In recent years, the field of coordination chemistry has experienced a surge in interest regarding the synthesis and characterization of coordination complexes for diverse applications. This study is dedicated to investigating coordination compounds resulting from the interaction of nonsteroidal anti-inflammatory drugs (NSAIDs) with metal ions. The study research places significant emphasis on understanding the stability and thermal behavior of these coordination compounds. The utilization of thermoanalytical techniques is crucial in achieving this goal. Thermal analysis and thermokinetics provide valuable insights into the underlying mechanisms, kinetics, and energetics of these reactions, thereby facilitating the optimization of synthesis procedures. The research employs concurrent techniques, namely thermogravimetric analysis (TG) and differential scanning calorimetry (DSC), to explore the thermal stability and decomposition pathways of these coordination compounds. Thermokinetic models and optimization methodologies are subsequently applied to identify key reaction parameters. The primary aim of this research is to unveil the thermal behavior, stability, and reaction kinetics of aceclofenac coordination compounds, thus contributing significantly to the understanding of thermokinetics and thermal analysis in the domain of coordination chemistry. Specifically, this study is focused on aceclofenac coordination complexes involving lanthanum and gadolinium, with the ultimate goal of advancing the field of coordination chemistry. years applications antiinflammatory anti inflammatory NSAIDs (NSAIDs ions mechanisms reactions procedures TG (TG DSC, DSC , (DSC) parameters Specifically gadolinium (DSC

The species Oryza sativa (rice) and Musa cavendishii (banana) are sources of cellulose-rich waste biomass in the Amazon region, Tocantins State. This research investigates the nanoscale production of cellulose through the interactions between three choline amino acid ionic liquids Ch[AA]IL and the respective fibers by pretreatment. To this end, the synthesis of three ILs was carried out: choline arginate Ch[Arg], choline glycinate Ch[Gly] and choline lysinate Ch[Lys], characterized by Fourier transform infrared spectroscopy (FTIR). The samples resulting from the pretreatment were analyzed by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). It was possible to infer from the SEM micrographs that Ch[Arg] caused greater fiber breakage than the other ILs. The TEM analyses identified fibers up to 16 nm in diameter. Positive effects were observed in the diffractograms, although no crystallinity was obtained in the pretreated samples. Thermogravimetry curves showed that the fibers treated with Ch[Arg] showed higher thermal stability. rice (rice banana (banana celluloserich rich region State ChAAIL Ch AA IL end out ChArg, ChArg Arg , ChGly Gly Ch[Gly ChLys, ChLys Lys Ch[Lys] FTIR. FTIR . (FTIR) SEM, (SEM) TEM, (TEM) Xray X ray XRD (XRD TGA. TGA (TGA) Ch[Arg 1 diameter diffractograms stability Ch[Lys (FTIR (SEM (TEM (TGA

Gold and platinum bimetallic nanoparticles, Au@PtNPs, have gained attention due to their plasmonic properties. The controlled synthesis of Au@PtNPs involves complex parameters, and the resulting synergy between Au and Pt introduces possibilities for tailoring their properties. This study explores the effects of key-parameters of synthesis (gold core diameters, reaction time, and Pt concentration) on the final properties of Au@PtNPs. Gold nanoparticles of varying diameters were synthesized and used as cores for the reduction of hexachloroplatinic acid, forming a surrounding shell of Pt nanoparticles. The parameters were systematically tuned to understand their impact on morphology, dimension, stability, and plasmonic properties of Au@PtNPs. Increasing Pt precursor concentration resulted in thicker and denser Pt shells, broadening the localized surface plasmon resonance (LSPR) band and improving Au@PtNPs stability. These properties are essential for applications such as photothermal treatment. The synthesis achieved satisfactory products within just 1 h of Pt4+ reduction at mild temperature without using surfactants. Only limited changes in plasmonic properties were observed after 4 h of synthesis, suggesting an optimal reaction period. Manipulating Au core diameter provided LSPR band control, with smaller cores exhibiting greater broadening towards the infrared region. This systematic exploration provided valuable insights for understanding key-parameters governing the synthesis and properties of Au@PtNPs. AuPtNPs PtNPs keyparameters key gold time acid morphology dimension stability shells (LSPR treatment Pt4 surfactants period control region

