The use of materials such as organofunctionalized silica for application in solid phase extraction (SPE) allows the preconcentration of several ions, including Pt, and subsequent detection. This work aims to synthesize and characterize an organofunctionalized silica (Sil-TMSDT) with the silylant N’(trimethoxysilyl)propylethylenetriamine and its application as a solid phase in the preconcentration Pt4+ ions in aqueous media, using detection by flame atomization atomic absorption spectroscopy (FAAS). The Fourier-transform infrared spectroscopy (FTIR) spectra and scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS) confirmed the aminofunctionalization of the silica. For the adsorption process, a preconcentration mini-column with 200 mg of Sil-TMSDT, a solution of 0.485 mg L−1 of K2[PtCl6] at pH 10 and HNO3 0.5 mol L−1 as eluent were used, obtaining an enrichment factor of 15-fold with retention efficiency higher than 99%. The Pt4+ ion determined by FAAS showed a linear response between 0.02 and 0.40 mg L−1; a linear coefficient where R = 0.9981; a 16-fold preconcentration factor; a limit of quantification (LOQ) and limit of detection (LOD) of 0.045 and 0.014 mg L−1, respectively. The proposal system showed analytical applicability to determining Pt4+ ion in an aqueous medium and could be used to detect traces of this potentially toxic metal in biological fluids such as urine and blood. SPE (SPE Pt SilTMSDT Sil TMSDT (Sil-TMSDT Ntrimethoxysilylpropylethylenetriamine N trimethoxysilyl propylethylenetriamine Pt4 media FAAS. . (FAAS) Fouriertransform Fourier transform FTIR (FTIR SEM (SEM energydispersive energy dispersive EDS (EDS process minicolumn mini column 20 SilTMSDT, TMSDT, Sil-TMSDT 0485 0 485 0.48 L1 L 1 L− K2PtCl6 KPtCl K2 PtCl6 K PtCl K2[PtCl6 HNO 05 5 0. 15fold fold 15 99 99% 002 02 0.0 040 40 0.4 0.9981 09981 9981 16fold 16 LOQ (LOQ LOD (LOD 0045 045 0.04 0014 014 0.01 respectively blood (FAAS 2 048 48 K2PtCl K2[PtCl 9 00 04 4 0.998 0998 998 004 001 01 0.99 099 0.9 09

ABSTRACT The estimation of evapotranspiration (ET) and crop water requirements are crucial for the proper management and allocation of water resources in terms of quantity, quality, and timeliness. Therefore, remote sensing estimation of ET using the SEBAL algorithm (Surface Energy Balance Algorithm for Land) can provide spatio-temporal, non-punctual data, unlike traditional calculations relying on the nearest meteorological station. This research analyzed ET using SEBAL, based on ten Landsat 8 satellite images processed with a program developed in the Model Builder of ArcGis® version 10.2. The analysis was conducted during the vegetative period of starchy corn from May to October 2016. Validation of the results happened with a drainage lysimeter installed in a monitoring plot. Additionally, the statistical indices - such as percentage relative error (PRE) (0,09), root mean square error (RMSE) (0,30), R2 (0,92), and Nash-Sutcliffe efficiency (NASH) (0,91) - indicated a good correlation of ET for starchy corn in the central highlands of Peru. The ET identified at ten monitoring points ranged from 1,05 to 7,79 mm d-1. (ET quantity quality timeliness Therefore Surface Land spatiotemporal, spatiotemporal spatio temporal, temporal spatio-temporal nonpunctual non punctual data station ArcGis 102 10 2 10.2 2016 plot Additionally PRE (PRE 0,09, 009 0,09 , 0 09 (0,09) RMSE (RMSE 0,30, 030 0,30 30 (0,30) R 0,92, 092 0,92 92 (0,92) NashSutcliffe Nash Sutcliffe NASH (NASH 0,91 091 91 (0,91 Peru 105 1 05 1,0 779 7 79 7,7 d1. d1 d 1. d-1 10. 201 00 0,0 (0,09 03 0,3 3 (0,30 0,9 9 (0,92 (0,9 1, 77 7, d- 20 0, (0,0 (0,3 (0, (0 (

