Abstract (Introduction): The current cultivation of trees is insufficient to cover the national demand for wood, in this way small producers become an alternative solution to this situation, since despite having small areas, in the country there are abundant farms with these conditions; However, the current forest management scheme does not meet adequate standards for the incorporation of these small producers. (Objective): To present an adaptive forest management scheme (AFMS) to the needs of the small farmer, in addition, to demonstrate the institutional availability to change according to expert criteria. (Methodology): 1) the factors that influence the decision to adopt an agricultural or forestry production system were identified; 2) a profile of an ideal productive system that met the interests and preferences of the small producer was made, which was compared with the characteristics of agricultural and forestry production; 3) the proposal of an EMFA adjusted to the preferences and interest of the producer was made, which was also compared with the ideal profile; 4) three proposed change actions were presented to experts, obtaining different degrees of possibility of changes in the EMFA. (Results): The discrepancy of the forest management scheme for the cultivation of trees with the perspective that a small producer has on an ideal production system was evidenced, as well as the substantial improvement that an EMFA would have in the valuation of the small producer and the institutional availability to change the EMFA according to the perspective of the small producers. (Conclusions): The adjustment of the forest management scheme allows a greater adoption of the activity by the small producer, but it was recognized that any proposal that is made would be successful only if forest governance makes it more flexible and allows change.

Resumen (Introducción): El cultivo actual de árboles es insuficiente para cubrir la demanda nacional de madera, de este modo, los pequeños productores se tornan como una alternativa de solución ante esta situación, ya que pese a contar con áreas pequeñas, en el país son abundantes las fincas con estas condiciones; sin embargo, el esquema actual de manejo forestal no cumple con estándares adecuados para la incorporación de estos pequeños productores. (Objetivo): Presentar un esquema de manejo forestal adaptativo (EMFA) a las necesidades del pequeño productor, además de evidenciar la disponibilidad institucional al cambio, según el criterio experto. (Metodología): 1) se identificaron los factores que influyen en la decisión de adopción de un sistema productivo agrícola o forestal; 2) se realizó un perfil de un sistema productivo ideal que cumpliera con los intereses y preferencias del pequeño productor, el cual se confrontó con las características de la producción agrícola y forestal; 3) se efectuó la propuesta de un EMFA ajustado a las preferencias e interés del productor, que fue también confrontada con el perfil ideal; 4) se expusieron tres acciones de cambio propuestas ante expertos, obteniendo diferentes grados de posibilidad de cambios en el EMFA. (Resultados): Se evidenció la discrepancia del esquema de manejo forestal para el cultivo de árboles con la perspectiva que un pequeño productor tiene sobre un sistema de producción ideal, asimismo la mejora sustancial que un EMFA tendría en la valoración del pequeño productor y la disponibilidad institucional al cambio del EMFA, según la perspectiva de los pequeños productores. (Conclusiones): El ajuste del esquema de manejo forestal permite una mayor adopción del cultivo de árboles por parte del pequeño productor, pero se reconoció que cualquier propuesta que se realice lograría ser exitosa si la gobernanza forestal flexibiliza y posibilita el cambio.

Résumé La connaissance de la relation entre les politiques publiques, les partis politiques et le vote présidentiel au Brésil est largement concentrée dans l’analyse des programmes de transfert de revenus, limitant ainsi la compréhension de la manière dont différents aspects de la conception et de la mise en œuvre des politiques sont liés au jeu politique-électoral. Dans cet article, à l’aide de régressions linéaires appliquées à toutes les municipalités brésiliennes, nous analysons la dynamique électorale du programme de logement Minha Casa Minha Vida, de sa création jusqu’aux élections de 2014, avec des résultats détaillés par modalités, phases de mise en œuvre et adhésion au déficit de logement. Les estimations montrent que les villes dirigées par des partis appartenant à la coalition du gouvernement fédéral n’ont pas reçu plus d’unités de logement, à l’exception de la modalité destinée à l’électorat le plus pauvre. De plus, le retour électoral obtenu par le PT était positif lorsque la mise en œuvre du programme était liée au déficit de logement, notamment en 2010. publiques lanalyse l analyse revenus politiqueélectoral. politiqueélectoral politique électoral. politique-électoral article laide aide brésiliennes Vida jusquaux jusqu aux 2014 modalités nont n ont dunités d unités lexception exception lélectorat électorat pauvre 2010 201 20 2