Food contamination is a public health problem, and the search for natural additives to increase food stability and safety is challenging. This research aimed to study nanoemulsions produced with coriander essential oil and kefiran, an exopolysaccharide extracted from kefir grains. The composition of coriander essential oil was evaluated, revealing linalool as the main component. An experimental design consisting of six trials was conducted. The NE2 formulation (0.5% kefiran and 1.5% coriander essential oil) exhibited smaller particle size, monodispersity, a lower centrifugal stability coefficient, and higher absolute zeta potential values (> 30 mV), indicating high electrical stability. Morphology, thermal stability, and toxicity tests were performed. The minimum bactericidal concentration was determined and applied to commercial cheese. Thermal stability tests demonstrated an increase in the stability of NE2 compared to its individual components, and it was also proven to be non-toxic. The concentration of 25% m v-1 was identified as the minimum bactericidal concentration and was applied to commercial cheese. problem challenging grains evaluated component conducted NE 0.5% 05 0 5 (0.5 15 1 1.5 size monodispersity coefficient > ( 3 mV, mV , mV) Morphology performed cheese components nontoxic. nontoxic non toxic. toxic non-toxic 25 v1 v v- 0.5 (0. 1. 2 0. (0

We created a fast and effective thin-layer chromatography method to detect homoisoflavones in Polygonatum odoratum (Mill.) Druce (POD), demonstrating high sensitivity, specificity, and stability. Utilizing this method, we assessed the quality of 20 commercial batches of POD. Our results indicated that homoisoflavones (III, IV, and V) were present in 8 samples, absent in 7, and detected in 5. This method facilitates the effective evaluation of POD germplasm resources, laying a strong foundation for enhancing quality standards. This advancement aids in the standardization and quality control of POD, ensuring the consistency of its active ingredients and thereby supporting its therapeutic applications. thinlayer thin layer Mill. Mill (Mill. , (POD) sensitivity specificity stability 2 III, III (III IV V samples 7 5 resources standards applications (Mill (POD

Acetic acid bacteria (AAB) are versatile organisms that catalyze the conversion of a wide range of carbon sources into biomolecules of great industrial interest. In this study, we exploited the ability of Gluconobacter spp. to synthesize levans. Among the isolated strains, Gluconobacter cerinus UELBM11 produced approximately 14.0 g L−1 of levan under non-optimized conditions. Gas chromatography-mass spectrometry (GC-MS), Fourier transform infrared spectroscopy (FTIR), and nuclear magnetic resonance (NMR) analyses confirmed that levan obtained from G. cerinus UELBM11 consisted of a β-(2→6)-D-fructose backbone with some β-(2→1) ramifications. The average molecular weight (Mw) of the purified levan was 8.78 × 105 Da. Thermogravimetric/differential thermogravimetric (TGA/DTG) analysis indicated high thermal stability, with the maximum decomposition rate observed at 227.44 °C. Scanning electron microscopy (SEM) revealed a microporous morphology, and the antioxidant activity assays demonstrated that levan had a high scavenging capacity of 2,2’-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and hydroxyl radicals. Therefore, it has been demonstrated the levan produced by G. cerinus UELBM11 is a promising natural antioxidant and, owing to its microporosity and excellent thermal properties and stability, is a potential candidate as an additive in cosmetics, pharmaceuticals, and food products. AAB (AAB interest study spp levans strains UELBM UELBM1 140 14 0 14. L1 L 1 L− nonoptimized non optimized conditions chromatographymass chromatography mass GCMS, GCMS GC MS , (GC-MS) FTIR, FTIR (FTIR) NMR (NMR G β2→6Dfructose β26Dfructose βDfructose β 2→6 D fructose 2 6 β2→1 β21 2→1 β-(2→1 ramifications Mw (Mw 878 8 78 8.7 10 Da Thermogravimetricdifferential Thermogravimetric differential TGA/DTG TGADTG TGA DTG (TGA/DTG stability 22744 227 44 227.4 C °C SEM (SEM morphology 2,2azinobis 22azinobis azinobis 2,2 azino bis 3ethylbenzothiazoline6sulfonic ethylbenzothiazolinesulfonic 3 ethylbenzothiazoline sulfonic ABTS (ABTS radicals Therefore cosmetics pharmaceuticals products (GC-MS (FTIR β2 6Dfructose Dfructose 26 2→ β2→ 21 β-(2→ 87 7 8. 2274 22 4 227. 2azinobis 2, β-(2 β-( β-