This study presents a solution to solid waste problems, focusing on spent lithium-ion batteries (LiBs) and iron ore tailings (IOT) from the Mariana environmental accident in Brazil. The approach involves the production CoFe2O4 from LiBs and IOT, which serves as a catalyst for solar photo-Fenton reactions for methylene blue (MB) decolorization and as an electrochemical sensor for ascorbic acid (AA) detection. Chemical analysis showed recycling potential, with 45.22 ± 0.22% m m−1 Co from LiBs and 14.9 ± 1.5% m m−1 Fe from IOT, determined by inductively coupled plasma atomic emission spectroscopy (ICP OES) and flame atomic absorption spectrometry (FAAS). The sol-gel synthesized CoFe2O4 exhibited a crystallite size of 51.9 ± 1.3 nm and agglomerated crystal clusters. Recycled-CoFe2O4 exhibited a 98.1% MB decolorization efficiency in 60 min under solar irradiation and remained above 92.3% in all 7 reuse cycles. The electrochemical sensor exhibited a coefficient of determination of 0.9987, a sensitivity of 3.352 ± 0.0428 μA mol L−1, and a limit of detection of 0.5511 µM in the concentration range of 1.96 to 23.08 mmol L−1 for AA detection. This study demonstrates the potential of recycled-CoFe2O4 in an environmentally friendly dye removal and as an electrochemical sensor, offering sustainable waste management and resource utilization with solar energy. problems lithiumion lithium ion (LiBs IOT (IOT Brazil CoFeO CoFe O CoFe2O photoFenton photo Fenton (MB (AA 4522 45 22 45.2 022 0 0.22 m1 1 m− 149 14 9 14. 15 5 1.5 ICP OES FAAS. FAAS . (FAAS) solgel sol gel 519 51 51. 13 3 1. clusters RecycledCoFe2O4 RecycledCoFeO Recycled Recycled-CoFe2O 981 98 98.1 6 923 92 92.3 cycles 09987 9987 0.9987 3352 352 3.35 00428 0428 0.042 L1 L 05511 5511 0.551 196 96 1.9 2308 23 08 23.0 L− recycledCoFe2O4 recycledCoFeO recycled recycled-CoFe2O energy 452 4 2 45. 02 0.2 (FAAS RecycledCoFe RecycledCoFe2O 98. 92. 0998 998 0.998 335 35 3.3 0042 042 0.04 0551 551 0.55 19 230 23. recycledCoFe recycledCoFe2O 0. 099 99 0.99 33 3. 004 04 0.0 055 55 0.5 09 0.9 00 05

ABSTRACT The mechanized cutting of sugarcane requires improvements, as cutting tools can affect the longevity of sugarcane fields and increase production costs. Furthermore, these tools can increase the energy demand of machines in the field. This study evaluated the sugarcane harvester performance equipped with different basal cutting devices: impact cutting (blades) and continuous cutting (saws) in three commercial sugarcane production areas. The experimental design was completely randomized in a 3 × 2 factorial scheme with six repetitions. Effective fuel consumption and harvesting capacity were evaluated. The saws increased fuel consumption per area by 3.9 and 8.9% per Mg harvested. The crop’s yield characteristics determine harvesting systems’ energy demand. For yields above 90 Mg ha-1, energy demand has stabilized up to 120 Mg ha-1. The fuel demand for harvesting ranged between 1.0 and 1.2 L Mg-1 of harvested material. Regardless of the cutting system, each Mg requires 37.3 kJ of energy to be removed from the field. improvements costs Furthermore field devices blades (blades (saws areas repetitions 39 9 3. 89 8 8.9 crops crop s systems ha1, ha1 ha 1, 1 ha-1 12 ha1. 1. 10 0 Mg1 Mg- material system 373 37 37. 8. ha-

