnels avec les structures et acteurs économiques et sociaux, qui, impactant la tridimensionalité de l’État, entraînent des changements de régime ou dans le régime. historiquecomparative, historiquecomparative historique comparative, comparative historique-comparative ÉtatsUnis, ÉtatsUnis États Unis, Unis États-Unis lAllemagne l Allemagne Brésil jusquen jusqu 2019 post2008. post2008 post 2008. 2008 post-2008 distinctes actuelles lÉtat État coalitions Jargumente J argumente lobservation observation continuités dautocratie d autocratie dune une proentreprises, proentreprises pro entreprises, entreprises pro-entreprises lengagement engagement soppose s oppose lautocratisation. lautocratisation autocratisation. autocratisation l’autocratisation daborder aborder dautocratisation démocratisation Léviathan lÉtat, État, sociales politicoinstitutionnelles. politicoinstitutionnelles politico institutionnelles. institutionnelles politico-institutionnelles dintersection intersection politicoinstitutionnels institutionnels sociaux qui 201 post200 200 post-200 20 post20 post-20 2 post2 post-2 post-

Resumen Por medio del método histórico comparativo, se abordan los impactos en los Estados de Estados Unidos, Alemania y Brasil, de las cuatro crisis económicas internacionales que han ocurrido hasta 2019, enfocándose, principalmente, en sus efectos en el régimen político y en el periodo posterior a 2008. Los países seleccionados tuvieron distintas experiencias autoritarias, antiguas o actuales. Defino al Estado de una forma tridimensional: régimen político, aparato decisor y estructura de dominación política respaldada en coaliciones. Argumento que las respectivas coyunturas críticas internacionales tienden a impactar esta tridimensionalidad, facilitando la observación de sus variaciones y continuidades. Así, formulo y corroboro tres hipótesis sobre esas crisis: tienden a aumentar o disminuir los niveles de democracia o autocracia de los regímenes o a cambiarlos; la respuesta autocratizante depende de una relación de fuerzas proempresarial que subordina a los trabajadores; y el compromiso democrático de los actores opera contra la autocratización. La contribución a la literatura se relaciona con el modo de abordar los procesos de autocratización y democratización aquí investigados por los impactos de las crisis económicas internacionales en los Estados. Las coyunturas críticas vislumbran componentes clave de la mutabilidad del Leviatán. Se investiga el régimen político a partir de la economía política de las relaciones entre Estado, mercados y clases sociales, y no exclusivamente por las variables político-institucionales. Se analizan mecanismos de intersección de la esfera y de los actores político-institucionales con las estructuras y actores económicos y sociales, que, impactando en la tridimensionalidad del Estado, implican cambios de régimen o en el régimen. comparativo Unidos Brasil 2019 enfocándose principalmente 2008 autoritarias actuales tridimensional coaliciones continuidades Así cambiarlos trabajadores Leviatán sociales políticoinstitucionales. políticoinstitucionales institucionales. institucionales 201 200 20 2

Abstract This study uses a historical-comparative method to examine the impacts of the four international economic crises that occurred until 2019 on the United States, Germany, and Brazil, focusing primarily on their effects on the political regime and the post-2008 period. The selected countries had different authoritarian experiences, either in the distant past or more recently. The State is conceptualized along three dimensions: political regime, decision-making apparatus, and the structure of political domination supported by coalitions. The argument is that the respective international critical junctures tend to impact this three-dimensionality, making it easier to observe their variations and continuities. Three hypotheses are formulated and corroborated regarding these crises: they tend to increase or decrease the levels of democracy or autocracy in regimes or change them; autocratization depends on a pro-business power balance that subordinates workers; the democratic commitment of actors operates against autocratization. This study’s contribution to the literature lies in the approach to processes of autocratization and democratization, which are investigated here through the impacts of international economic crises on States. Critical junctures shed light on key components of the mutability of the Leviathan. It investigates the political regime through the political economy of the relationships between the State, markets, and social classes, not exclusively through political-institutional variables. Mechanisms of intersection between the political-institutional sphere and economic and social structures and actors are analyzed. These mechanisms impact the three-dimensionality of the State, leading to changes in the regime or within the regime. historicalcomparative historical comparative 201 States Germany Brazil post2008 post 2008 post-200 period experiences recently dimensions decisionmaking decision apparatus coalitions threedimensionality, threedimensionality dimensionality, dimensionality continuities them probusiness pro business workers studys s democratization Leviathan markets classes politicalinstitutional institutional variables analyzed 20 post200 200 post-20 2 post20 post-2 post2 post-