The composites of poly (butylene adipate co-terephthalate) / poly (lactic acid) (PBAT/PLA) blend and montmorillonites functionalized using imidazole-derived ionic liquids with different carbon chain sizes (butyl, octyl, and dodecyl) proved to be a promising alternative for improving the thermal and mechanical properties of the polymer blend. Functionalization of montmorillonites by ionic liquids was confirmed by increasing the basal spacing, and spectroscopical and thermal analysis evidence. The composite synthesis was carried out by casting technique generating homogeneous polymeric films. X-ray diffraction analyses suggested that montmorillonite functionalization with the ionic liquid of the butyl carbon chain fostered exfoliation and incorporation of the clay into the polymer. Furthermore, an increase in the thermal stability and mechanical properties of the material was observed. The other composites formed between the PBAT/PLA blend and the montmorillonite functionalized by ionic liquids of higher carbonic chain showed micro composites formation. Thus, their thermal and mechanical properties had no significant improvements. butylene coterephthalate co terephthalate co-terephthalate lactic acid PBATPLA PBAT PLA (PBAT/PLA imidazolederived imidazole derived butyl, (butyl octyl dodecyl spacing evidence films Xray X ray Furthermore observed formation Thus improvements

Computational predictive approaches present themselves as an attractive alternative in the search for new compounds that may present toxic or growth regulatory activity in Aedes aegypti. Aspergillus species is a producer of secondary metabolites with diverse biological activities. In this study, it was possible to evaluate the pharmacokinetic and toxicological properties in silico, as well as the prediction of the insecticidal biological activities of the juvenile hormone of natural substances produced by the genus Aspergillus. Initially, 187 molecules were cataloged from various species of Aspergillus spp., and only seven molecules of indole alkaloids were found to exhibit a toxic dose 50% (TD50) after conducting toxicity predictions. The molecular dynamic simulation trajectories were utilized to study parameters such as root mean square deviation, root mean square fluctuation, radius of gyration and intermolecular hydrogen bond to understand the behavior and stability of proposed compounds in the binding pocket of the target protein. The N-β-acetyltryptamine molecule showed a binding affinity value of –8.100 ± 0.200 kcal mol-1, which classifies the compound as a potential insecticidal agent against the Aedes aegypti vector. silico Initially 18 spp spp. 50 TD50 TD (TD50 predictions deviation fluctuation protein Nβacetyltryptamine N β acetyltryptamine 8100 8 100 –8.10 0200 0 200 0.20 mol1, mol1 mol 1, 1 mol-1 vector 5 TD5 (TD5 810 10 –8.1 020 20 0.2 mol- (TD 81 –8. 02 2 0. –8 –