RESUMO O corte mecanizado da cana-de-açúcar necessita de aprimoramentos, visto que as ferramentas de corte podem afetar a longevidade dos canaviais e aumentar os custos de produção. Além disso, essas ferramentas podem aumentar a demanda energética das máquinas no campo. Este estudo avaliou o desempenho de colhedoras de cana-de-açúcar equipadas com distintos mecanismos de corte basal: corte por impacto (lâminas) e corte contínuo (serras) em três áreas comerciais de produção de cana-de-açúcar. O consumo efetivo de combustível e a capacidade efetiva de colheita das máquinas foram avaliados em cada tratamento. O delineamento experimental adotado foi inteiramente casualizado em esquema fatorial 3 × 2 com seis repetições. As serras aumentaram o consumo de combustível por área em 3,9 e 8,9% por Mg colhido. As características produtivas da cultura determinam a demanda energética dos sistemas de colheita. Para produtividades acima de 90 Mg ha-1, a demanda energética estabilizou-se até 120 Mg ha-1. A demanda de combustível para a colheita variou entre 1,0 e 1,2 L Mg-1 de material colhido. Os resultados mostram que independente do sistema de corte, cada Mg de cana colhida necessita em média de 37,3 kJ de energia para ser retirado do campo. canadeaçúcar açúcar aprimoramentos disso campo basal lâminas (lâminas (serras canadeaçúcar. açúcar. tratamento repetições 39 9 3, 89 8 8,9 colhido ha1, ha1 ha 1, 1 ha-1 estabilizouse estabilizou se 12 ha1. 1. 10 0 Mg1 Mg- 373 37 37, 8, ha-

Abstract The influence of occupant behaviour in buildings is widely discussed as one of the causes for the gap between energy use estimated via computer simulation and during building operation. Knowing the main drivers for adjustments in building systems is essential to guide the development of mathematical models for such behaviours. The aim of this study is to evaluate the main motivating agents for adjusting windows, luminaires, and air-conditioning in offices. Two offices were monitored using sensors that collected data from the internal environment and user interaction with such systems. Rainfall and external and internal air temperatures were considered influential for the interaction with window systems. The increase in internal and external temperatures had even more influence on interactions with air-conditioners. The main conclusions were: there is influence of the layout of the offices in the sharing and control of windows and efficiency of passive strategies, such as the use of natural and cross ventilation; and there is an influence of the increase in internal temperature compared to external temperature in the predictability of opening windows and turning air-conditioning devices on. operation behaviours luminaires airconditioning conditioning airconditioners. airconditioners conditioners. conditioners air-conditioners strategies ventilation

Resumo Ainfluência do comportamento dos usuários em edificações é amplamente discutida como uma das causas para discrepâncias entre consumos energéticos esperados, durante a fase de projeto, e consumos durante a operação. Conhecer os principais motivadores para ajustes nos sistemas de edificações é imprescindível para aprimorar a modelagem desses comportamentos. O objetivo deste estudo é avaliar os principais agentes motivadores para o ajuste das janelas, luminárias e aparelhos de ar-condicionado em escritórios. Dois escritórios foram monitorados por meio de sensores que coletaram dados de qualidade do ambiente interno e comportamento de usuário. Foram consideradas influentes para a interação com sistemas de janelas a pluviometria e as temperaturas do ar externo e interno. O aumento das temperaturas interna e externa apresentou ainda mais influência na interaçãocom aparelhos de ar-condicionado. Duas foram as principais conclusões: há influência do layout dos escritórios no compartilhamento e controle das janelas e eficiência de estratégias passivas, como o uso de ventilação natural e cruzada; e há influência do aumento da temperatura interna em comparação à externa na previsibilidade de abertura de janelas e acionamento de aparelhos de ar-condicionado. esperados projeto operação comportamentos arcondicionado condicionado usuário arcondicionado. condicionado. conclusões passivas cruzada

Abstract Sanitary ware waste (RLS) is proposed as an ecologically environmental alternative, replacing fine aggregates and gravel, used in the production of self-compacting concrete (SCC). The environmental efficiency in energy life cycles and carbon dioxide emissions of SCC with different mixtures of RLS, were compared with the self-compacting concrete without RLS (CAA_REF). The Life Cycle Assessment (LCA) showed that the replacement of RLS aggregates in CAA_REF, can generate an absolute reduction of approximately 45.42 MJ/m³ and 2.67 kg of CO2/m³ respectively, which corresponds to reductions of 2.2% and 0.6%. It was also verified that the use of an indicator of eco-efficiency of the environmental behavior in relation to the parameter mechanical resistance to compression, can contribute and be adequate in projects of dosages of SCC. Thus, it was observed that the use of RLS can contribute to environmental sustainability, reducing the inadequate disposal of RLS in the environment and implementing an adequate reuse. (RLS alternative gravel selfcompacting self compacting . (SCC) CAA_REF. CAAREF CAA_REF CAA REF (CAA_REF) LCA (LCA 4542 45 42 45.4 MJm³ MJm MJ m³ m MJ/m 267 2 67 2.6 CO2m³ COm CO2 CO CO2/m respectively 22 2.2 06 0 6 0.6% ecoefficiency eco compression Thus sustainability reuse (SCC (CAA_REF 454 4 45. 26 2. CO2m 0.6 0.

