Resumo A produção de tintas utilizando resíduos de beneficiamento de granito e mármore é uma nova alternativa para contribuir com o desenvolvimento sustentável na construção civil. Entretanto, a carência de estudos sobre a composição e o desempenho dessas tintas inviabiliza a disseminação desse novo material de construção. Logo, este estudo tem como objetivo investigar a composição dessas tintas utilizando ferramentas estatísticas para obter produtos com desempenho compatível com regulamentações técnicas e tintas comerciais. As formulações de tintas foram definidas através de um planejamento de misturas quaternárias. O teor de sólidos, pH, viscosidade, poder de cobertura e resistência à abrasão foram determinados para todas as amostras. As tintas produzidas com resíduos de granito apresentaram melhor poder de cobertura e resistência à abrasão, pois o resíduo de granito apresenta granulometria mais fina, além de ser predominantemente composto por sílica. Por fim, as tintas produzidas neste estudo e as tintas comerciais apresentaram comportamento semelhante, o que corrobora com o aproveitamento do resíduo do processamento de rochas ornamentais na produção de tintas. civil Entretanto Logo quaternárias sólidos pH viscosidade amostras fina sílica fim semelhante

Abstract The production of paints using waste from granite and marble processing is a new alternative to contribute to sustainable development in civil construction. However, the lack of studies on the composition and performance of these paints makes the dissemination of this new construction material unfeasible. Therefore, this study aims to investigate the composition of these paints using statistical tools to obtain products with performance compatible with technical regulations and commercial paints. The paint formulations were defined through a quaternary mixture planning. The solids content, pH, viscosity, hiding power, and abrasion resistance were determined for all samples. The paints produced with granite waste showed better hiding power and abrasion resistance, as granite waste has a finer granulometry, in addition to being predominantly composed of silica. Finally, the paints produced in this study and the commercial paints showed similar behavior, which supports the use of waste from the processing of ornamental rocks in paint production. However unfeasible Therefore planning content pH viscosity samples granulometry silica Finally behavior

RESUMO Os sistemas de produção integrados surgiram como uma estratégia de produção sustentável na intensificação do uso da terra com impacto mínimo nas funções do ecossistema. Este estudo utilizou ferramentas de agricultura de precisão para investigar a variabilidade espacial de propriedades do solo e da vegetação em área de Integração Lavoura-Pecuária-Floresta (ILPF) e área de Integração Pecuária-Floresta (IPF) em São Carlos, SP, Brasil. Consequentemente, foram avaliados: (1) as propriedades físico-químicas do solo, (2) a resistividade elétrica, e (3) os atributos da cultura do Eucalyptus urograndis que compõem a área de estudo. As amostragens foram realizadas em (1) agosto de 2021 nas profundidades de 0-0,2 e 0,2-0,4 m; (2) outubro de 2021 nas profundidades de 0-0,5, 0-1,0 e 0-2,0 m; e (3) abril de 2021 e abril de 2022. Os resultados indicaram que os valores dos parâmetros de fertilidade do solo foram adequados ao desenvolvimento da cultura e apresentaram baixa variabilidade espacial. As análises de solo indicaram baixa acidez, altos teores de matéria orgânica, teores médios de fósforo, potássio e capacidade de troca catiônica e altos teores de cálcio, magnésio e saturação por base. Entretanto, foram observados locais com maior variabilidade espacial para cálcio, refletindo variabilidade na capacidade de troca catiônica e saturação por base. A granulometria e a resistividade elétrica do solo apresentaram baixa variabilidade espacial na camada superficial. Mesmo sem diferenças nas propriedades do solo, houve diferença de 15% no maior volume de madeira no sistema IPF em comparação ao ILPF. ecossistema LavouraPecuáriaFloresta Lavoura Pecuária Floresta ILPF (ILPF PecuáriaFloresta (IPF Carlos SP Brasil Consequentemente avaliados 1 (1 físicoquímicas físico químicas 2 (2 3 (3 202 00,2 002 0 0,2 0-0, 0,20,4 0204 0,4 4 0,2-0, m 00,5, 005 0,5, 5 0-0,5 01,0 010 1,0 0-1, 02,0 020 2,0 0-2, 2022 acidez orgânica fósforo cálcio base Entretanto superficial 15 ( 20 00 00, 02 0, 0-0 0,20, 04 0,2-0 00,5 05 0,5 01 01, 10 1, 0-1 02, 2, 0-2 0- 0,20 0,2-