RESUMO: Em geral, alelopatia pode ser definido como o processo biológico no qual um organismo produz metabolitos que alteram a germinação, o crescimento, a sobrevivência e a reprodução de outros organismos, influenciando a estabilidade de agroecossistemas. O colesterol, o mais abundante esterol isolado da alga vermelha marinha Plocamium brasiliense, foi estudado quanto ao seu potencial efeito inibitório na germinação de sementes, alongamento das radículas e desenvolvimento do hipocótilo das ervas daninhas Mimosa pudica (malicia) e Senna obtusifolia (mata-pasto). Colesterol foi isolado do extrato em Hexano por métodos cromatográficos. Durante 15 dias, os bioensaios de germinação foram realizados a 25 ºC e fotoperíodo de 12 horas, enquanto os bioensaio de alongamento da radícula e do hipocótilo foram realizados a 25 ºC e fotoperíodo de 24 horas. Posteriormente, placas de Petri de 9,0 cm de diâmetro foram revestidas de papelfiltro, e 25 sementes foram mantidas em câmaras de germinação, enquanto seis sementes pré-germinadas foram postas em placas de Petri por 2-3 dias. Após dez dias, a extensão da radícula e do hipocótilo foi medida. O potencial inibitório do colesterol foi avaliado a 5, 10, 15 e 20 ppm. Em ambas as ervas M. pudica e S. obtusifolia, foram afetadas significativamente pela ação do cholesterol alcançando maiores percentuais de inibição na germinação das sementes (50% e 33%, respectivamente), alongamento da radícula (68% e 60%, respectivamente) e desenvolvimento do hipocótilo (66% e 55%, respectivamente). Os efeitos inibitórios foram dose-dependentes em todos os experimentos, tendo efeitos alelopaticos mais acentuados a 20 ppm. RESUMO geral crescimento organismos agroecossistemas brasiliense malicia (malicia matapasto. matapasto mata pasto . (mata-pasto) cromatográficos 1 dias 2 horas Posteriormente 90 9 0 9, papelfiltro prégerminadas pré germinadas 23 3 2- medida 5 10 ppm M S 50% 50 (50 33 33% respectivamente, respectivamente , 68% 68 (68 60 60% 66% 66 (66 55 55% respectivamente. dosedependentes dose dependentes experimentos (mata-pasto (5 6 (6 (

ABSTRACT: In general, allelopathy can be defined as a biological process by which an organism produces one or more metabolites that can change the germination, growth, survival, and reproduction of other organisms, and thus influencing the stability of agroecosystems. Cholesterol is a very abundant sterol isolated from the marine red alga Plocamium brasiliense that has been studied regarding its potential inhibitory effects on seed germination, radicle elongation, and hypocotyl development of the weeds Mimosa pudica (malicia) and Senna obtusifolia (mata-pasto). Cholesterol was isolated from a hexane extract by chromatographic methods. Over a 15-day period, germination bioassays were performed at 25 ºC with a 12-h photoperiod. Radicle elongation and hypocotyl development were assayed at 25 ºC with a 24-h photoperiod. Later, Petri dishes 9.0 cm in diameter were coated with filter paper, and 25 seeds were placed in a germination chamber. Six pre-germinated seeds were placed in the Petri dish for 2-3 days. After 10 days, radicle and hypocotyl extensions were measured, and the inhibitory potential of cholesterol was assessed at 5, 10, 15, and 20 ppm. In both herbs, M. pudica and S. obtusifolia, they were significantly affected by the action of cholesterol, achieving higher percentages of inhibition in seed germination (50% and 33%, respectively), radical germination (68% and 60%, respectively), and hypocotyl development (66% and 55%, respectively). The inhibition effects were dose-dependent in all experiments, having more pronounced allelopathic effects at 20ppm. ABSTRACT general growth survival organisms agroecosystems malicia (malicia matapasto. matapasto mata pasto . (mata-pasto) methods 15day day 15 period 2 12h h 12 photoperiod 24h 24 Later 90 9 0 9. paper chamber pregerminated pre germinated 23 3 2- days 1 measured 5 ppm herbs M S 50% 50 (50 33 33% respectively, respectively , respectively) 68% 68 (68 60 60% 66% 66 (66 55 55% respectively. dosedependent dose dependent experiments 20ppm (mata-pasto (5 6 (6 (