Resumo O resíduo de louça sanitária (RLS) é alvitrado como uma alternativa ecologicamente ambiental, em substituição aos agregados finos e pedriscos, empregados na produção de concretos autoadensáveis (CAA). A eficiência ambiental nos ciclos de vida energético e das emissões de dióxido de carbono de CAA com diferentes misturas de RLS, foram comparadas com o concreto autoadensável sem RLS (CAA_REF). A Análise do Ciclo de Vida (ACV) evidenciou que a substituição de agregados de RLS em CAA_REF, pode gerar uma redução absoluta de aproximadamente 34,70 MJ/m³ e 2,07 kg de CO2/m³, respectivamente, o que corresponde a reduções de 1,5% e 0,5%. Verificou-se ainda que o uso de um indicador de ecoeficiência do comportamento ambiental em relação ao parâmetro resistência mecânica à compressão, pode contribuir e ser adequado em projetos de dosagens de CAA. Assim, observou-se que o uso de RLS, pode colaborar para a sustentabilidade ambiental, reduzindo a disposição inadequada dos RLS no meio ambiente e implementado um reuso adequado. (RLS pedriscos . (CAA) CAA_REF. CAAREF CAA_REF REF (CAA_REF) ACV (ACV 3470 34 70 34,7 MJm³ MJm MJ m³ m MJ/m 207 2 07 2,0 CO2m³ COm CO2 CO CO2/m³ respectivamente 15 1 5 1,5 05 0 0,5% Verificouse Verificou se compressão Assim observouse observou (CAA (CAA_REF 347 3 7 34, 20 2, CO2m CO2/m 1, 0,5 0,

Abstract: The building envelope plays a crucial role in interior thermal comfort and energy efficiency. Hence, the importance of implementing the energy efficiency chapter of the Ecuadorian Construction Standard (NEC-HS-EE). This chapter establishes minimum requirements for thermal transmittance of envelope elements. However, it is unknown whether these values guarantee a satisfactory perception of indoor thermal comfort. This study aims to determine the thermal comfort perception in residential buildings in Loja city, through defining typologies and characterizing their envelope. Typologies are defined using information from the National Building Survey (ENED), while the envelope is characterized by surveying construction professionals in the locality. Finally, a thermal perception survey is conducted on occupants of the defined typologies. The results show that several construction packages comply with the NEC-HS-EE standard (except for the use of 7 cm thick brick wall, which is a common practice) and provide satisfactory comfort perception to occupants during the day, achieving a comfort perception within 80% acceptability. However, this is not maintained during the night.

Resumen: La envolvente desempeña un papel crucial en el confort térmico interior y eficiencia energética de las edificaciones, por ello la importancia de la implementación del capítulo de eficiencia energética de la Norma Ecuatoriana de la Construcción (NEC-HS-EE). Este capítulo establece requisitos mínimos de transmitancia térmica para elementos de la envolvente. Sin embargo, se desconoce si estos valores garantizan una percepción satisfactoria del confort térmico interior. El presente estudio tiene como objetivo determinar la percepción de confort térmico en edificaciones residenciales en la ciudad de Loja, a través de la definición de la tipologías y caracterización de su envolvente. Para la definición de tipologías se considera la información de la Encuesta Nacional de Edificaciones (ENED), mientras que, para la caracterización de la envolvente se encuesta a profesionales de la construcción en la localidad. Finalmente, se aplica una encuesta de percepción térmica a ocupantes de las tipologías definidas. Los resultados muestran que, varios paquetes constructivos cumplen con la NEC-HS-EE (a excepción del uso de pared de ladrillo de 7 cm de espesor, que representa una práctica común) y brindan una percepción satisfactoria de confort a los ocupantes durante el día, alcanzando una percepción de confort dentro del 80% de aceptabilidad, no obstante, esto no se mantiene durante la noche.