Resumen El conocimiento sobre la relación entre políticas públicas, partidos y elecciones presidenciales en Brasil está fuertemente concentrado en el análisis de programas de transferencia de renta, lo que limita la comprensión sobre cómo diferentes aspectos del diseño e implementación de las políticas se relacionan con el juego partidista electoral. En este artículo, por medio de regresiones lineares aplicadas a todos los municipios brasileros, analizamos la dinámica electoral de la política habitacional “Programa Minha Casa Minha Vida” desde su creación hasta las elecciones de 2014, con resultados detallados por modalidades, fases de implementación y adherencia al déficit de vivienda. Las estimaciones muestran que las ciudades gobernadas por partidos pertenecientes a la coalición del gobierno federal no recibieron más unidades habitacionales, con excepción de la modalidad dirigida al electorado más pobre. Además, el retorno electoral obtenido por el PT fue positivo en los casos en los que la implementación del programa estuvo relacionada con el déficit de vivienda, particularmente en 2010. públicas renta artículo brasileros Programa Vida 2014 modalidades vivienda habitacionales pobre Además 2010 201 20 2

Abstract The literature on the relationship between public policies, political parties, and presidential voting strongly focuses on analyses of income transfer programs, which limits the understanding of how different aspects of policy design and implementation relate to the partisan-electoral game. Through linear regressions applied to all Brazilian municipalities, this article analyzes the electoral dynamics of the Minha Casa Minha Vida (My House My Life) housing policy program. From the program’s inception to the 2014 elections, it details results by policy modalities, implementation phases, and adherence to the housing deficit. The results show that municipalities governed by parties belonging to the federal government’s coalition did not receive more housing units, except for the modality targeted at the poorest electorate. Moreover, the Worker’s Party’s (PT) electoral return was positive where the program’s implementation was related to the housing deficit, particularly in 2010. policies programs partisanelectoral partisan game Life program s 201 elections modalities phases deficit governments government units electorate Moreover Workers Worker Partys Party PT (PT 2010 20 2

Resumo O conhecimento sobre a relação entre políticas públicas, partidos e voto para presidente no Brasil está fortemente concentrado em análises de programas de transferência de renda, o que limita a compreensão sobre como diferentes aspectos do desenho e implementação das políticas se relacionam com o jogo partidário-eleitoral. Neste artigo, por meio de regressões lineares aplicadas a todos os municípios brasileiros, analisamos a dinâmica eleitoral da política habitacional Programa Minha Casa Minha Vida, considerando desde sua criação até as eleições de 2014, com resultados detalhados por modalidades, fases de implementação e aderência ao deficit habitacional. As estimativas mostram que cidades governadas por partidos pertencentes à coalizão do governo federal não receberam mais unidades habitacionais, à exceção da modalidade direcionada para o eleitorado mais pobre. Além disso, o retorno eleitoral obtido pelo PT foi positivo quando a implementação do programa esteve relacionada com o deficit habitacional, particularmente em 2010. públicas renda partidárioeleitoral. partidárioeleitoral partidário eleitoral. partidário-eleitoral artigo brasileiros Vida 2014 modalidades habitacionais pobre disso 2010 201 20 2

Résumé Cet article explore la grammaire institutionnelle de la protection des données et de la vie privée au Brésil. En adoptant la perspective analytique de l’Institutional Grammar Tool (IGT), nous déconstruisons les énoncés institutionnels des décrets réglementaires de la Loi Générale sur la Protection des Données des états brésiliens, afin de classifier les différents éléments grammaticaux informant les stratégies étatiques de protection et de gouvernance des données. Nous examinons dans cet article la construction des concepts de protection des données, de gouvernance des données et de vie privée, ainsi que la construction institutionnelle de la protection des données au Brésil. L’étude a une orientation empirique afin de répondre aux questions suivantes: quel est le dessin institutionnel des stratégies adoptées par les états, dans le contexte de la fédération, pour la protection des données personnelles et de la vie privée des citoyens? Quelles sont les implications de ce dessin pour l’efficacité de la protection des données au Brésil? L’article conclut que les stratégies de protection des données formulées au niveau des états sont davantage orientées vers le contrôle bureaucratique du traitement des données que vers la réalisation effective des droits émergents de la citoyenneté. Brésil lInstitutional l Institutional IGT, IGT , (IGT) brésiliens Létude L étude suivantes fédération citoyens lefficacité efficacité Larticle citoyenneté (IGT