Resumo Aborda-se, pelo método histórico-comparativo, impactos, nos Estados dos EUA, Alemanha e Brasil, das quatro crises econômicas internacionais ocorridas até 2019, focando-se, principalmente, em seus efeitos no regime político e no pós-2008. Os países selecionados tiveram distintas experiências autoritárias, remotas ou atuais. Conceituo o Estado tridimensionalmente: regime político, aparato decisor e estrutura de dominação política escorada em coalizões. Argumento que as respectivas conjunturas críticas internacionais tendem a impactar nesta sua tridimensionalidade, facilitando a observação de suas variações e continuidades. Formulo e corroboro três hipóteses sobre essas crises: elas tendem a aumentar ou diminuir os níveis de democracia ou autocracia dos regimes ou a mudá-los; a resposta autocratizante depende de uma relação de forças pró-empresarial, que subordine os trabalhadores; o compromisso democrático dos atores opera contra a autocratização. A contribuição com a literatura está no modo de abordagem dos processos de autocratização e democratização, aqui investigados pelos impactos das crises econômicas internacionais nos Estados. As conjunturas críticas iluminam componentes-chave da mutabilidade do Leviatã. Investiga-se o regime político pela economia política das relações entre Estado, mercados e classes sociais, e não exclusivamente pelas variáveis político-institucionais. Analisam-se mecanismos de intersecção da esfera e dos atores político-institucionais com as estruturas e atores econômicos e sociais, que, impactando na tridimensionalidade do Estado, ensejam mudanças de regime ou no regime. Abordase, Abordase Aborda se, se Aborda-se históricocomparativo, históricocomparativo histórico comparativo, comparativo histórico-comparativo EUA Brasil 2019 focandose, focandose focando focando-se principalmente pós2008. pós2008 pós 2008. 2008 pós-2008 autoritárias atuais tridimensionalmente coalizões continuidades mudálos mudá los mudá-los próempresarial, próempresarial pró empresarial, empresarial pró-empresarial trabalhadores democratização componenteschave componentes chave Leviatã Investigase Investiga sociais políticoinstitucionais. políticoinstitucionais institucionais. institucionais Analisamse Analisam 201 pós200 200 pós-200 20 pós20 pós-20 2 pós2 pós-2 pós-

Résumé Cet article a pour but de démontrer la pertinence de l´approche transversale des chiffres et des cartes afin de mettre en évidence le pouvoir performatif qui se dégage de leurs intersections tecnhopolitiques telles que le concept de densité de population et la régionalisation du territoire. Appliquée au Brésil, l´étude croisée met en lumière des aspects du processus de construction de l´État, de la centralisation de l´autorité politique et de la création de nouvelles catégories de personnes et d´espaces de gouvernement. Pour ce faire, les tendances qui ont rapproché la statistique et la cartographie au cours de l´Empire brésilien y sont annalysées, en comprenant leur rôle en tant qu´instruments descriptifs du pouvoir souverain. De même, l´article aborde les circonstances qui conduissent à l´importance croissante des chiffres et des cartes comme une référente commune pour l´action collective et la production d´identités sociales. Basé sur le cadre de la sociologie de la quantification, l´article s´intéresse à l´émergence de la cartographie statistique et la régionalisation croissante des données officielles entre les années 1920 et 1940, liée à une nouvelle façon de definir la «brésilité », d´ordonner le territoire et de gouverner la population. On conclut que quantifier, c´est aussi visualiser et imaginer des grandeurs démographiques et économiques dans une spatialité cohérente et unitaire une fois stabilisée par des conventions d´équivalence. lapproche l approche Brésil létude étude lÉtat État l´État lautorité autorité despaces d espaces gouvernement faire lEmpire Empire annalysées quinstruments qu instruments souverain même larticle limportance importance laction action didentités identités sociales quantification sintéresse s intéresse lémergence émergence 192 1940 brésilité » dordonner ordonner quantifier cest c est déquivalence équivalence d´équivalence 19 194 1

Abstract This article takes a cross-disciplinary approach to numbers and maps to demonstrate the performative power that emerges from their technopolitical intersections, such as the concept of population density and regional delineation of territory. Applied to the Brazilian context, this combined analysis sheds light on aspects related to the construction of State authority and its power to create categories of people and places. To do so, this paper examines trends that bring statistics and cartography together in the Brazilian Empire, indicating a common status for maps and numbers as descriptive instruments of sovereign power, including their modes of use and conditions for producing and validating truth. Subsequently, it addresses the factors leading to the growing importance of numbers and maps for collective action and the production of shared identities. Drawing on references from the sociology of quantification, this paper focuses on the emergence of statistical cartography and the increasing regionalization of official data between the 1920s and 1940s – linked to a new way of defining Brazilian identity, organizing territory, and managing population. It concludes that quantifying is also visualizing demographic and economic quantities in a coherent and unitary spatiality, once stabilized by conventions of equivalence. crossdisciplinary cross disciplinary intersections territory context places so Empire truth Subsequently identities quantification s identity spatiality equivalence

Resumen Este artículo realiza un abordaje cruzado de números y mapas con el fin de evidenciar el poder performativo que emerge de sus intersecciones tecnopolíticas, como el concepto de densidad poblacional y el recorte regional del territorio. Aplicado al caso brasilero, el análisis combinado ilustra aspectos relativos a la construcción de la autoridad del Estado y su poder de crear categorías de personas y lugares. Para ese propósito, examinamos las tendencias que aproximan la estadística de la cartografía en Brasil Imperio y que indican un estatuto común a mapas y números como instrumentos descriptivos del poder soberano, sus modalidades de uso y sus condiciones de producción y validación de la verdad. Luego, abordamos los factores que conducen a la creciente importancia de los números y de los mapas para la acción colectiva y para la producción de identidades compartidas. Con base en las referencias de la sociología de la cuantificación, nos enfocamos en la emergencia de la cartografía estadística y en la creciente regionalización de los datos oficiales entre las décadas de 1920 y 1940, vinculadas a un nuevo modo de definir la “brasilidad”, ordenar el territorio y administrar la población. Concluimos que cuantificar es también visualizar cantidades demográficas y económicas en una espacialidad coherente y unitaria, una vez estabilizada por convenciones de equivalencia. tecnopolíticas brasilero lugares propósito soberano verdad Luego compartidas cuantificación 192 1940 brasilidad, brasilidad , “brasilidad” población unitaria equivalencia 19 194 “brasilidad 1