Abstract: This study addresses the application of the Cross-Industry Standard Process for Data Mining (CRISP-DM) methodology in the analysis of dissolved gases in oil of power transformers, being this a critical component in electrical systems. The adoption of this six-phase structured method allowed a comprehensive evaluation of the condition of the transformer units of the Ecuadorian electrical system based on the analysis of investment and expansion data of the sector, as well as the study of 1 099 DGA (Dissolved Gas Analysis) profiles obtained from a population of 153 transformers located in the different regions of continental Ecuador. The findings described in this work have the potential to significantly improve investment and maintenance strategies and policies. In addition, the adoption of automation techniques in the DGA classification process is proposed, using supervised learning models to enhance the reliability and efficiency of the public energy service. The results suggest that this approach not only improves the diagnosis within the maintenance activities, but also provides a solid basis to draw a roadmap towards a predictive asset management, resulting in a substantial improvement of the reliability of the national power system.

Resumen: Este estudio aborda la aplicación de la metodología Cross-Industry Standard Process for Data Mining (CRISP-DM) en el análisis de los gases disueltos en aceite de transformadores de potencia, siendo este un componente crítico en los sistemas eléctricos. La adopción de este método estructurado de seis fases permitió evaluar de forma integral la condición de las unidades de transformación del sistema eléctrico ecuatoriano a partir del análisis de datos de inversión y expansión del sector, así como del estudio de 1 099 perfiles DGA (Dissolved Gas Analysis) obtenidos de una población de 153 transformadores ubicados en las distintas regiones de Ecuador continental. Los hallazgos descritos en este trabajo tienen el potencial de mejorar significativamente las estrategias y políticas de inversión y mantenimiento. Además, se propone la adopción de técnicas de automatización en el proceso de clasificación DGA, utilizando modelos de aprendizaje supervisado para potenciar la confiabilidad y eficiencia del servicio público de energía. Los resultados sugieren que este enfoque no solo mejora el diagnóstico dentro de las actividades de mantenimiento, sino que también proporciona una base sólida para trazar una hoja de ruta hacia una gestión predictiva de los activos, lo que se traduce en una mejora sustancial de la confiabilidad del sistema eléctrico nacional.

Abstract: The Galapagos Islands present distinctive challenges in managing their electrical system due to their remote geographical position. Currently, their energy sources are limited to non-renewable energy and partially dependent on renewable energy sources like wind and solar power. The intermittence of these sources poses a threat to the stability and reliability of power systems. The battery energy storage systems (BESS) are a commonly adopted approach for promoting the stability of frequency and voltage in power systems. However, the effectiveness of these systems in accomplishing this objective is contingent on the type of controller and operation used in the storage system. Electrical energy storage systems implement two primary modes of operation; Grid Following and Grid Forming. This paper focuses on the implementation and evaluation in different scenarios of the network-forming mode of operation of the storage system, with the purpose of contributing to the primary frequency regulation in the MRE of the Galapagos Islands. The results obtained demonstrate significant improvements in the stability of the MRE, and greater efficiency in primary frequency regulation.

Resumen: Las Islas Galápagos, debido a su ubicación geográfica aislada, enfrentan desafíos únicos en la gestión de su Microrred eléctrica (MRE), pues actualmente depende de energías no renovables y en una medida considerable de fuentes de energías renovables, como la energía solar y eólica. Estas fuentes de energía intermitentes, afectan la confiabilidad y estabilidad de la MRE. Una solución destacada en la actualidad es la implementación de los sistemas de almacenamiento de energía con baterías, pues estos sistemas aportan a la estabilidad de frecuencia y voltaje, sin embargo, estos aportes a la estabilidad de frecuencia y voltaje de la MRE están en función del tipo de controlador y operación que se emplee al sistema de almacenamiento. Existen dos modos de operación en sistemas almacenamiento de energía eléctrica; seguidor de red y formador de red. Este trabajo se enfoca en la implementación y evaluación en diferentes escenarios, del modo de operación formador de red del sistema de almacenamiento, con el propósito de aportar a la regulación primaria de frecuencia en la MRE de las Islas Galápagos. Los resultados obtenidos demuestran las mejoras significativas en la estabilidad de la MRE, y una mayor eficiencia en la regulación primaria de frecuencia.