Resumen Este artículo investiga la gramática institucional de la protección de datos y de la privacidad en Brasil. Adoptando la perspectiva analítica del Intitutional Grammar Tool (IGT), deconstruimos los enunciados institucionales de los decretos reglamentarios de la Ley General de Protección de Datos de los estados brasileros, con el fin de clasificar los diferentes elementos gramaticales que informaron las estrategias estaduales de protección y gobernanza de datos. Examinamos la construcción de los conceptos de protección de datos, gobernanza de datos y privacidad, así como la construcción institucional de la protección de datos en Brasil. El estudio tiene un abordaje empírico, con el fin de responder a las siguientes cuestiones: ¿cuál es el diseño institucional de las estrategias adoptadas por los estados, en el contexto de la federación, para la protección de datos personales y de la privacidad de los ciudadanos? ¿cuáles son las implicaciones de ese diseño para la efectividad de la protección de datos en Brasil? El artículo concluye que las estrategias de protección de datos formuladas en los estados tienen más un enfoque de control burocrático de tratamiento de datos que propiamente la implementación de derechos emergentes de ciudadanía. Brasil IGT, IGT , (IGT) brasileros empírico cuestiones cuál federación ciudadanos cuáles ciudadanía (IGT

Abstract This article investigates the institutional grammar of data protection and privacy in Brazil. By adopting the analytical lens of the Institutional Grammar Tool (IGT), it deconstructs the institutional statements within the regulatory decrees of the General Data Protection Law (LGPD) in Brazilian states, classifying the different grammatical elements that inform state-level strategies for data protection and governance. It examines how the concepts of data protection, data governance, and privacy are formulated, as well as the institutional construction of data protection in Brazil. By taking an empirical approach, it aims to address the following questions: What is the institutional design of the strategies adopted by Brazilian states, within the federation, to protect personal data and citizens’ privacy? What are the implications of this design on how effective data protection is in Brazil? The article concludes that the data protection strategies formulated by the states lean more toward bureaucratic control of data processing than the actual realization of emerging citizenship rights. Brazil IGT, IGT , (IGT) LGPD (LGPD statelevel state level governance approach questions federation citizens rights (IGT

Resumo Este artigo investiga a gramática institucional da proteção de dados e da privacidade no Brasil. Adotando a lente analítica do Intitutional Grammar Tool (IGT), desconstruímos os enunciados institucionais dos decretos regulamentadores da Lei Geral de Proteção de Dados dos estados brasileiros, de forma a classificar os diferentes elementos gramaticais que informam as estratégias estaduais de proteção e governança de dados. Examinamos nesse artigo a construção dos conceitos de proteção de dados, governança de dados e privacidade, assim como a construção institucional da proteção de dados no Brasil. O estudo tem um viés empírico, de maneira a responder às seguintes questões: qual o desenho institucional das estratégias adotadas pelos estados, no contexto da federação, para a proteção de dados pessoais e da privacidade dos cidadãos? Quais as implicações desse desenho para a efetividade da proteção de dados no Brasil? O artigo conclui que as estratégias de proteção de dados formuladas nos estados têm mais o viés de controle burocrático do tratamento de dados do que propriamente a efetivação de direitos emergentes de cidadania. Brasil IGT, IGT , (IGT) brasileiros empírico questões federação cidadãos cidadania (IGT