ABSTRACT Integrated production systems have emerged as a sustainable production strategy in intensifying land use with minimal impact on ecosystem functions. This study used precision agriculture tools to investigate the spatial variability of soil and vegetation properties in an integrated crop-livestock-forestry (ICLF) and in an integrated livestock-forestry (ILF) area of São Carlos city, SP, Brazil. Consequently, the following were assessed: (1) the soil physicochemical properties, (2) the electrical resistivity, and (3) the attributes of the Eucalyptus urograndis crop comprising the study area. Samplings were performed in (1) August 2021 at depths of 0-0.2 and 0.2-0.4 m; (2) October 2021 at depths of 0-0.5, 0-1.0, and 0-2.0 m; and (3) April 2021 and April 2022. Results indicated that the values for soil fertility parameters were suitable for crop development and presented low spatial variability. Soil analyses indicated low acidity, high levels of organic matter, average cation exchange capacity, phosphorus and potassium contents, high base saturation, and calcium and magnesium levels. However, locations with greater spatial variability for calcium were observed, reflecting cation exchange capacity and base saturation variability. Soil granulometry and electrical resistivity had a low spatial variability at the surface layer. Even without differences in the soil properties, there was a difference of 15% in the larger wood volume in the ILF then ICLF system. functions croplivestockforestry livestock forestry (ICLF livestockforestry (ILF city SP Brazil Consequently assessed 1 (1 2 (2 3 (3 202 00.2 002 0 0.2 0-0. 0.20.4 0204 0.4 4 0.2-0. m 00.5, 005 0.5, 5 0-0.5 01.0, 010 1.0, 0-1.0 02.0 020 2.0 0-2. 2022 acidity matter contents However observed layer 15 system ( 20 00 00. 02 0. 0-0 0.20. 04 0.2-0 00.5 05 0.5 01 01.0 10 1.0 0-1. 02. 2. 0-2 0- 0.20 0.2- 01. 1. 0-1

ABSTRACT The city of Bahía Blanca, located in the southwest of the province of Buenos Aires, has sustained for several decades a strong process of territorial expansion towards urban peripheral sectors. The use of land in the east and southeast of the city is currently manifested as an important element in the urban structure, sometimes without an adequate geotechnical study to know their response to the loads they can bear when used as physical support for engineering structures. With the aim of characterizing and classifying the soils of the outcropping and subsoil units of the sector, standardized in situ tests were carried out: resistance to penetration to estimate the compactness of the soil in its natural state and density of the soil in situ by the cone of sand method. In the laboratory, the granulometry determination method was applied by wet sieving and the Atterberg limits were determined. Based on the established parameters, the Unified Soil Classification System (USCS) was carried out. The preliminary studies carried out allowed us to define that, in the study area, the soils vary in depth from fine soils, clays of medium to high plasticity and silts of low plasticity, which grade to clayey sands / silty sands. The soils studied are mainly made up of: soils type CH and Cl on the surface that grade to SC and

RESUMEN La ciudad de Bahía Blanca, ubicada en el sudoeste de la provincia de Buenos Aires, sostiene desde hace varias décadas un fuerte proceso de expansión territorial hacia sectores periféricos urbanos. El uso de las tierras en el este y sudeste de la ciudad, se manifiesta actualmente como un elemento importante en la estructura urbana, en ocasiones sin un adecuado estudio geotécnico para estudiar su respuesta ante las cargas que puedan soportar cuando son utilizados como soporte físico de estructuras ingenieriles. Con el objetivo de caracterizar y clasificar los suelos de las unidades aflorantes y del subsuelo del sector, se realizaron ensayos normalizados in situ: resistencia a la penetración para estimar la compacidad del suelo en estado natural y densidad del suelo in situ por el método de cono de arena. En laboratorio se aplicó método de determinación de la granulometría mediante tamizado por vía húmeda y se determinaron los límites de Atterberg. En función a los parámetros establecidos se realizó la Clasificación Unificada de Suelos (Unified Soil Classification System, USCS). Los estudios preliminares realizados permitieron definir que, en el área de estudio los suelos varían en profundidad desde suelos finos, arcillas de plasticidad media a alta y limos de baja plasticidad, que gradan a arenas arcillosas / arenas limosas. Los suelos estudiados están constituidos principalmente por: suelos tipo CH y Cl en superficie que gradan a SC y SM.

Abstract We present the results of ongoing research on different clay sources at Antofagasta de la Sierra, evaluating their potential for pottery-making. It included outcrops mapping, sample collection, petrographic characterisation and experimental archaeology to characterise different clay sources in Antofagasta de la Sierra. The former allowed locating and analysing clay components and the experimentation defined clay behaviour during pottery-making, both before and after firing. Our analyses established different categories based on clay appropriateness for pottery making: highly appropriate, slightly appropriate and non-appropriate clays. According to experimentation, this difference takes place after firing, as many highly-plastic and plastic clays disaggregate and peel off generating slightly hard and disaggregated fabrics due to the presence of small to large carbonate inclusions. These results provide a reference for archaeological studies of fabrics including the composition, granulometry and abundance of inclusions naturally present in local clays. In addition, data from experimental archaeology such as malleability and plasticity, contraction rate, thermal resistance and strength will help define the processes involved in pottery manufacture.