Abstract Since 2010, there has been an approximate annual increase of 1% in CO2 emissions due to buildings. The reduction of energy consumption and consequently the mitigation of Greenhouse Gases are global goals due to the global issue of climate change. A key step in achieving these goals is to improve the energy performance of buildings, thereby reducing energy consumption and emissions generated by the built environment. In this regard, the present research focuses on identifying and estimating strategies to reduce energy consumption in buildings known as Community Police Units (UPCs) located in the city of Guayaquil, which corresponds to a very hot and humid climate zone. The study consists of statistical analysis of the historical energy performance of 43 buildings sharing the same architectural design. Additionally, the selection of a representative building was made for energy use monitoring and energy simulation. The results revealed a potential saving of 16 000 kWh per year by reducing the control temperature of the air conditioning system by 1°C and adjusting the on/off schedule. This is equivalent to 1 150 USD and 5 metric tons of CO2 emissions.

Resumen: Desde el 2010 existe un incremento aproximado del 1% anual respecto a las emisiones de CO2 a causa de los edificios. La disminución del consumo energético y consecuentemente la mitigación de los Gases de Efecto Invernadero son metas a nivel mundial debido a la problemática global del cambio climático. Un paso clave para alcanzar estas metas es mejorar el desempeño energético de las edificaciones y de esta manera reducir la energía consumida y las emisiones generadas por el parque edificado. En este sentido, la presente investigación se centra en identificación y estimación de estrategias para reducir el consumo de energía de los edificios llamados Unidades de Policía Comunitaria (UPC) localizadas en la ciudad de Guayaquil, y que corresponde a una zona climática húmeda muy calurosa. El estudio está compuesto por el análisis estadístico del rendimiento energético histórico de 43 edificios, que comparten el mismo diseño arquitectónico. Además, se realizó la selección de un edificio representativo para el monitoreo del uso de energía y simulación energética. Los resultados evidenciaron un potencial de ahorro de 16 000 kWh al año, al disminuir 1°C la temperatura de control del sistema de climatización y modificando el horario de encendido y apagado. Esto es equivalente a 1 150 USD y 5 toneladas equivalentes de CO2.

Abstract: The integration of electric mobility is real nowadays. Government policies increasingly focus on encouraging the use of electric vehicles (EVs); particularly, replacing conventional public mobility with electric buses. An adequate energy management of electric bus systems must optimize resource usage, and extend the lifespan of transport units and charging stations, while providing quality service to users. The performance of the EV transport system depends on various deterministic and stochastic variables that need to be accurately simulated to analyze its behavior as closely as possible to real conditions. In this study, a model for the energy analysis of EVs has been implemented, by using the software SUMO (Simulation of Urban Mobility) and applying it to public transport routes in Quito, Ecuador. Through the executed simulations, energy consumption has been estimated and, a sensitivity analysis of the energy consumption of electric bus units to the variations in relevant parameters in the energy management of public transport systems, has been carried out. The impact of certain parameters on energy consumption has been verified, by indicating a significant decrease in the autonomy of EVs on the simulated route under very similar to reality operating conditions. For study case, autonomy reduction of electric bus is around 27% in comparison with manufacturer's specifications. The analysis of energy performance under various traffic scenarios will allow future optimizations of the electric public transport system operation, since traffic levels, variable traffic flow, and pronounced changes in terrain elevation, are considered.

Resumen: La integración de la movilidad eléctrica es una realidad en el mundo actual, las políticas gubernamentales se enfocan cada vez más en incentivar el uso de vehículos eléctricos (VE) particulares, pero, principalmente en reemplazar la movilidad pública convencional por el uso de buses eléctricos. Una adecuada gestión energética de los sistemas de buses eléctricos debe optimizar el uso de recursos, prolongando la vida útil de las unidades de transporte, estaciones de carga y brindando siempre un servicio de calidad a sus usuarios. El desempeño del sistema de transporte mediante VE depende de diversas variables determinísticas y estocásticas que necesitan ser debidamente simuladas a fin de analizar su comportamiento, lo más cercano a las condiciones reales. En el presente trabajo, mediante la aplicación del software SUMO (Simulation of Urban Mobility), se ha implementado un modelo para el análisis energético de VE y se lo ha aplicado en rutas de transporte público en Quito-Ecuador. A partir de las simulaciones realizadas se ha estimado el consumo energético y se ha efectuado un análisis de sensibilidad del consumo energético de las unidades de buses eléctricos ante variaciones de parámetros relevantes en la gestión energética de sistemas de transporte público. Para el caso de estudio se comprueba la reducción de la autonomía del bus eléctrico en 27% de acuerdo con la información del fabricante. El análisis del desempeño energético realizado bajo diversos escenarios de tráfico permitirá en futuros trabajos optimizar la operación de los sistemas de transporte público eléctrico, considerando niveles de tráfico, flujo vehicular variable y pronunciados desniveles en su relieve.