EFFECT OF LIQUID SWINE WASTEWATER DOSES ON PHYSICAL, CHEMICAL AND ELECTROCHEMICAL ATTRIBUTES IN A CERRADO OXISOL. The addition of organic residues enhances soil and plant organic matter and nutrient content. To gauge the impact of varying liquid swine waste (LSW) levels on soil, we studied changes in a clayey Oxisol’s physical, chemical, and electrochemical traits from the Cerrado. LSW doses (0, 50, 150, 450, 600 m3 ha−1) were applied to the 0-0.20 m layer in a randomized design with three replicates. Post a 30-day incubation at 60% field capacity, the soil underwent mineralogical, physical (clay dispersed in water - CDW), chemical (sodium adsorption ratio - SAR, cation exchange capacity - CEC, base saturation - V%), and electrochemical (pH in H2O and KCl, ApH, point of zero charge - PZC, point of zero salt effect - PZSE, surface electric potential - iµo, and electrical conductivity - EC) analyses. The levels of exchangeable Ca, K, Mg, Na, and available P increased with increasing LSW doses. Increasing LSW doses in the soil led to an increase in EC, but soil salinization was not observed at the highest dose. With the application of LSW doses, there was a decrease in pH, ApH, PZSE, and an increase in CEC, PZC and ψo. Despite the increase in ψo, low clay dispersibility was observed. PHYSICAL OXISOL content (LSW Oxisols Oxisol s Cerrado 0, 0 (0 50 150 450 60 ha−1 ha1 ha 1 00.20 0020 0.20 20 0-0.2 replicates 30day day 30 mineralogical CDW, CDW , CDW) sodium SAR CEC V%, V V% V%) pH HO H O KCl ApH PZSE iµo EC analyses Ca K Mg Na dose ψo ( 5 15 45 6 ha− 00 00.2 002 020 0.2 2 0-0. 3 4 00. 02 0. 0-0 0-

This study aims to propose a new method for derivatizing fatty acids (FAs) from human milk (HM), eliminating the lipid extraction step, and simplifying the preparation for gas chromatography with a flame ionization detection (GC-FID) analysis to quantify the FAs. The Design Expert software optimized the reaction times, concentrations, and sample amount. The proposed method (PM) was validated for lyophilized HM and results for the figures of merit for precision in relative standard deviation (RSD) (RSDintra-day 1.34-4.03% and RSDinter day 2.08 5.16%), accuracy (99.87-102.16%), and robustness are within a linear range of 3 to 38% lipids in HM samples. The atmospheric solids analysis probe tandem mass spectrometry (ASAP-MS/MS) technique confirmed the efficiency of PM by expressing the molecular composition of triacylglycerol formed by FAs from the GC-FID technique. The PM requires a small sample size and conducts derivatization directly in the sample matrix, minimizing extraction errors. (FAs HM, , (HM) step GCFID GC FID (GC-FID times concentrations amount (PM RSD (RSD RSDintraday RSDintra 1.344.03% 134403 1.34 4.03% 1 34 4 03 1.34-4.03 208 2 08 2.0 5.16%, 516 5.16% 5 16 5.16%) 99.87102.16%, 998710216 99.87 102.16% 99 87 102 (99.87-102.16%) 38 samples ASAPMS/MS ASAPMSMS ASAP MS/MS MS (ASAP-MS/MS matrix errors (HM 344 1.344.03 13440 134 1.3 403 4.03 0 1.34-4.0 20 2. 51 5.16 87102 99.87102.16% 99871021 9987 99.8 10216 102.16 9 8 10 (99.87-102.16% ASAPMS MSMS 1.344.0 1344 13 1. 40 4.0 1.34-4. 5.1 8710 99.87102.16 9987102 998 99. 1021 102.1 (99.87-102.16 1.344. 4. 1.34-4 5. 871 99.87102.1 998710 102. (99.87-102.1 1.344 1.34- 99.87102. 99871 (99.87-102. 99.87102 (99.87-102 99.8710 (99.87-10 99.871 (99.87-1 (99.87- (99.87 (99.8 (99. (99 (9 (