The present work aims to extract and test cashew nut peel oil as a natural antioxidant in the oxidative stabilization of biodiesel. Therefore, determinations of the ideal time of Soxhlet and thermal extractions, Fourier transform infrared spectroscopy (FTIR) analyses, and evaluation of the oxidative stability by Rancimat method were carried out. FTIR analyses revealed that the 3rd cycle of extraction was sufficient to extract all the oil, with an average yield of 30.0%. For the thermal extraction of the laboratory technical cashew nut peel oil, the best extraction, based on statistical analysis, was 60 min, yielding 20.0%. The FTIR analysis of the extracted cashew nut peel oil showed characteristic peaks of phenolic groups and organic acids, showing differences in the intensities of the absorption bands. The oxidative stability showed induction period of 8 h 40 min for the hydraulic press extraction, 10 h 35 min for the Soxhlet extraction, and 10 h 65 min for the industrial technical extraction of the cashew nut peel oil. All values were below the 12-h limit established by the National Agency for Petroleum, Natural Gas and Biofuels (ANP). The technical cashew nut peel oil extracted in the laboratory presented an induction period of 11 h 12 min, close to that recommended by ANP, proving to be a promising natural antioxidant. Cardanol presented satisfactory results with 25 h 22 min, double that suggested by ANP. Thus, cashew nut peel oil showed important and promising results as a natural antioxidant for biodiesel. biodiesel Therefore extractions (FTIR out rd 300 30 0 30.0% 6 200 20 20.0% acids bands 4 1 3 12h Petroleum ANP . (ANP) 2 Thus 30.0 20.0 (ANP 30. 20.

This study highlights the synthesis of innovative polyurethane materials derived from Moringa oleifera oils extracted from two distinct sources. The oils were converted into their respective polyols through the in situ generated performic acid method. Diverse material characteristics were observed due to different agroclimatic and cultivation conditions for the sources. Extraction yields were 45.21% (source 1) and 40.32% (source 2), with acid values of 28.70 and 26.00 mg KOH per g of oil, respectively. Oleic acid constituted 79.87 and 67.11% of the oils composition, respectively. Nuclear magnetic resonance and Fourier transform infrared spectroscopy (FTIR) confirmed the hydroxylation of the oils. FTIR also identified the isocyanate structures in the synthesized polyurethane materials. Gel permeation chromatography analysis revealed a higher oligomer content in the polyol synthesized from the oil extracted from source 2. Thermogravimetric analysis demonstrated enhanced thermal stability post-oil conversion, highlighting decomposition stages for rigid and flexible segments. Differential scanning calorimetry indicated higher unsaturation in the oil extracted from source 1, resulting in an elevated crystallization temperature. Tensile testing showed increased elasticity as the [NCO]/[OH] ratio decreased in the material, emphasizing the influence of polyol and crosslinking agent concentrations on mechanical resistance of polyurethane materials. sources method 4521 45 21 45.21 1 4032 40 32 40.32 2, 2 , 2) 2870 28 70 28.7 2600 26 00 26.0 respectively 7987 79 87 79.8 6711 67 11 67.11 composition (FTIR postoil post conversion segments temperature NCO/OH NCOOH NCO / OH [NCO]/[OH 452 4 45.2 403 3 40.3 287 7 28. 260 0 26. 798 8 79. 671 6 67.1 45. 40. 67.

ABSTRACT The cowpea is a legume that is widely grown in the north-east of Brazil, and which has been gaining ground in other regions of the country. The main producer is the state of Ceará, with a large planted-area, albeit low productivity due to a lack of producer technology and adapted cultivars. The aim of this study was to identify and recommend superior genotypes in terms of adaptability and stability under rainfed and irrigated conditions, in addition to genotypes with reduced grain darkening. To this end, six experiments were conducted in different districts of Ceará (Crato, Pentecoste, Crateús, Madalena, Bela Cruz and Limoeiro do Norte) and one laboratory experiment, to evaluate grain darkening. The experimental design of the field trials was of randomised blocks, with 14 genotypes and 4 replications. The analysis of variance showed a significant effect from the genotypes and environments and their interaction, so GGE Biplot analysis was carried out to evaluate adaptability and stability. To evaluate grain darkening, a completely randomised design was used in a simple factorial scheme with six previously selected genotypes and five different storage times (0, 2, 4, 6 and 8 months). There was a significant effect from the genotypes and storage time. Genotype 1 showed the least darkening, and can be recommended for environments to which it is best adapted (Crato and Crateús). Genotype 9 was considered the most stable for grain yield, and can be more broadly recommended for the semi-arid region of the state of Ceará. northeast north east Brazil country plantedarea, plantedarea planted area, area planted-area cultivars conditions darkening end Crato, Crato Pentecoste Crateús Madalena Norte experiment blocks replications interaction 0, 0 (0 2 months. months . months) time Crateús. Crateús) yield semiarid semi arid (