ABSTRACT Aeration is carried out by blowing external air into the silo, with the aim to keep the temperature in the mass of stored grains at safe levels. In the present study, the energy efficiency of aeration of stored sunflower grains was estimated, and a model was proposed and tested to estimate the energy efficiency of aeration, using different algorithms in supervised and unsupervised machine learning. The objective of the work was to develop a Web application based on data mining and modeling with machine learning. The database was composed of information on the average temperature at the height of the sensors, average temperature of the silo, external ambient temperature, occurrence of aeration, if there was cooling, heating and direct heating during aeration, and the energy efficiency of the aeration process. The model for estimating the energy efficiency of the aeration process proved to be efficient, identifying that the energy efficiency was 97.78% during the aeration of stored sunflower grains. Among the classifier algorithms tested, Support Vector Machine (SVM-Poly) showed the best metrics and indicators, hence being recommended for implementation in system development networks capable of predicting the aeration status of stored grains. silo levels study estimated learning sensors cooling efficient 9778 97 78 97.78 SVMPoly SVM Poly (SVM-Poly indicators 977 9 7 97.7 97.

RESUMO A aeração é realizada por meio da insuflação do ar externo para dentro do silo, tendo como objetivo manter a temperatura da massa de grãos armazenados em níveis seguros. No presente estudo foi estimada a eficiência energética da aeração de grãos de girassol armazenados, assim como proposto e testado um modelo de estimativa da eficiência energética da aeração, utilizando diferentes algoritmos no aprendizado de máquinas supervisionado e não supervisionado. O objetivo no trabalho foi desenvolver uma aplicação Web a partir da mineração e modelagem dos dados com o aprendizado de máquinas. O banco de dados foi composto pelas informações da temperatura média do nível dos sensores, temperatura média do silo, temperatura ambiente externa, ocorrência de aeração, se houve resfriamento, aquecimento e aquecimento direto durante aeração, e a eficiência energética do processo de aeração. O modelo de estimativa da eficiência energética do processo de aeração demonstrou-se eficiente, identificando que durante a aeração de grãos de girassol armazenados a eficiência energética foi de 97,78%. Dentre os algoritmos classificadores testados na Máquina de Vetores de Suporte (SVM-Poly) apresentou as melhores métricas e indicadores, sendo recomendado para implementação em redes de desenvolvimento de sistemas capaz de predizer o status da aeração de grãos armazenados. silo seguros sensores externa resfriamento demonstrouse demonstrou eficiente 9778 97 78 97,78% SVMPoly SVM Poly (SVM-Poly indicadores 977 9 7 97,78 97,7 97,

ABSTRACT. Due to its beneficial biological properties, chitosan extracted from crustacean byproducts emerges as a viable strategy to mitigate the anti-nutritional factors in vegetable-based diets for juvenile white snook (Centropomus viridis). The growth, survival, and nutritional efficiency of juvenile white snook-fed diets containing chitosan were evaluated. Chitosan was extracted chemically and enzymatically from shrimp byproducts (exoskeletons and heads). It was then included in a soybean meal-based diet (48% protein and 19% kJ g-1 gross energy) at 0, 0.5, and 1.0% chitosan levels (D-Control, CHI-0.5%, and CHI-1.0%). Juvenile snook (initial weight: 44.5 ± 4.2 g) were randomly distributed into 300 L tanks and fed the experimental diets three times daily for 45 days. Fish fed the CHI-0.5% and CHI-1.0% diets were significantly (P < 0.05) higher in growth rates than the D-Control diet. No significant differences in survival were observed. The FCR of the CHI-0.5% and CHI-1.0% diets were lower when compared to the D-Control (P < 0.05). The results suggest the utilization of chitosan in diets with high soybean meal content for snook to obtain better growth and survival.