Resumen Presentamos los primeros resultados de una investigación, cuyo objetivo principal fue estudiar las diferentes fuentes de arcilla de Antofagasta de la Sierra y evaluar su potencialidad para la manufactura cerámica. A partir del mapeo de los distintos afloramientos, la toma de muestras, el análisis petrográfico y la arqueología experimental, se caracterizaron distintas fuentes de arcilla de Antofagasta de la Sierra. Los primeros estudios posibilitaron ubicar y analizar los componentes de las mismas y la experimentación permitió evaluar los comportamientos de las arcillas en los procesos de manufactura cerámica, antes y después de la cocción. Los análisis implementados permitieron establecer diferentes categorías en función de su adecuación a la producción cerámica: arcillas muy aptas, arcillas poco aptas y arcillas no aptas. Los resultados de la experimentación permitieron observar que esta diferencia tiene lugar luego del proceso de cocción, en el cual muchas de las arcillas que presentan una buena a muy buena plasticidad y maleabilidad, se disgregan y descascaran dando como resultado cerámicas con poca dureza y una textura disgregable debido, en todos los casos, a la presencia de inclusiones de carbonatos de tamaños medianos a grandes. Esta información resultará útil a la hora de abordar el estudio de la tecnología cerámica, al proporcionar datos de referencia para el análisis arqueológico, como la composición, la granulometría y la abundancia de los clastos presentes en las arcillas locales.

Abstract Mining is the largest economic activity in Peru, contributing a considerable percentage of the country's Gross Domestic Product. However, the process of this activity evidences several socio-environmental conflicts. The generation of mining waste or expressed as mining tailings from the various processes is a latent threat that affects the spheres of sustainable development. The objective of this study was to propose the valorization of mining tailings as aggregates for road construction in the Andean region of Peru under a circular economy approach. Consequently, several analyses were carried out to evaluate its viability, such as the meteorological factor of precipitation, acidity or alkalinity, elements present in the sample, granulometry, California Bearing Ratio (CBR) and Marshall test. The results have shown that the proposal complies with the parameters established at the national level with a stability of 877.67 kg and a 25% utilization of mine tailings. In conclusion, the use of mine tailings as aggregates for construction is a viable proposal for road construction under a circular economy approach. Finally, the analysis of the valorization of mining waste in other elements of the construction sector is recommended to continue promoting the circular economy and sustainable development.

Resumen La minería en el Perú es la más grande actividad económica aportando un porcentaje considerable al Producto Bruto Interno nacional. Sin embargo, el proceso de esta actividad evidencia diversos conflictos socio-ambientales. La generación de residuos mineros o expresados como relaves mineros provenientes de los diversos procesos es una amenaza latente que afecta las esferas del desarrollo sostenible. Este estudio tuvo como objetivo la propuesta de valorización de relaves mineros como áridos para la construcción de carreteras en la región andina del Perú bajo un enfoque de economía circular. En consecuencia, se realizó diversos análisis para evaluar su viabilidad como el factor meteorológico de precipitación, acidez o alcalinidad, elementos presentes en la muestra, granulometría, California Bearing Ratio (CBR) y prueba Marshall. Los resultados han demostrado que la propuesta cumple con los parámetros establecidos a nivel nacional con una estabilidad de 877,67 kg y un aprovechamiento del 25% de los relaves mineros. En conclusión, el uso de relaves mineros como áridos para la construcción es una propuesta viable para la construcción de carreteras bajo un enfoque de economía circular. Finalmente, se recomienda el análisis de valorización de residuos mineros en otros elementos del sector construcción para continuar promoviendo la economía circular y desarrollo sostenible.

Abstract: The clay fraction of earthen plasters is the part responsible for the acquisition of cohesion and adherence that they possess against deterioration factors. Adherence is the property responsible for keeping the plaster together with the wall and is influenced by the percentage content of clay as well as by its mineralogy and the heterogeneity of minerals that may be present. However, it is still unknown in depth how clay minerals perform in the adherent properties of earthen plasters when the composition is heterogeneous in the material. The objective of this study is to evaluate the incidence of the mineralogical complexity of clay mineralogy in the variability of the adherence of earth plasters. To evaluate the variability, considering that the mineralogy of the soils depends directly on the place and the formation processes, eight soils from Tucumán (Argentina) corresponding to different physiographic units were analyzed. A methodology was designed for sample preparation that allows soils to be compared through adhesion tests. They were characterized by XRD to determine their mineralogical composition and by the hydrometric method to determine their granulometry. To evaluate the adherence of mixtures made with the respective soils, it was proposed in the first instance to compensate the granulometry of the soils to equate them and, once the plasters were made, this property was evaluated through shear and pull-off tests. The results showed that they allowed us to identify that the soils presented a pattern of mineralogical composition common to all the physiographic units, made up of the Ill and K pair, the former being predominant. For this pattern, it was observed in particular that there is a positive correlation between the increase in Ill content with the increase in the adhesive strength of the plasters. Clay minerals from the Sm group also contribute to the increase in adherence when the percentage is greater than or equal to 11%. On the contrary, K and Cl do not influence the increase in adhesive strength