ABSTRACT: The study of adaptability, stability, and productivity is essential for selecting and recommending superior genotypes. This fact is particularly the case for the introduction of common bean cultivars in Rio de Janeiro, Brazil, whose production is negligible and does not meet the internal demand. Thus, this study estimated genetic parameters and selection gains and undertake a simultaneous selection for adaptability, stability, and productivity in black bean genotypes via mixed models. The investigation was carried out in three municipalities in the state of Rio de Janeiro during three crop years. The trials were set up in a randomized block design with 11 genotypes and three replications. High mean heritability (81%) and selection accuracy (90%), as well as good selection prospects, were observed. Gains between 1.03 and 9.49% were achieved for grain yield. Simultaneous selection was efficient, indicating two black bean lines (CNFP 15290 and CNFP 15361) as the most productive, adaptable, and stable. As such, these lines have the potential to be released as new black bean cultivars for the state of Rio de Janeiro. ABSTRACT adaptability stability Brazil demand Thus models years 1 replications 81% 81 (81% 90%, 90 90% , (90%) prospects observed 103 03 1.0 949 9 49 9.49 yield efficient 1529 15361 productive adaptable stable such 8 (81 (90% 10 0 1. 94 4 9.4 152 1536 (8 (90 9. 15 153 ( (9

RESUMO: O estudo de adaptabilidade, estabilidade e produtividade é importante para selecionar e recomendar genótipos superiores. Esse fato é particularmente válido para a introdução de cultivares de feijão comum no Rio de Janeiro, Brasil, cuja produção é ínfima e não atende a demanda interna. Assim, este trabalho teve como objetivo estimar parâmetros genéticos e ganhos de seleção e realizar uma seleção simultânea para adaptabilidade, estabilidade e produtividade de genótipos de feijão preto através de modelos mistos. O estudo foi realizado em três municípios do estado do Rio de Janeiro e em três anos agrícolas. Os ensaios foram instalados em delineamento de blocos casualizados com 11 genótipos e três repetições. Observou-se alta herdabilidade média (81%), acurácia seletiva (90%) e boas perspectivas de seleção. Também foram observados ganhos satisfatórios para a característica entre 1,03 e 9,49%. A seleção simultânea foi eficiente e permitiu selecionar duas linhagens de feijão preto CNFP (15290 e 15361) como sendo as mais produtivas, adaptáveis e estáveis e, portanto, têm potencial para serem lançadas como novas cultivares de feijão preto para o estado do Rio de Janeiro. RESUMO adaptabilidade superiores Brasil interna Assim mistos agrícolas 1 repetições Observouse Observou se 81%, 81 81% , (81%) 90% 90 (90% 103 03 1,0 949 9 49 9,49% 15290 (1529 15361 produtivas portanto 8 (81% (90 10 0 1, 94 4 9,49 1529 (152 1536 (81 (9 9,4 152 (15 153 (8 ( 9, 15 (1

Abstract There are several characteristics that influence fire resistance of load-bearing masonries, wherein stand out the bricks compressive strength. Verification of wall systems fire behavior was conducted as prescribed by NBR 5628. This research aims to comparatively analyze fire resistance in real scale load-bearing walls, considering thermal insulation, structural stability, and airtightness. The thickness of the coating and laying mortar were standardized for all specimens just varying brick geometry and septs design in blocks of EST 60, 100, and 140 class. The obtained results show that the compressive strength of the bricks can induce both the structural stability of the constructive systems and its thermal insulation, being a typically critical characteristic for clay brick walls in a building fire. The sample with the highest compressive strength obtained the shortest local displacement, contributing to mitigate the generation of fissures in the system, enhancing the thermal insulation of the clay brick wall, and, thereby, its fire resistance. loadbearing load bearing masonries 5628 airtightness 60 100 14 class displacement system thereby 562 6 10 1 56 5