The selective separation of precious metals from complex aqueous solutions is important in protecting the environment, aquatic ecosystems, water resources and recycling resources. In this study, cysteine-containing polymeric nanoparticles were synthesized using the molecular imprinting (MIP) technique with the mini-emulsion polymerization method. The basis of the polymer design is inspired by affinity of silver to cysteine in biological systems. The synthesized silver ion imprinted (Ag+-IIP) poly(hydroxyethylmethacrylate-N -methacryloyl-L-cysteine) poly(HEMA-MAC) nanoparticles were characterized by elemental analysis, zeta sizer, Fourier transform infrared (FTIR) spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM). The effects of pH, ionic strength and interaction time on adsorption of Ag+ ions were investigated. In experimental studies, the highest adsorption amount (196.9 mg g1 nanoparticle) was reached in a short period of 40 min at pH 5.0 and 150 mg L-1 concentration. Selectivity studies of synthesized Ag+-IIP nanoparticles against silver (Ag+) ions were carried out in the presence of lithium (Li+), barium (Ba2+), mercury (Hg2+) and cadmium (Cd2+) ions. Experimental results indicate that nanoparticles adsorb Ag+ ions with high selectivity. Ag+-IIP nanoparticles have 3.7, 3.1, 2.4, and 2.6 times more selective or higher affinity for Ag+ ions compared to Li+, Ba2+, Hg2+ and Cd2+ ions, respectively, compared to Ag+-non-imprinted (NIP) nanoparticles. environment ecosystems study cysteinecontaining containing MIP (MIP miniemulsion mini emulsion method systems Ag+IIP AgIIP IIP Ag (Ag+-IIP polyhydroxyethylmethacrylateN poly hydroxyethylmethacrylate N methacryloylLcysteine methacryloyl L -methacryloyl-L-cysteine polyHEMAMAC HEMA MAC poly(HEMA-MAC analysis sizer FTIR (FTIR spectroscopy AFM, AFM , (AFM) SEM. SEM . (SEM) investigated 196.9 1969 196 9 (196. g nanoparticle 4 50 5 0 5. 15 L1 1 L- concentration (Ag+ Li Li+ (Li+) Ba2 Ba Ba2+ (Ba2+) Hg2 Hg (Hg2+ Cd2 Cd (Cd2+ selectivity 37 3 7 3.7 31 3.1 24 2 2.4 26 6 2. respectively Ag+nonimprinted Agnonimprinted non NIP (NIP (AFM (SEM 196. 19 (196 (Ag (Li+ (Ba2+ (Hg2 (Cd2 3. nonimprinted (19 (Li (Ba2 (Hg (Cd (1 (Ba (

Analysis of variance (ANOVA)-simultaneous component analysis (ASCA) is a method of choice for factorial design studies of environmental impacts on plant metabolomes and can be used to quantitatively carry out this comparative analysis. The impacts of seven mixture design extractor systems made up of ethanol, dichloromethane, and hexane and their 1:1 binary and 1:1:1 ternary solvents for several replicate experiments (n = 3, 4, 5) were assessed using ASCA models determined from Fourier-transform infrared (FTIR), near-infrared (NIR), and UV-Vis spectroscopic measurements on yerba mate leaf extracts. This analysis considered two-factor effects: secondary sexual dimorphism (male and female plants) and cultivation systems (monoculture and agroforestry), as well as their interaction effect. The three binary solvents were found to be more efficient extractor systems for all four detectors as they found 83 main and interaction effects significant at or above the 95% confidence level compared with only 47 for the pure solvent extracts. Binary solvent extracts resulted in averages between 44.04 and 86.61% for the ASCA total effect variances compared with 40.62 to 71.07% for pure extractors. Of the 60 significant effects found for experiments with 5 repetitions 53 or 88% were obtained with only triplicate determinations. The choice of spectroscopic technique and solvent system have large impacts on metabolomic analysis results. ANOVAsimultaneous ANOVA simultaneous (ASCA ethanol dichloromethane 11 1 1: 111 1:1: n 3 4 Fouriertransform Fourier transform FTIR, FTIR , (FTIR) nearinfrared near NIR, NIR (NIR) UVVis UV Vis twofactor two factor male plants monoculture agroforestry, agroforestry agroforestry) 8 95 4404 44 04 44.0 8661 86 61 86.61 4062 40 62 40.6 7107 71 07 71.07 extractors 6 88 determinations results (FTIR (NIR 9 440 0 44. 866 86.6 406 40. 710 7 71.0 86. 71.