ABSTRACT Introduction: The extruded products in Cuba are produced from corn meal, a raw material obtained from imported corn grain. Extrusion technology allows the production of products from flour mixtures. Objective: To determine the adequate proportion of the corn and rice flour mixture and the extruder operating temperature. Materials and Methods: A granulometric analysis of both flours was made. Mixtures of corn flour (M) and rice four (A) were prepared. An industrial extruder with a capacity of 200 kg/h and a nozzle diameter of 4 mm was used. The experimental variables were M/A ratio (90 M/10 A, 75 M/25 A y 60 M/40 A) and temperature (190 y 210 °C). The investigated variables were expansion and humidity as well as those corresponding to the sensorial evaluation. Results and Discussion: Rice flour shows a finer granulometry than corn flour; this may limit its level of addition to the mixture. The investigated variables were found to be independent of temperature, but dependent on the proportion of the flours. From the desirability function, the best result was obtained for 60 M/40 A and 190 ºC. Conclusions: Corn and rice flours have similar starch content. The level of rice flour addition is determined by the incorporation of smaller particle sizes into the mixture. The overall sensory quality, according to the desirability function, was 7.4, equivalent to good.

RESUMEN Introducción: Los productos extruidos en Cuba se elaboran a partir de harina de maíz, materia prima obtenida de la importación del maíz en grano. La tecnología de extrusión permite elaborar productos a partir de mezclas de harinas. Objetivo: Determinar la proporción adecuada de la mezcla de harinas de maíz y arroz y la temperatura de operación del extrusor. Materiales y Métodos: Se realizó un análisis granulométrico de ambas harinas. Se prepararon mezclas de harina de maíz (M) y harina de arroz (A). Se utilizó un extrusor industrial de 200 kg/h de capacidad y 4 mm de diámetro de boquilla. Las variables experimentales fueron la proporción M/A (90 M/10 A, 75 M/25 A y 60 M/40 A) y la temperatura (190 y 210 °C). Las variables investigadas fueron el índice de expansión y la humedad, así como las correspondientes a la evaluación sensorial. Resultados y Discusión: La harina de arroz presenta una granulometría más fina que la de maíz; ello puede limitar su nivel de adición a la mezcla. Las variables investigadas resultaron independientes de la temperatura, pero dependientes de la proporción de las harinas. A partir de la función de deseabilidad se obtuvo el mejor resultado para 60M/40A y 190 °C. Conclusiones: Las harinas de maíz y arroz tienen un contenido de almidón similar. El nivel de adición de harina de arroz queda determinado por la incorporación a la mezcla de partículas con menor tamaño. La calidad sensorial global, según la función de deseabilidad fue de 7,4 equivalente a buena.

ABSTRACT. This study aimed to correlate the physical characteristics of ground corn, at different crushing intensities, with the zootechnical performance of piglets in the nursery phase. Forty piglets (20 castrated males and 20 females) with an initial average weight of 15.7±1.98 kg and final weight of 32.5±3.27 kg were used. They were subjected to the same type of experimental diet (4% of commercial premix for the phase, 29% of soybean meal, and 67% of ground corn), with the only difference being the corn grinding process. The corn used was fractionated into five portions, and each one of them was crushed in a hammermill equipped with a different screen hole diameter (2; 2.5; 3; 3.5 and 4 mm). Which resulted in ground corn with the following particle sizes (PS): 518, 580, 628, 706 and 740 μm, and the following corn geometric standard deviations (GSD): 1.72, 1.71, 1.75, 1.80 and 1.90, respectively. The piglets were distributed in a completely randomized design with five treatments and four replications, with the experimental units being formed by pens with two piglets each. There was no effect (p > 0.10) from grinding intensities on daily feed intake (DFI) and daily weight gain (DWG). Conversely, there was an effect (p < 0.10) from different grinding intensities on feed conversion (FC). The PS and GSD of both the corn and diet, as well as the corn fractions retained on the 4-, 2- and 1.2-mm test sieves showed positive correlations with FC (p < 0.05). On the other hand, the corn fractions retained on the 0.6-, 0.3- and 0.15-mm teste sieves showed negative correlations with FC (p < 0.05). The linear model was the one that fitted the estimated data into the data observed for FC. A corn PS reduction from 740 to 580 μm promoted a linear improvement in FC. The use of corn fractions, retained on the 1-, 2- and 0.3-mm test sieves, and the use of corn GSD and diet GSD as independent variables showed a higher R² than that obtained with the use of corn PS as an independent variable in linear equations for estimating FC. ABSTRACT phase (2 2 females 157198 15 7 1 98 15.7±1.9 325327 32 5 3 27 32.5±3.2 4% (4 29 meal 67 , corn) process portions 2.5 25 35 3. mm. mm . mm) (PS) 518 628 70 74 (GSD) 172 72 1.72 171 71 1.71 175 75 1.75 180 80 1.8 190 90 1.90 respectively replications p 0.10 010 0 10 DFI (DFI DWG. DWG (DWG) Conversely (FC) 4, 4- 1.2mm 12mm 1.2 0.05. 005 0.05 05 0.05) hand 0.6, 06 0.6 6 0.6- 0.3 03 0.15mm 015mm 0.15 58 1, 1- 0.3mm 03mm R ( 15719 9 15.7±1. 32532 32.5±3. 2. (PS 51 62 (GSD 17 1.7 18 8 1. 19 1.9 0.1 01 (DWG (FC 2mm 12 00 0.0 0. 15mm 015 3mm 1571 15.7±1 3253 32.5±3 157 15.7± 325 32.5± 15.7 32.5 15. 32.