Resumo Este artigo realiza uma abordagem cruzada de números e mapas de modo a evidenciar o poder performativo que emerge de suas interseções tecnopolíticas, como o conceito de densidade populacional e o recorte regional do território. Aplicada ao caso brasileiro, a análise combinada ilumina aspectos relativos à construção da autoridade do Estado e seu poder de criar categorias de pessoas e lugares. Para tanto, examinamos as tendências que aproximam a estatística da cartografia no Brasil Império e que indicam um estatuto comum a mapas e números enquanto instrumentos descritivos do poder soberano, como suas modalidades de uso, e suas condições de produção e validação da verdade. Na sequência, abordamos os fatores que levam à crescente importância dos números e dos mapas para a ação coletiva e para a produção de identidades compartilhadas. Com base nas referências da sociologia da quantificação, enfocamos a emergência da cartografia estatística e a crescente regionalização dos dados oficiais, entre as décadas de 1920 e 1940, ligadas a um novo modo de definir a brasilidade, ordenar o território e gerir a população. Concluímos que quantificar é também visualizar quantidades demográficas e econômicas em uma espacialidade coerente e unitária, uma vez estabilizada por convenções de equivalência. tecnopolíticas brasileiro lugares tanto soberano uso verdade sequência compartilhadas quantificação oficiais 192 1940 brasilidade população unitária equivalência 19 194 1

Schiff bases are diverse organic compounds with an azomethine structure (–C=N–), holding potential in both chemistry and biology. They serve as catalysts, stabilizers, and exhibit various biological activities. The molecular structure of Schiff bases influences their biological properties, including antimicrobial effects. Redox-active compounds with more negative potentials tend to be more effective against microbes. In one of our recent studies, we explored the antimicrobial properties of two Schiff bases derivatives, SB-1 ((E)-4-amino-3-((3,5-di-tert-butyl-2-hydroxybenzylidene)amino) and SB-2 ((E)-2-((4-nitrobenzilidene)amino)aniline). SB-1 showed antibacterial activity against certain Gram-positive bacteria, while SB-2 did not. The difference in their cyclic voltametric profiles, especially SB-1’s more negative reduction potential, prompted us to carry out further characterizations, including scan-rate studies, solvent analysis, and computational calculations. We found that SB-1, which presents a stable intramolecular hydrogen bond, undergoes irreversible oxidation, likely at the –NH2 group, and a quasi-reversible reduction via an intramolecular reductive coupling of the (–C=N–) azomethine group, supported by orbital theoretical calculations. This research sheds light on the potential applications of Schiff bases in antimicrobial contexts, guided by their redox properties and structure. –C=N–, CN –C=N– , C N biology catalysts stabilizers activities effects Redoxactive Redox active microbes studies derivatives SB1 SB 1 SB- E4amino33,5ditertbutyl2hydroxybenzylideneamino E4amino335ditertbutyl2hydroxybenzylideneamino Eaminoditertbutylhydroxybenzylideneamino E 4 amino 3 3,5 di tert butyl 2 hydroxybenzylidene 5 ((E)-4-amino-3-((3,5-di-tert-butyl-2-hydroxybenzylidene)amino SB2 E24nitrobenzilideneaminoaniline. E24nitrobenzilideneaminoaniline Enitrobenzilideneaminoaniline nitrobenzilidene aniline . ((E)-2-((4-nitrobenzilidene)amino)aniline) Grampositive Gram positive bacteria not profiles SB1s SBs s characterizations scanrate scan rate analysis calculations SB1, 1, bond oxidation NH2 NH –NH group quasireversible quasi reversible (–C=N– contexts –C=N E4amino33 5ditertbutyl2hydroxybenzylideneamino ditertbutyl hydroxybenzylideneamino 35 3, nitrobenzilideneaminoaniline ((E)-2-((4-nitrobenzilidene)amino)aniline (–C=N Eamino E4amino3 ditertbutylhydroxybenzylideneamino E4amino