Food contamination is a public health problem, and the search for natural additives to increase food stability and safety is challenging. This research aimed to study nanoemulsions produced with coriander essential oil and kefiran, an exopolysaccharide extracted from kefir grains. The composition of coriander essential oil was evaluated, revealing linalool as the main component. An experimental design consisting of six trials was conducted. The NE2 formulation (0.5% kefiran and 1.5% coriander essential oil) exhibited smaller particle size, monodispersity, a lower centrifugal stability coefficient, and higher absolute zeta potential values (> 30 mV), indicating high electrical stability. Morphology, thermal stability, and toxicity tests were performed. The minimum bactericidal concentration was determined and applied to commercial cheese. Thermal stability tests demonstrated an increase in the stability of NE2 compared to its individual components, and it was also proven to be non-toxic. The concentration of 25% m v-1 was identified as the minimum bactericidal concentration and was applied to commercial cheese. problem challenging grains evaluated component conducted NE 0.5% 05 0 5 (0.5 15 1 1.5 size monodispersity coefficient > ( 3 mV, mV , mV) Morphology performed cheese components nontoxic. nontoxic non toxic. toxic non-toxic 25 v1 v v- 0.5 (0. 1. 2 0. (0

ABSTRACT There is great interest in varieties with greater competitive ability against weeds. This can be facilitated by path analysis, which involves the statistical evaluation and interpretation of the relationship between yield and its components. In this analysis, the occurrence of multicollinearity results in inconsistent estimates of the coefficients, and overestimates of the direct effects of the explanatory variables on the response variable. The aim of this study was to identify the characteristics with the greatest direct effect on pod yield and green and dry bean yields in traditional cowpea varieties, evaluated in competition with weeds in two experiments. In addition, the presence of multicollinearity was investigated in the analyses. In Experiment-1, twelve varieties with the highest bean yields in a preliminary evaluation were assessed in a randomized block design with five replications. In Experiment-2, six varieties, selected in the preliminary evaluation, were assessed using two methods of weed management: three of the most productive and three of the least productive. Randomized blocks and split plots were used, with five replications. Multicollinearity, indicated by the number of conditions and the variance inflation values, was greater in Experiment-2. In the six cases under study (three yields x two experiments), the number of pods per plant had the greatest direct effect on yield. analysis components coefficients variable experiments addition analyses Experiment1, Experiment1 Experiment 1, 1 Experiment-1 replications Experiment2, Experiment2 2, 2 Experiment-2 management used Multicollinearity values Experiment2. 2. experiments, , experiments) Experiment-

ABSTRACT Chia (Salvia hispanica L.) seeds have attracted great economic interest for their high levels of linoleic and α-linolenic acids. In Brazil, there is a lack of studies on the agronomic characteristics and physiological quality of chia, necessitating research on germination processes and strategies to enhance yield under field conditions. There are no studies assessing the development of seeds with different coat colors in the presence of fungicides. This study aimed to assess the physiological quality of chia seeds as a function of coat color and fungicide treatment. The experiment followed a completely randomized design with a 2 × 2 factorial arrangement and six replications. For this, seeds were divided into two groups according to coat color (black and white) and subjected or not to treatment with carboxin + thiram. Germination speed index, germination rate, and shoot length were evaluated in plants sown at 0, 90, and 180 days after seed treatment. Germination rate and speed index differed significantly between coat colors, with white seeds having higher vigor than black seeds. Shoot length, however, differed only for seeds sown on the day of treatment, indicating that treated seeds were more vigorous. Salvia L. L αlinolenic α linolenic acids Brazil conditions fungicides replications this thiram 0 90 18 however vigorous 9 1

ABSTRACT The aim of this study was to verify the response of the melon accessions MR1 and C14 to gamma radiation in terms of germination and morphology.The melon accessions came from the germplasm collection of the Federal Rural University of the Semi-arid Region, and were submitted to five doses of gamma radiation (0, 100, 200, 300, 400 Gy) in four replications, each comprising 25 seeds, at the Center for Nuclear Energy in Agriculture of the University of São Paulo. The seeds were grown in a greenhouse at UFERSA employing a completely randomised design. The germination potential, rate and index were evaluated during the first stage of the trial. During the second stage, the germinated plants were transplanted into eight-litre buckets containing substrate and sand, in four replications of 15 plants each. The inflorescence, leaf blade and fruit were evaluated. The IMAGE J image analysis software was used to obtain the leaf and fruit data. The germination potential varied for the gamma-ray doses being tested, while the germination rate and index were not affected; phenotypic variations were seen in the leaves. The gamma-ray doses had no effect on the germination process. MR C C1 morphologyThe morphology Semiarid Semi arid Region 0, 0 (0 100 200 300 40 Gy 2 Paulo design trial eightlitre eight litre sand 1 inflorescence data gammaray ray tested affected leaves process ( 10 20 30 4 3