ABSTRACT Kaolinite is the main clay mineral in most soils around the world and has been widely used for industrial purposes. This research aimed to study chemical, morphological and crystallographic characteristics of kaolinite, and establish the origin of kaolinitic samples on Serra do Mar and kaolinitic layers on peatlands, located at Southern Brazil. Samples were collected on different geomorphological positions: two samples at Serra do Mar (kaolinitic saprolite – SAP, and kaolinitic layers - KL); and two cores at the peatland with Sapric Histosols from Quaternary sedimentary basin. Granulometry and total organic carbon (TOC) were determined in soil samples. Kaolinite in silt and clay fractions was studied by chemical extractions, X-ray diffraction (XRD), thermal analysis (DTA/TG), and scanning electron microscopy with energy dispersive spectroscopy – SEM/EDS. Chemical and mineralogical characteristics of kaolinite were divided into two groups, according to the particle size and the location of the deposit in the relief. Silt fraction: i) SAP – genesis mainly derived from mica weathering; ii) peatland, containing pseudomorph crystals smaller than those found in Serra do Mar; Clay fraction: i) Serra do Mar – there was a larger contribution of K-feldspar weathering in the genesis of kaolinite from KL in relation to SAP; ii) peatland – the stronger weathering and the hydromorphic conditions resulted in less neoformed crystalline kaolinites. For both environments, the substitution of Al3+ by Fe3+ into the octahedral sheet led to a reduction in the mineral thickness and also increased the occurrence of structural deformations in clay kaolinite. Kaolinite in peatland is a combination of the following genesis processes: transportation from Serra do Mar (mainly in the silt fraction) and; formation in situ through neogenesis process (dominant in the clay fraction). purposes peatlands Brazil positions KL) basin TOC (TOC extractions Xray X ray XRD, XRD , (XRD) DTA/TG, DTATG DTA/TG DTA TG (DTA/TG) SEMEDS SEM EDS SEM/EDS groups relief fraction i ii Kfeldspar K feldspar kaolinites environments Al3 Al Fe3 Fe processes dominant fraction. . (XRD (DTA/TG

ABSTRACT Physical properties of the Technosols formed by the tailings deposition may constitute a physical barrier that limits water movement and plant development due to the properties received from those sediments. This study aimed to evaluate the physical quality of the Technosols formed by the deposition of sediments displaced by the Fundão Dam failure, Mariana, Minas Gerais State, Brazil, based on the evaluation of physical properties and Load Bearing Capacity Models (LBCM). For that, three areas under different vegetation types were selected: eucalyptus (Euc), forest with human-assisted revegetation (RF), and forest with native vegetation (NF). Three sampling subareas were demarcated in each area: non-impacted areas (Ni), and Technosols formed in directly impacted areas (Di), and partially impacted areas (Pi). Undisturbed samples were collected in two layers and subjected to the uniaxial compression test after equilibration at five matric potentials. Soil compression curves and LBCM were determined. Soil bulk density (BD), total porosity (TP), organic matter (OM), granulometry, and particle density (PD) were also determined. Clay content was less significant, and the silt and very fine sand content was significantly higher in the Technosols, generating an increase in BD and reduction in TP. Technosols generally exhibited greater load-bearing capacity due to higher pre-consolidation pressure values attained by these soils due to the lower clay and OM contents. High resistance of these soils is one limitation for revegetation of the areas evaluated, being necessary management practices to improve physical properties of the Technosols. failure Mariana State Brazil LBCM. . (LBCM) selected Euc, Euc , (Euc) humanassisted human assisted RF, RF (RF) NF. NF (NF) area nonimpacted non Ni, Ni (Ni) Di, Di (Di) Pi. Pi (Pi) potentials determined BD, (BD) TP, TP (TP) OM, (OM) granulometry PD (PD significant loadbearing load bearing preconsolidation pre consolidation contents evaluated (LBCM (Euc (RF (NF (Ni (Di (Pi (BD (TP (OM