BiOCl/KBiO3 p-n heterostructures with hierarchical mesoporous architectures were successfully synthesized via a facile in situ method. The X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM) results indicate the formation of heterojunctions between BiOCl and KBiO3. The photocatalytic performance of the as-prepared samples was investigated by the degradation of dye Rhodamine B (RhB) under visible light irradiation. BiOCl/KBiO3 composite has never been used to photodegrade the RhB which is a common dye and very difficult to degrade. The results demonstrated that KBiO3 combined with proper amount of BiOCl nanosheets exhibited high efficiency in the photocatalytic process, and BiOCl/KBiO3 with the molar ratio of 70/30 demonstrated the highest photocatalytic activity due to its large surface area, excellent charge separation characteristics and the suppressed recombination of electron-hole pairs. The results of active species detection reveal that the superoxide radical anions (O2-), hydroxyl free radicals (·OH), photogenerated holes (h+) and photogenerated electrons (e-) reactive species work together for the photocatalytic degradation of RhB. A possible and new mechanism of photocatalysis that differs from other teams was also explored and proposed. The present study will benefit the development of the new p-n heterojunction photocatalysts and would be of great importance to meet ever-increasing environmental demands in the future. BiOClKBiO3 BiOClKBiO KBiO BiOCl/KBiO pn p n method Xray X ray XRD, XRD , (XRD) XPS (XPS SEM (SEM asprepared as prepared (RhB irradiation degrade process 7030 70 30 70/3 area electronhole hole pairs O2, O2 O (O2-) ·OH, OH ·OH (·OH) h+ h (h+ e (e- proposed everincreasing ever increasing future (XRD 703 7 3 70/ (O2- (·OH (h (e (O2 (O

Resumo O Distrito Industrial de Marabá (DIM) é um local vinculado à transformação e ao beneficiamento de recursos sob uma ótica de agregação de valor ao minério de ferro de Carajás-PA. Porém, indústrias locais promoveram grande transformação espacial com o emprego de técnicas e tecnologias arcaicas e poluentes que, após aumento nos custos e alteração nos preços internacionais, tiveram as áreas abandonadas, indicando um processo de campo marrom (brownfield) em formação no DIM e áreas conexas. Seguiu-se um processo de transumância, acompanhado de ciclos de retração e concentração econômica. Verifica-se uma condição de periferia mineroindustrial na implantação e concepção do DIM, bem como a formação como um campo marrom, inclusive com repercussões espaciais, econômicas, demográficas e ambientais. (DIM CarajásPA. CarajásPA Carajás PA. PA Carajás-PA Porém que internacionais abandonadas brownfield (brownfield conexas Seguiuse Seguiu se transumância econômica Verificase Verifica espaciais econômicas ambientais

Abstract The Marabá Industrial District (MID) is a place connected with the transformation and processing of resources from the perspective of adding value to the iron ore of Carajás (State of Pará). However, local industries have promoted a great spatial transformation, using archaic and polluting techniques and technologies. After an increase in costs and changes in international prices, the areas of these industries were abandoned, indicating a brownfield process under formation in the MID and related areas. This was followed by a process of transhumance, accompanied by cycles of economic contraction and concentration. A mining-industrial periphery condition is perceived in the implementation and conception of the MID, as well as its formation as a brownfield, with spatial, economic, demographic, and environmental repercussions. (MID State Pará. Pará . Pará) However technologies prices abandoned transhumance concentration miningindustrial mining industrial demographic repercussions

The history of the discovery, use, and development of dyes is closely linked to the history of humanity itself. Among the first records of human civilization are cave paintings made from, e.g., fruits, plants, minerals, and insects. Over the centuries, using different techniques, colors have been given to all types of materials and products, from clothing to food. The chemicals responsible for colors are dyes - a vast collection of molecules of the most varied compositions, but which have in common the absorption of light within the visible window of the electromagnetic spectrum. This article aims not only to review the properties of some classes of natural dyes, their origins, and their applications but also to describe the various computational chemistry methods involved in designing new bio-inspired molecules. discovery use itself eg e g e.g. fruits plants minerals insects centuries techniques products food compositions spectrum origins bioinspired bio inspired e.g

This paper elucidates the inseparable connection between the pursuit of a more ecologically sustainable society and the quest for socioeconomic justice. It also demonstrates why Unconditional Basic Income (UBI) is an effective policy to act on both fronts. First, the corresponding theory on environmental and socioeconomic oppression sheds light on the argument that both types of domination stem from the same historical process and are inherently interconnected. Addressing one without considering the other is essentially flawed; they are both features and consequences of present society. Acknowledging the historical debt owed to vulnerable economic classes and developing countries is imperative. Green republicanism could potentially establish a theoretical foundation for social-ecological thinking. Defining freedom as non-domination and applying this concept to nature are essential prerequisites for overcoming socioeconomic and environmental oppression. UBI is presented and discussed theoretically as a strong solution to address these two challenges. It serves not only as a means to facilitate the transition to a post-productivist society, transforming labor relations, but also as a catalyst for the development of circular economies and more sustainable occupations. Additionally, the basic income policy implemented in the city of Maricá, Brazil, is cited as empirical evidence showcasing the environmental and socioeconomic values of UBI. justice (UBI fronts First interconnected flawed imperative socialecological social ecological thinking nondomination non challenges postproductivist post productivist relations occupations Additionally Maricá Brazil