ABSTRACT Given the large differences in the results of inoculation and co-inoculation in the bean crop, an experiment in cultivating winter beans was carried out in 2019 under greenhouse conditions with the aim of evaluating the performance of the beans and a possible increase in plant growth and grain production, using seeds inoculated or co-inoculated with Rhizobium tropici and Azospirillum brasilense, with and without fungicide and/or insecticide, in sandy and clayey soils. A total of 112 pots were used, and 14 treatments were applied in a completely randomised experimental design, with four replications. The Scott-Knott test was used to analyse the results, and showed that whether using untreated seeds or carrying out complete chemical treatment with fungicide and insecticide plus co-inoculation with R. tropici and A. brasilense, winter bean production was reduced in clayey soil, while the joint use of fungicide and insecticide, fungicide and R. tropici, or fungicide, insecticide and R. tropici, favoured shoot development. Inoculating with A. brasilense, without R. tropici and with insecticide, or insecticide and fungicide, favoured greater root growth in clayey soil. In sandy soil, grain production was higher using seeds treated solely with insecticide, solely with R. tropici, or with a combination of both. Production was lower in the joint treatment with fungicide, insecticide and the co-inoculation of bacteria, or when using insecticide together with A. brasilense. coinoculation co crop 201 coinoculated brasilense andor soils 11 1 design replications ScottKnott Scott Knott R soil development both bacteria 20 2

This study expands and shows the versatility of applications in hydrophilic interaction chromatography coupled with triple quadrupole mass spectrometry (HILIC-MS/MS) using a FRULIC-N column to determine 31 phenolic compounds in beverage industry residues (coffee, apple juice, beer, and wine). Optimization, via Doehlert design, determined the acetonitrile proportion (50-90%) and pH (3.0-7.0) in the mobile phase (MP). A 22 factorial design assessed the concentration of ammonium acetate (10-110 mmol L-1) in the MP and column temperature (20-60 °C). Injection volume (5-45 µL) was univariately optimized. Separations at 60 °C reduced chromatographic run time to less than 11 min. Gradient elution (500 µL min-1) employed an MP comprising acetonitrile and ammonium acetate (110 mmol L-1, pH 7). Validation demonstrated average coefficient of determination (R2) 0.9707, limit of detection 0.001-0.503 mg L-1 and quantification 0.004-1.524 mg L-1, precision < 12.2%, recovery 92.4-110.8%. The method was applied to five residues, indicating its viability for determining phenolics in beverage production residues. HILICMS/MS HILICMSMS HILIC MS/MS MS (HILIC-MS/MS FRULICN FRULIC N 3 coffee, coffee (coffee juice beer wine. wine . wine) Optimization 5090% 5090 50 90% 90 (50-90% 3.07.0 3070 3.0 7.0 0 7 (3.0-7.0 MP. (MP) 2 10110 10 110 (10-11 L1 L 1 2060 20 (20-6 °C. C °C) 545 5 45 (5-4 optimized 6 min 500 (50 min1 min-1 (11 L1, 1, 7. 7) R2 R (R2 09707 9707 0.9707 0.0010.503 00010503 0.001 0.503 001 503 0.001-0.50 L- 0.0041.524 00041524 0.004 1.524 004 524 0.004-1.52 122 12 12.2% 92.4110.8%. 9241108 92.4 110.8%. 92 4 8 92.4-110.8% HILICMS MSMS 509 9 (50-90 07 3.07. 307 30 3. 70 (3.0-7. (MP 1011 (10-1 206 (20- 54 (5- (5 min- (1 (R 0970 970 0.970 0010 0.0010.50 0001050 0001 0.00 0503 0.50 00 0.001-0.5 0041 0.0041.52 0004152 0004 1524 1.52 52 0.004-1.5 12.2 4110 92.4110.8% 924110 924 92. 1108 110.8% 92.4-110.8 (50-9 3.07 (3.0-7 101 (10- (20 ( 097 97 0.97 0.0010.5 000105 000 0.0 050 0.5 0.001-0. 0.0041.5 000415 152 1.5 0.004-1. 12. 411 92.4110.8 92411 110.8 92.4-110. (50- (3.0- (10 (2 09 0.9 0.0010. 00010 0. 05 0.001-0 0.0041. 00041 15 1. 0.004-1 41 92.4110. 9241 110. 92.4-110 (3.0 0.0010 0.001- 0.0041 0.004- 92.4110 92.4-11 (3. 92.411 92.4-1 (3 92.41 92.4-