Abstract: Passive Optical Networks (PONs) are essential in optical communications to meet the increasing demand for network capacity and connected users, ensuring reliable and adaptable connections for data transmissions. These networks also simplify infrastructures and efficiently utilize energy by eliminating the need for active devices. In this context, Ultra- Dense Wavelength Division Multiplexing (UDWDM) is one of the most prominent solutions for data transmission. This technology uses the narrow separation between channels from 25GHz and even as small as 6.25GHz to increase the transmission capacity. This document analyzes the performance of UDWDM considering the transmission of three simultaneous channels in a PON network for which three different scenarios have been considered for the analysis with the following parameters: i) transmission speed from 10 Gbps to 17 Gbps, ii) the distance from 10 km to 20 km and iii) the separation between channels of 15GHz, 20GHz, and 25GHz. The performance metrics for the analyzed scenario are the bit error rate and the eye diagram. To ensure the reception of the transmitted channel, an analysis of raised cosine and Gauss filters is also discussed. Including these filters allows for verifying whether their use enhances the performance of the channels compared to transmission without a filter. This is crucial for understanding how filters can optimize the quality and reliability of data transmission in a PON, which is of great importance in environments where high efficiency and connection quality are required.

Resumen: Las redes ópticas pasivas (PON) son esenciales en las comunicaciones ópticas para satisfacer la creciente demanda de capacidad de red y usuarios conectados, garantizando conexiones fiables y adaptables para la transmisión de datos. Estas redes también ofrecen un uso eficiente de la energía y la simplificación de las infraestructuras, eliminando la necesidad de dispositivos activos. En este contexto, la multiplexación por división de longitud de onda ultradensa (UDWDM) es una de las soluciones más destacadas para la transmisión de datos; esta tecnología aprovecha la estrecha separación entre canales a partir de 25GHz e incluso de tan solo 6,25GHz para aumentar la capacidad de transmisión. Este documento analiza el rendimiento de UDWDM considerando la transmisión de tres canales simultáneos en una red PON para la que se han considerado tres escenarios diferentes para el análisis con los siguientes parámetros: i) velocidad de transmisión de 10 Gbps a 17 Gbps; ii) la distancia de 10 km a 20 km; y iii) la separación entre canales de 15GHz, 20GHz, y 25GHz. Las métricas de rendimiento para el escenario analizado son la tasa de errores de bit y el diagrama de ojo. Para garantizar la recepción del canal transmitido, también se analiza la utilización de filtros coseno elevado y Gauss. La inclusión de estos filtros permite comprobar si su uso mejora el rendimiento de los canales en comparación con la transmisión sin filtro. Esto es crucial para entender cómo los filtros pueden optimizar la calidad y fiabilidad de la transmisión de datos en una PON, lo que es de gran importancia en entornos donde se requiere una alta eficiencia y calidad de conexión.

The generally accepted view in rock blasting is that the sources of energy for the fracture and movement of rock reside in the shock wave and gas action resulting from the explosion, and yet the mechanisms by which these sources interact with the rock have remained unclarified. It has also been noted that up to 50% of the work capacity of an explosive released in a blast cannot be accounted for by field measurements of energy partitioning. In this study, we describe a physical model that details the response of rock to both shock wave and gas action. An analytical model based on momentum conservation is derived to describe the dynamics of shock-driven expansion of the blasthole. Radial expansion of the hole is the key parameter that permits the derivation of the following characteristics of rock response to shock loads: hole expansion time; volume of displaced rock; energy consumed per unit volume; expansion energy efficiency; stress wave pulse length; gas pressure in enlarged hole. Soon after the completion of hole expansion, the shock wave degenerates to an elastic stress wave that runs through the burden. Blasthole expansions of between 50% and 300% of diameter are completed in under 1 ms and, depending on rock properties, consume 32% to 42% of the detonation energy or about 55% of the available mechanical (Gurney) energy. Gas pressure in the enlarged holes in five rock types is between 35 MPa and 650 MPa, and drives the mass movement of burden rock.