ABSTRACT Moringa oleifera Lam. is an arboreal forest species of great economic potential, adapted to the climatic conditions of the Brazilian semi-arid region, whose multiplication is mainly by seeds. Rapid viability and vigor tests help in the choice of lots. Thus, the objective of this study was to assess the efficiency of the pH of exudate and primary root protrusion tests in the evaluation of viability and vigor, respectively. Two seed lots were initially evaluated for moisture content, germination, first count, germination speed index, seedling length, seedling dry mass and electrical conductivity. For the pH of exudate test, phenolphthalein (1%) and sodium carbonate (2 and 4 g L-1) solutions were prepared, with three soaking periods (1, 3 and 5 h) and three temperatures (25, 30 and 35 °C). Exudate solution in strong to light pink color indicated viable seeds, whereas very light pink color to colorless indicated non-viable seeds. The primary root protrusion test was performed under 25, 30 and 35 °C, evaluating the primary root protrusion of at least 2 mm, every 12 h until 196 h. The experimental design was completely randomized, with four replicates. pH of exudate test with 1 h of soaking at 25 or 30 °C with 2 g L-1 sodium carbonate solution was promising, but further studies are needed before it is indicated as routine use for the species. Primary root protrusion test is efficient and can be conducted at 35 °C with evaluation after 48 h. Lam potential semiarid semi arid region seeds Thus respectively content count index length conductivity 1% (1% ( L1 L prepared 1, (1 (25 °C. C . °C) nonviable non mm 19 randomized replicates L- promising

RESUMO Kalanchoe daigremontiana é uma espécie ornamental de propagação obrigatoriamente assexuada. Entretanto, nenhum estudo in vitro foi realizado para avaliar a relação entre mudanças no ambiente de cultivo e variações genéticas de K. daigremontiana. Portanto, o objetivo deste estudo foi estabelecer a melhor concentração de sais no meio Murashige & Skoog (MS) e a concentração de sacarose no meio de cultura, além da qualidade da luz, no desenvolvimento de plântulas de explantes foliares de K. daigremontiana. Além disso, realizamos uma avaliação genética das plântulas resultantes para estudar alterações fenotípicas que poderiam ser atribuídas à variação somaclonal utilizando marcadores da Amplificação Aleatória de DNA polimórfico (RAPD). Para tanto, explantes foliares de K. daigremontiana foram desinfestados e inoculados em diferentes concentrações de sais do meio MS (25, 50 ou 100%), sem sacarose. As culturas foram transferidas para sala de crescimento e submetidas a três condições de luz (branca, azul e vermelha) com fotoperíodo de 16 horas, mais a ausência de luz, sob temperatura de 27 ± 1 °C. Os explantes também foram inoculados em 25% das concentrações de sais do meio MS, suplementado com diferentes concentrações de sacarose (controle - sem sacarose; 1,5; 3,0; 4,5 e 6,0%). Os explantes foliares de K. daigremontiana desenvolveram-se melhor sob luz branca e em qualquer uma das concentrações de sal do meio MS. Meio de cultura isento de sacarose pode ser utilizado e nenhuma variação no perfil genético das plântulas foi observada em comparação com as plantas-mãe nas condições de cultura testadas. assexuada Entretanto K Portanto (MS disso RAPD. RAPD . (RAPD) tanto 25, 25 (25 5 100%, 100 100% , 100%) branca, (branca vermelha horas 2 C °C controle 1,5 15 3,0 30 3 0 45 4 4, 6,0%. 60 6,0% 6 6,0%) desenvolveramse desenvolveram se plantasmãe plantas mãe testadas (RAPD (2 10 1, 3, 6,0 ( 6,

ABSTRACT Kalanchoe daigremontiana is an ornamental species propagated exclusively asexually. However, no in vitro studies have been conducted to assess the relationship between changes in the culture environment and genetic variations of K. daigremontiana. Therefore, this study aimed to determine the optimal concentration of salts in the Murashige & Skoog (MS) medium and the optimal concentration of sucrose in the culture medium, in addition to the quality of light, in the development of in vitro plantlets from leaf explants of K. daigremontiana. Additionally, a genetic evaluation of the resulting plantlets was conducted to study phenotypic changes that could be attributed to somaclonal variation using Random Amplified Polymorphic DNA (RAPD) markers. For this purpose, leaf explants of K. daigremontiana were disinfected and inoculated in different salt concentrations (25, 50, and 100%) of MS medium without sucrose. The cultures were transferred to a growth chamber and subjected to three light conditions (white, blue, and red) with a 16-hour photoperiod, plus the absence of light, at a temperature of 27 ± 1 °C. Explants were also inoculated in 50% salt concentrations of MS medium supplemented with various concentrations of sucrose (control - without sucrose, 1.5, 3.0, 4.5, and 6.0%). K. daigremontiana leaf explants showed optimal development under white light and in any MS medium salt concentrations. A sucrose-free culture medium was viable, and no genetic variation was observed in the plantlets compared to the parent plants under the tested conditions. asexually However K Therefore (MS Additionally RAPD (RAPD markers purpose 25, 25 (25 50 100% 100 white, (white blue red 16hour hour 16 photoperiod 2 C °C control 15 5 1.5 30 3 0 3.0 45 4 4.5 6.0%. 60 6.0% . 6 6.0%) sucrosefree free viable (2 10 1. 3. 4. 6.0 ( 6.