INFLUENCE OF THE PROCEDURE FOR GRANULOMETRIC SAMPLE ADJUSTMENT OF RED CERAMIC AGGREGATED WITH DIMENSION STONE WASTES FOR CLASSIFICATION ACCORDING TO THE ABNT CRITERIA’S. In order to clarify questions about the granulometric preparation of samples for the classification of solid wastes according to the Brazilian technical standard (NBR 10004/04), solubilization tests were carried out on red ceramic specimens made with conventional clay aggregated with ornamental rock residues. Samples were prepared by fragmentation and milling to verify the effects on metals releasing to the extractor medium. The specimens were made with 80% clay, 20% residue and 10% (m/m) moisture and sintered at 1000 °C. The data show that ceramics made with conventional clay, when discarded, will produce non inert wastes, as well as the ceramics made with dimension stone wastes added to the conventional raw material, according to the granulometry of its particles. After all, the metals concentration in the solubilization test are influenced by the sample granulometry. This paper shows that the method of granulometric adjustment should be detailed in the technical standard for solubilization tests (NBR 10006/04), in order to ensure the reliability of the method for classification of solid wastes. CRITERIAS. CRITERIAS CRITERIA S. S CRITERIA’S NBR 10004/04, 1000404 10004/04 , 10004 04 10004/04) residues medium 80 20 10 m/m mm m (m/m 100 C °C discarded material particles all 10006/04, 1000604 10006/04 10006 10006/04) 100040 10004/0 0 8 2 1 100060 10006/0 10004/ 10006/

Abstract Finding ways to reuse residue is an alternative not only to reduce its presence in urban and natural environments, but also to reduce costs and consumption of resources by industries. The objective of this paper is to evaluate the properties of concretes made by replacing conventional coarse and fine aggregates with marble residue. Morphological, granulometry, specific gravimetry and crystalline phase analyses were carried out in the aggregates. The composition of the constituents, by mass, was 1:1,2:3 of Portland cement CPIII-32 RS, fine aggregates, and coarse aggregate, respectively, with the addition of 0.4 of water, molded and cured in water. About 25 concrete samples were made, varying the amount of coarse/fine aggregate in the cement mass according to the aggregates proportions of: A= 100% gravel/ 100% sand, B= 100% coarse RRO/ 50% fine RRO + 50% sand, C= 50% coarse RRO + 50% gravel/ 100% fine RRO, and D = 100% coarse RRO/100% fine RRO. The cylindrical samples measuring ∅50 x 100 mm were subjected to water absorption and compressive strength tests, and the results were compared with standards and literature. The water absorption was smaller than 2.5% and the compressive strength values were between 27-33 MPa, close to the resistance of cement used. Composition B presented the best results among the others, indicating the possibility of using the residue from marble for production of concretes for various purposes such as low load paving, sidewalks, blocks, among others. However, for interlocking floors, higher performance cement should be used to achieve the required strength. This type of concrete adds value to the residue and mitigates environmental impacts. environments industries Morphological granulometry constituents 11,23 1123 1 1,2 3 2 1:1,2: CPIII32 CPIII 32 CPIII-3 RS respectively 04 0 4 0. coarsefine A gravel sand 50 C RRO100 RRO/100 ∅5 10 tests literature 5 2.5 2733 27 33 27-3 MPa others paving sidewalks blocks However floors impacts 11 23 11,2 112 12 1, 1:1,2 CPIII3 CPIII- RRO10 RRO/10 ∅ 2. 273 27- 11, 1:1, RRO1 RRO/1 1:1 1:

Resumo Encontrar formas de reaproveitar resíduos é uma alternativa não só para reduzir sua presença em ambientes urbanos e naturais, mas também para reduzir custos e consumo de matérias primas pelas indústrias. O objetivo deste trabalho é avaliar as propriedades de concretos fabricados através da substituição de agregados graúdos e miúdos convencionais por resíduo de mármore. Foram realizadas análises de morfologia, granulometria, massa específica e da fase cristalina dos agregados. A composição dos constituintes, em massa, foi 1:1,2:3 de cimento Portland CPIII-32 RS, agregados miúdos e agregados graúdos, respectivamente, com adição de 0,4 de água, moldados e curados em água. Foram confeccionadas cerca de 25 amostras de concreto, variando a quantidade de agregado graúdo/fino na massa de cimento de acordo com as proporções de agregados de: A= 100% brita/ 100% areia, B= 100% RRO grosso/ 50% RRO fino + 50% areia, C= 50% RRO grosso + 50% cascalho/ 100% RRO fino, e D = 100% RRO grosso/100% RRO fino. As amostras cilíndricas medindo ∅50 x 100 mm foram submetidas a testes de absorção de água e resistência à compressão, e os resultados obtidos foram comparados com algumas normas e com a literatura. A absorção de água foi inferior a 2,5% e a resistência à compressão ficou entre 27-33 MPa, valor próximo à resistência do cimento utilizado. A composição B apresenta os melhores resultados entre as demais, indicando a possibilidade de utilização do resíduo do mármore para produção de concretos para diversas finalidades como pavimentação de baixa carga, calçadas, blocos, entre outros. No entanto, para pisos intertravados, deve-se utilizar cimento de maior desempenho para atingir a resistência necessária. Esse tipo de concreto agrega valor ao resíduo e mitiga os impactos ambientais. naturais indústrias morfologia granulometria constituintes 11,23 1123 1 1,2 3 2 1:1,2: CPIII32 CPIII 32 CPIII-3 RS respectivamente 04 0 4 0, graúdofino graúdo brita areia 50 C cascalho grosso100 grosso/100 ∅5 10 literatura 5 2,5 2733 27 33 27-3 MPa utilizado demais carga calçadas blocos outros entanto intertravados devese deve se necessária ambientais 11 23 11,2 112 12 1, 1:1,2 CPIII3 CPIII- grosso10 grosso/10 ∅ 2, 273 27- 11, 1:1, grosso1 grosso/1 1:1 1:

ABSTRACT Coffee grounds (SCG) and rice husk ash (RHA) are used in this study as raw materials to obtain lightweight aggregates (LWAs), replacing clay. The waste generated during the processing of coffee and rice is commonly disposed of in landfills and rubbish dumps, aggravating environmental impacts. Combined with the scarcity of natural resources and the sustainable management of this waste, its properties favour the development of LWAs. However, research into their use is scarce and superficial. The aim of this research is to evaluate the application of SCG and RHA as raw materials in the production of a new sustainable LWA. The starting materials were benefited and then characterized by laser granulometry, X-ray fluorescence and diffraction, and scanning electron microscopy. The mixtures were then formulated according to the Riley diagram. The specimens developed were then dried and sintered at temperatures of 1100 to 1250 °C. A total of 20 different specimens were produced, with clay substitution ranging from 15% to 62%, 12 of which have at least one engineering application. The manufactured aggregates had a bloating index (BI ) of –79.90% to –7.80%, loss of mass (LOI ) of 15% to 53%, particle density ( ρd ) of 0.88 to 2.23 g/cm3, water absorption (WA24H) of 0.1% to 61.7% and crushing strength (S ) of 0.81 to 29.32 MPa, as well as being assessed for mineralogy and microstructure. In general, the main properties of LWAs were affected by the firing method and the proportions of starting materials. The results show that the production of sustainable LWAs from SCG and RHA is feasible, with the appropriate indices being achieved for application in engineering works and services. (SCG (RHA LWAs, , (LWAs) dumps impacts However superficial LWA granulometry Xray X ray diffraction microscopy diagram 110 125 C °C 2 produced 15 62 62% 1 BI 7990 79 90 –79.90 780 7 80 –7.80% LOI 53 53% 088 0 88 0.8 223 23 2.2 gcm3 gcm g cm3 cm g/cm3 WA24H WAH WA H (WA24H 01 0.1 617 61 61.7 S 081 81 2932 29 32 29.3 MPa microstructure general feasible services (LWAs 11 6 799 9 –79.9 78 8 –7.80 5 08 0. 22 2. g/cm 61. 293 3 29. –79. –7.8 –79 –7. –7 –

ABSTRACT This study primarily focuses on analyzing the pore structure characteristics and predicting permeability in binary blended pervious concretes, both with and without fines. The pervious concretes included fly ash, a class 'C' material, as a partial cement replacement (10% and 20%). The aggregates consisted of a mix of coarse aggregates, with sizes ranging from 19–9.5 mm and 9.5–4.75 mm, and fine aggregates substituted a portion of the coarse aggregates at specific levels (5–15%). The area fraction (ϕA) and volumetric methodology (ϕV) were used for assessing the porosity of the binary blended pervious concrete mixtures. The properties of the pore size were measured through morphological techniques. The Katz-Thompson (K-T) relationship utilized porosity and pore size data from image analysis to predict permeability in pervious concretes. Comparing the two porosity calculation methods, the porosities obtained through image analysis (area fraction) were slightly higher than those obtained through the volumetric technique. The pore characteristics identified through techniques like Two-Point Correlation and granulometry were found to be quite similar. Results indicated a strong agreement between the experimentally determined and predicted permeability values. fines ash C 'C material 10% 10 (10 20%. 20 20% . 20%) 1995 19 9 5 19–9. 95475 4 75 9.5–4.7 5–15%. 515 5–15% 15 (5–15%) ϕA (ϕA ϕV (ϕV mixtures KatzThompson Katz Thompson KT K T (K-T methods technique TwoPoint Two Point similar values 1 (1 2 199 19–9 9547 7 9.5–4. 51 5–15 (5–15% ( 19– 954 9.5–4 5–1 (5–15 95 9.5– 5– (5–1 9.5 (5– 9. (5