RESUMO O pimentão, cultura de importância nutricional, destaca-se por seu valor de vitamina C. Diante da necessidade de práticas agrícolas sustentáveis, o estudo explorou o uso de biocarvões derivados de resíduos regionais como alternativa na cultura de pimentão. Nesse contexto, objetivou-se avaliar o efeito de biocarvões provenientes de cama de frango, fibra de coco e palha de arroz, nas características biométricas e físico-químicas de frutos de pimentão verde, na produção de frutos por planta e na produtividade. A pesquisa foi conduzida em campo no delineamento em blocos casualizados, em esquema fatorial 5 × 3 + 1, referentes a cinco doses de biocarvão (0, 3, 6, 9 e 12 t ha-1) e três tipos de biocarvão (fibra de coco, cama de aviário e palha de arroz) com quatro repetições, mais um tratamento adicional (adubação mineral). Foram avaliadas variáveis biométricas (comprimento e diâmetro dos frutos, espessura da casca, número de frutos, massa do fruto) e físico-químicas dos frutos (sólidos solúveis, acidez titulável, pH, vitamina C e teor de cinzas), produção e produtividade dos frutos. A produção de frutos de pimentão verde não foi influenciada pelos biocarvões, porém as doses de biocarvões influenciaram todas as variáveis analisadas com exceção da espessura da casca. Os teores de vitamina C e de sólidos solúveis foram maiores nos tratamentos com biocarvões e menores com adubação mineral. A maior influência na acidificação dos frutos foi com o biocarvão produzido com palha de arroz. nutricional destacase destaca se sustentáveis contexto objetivouse objetivou frango arroz físicoquímicas físico químicas casualizados 1 0, 0 (0 6 ha1 ha ha-1 repetições mineral . mineral) comprimento casca fruto titulável pH cinzas, cinzas , cinzas) ( ha-

ABSTRACT Bell pepper, a crop of nutritional importance, stands out for its vitamin C content. Given the need for sustainable agricultural practices, the present study explored the use of biochars derived from regional waste as an alternative in bell pepper cultivation. In this context, the present study aimed to evaluate the effect of biochars from poultry litter, coconut fiber, and rice straw on the biometric and physicochemical characteristics of bell pepper fruits, on fruit production per plant and on fruit yield. The experiment was performed in the field in a randomized block design, in a 5 × 3 + 1 factorial scheme, referring to five doses of biochar (0, 3, 6, 9, and 12 t ha-1) and three types of biochar (coconut fiber, poultry litter, and rice straw) with four repetitions, plus an additional treatment (mineral fertilization). Biometric variables (fruit length and diameter, skin thickness, number of fruits, fruit mass) and physicochemical variables of the fruits (soluble solids, titratable acidity, pH, vitamin C, and ash content), production and yield of the fruits were evaluated. The production of bell pepper fruits was not influenced by biochars, but the doses of biochars influenced all variables analyzed with the exception of skin thickness. Vitamin C and soluble solids contents were higher in treatments with biochar and lower with mineral fertilizer. Biochar produced from rice straw had the greatest influence on fruit acidification. importance content practices cultivation context litter fiber design scheme 0, 0 (0 6 9 ha1 ha ha-1 repetitions fertilization. fertilization . fertilization) diameter thickness mass acidity pH content, , content) evaluated fertilizer acidification ( ha-

The history of the discovery, use, and development of dyes is closely linked to the history of humanity itself. Among the first records of human civilization are cave paintings made from, e.g., fruits, plants, minerals, and insects. Over the centuries, using different techniques, colors have been given to all types of materials and products, from clothing to food. The chemicals responsible for colors are dyes - a vast collection of molecules of the most varied compositions, but which have in common the absorption of light within the visible window of the electromagnetic spectrum. This article aims not only to review the properties of some classes of natural dyes, their origins, and their applications but also to describe the various computational chemistry methods involved in designing new bio-inspired molecules. discovery use itself eg e g e.g. fruits plants minerals insects centuries techniques products food compositions spectrum origins bioinspired bio inspired e.g