Résumé Les études sur les coalitions se concentrent exclusivement sur l’aspect partisan des alliances politiques du président. Cet article analyse la présence proportionnelle des États dans les bureaux ministériels formés durant les gouvernements de Fernando Henrique Cardoso, Lula da Silva et Dilma Rousseff. À partir du lieu d’origine politique de 265 ministres, nous avons développé un indice pour mesurer le taux de coalescence fédérative des cabinets. Cet indice estime la proportionnalité de la représentation des État au sein des équipes ministérielles année par année durant ces gouvernements. Au-delà de la surreprésentation de certains États par rapport au poids effectif de leurs caucus au Congrès national, nos résultats permettent de comparer les valeurs de la coalescence fédérative avec la coalescence partisane au fil du temps. L’indice montre que le président de la République cherche à privilégier certaines factions étatiques au sein des partis de la base alliée, exprimant ainsi une nouvelle dimension du présidentielle de coalition. laspect l aspect Cardoso Rousseff dorigine d origine 26 ministres cabinets Audelà Au delà national temps Lindice L alliée coalition 2

Resumo Estudos sobre coalizões estão focados exclusivamente no aspecto partidário das alianças políticas do presidente. O artigo analisa a presença proporcional dos estados nos gabinetes ministeriais formados nos governos de Fernando Henrique Cardoso, Lula da Silva e Dilma Rousseff. A partir do local de origem política de 265 ministros, desenvolvemos um índice para mensurar a taxa de coalescência federativa dos gabinetes. Esse índice estima a proporcionalidade da representação estadual das equipes ministeriais ano a ano nesses governos. Mais do que a sobrerrepresentação de alguns estados em relação ao peso efetivo de suas bancadas no Congresso Nacional, nossos resultados permitem comparar os valores da coalescência federativa com a coalescência partidária ao longo do tempo. O índice mostra que o presidente da República procura privilegiar certas facções estaduais dentro dos partidos da base aliada, expressando assim uma nova dimensão do presidencialismo de coalizão. Cardoso Rousseff 26 ministros Nacional tempo aliada coalizão 2

Resumen Los estudios sobre las coaliciones se centran exclusivamente en el aspecto partidista de las alianzas políticas del presidente. El artículo analiza la presencia proporcional de los estados en los gabinetes ministeriales formados por los gobiernos de Fernando Henrique Cardoso, Lula da Silva y Dilma Rousseff. Basándonos en el lugar de origen político de 265 ministros, desarrollamos un índice para medir la tasa de coalescencia federativa de los gabinetes. Este índice estima la proporcionalidad de la representación estatal de los equipos ministeriales año tras año en estos gobiernos. Más que la sobrerrepresentación de algunos estados en relación con el peso efectivo de sus grupos en el Congreso Nacional, nuestros resultados nos permiten comparar los valores de la coalescencia federal con la coalescencia de los partidos a lo largo del tiempo. El índice muestra que el Presidente de la República busca favorecer a determinadas facciones estatales dentro de los partidos de la base aliada, expresando así una nueva dimensión del presidencialismo de coalición. presidente Cardoso Rousseff 26 ministros Nacional tiempo aliada coalición 2

Abstract While existing studies on coalitions focus primarily on the party-level dynamics of a president’s political alliances, this paper examines the proportional representation of states within ministries during the terms of Fernando Henrique Cardoso, Lula da Silva, and Dilma Rousseff. Based on the political origins of 265 ministers, we developed an index to measure the extent of state-level coalescence of the ministries. This index allows us to assess the year-by-year proportionality of state-level representativeness within the ministries. More than merely identifying over-representation of certain states relative to their congressional influence, our results enable a comparative analysis of federative coalescence as compared to party coalescence over time. Our findings signal a trend in which the President of the Republic tends to favor specific state factions within allied parties, shedding light on a previously unexplored dimension of coalition presidentialism. partylevel level presidents president s alliances Cardoso Silva Rousseff 26 ministers statelevel yearbyyear year by overrepresentation influence time parties presidentialism 2

Abstract Jouni-Matti Kuukkanen has theorized that narrative does not involve rational content. Rather, he suggested, narrative is only a descriptive practice consisting of singular statements. Kuukkanen thus divorced the rational and narrative frameworks, arguing that historiography belongs to the former and not the latter. This article establishes a new conceptual framework that provides a revised understanding of narrative as a rational practice. I argue that the principles of organization brought to light by the Gestalt school of experimental psychology illuminate the underlying organizational logic that historians engage with when constructing narratives. To illustrate how these principles operate in historical narratives and how they are rational, I examine classic historical works such as Karl Marx’s introduction of the concept of surplus value; Giambattista Vico’s Autobiography and Jacob Burckhardt’s The Civilization of the Renaissance; Reinhart Koselleck’s Futures Past; and E. P. Thompson’s The Making of the English Working Class and Johan Huizinga’s Waning of the Middle Ages. My analysis shows that narrative entails its own kind of explanatory structure. It is a way of thinking that provides meaning and structure to that which is otherwise unstructured and undetermined. Finally, my new framework offers a foundation for the rational evaluation of narratives by showing how the context of discovery and the context of justification cannot be separated in the case of narrative histories.