Abstract Beach classification models are widely used to describe the state of the beach in response to the prevailing environmental conditions and have set the theoretical grounds for equilibrium and in-plant profile models of a beach and their various applications. This study determined the morphodynamic state of 54 sandy biogenic beaches on the northeast coast of Cuba. This was done based on the identification of coastal geoforms found in land works between August 2018 and March 2022 and the geoforms identified in high-resolution satellite images from Google Earth Pro (CNES/Airbus, Maxar Technologies). In addition, on 12 representative beaches on the northeast coast, we explored whether the coastal geoforms indicative of certain morphological states observed during fieldwork match those predicted by the Ω dimensionless parameter or Dean’s index, which classified beaches as dissipative, reflective, and intermediate. The main geomorphological features include an average beach width of more than 50 m, an 11 m-wide face, and a narrow or absent flat zone with a mean height of 1.35 m, lacking cusps and rhythmic topography, except for 26 % of beaches and only in winter. The submerged zone shows a low sand bar without rip currents. Coral reefs that protect the beaches from the highest waves in 93 % of the cases represent the distinctive geomorphological feature of the beaches studied. The dimensionless parameter confirmed that the beaches of Cuba’s northeast coast correspond to intermediate morphodynamic states with a trend toward reflective rather than dissipative modal states. These findings correspond to the coastal geoforms and sediment granulometry on the beaches studied. The figures obtained with the dimensionless parameter Ω and the sedimentary characteristics of the beaches are consistent with the characteristics of intermediate beaches reported by Australian researchers, but we did not find the geoforms for intermediate beaches reported by them. The beaches studied showed no rip currents, chains of coastal furrows, low-tide terraces, marked rhythmic topography, and cusps. Other studies have also pointed out that the beach classification proposed by Australian researchers, which considers the characteristics of waves and the sedimentation rate, is not always applicable. In the study area, this is mainly due to the presence of coral reefs close to the coast, low wave energy, and the influence of geological factors, in addition to the prevalence of longitudinal over transverse sand transport. Our results confirm that beach classification considering their morphodynamic state is essential to understanding the spatio-temporal dynamics of the hydrodynamic processes on beaches and contributes to a better local and regional knowledge of them. In addition, they highlight that the hydrodynamic and sedimentary characteristics of each coastline should be studied before using beach equilibrium profile models and the equations derived from them for erosion control actions.

Resumen Los modelos de clasificación de playa son ampliamente usados para describir el estado de la playa en respuesta a las condiciones ambientales reinantes y han establecido las bases teóricas sobre los modelos de perfil de equilibrio y en planta de una playa y sus diversas aplicaciones. En el estudio se determina el estado morfodinámico en 54 playas biogénicas arenosas del litoral nororiental de Cuba, a partir de la identificación de las geoformas litorales encontradas en trabajos de terrenos, para el periodo comprendido entre agosto de 2018 y marzo del año 2022, y las geoformas identificadas en imágenes satelitales de alta resolución de Google Earth Pro (CNES/Airbus, Maxar Technologies). Además, se comprobó en 12 playas representativas del litoral nororiental, si las geoformas litorales observadas en los trabajos de campo, indicativas de ciertos estados morfológicos, se corresponden con las pronosticadas mediante el parámetro adimensional Ω o Índice de Dean, que permite clasificar las playas en disipativas, reflejantes e intermedias. Como rasgos geomorfológicos fundamentales destacan un ancho medio de la playa superior a 50 m, una cara de 11 m de ancho y bermas estrechas o ausentes, con altura media de 1.35 m, sin la presencia de cúspides y topografías rítmicas, excepto en el 26% de las playas y únicamente en la etapa invernal. En la parte sumergida aparece una barra de arena de poca altura, sin la presencia de corrientes de resaca. La presencia de arrecifes coralinos que protegen las playas del oleaje de mayor altura, en el 93% de los casos, constituye el rasgo geomorfológico más significativo de las playas objeto de estudio. El cálculo del parámetro adimensional confirmó que las playas del litoral nororiental de Cuba corresponden a estados morfodinámicos de tipo intermedio y tienden más a estados modales reflejantes que disipativos, resultados que se corresponden con las geoformas litorales y la granulometría de los sedimentos encontrados en las playas objetos de estudio. Aun cuando las características reportadas por investigadores australianos, para playas intermedias coincidan con los valores pronosticados mediante el cálculo del parámetro adimensional Ω y con las características sedimentarias de las playas, las geoformas reportadas por estos, para playas intermedias, no fueron encontradas en las playas objeto de estudio. En ellas no aparecen corrientes de retorno, cadenas de surcos litorales, terrazas de bajamar, marcada topografía rítmica y cúspides. Otros estudios también han señalado que no siempre se cumple la clasificación de las playas, que tiene en cuenta las características de las olas y la velocidad de caída de los sedimentos, propuestas por investigadores australianos, debido particularmente a la presencia de arrecifes coralinos cercanos a la costa, la baja energía del oleaje y el control geológico. A ello habría que añadir el predominio del transporte longitudinal de arena sobre el transporte transversal en el área de estudio. Los resultados confirman que la clasificación de las playas, atendiendo a su estado morfodinámico es esencial para comprender la dinámica espacio-temporal de los procesos hidrodinámicos que tienen lugar en las playas y un mejor conocimiento local y regional de las mismas. Además, reafirman la necesidad de contar con estudios específicos de las características hidrodinámicas y sedimentarias propias de cada litoral, antes de extrapolar modelos de perfil de equilibrio en playas y las ecuaciones que se deriven de ellos en las actuaciones para el control de la erosión.