Resumo Diversas características influenciam a resistência ao fogo de sistema de parede em alvenaria estrutural, dentre as quais pode se incluir sua resistência à compressão. O comportamento desse sistema é validado experimentalmente conforme a norma NBR 5628. Esse estudo tem como objetivo analisar comparativamente a resistência ao fogo obtida através de ensaios em escala real em alvenaria estrutural, envolvendo as características de isolamento térmico, estanqueidade a passagem de gases e fumaça e estabilidade estrutural. Foram avaliados componentes com a mesma configuração em termos de revestimento e assentamento, assumindo como variável a resistência a compressão dos blocos, tendo sido considerados neste estudo blocos de classe EST 60, 100 e 140. Os resultados obtidos apontam que a resistência à compressão da alvenaria pode influenciar, além da estabilidade estrutural do sistema, também seu isolamento térmico, critério tipicamente crítico para alvenarias de blocos cerâmicos em situação de incêndio. A amostra de maior resistência à compressão apresentou menor deslocamento horizontal, contribuindo para mitigar a geração de fissuras, aumentando a oposição da alvenaria à passagem da temperatura ao longo de sua seção transversal e assim aumentar sua resistência ao fogo. 5628 térmico assentamento 60 10 140 influenciar incêndio horizontal fissuras 562 6 1 14 56 5

Resumen La investigación tuvo como objetivo comprender las experiencias alrededor de la sexualidad desde la teoría de los holones en un grupo de mujeres diagnosticadas con cáncer ginecológico en la ciudad de Pereira, Colombia. Se implementó un diseño cualitativo y fenomenológico, con la participación de seis mujeres entre 30 y 60 años, a quienes se aplicaron entrevistas semiestructuradas explorando los holones de reproductividad, género, erotismo y vinculación afectiva interpersonal. Las entrevistas fueron transcritas y analizadas de forma manual, mediante codificación abierta y axial para identificar categorías emergentes. En los discursos de las mujeres se evidenciaron elementos relacionados a los holones de la sexualidad. En el holón de reproductividad, se encontró una resignificación del rol reproductivo como madres; en el holón de género, se presentaron actitudes positivas hacia el cuerpo y amenazas a la identidad de género por causa de los cambios provocados por la enfermedad; en el holón de erotismo, las mujeres relataron experiencias sexuales marcadas por el dolor y el apoyo erótico de la pareja; y en el holón de vinculación afectiva interpersonal, se evidenciaron situaciones de estabilidad conyugal, separación temporal con la pareja y sostenimiento de vínculos abusivos durante el proceso de tratamiento oncológico. Estos hallazgos muestran una amplia reconfiguración integral de la sexualidad femenina en cada uno de los holones y realizan un aporte significativo a la comprensión de las subjetividades de las mujeres en el proceso de afrontar el cáncer ginecológico. Se recomienda realizar nuevas investigaciones con mayor cantidad de participantes y en otras regiones de Colombia.

Abstract The research aimed to understand the experiences around sexuality, from the holon theory, in a group of women diagnosed with gynecological cancer from Pereira, Colombia. A qualitative and phenomenological design was carried out, with the participation of six women between 30 and 60 years of age, to whom semi-structured interviews were applied, exploring the holons of reproductivity, gender, eroticism and interpersonal affective bonding. The interviews were transcribed and analyzed manually, using open and axial coding to identify emerging categories. In the women's discourses, elements related to the holons of sexuality were evident. In the holon of reproductivity, a resignification of the reproductive role as mothers was found; in the holon of gender, positive attitudes towards their bodies and threats to gender identity due to the changes caused by the disease were presented; in the holon of eroticism, women reported sexual experiences characterized by pain and erotic support from their partners; and in the holon of affective interpersonal bonding, they reported situations of marital stability, temporary separation from their partners and abusive ties during the process of cancer treatment. These findings show a comprehensive reconfiguration of female sexuality in each of the holons and make a significant contribution to the understanding of women's subjectivities in the process of coping with gynecological cancer. Further research with a larger number of participants and in other regions of Colombia is recommended.