Resumen Jouni-Matti Kuukkanen ha teorizado que las narrativas no involucran un tipo de actividad racional, en cambio, parecieran ser sólo una práctica descriptiva que consiste en afirmaciones singulares. Es así que Kuukkanen separa el marco racional del narrativo, argumentando que la historiografía pertenece al primero y no al segundo. Este artículo establece un nuevo marco conceptual que proporciona una comprensión revisada de la narrativa como práctica racional. Sostengo que los principios de organización sacados a la luz por la escuela de psicología experimental de la Gestalt iluminan la lógica organizacional subyacente con la que se involucran los historiadores cuando construyen narrativas. Para ilustrar cómo operan estos principios en las narrativas históricas y cómo son racionales, examino obras históricas clásicas como la introducción del concepto de plusvalía de Karl Marx; la Autobiografía de Giambattista Vico y La civilización del Renacimiento en Italia de Jacob Burckhardt; Futuro Pasado de Reinhart Koselleck; y La formación de la clase obrera en Inglaterra de E.P Thompson y El Otoño de la Edad Media de Johan Huizinga. Mi análisis muestra que la narrativa implica su propio tipo de estructura explicativa ya que es una forma de pensar que proporciona significado y estructura a lo que de otro modo está desestructurado y es indeterminado. Finalmente, mi nuevo marco ofrece una base para la evaluación racional de las narrativas al mostrar cómo el contexto de descubrimiento y el contexto de justificación no pueden separarse en el caso de las historias narrativas.

Resumo No Brasil, construções em madeira do tipo light woodframe possuem envelopamento estrutural do painel dependente do uso de chapas de OSB (Oriented Strand Board), o que implica em uma dificuldade em seu acesso por parte da população. Para ampliar a aplicação do sistema, uma possibilidade consiste em um projeto não atrelado aos monopólios de componentes construtivos. Uma possibilidade é a substituição da camada de envelopamento estrutural dos painéis por tábuas de madeira serrada convencional. Como objetivo esta pesquisa analisa a viabilidade de utilização e o comportamento de painéis de madeira serrada com envelopamento em tábuas de pinus quando solicitados a esforços horizontais, utilizando modelo numérico de simulações em software. O trabalho estuda cinco diferentes tipologias de painéis: um modelo digital de calibração baseado em experimento ensaiado em laboratório; quatro modelos de diferentes configurações, comparando entre si o desempenho estrutural de cada um com dados publicados na literatura. A modelagem digital utilizou dados experimentais já obtidos em trabalhos anteriores. Dos cinco tipos estudados quanto à tensão-deformação, apenas o Modelo 05 não se mostrou viável pela alta concentração de tensão observada nos conectores. Os demais modelos se mostraram adequados aos critérios preconizados por normas e documentos técnicos referenciados. Brasil Oriented Board, Board , Board) população sistema construtivos convencional horizontais software laboratório configurações literatura anteriores tensãodeformação, tensãodeformação deformação, deformação tensão-deformação 0 conectores referenciados

Abstract In Brazil, light woodframe buildings rely on the use of OSB (Oriented Strand Board), what implies a difficulty in its access by part of the population. To increase the applicability of the system one proposition consists in a woodframe project that is not bound by the monopoly over constructive components. A possible way consists in the substitution of the coating of the panels with standard Pinus boards. The objective of this research is therefore to analyze the viability and the behavior of wood panels with Pinus board coating when submitted to horizontal loads, utilizing as method digital simulations. This paper lists five different panel topologies, to calibrate it: one digital model of a previous lab experiment; four panels with different configurations, comparing them between themselves and with the literature in regards of structural performance. The utilized method was of the digital simulation with previous laboratory data calibration. Among the five types studied, only Model 05 exhibited high stress concentrations at connectors, rendering it unviable. The other models meet the criteria of referenced standards and technical documents. Brazil Oriented Board, Board , Board) population components boards loads simulations topologies experiment configurations performance calibration studied 0 connectors unviable documents

Abstract This article aims to examine the evolution of China’s foreign policy from the adoption of the “peaceful rise” policy to the present one which stems from the concept of the “Chinese dream” presented by Xi Jinping. The analysis is carried out in the light of major traditional international relations theories and introduces the doctrine underpinning the “Chinese dream” known as Tianxia. It finds that western traditional doctrine lacks rigorous consideration of Asian historical and cultural singularities that prevent them from fully explaining the international actions of the People’s Republic of China. In particular, China’s increasing assertiveness in its international relations along with its economic, military and technological advances, as well as the military conflicts in Ukraine and Israel, have exacerbated differences with the West. It is imperative to provide diplomacy with tools to assess the international context and the opposing positions of the West and the PRC that considers a theoretical framework that incorporates elements such as Tianxia, not as a substitute for Western tradition frameworks of analysis, but to enrich them. This is particularly true for the defense and projection of the interests of developing countries, which will require extensive diplomatic skills to navigate this complex context effectively as proactive players rather than bystanders in the international arena.

Resumen Este artículo tiene como objetivo examinar la evolución de la política exterior china desde la adopción de la política del “ascenso pacífico” hasta la actual, basada en el concepto del “sueño chino” expuesto por Xi Jinping. El análisis se lleva a cabo a la luz de las principales teorías de relaciones internacionales tradicionales e introduce la doctrina que sustenta al “sueño chino” conocida como Tianxia. Se encuentra que la doctrina occidental tradicional carece de una consideración rigurosa de las aristas históricas y culturales asiáticas y esto le impide explicar plenamente el comportamiento internacional de la República Popular China (RPC). En particular, la creciente asertividad de China en sus relaciones internacionales junto a sus avances económicos, militares y tecnológicos, así como los conflictos militares en Ucrania e Israel, han exacerbado las diferencias con Occidente. Es imperativo dotar a la diplomacia de herramientas que permitan valorar el contexto internacional y las posiciones contrapuestas entre Occidente y la RPC a partir de un marco teórico que incorpore elementos como el Tianxia, no en sustitución de los esquemas de análisis de tradición occidental, sino en adhesión, para enriquecerlos. Esto es particularmente cierto, para la defensa y proyección de los intereses de los países en desarrollo, los cuales requerirán de amplias destrezas diplomáticas para navegar este complejo contexto de manera efectiva, como actores proactivos y no espectadores en la arena internacional.

RESUMEN En este artículo se buscará desarrollar un análisis de la teoría aristotélica de la sustancia, específicamente de la discusión en torno a su particularidad o universalidad. Primero revisaremos el planteamiento del problema tal como aparece en Categorías. Posteriormente, llevaremos la discusión a Metafísica, específicamente el libro Z, donde se puede encontrar una visión más desarrollada y elaborada de las ideas expuestas por el filósofo que en el Organon. A partir de allí revisaremos la visión universalista y particularista para evaluarlas en su mérito e intentar determinar cuál de las dos resulta ser más adecuada para la ontología aristotélica. Finalmente, se revisarán algunas posibles soluciones al problema de cognoscibilidad que presenta la visión particularista y se intentará dilucidar esos problemas a la luz de la aplicación que tiene cuando se transporta el conflicto al problema del alma en De Anima.

ABSTRACT In this paper, we seek to develop an analysis of the Aristotelian theory of substance, specifically of the discussion about its particularity or universality. We will first review the statement of the problem as it appears in Categories. We will then take the discussion to Metaphysics, specifically book Z, where a further developed and elaborated view of the ideas presented by the philosopher can be found compared to the Organon. From there we will review the universalist and particularist views to evaluate them on their merit and try to determine which of the two turns out to be more adequate for Aristotelian ontology. Finally, we will review some possible solutions to the problem of cognizability presented by the particularist view and attempt to clarify these problems in light of the application it has when the conflict is transposed to the problem of the soul in De Anima.

Abstract Light wells in residential buildings represent a context that has received relatively little attention in daylighting analyses. This study aims to analyze the daylighting performance of a residential space with a window facing a light well, in order to contribute to the revision of NBR 15575:2013. The study conducted 1,152 daylighting analyses considering windows facing a light well, located on the first and fourth floors of a 4-story building. Clear and intermediate skies were considered in four Brazilian cities with different latitudes. Both the prescriptive method and point-in-time simulations were applied. The effectiveness of achieving daylit interior spaces through light wells strongly depends on the geometry of the light well and the external illuminance conditions of the city. Narrow light wells were found to be unsuitable for adequately daylighting the lower floor spaces. Furthermore, the prescriptive method was insufficient in representing daylighting originating solely from external wall interreflections. The study found that intermediate and superior performance levels, when achieved through point-in-time or spatial daylighting availability simulations, were never attained for the first-floor space. Therefore, the authors recommend that dense urban canyon situations and light wells be carefully considered in the revision of the standard. 155752013. 155752013 15575 2013. 2013 15575:2013 1152 1 152 1,15 4story story 4 building latitudes pointintime point time applied city Furthermore interreflections levels firstfloor Therefore standard 15575201 1557 201 15575:201 115 15 1,1 1557520 155 20 15575:20 11 1, 155752 2 15575:2 15575:

Resumo Poços de luz em edifícios residenciais representam um contexto com pouca atenção nas análises de iluminação natural. Esse estudo propõe analisar o desempenho de iluminação natural de um espaço residencial com janela voltada para poço de luz visando objetivo de contribuir com a revisão da NBR 15575:2013. O estudo realizou 1.152 análises de desempenho considerando a janela voltada para o poço de luz localizada no 1º e 4º pavimentos de uma edificação de quatro pavimentos. Foram considerados céu claros e intermediários em quatro cidades brasileiras com diferentes latitudes. O método prescritivo e simulação ponto-no-tempo foram aplicados. A solução de iluminação de espaços internos por meio de poços de luz depende fortemente de sua geometria e das condições de iluminância externa da cidade. Poços estreitos mostraram-se inaptos para levar luz suficiente para os ambientes inferiores. O método prescritivo não é capaz de representar adequadamente situações de iluminação natural oriunda exclusivamente de interreflexões de paredes externas. Os níveis intermediários e superiores de desempenho por simulação ponto-no-tempo ou por análises baseadas no clima não foram atendidos no 1º pavimento. Os autores recomendam que situações de cânions urbanos densos e poços de luz sejam cuidadosamente consideradas na análise da revisão da norma. 155752013. 155752013 15575 2013. 2013 15575:2013 1152 1 152 1.15 º latitudes pontonotempo ponto tempo aplicados cidade mostraramse mostraram se inferiores externas pavimento norma 15575201 1557 201 15575:201 115 15 1.1 1557520 155 20 15575:20 11 1. 155752 2 15575:2 15575: