Serial numbers are marks present on several day-to-day objects, created by manufacturers for purposes such as quality control, product tracking and to prevent counterfeiting. In the case of firearms, these characters can be obliterated or damaged by natural processes or intentionally by criminals to prevent positive identification of stolen property. One non-destructive method employed by crime laboratories for the restoration of obliterated characters is the magnetic particle method. The present work aims to study the synthesis and application of waste-made magnetic nanoparticles in the recovery of adulterated markings. A set of analytical-grade materials and metallic waste magnetic nanoparticles were synthesized for comparison purposes. Chemical characterization tests by X-ray fluorescence, morphological tests by scanning electron microscopy (SEM), and magnetization tests by vibrating sample magnetometer (VSM) were performed. The efficacy of the synthesized nanoparticles was tested on 1020 steel plates previously engraved and adulterated by sanding. Both homemade magnetic nanoparticles demonstrated superior performance compared to commercial magnetic particles. The application of homemade magnetic particles, especially using waste as the source of production, decreases the cost of the material and is environmentally friendly. The development of this material makes magnetic serial number restoration a better option for widespread use in forensic procedures. daytoday day objects control counterfeiting firearms property nondestructive non destructive wastemade made markings analyticalgrade analytical grade Xray X ray fluorescence SEM, SEM , (SEM) VSM (VSM performed 102 sanding particles production friendly procedures (SEM 10 1

Asphaltenes are complex molecules with a tendency to aggregate. This property can be an issue for the oil industry due to CO2 reinjection into reservoirs to mitigate these gas emissions. The present theoretical study aimed to study the CO2 interaction with no-substitute and substituted coronene as an asphaltene model compound at CAM-B3LYP-D3/6-311G(d,p) level. The electronic properties were evaluated using harmonic oscillator model of aromaticity (HOMA), quantum theory of atoms in molecules (QTAIM), and reduced density gradient (RDG) methods. The results showed that the coronene’s functionalization by a sulfur atom changes the coronene’s electronic structure. However, functionalization does not change the type of interactions between the monomers, as they remain predominantly van der Waals interactions. CO2 interaction with substituted coronene barely changed due to the presence of sulfur atoms. However, in dimers, the position of the heteroatom directly influences the interaction with CO2, although it is insufficient to change the interaction’s magnitude. For this reason, our results indicate that the sulfur heteroatom in asphaltenes should be addressed. However, new studies must be conducted by increasing the number of substituents, CO2 numbers, and the model size. aggregate CO emissions nosubstitute no substitute CAMB3LYPD3/6311Gd,p CAMB3LYPD36311Gdp CAMBLYPDGdp CAM B3LYP D3/6 311G d,p D3 6 d p B LYP D G CAM-B3LYP-D3/6-311G(d,p level HOMA, HOMA , (HOMA) QTAIM, QTAIM (QTAIM) RDG (RDG methods coronenes s structure However monomers dimers magnitude reason addressed substituents numbers size CAMB3LYPD3 6311Gd CAMB LYPD Gd Gdp BLYP D36 D3/ dp (HOMA (QTAIM CAMBLYPD CAMB3LYPD

RESUMO: O estudo foi realizado em um ovino, fêmea, de três anos de idade, da raça santa inês, procedente de uma propriedade localizada do município de Santo Antônio de Tauá, oeste do Pará. O animal acometido tinha histórico de exoftalmia no olho esquerdo, secreção nasal e dificuldade respiratória há mais de três meses. Ao exame físico o animal apresentava baixo escore corporal, apatia, assimetria facial unilateral, moderada exoftalmia unilateral esquerda, dispneia mista e exsudação nasal serossanguinolenta profusa unilateral. À necropsia, foi observada grande massa nasal, predominantemente branco-amarelada com áreas vermelho enegrecidas, de superfície irregular, finamente granular, úmida e friável. A massa invadia desde a junção mucocutânea do nariz esquerdo até as coanas, se infiltrava pelos seios nasais frontais, placa cribiforme e alcançava as meninges e a porção frontal do cérebro. À microscopia da superfície do epitélio nasal notou-se severa destruição dos cornetos e dos epitélios, evidenciada por extensas áreas de necrose com muitos debris celulares, ulceração e infecção bacteriana secundária. No sistema nervoso central (SNC) havia meningite piogranulomatosa com acentuada congestão de vasos, focos de necrose e inflamação granulomatosa. O diagnóstico de rinite granulomatosa de origem micótica associada ao fungo Conidiobolus lamprauges foi baseado nos achados da imuno-histoquímica. RESUMO ovino fêmea idade inês Tauá Pará meses corporal apatia esquerda necropsia brancoamarelada branco amarelada enegrecidas irregular granular friável coanas frontais cérebro notouse notou epitélios celulares secundária SNC (SNC vasos imunohistoquímica. imunohistoquímica imuno histoquímica. histoquímica imuno-histoquímica

ABSTRACT: The study was conducted on a 3-year-old female Santa Inês sheep from a property located in the municipality of Santo Antônio de Tauá, west of Pará. The affected animal had a history of exophthalmos in the left eye, nasal discharge, and breathing difficulty for more than three months. On physical examination, the animal had a low body score, apathy, unilateral facial asymmetry, moderate unilateral left exophthalmos, mixed dyspnea and unilateral profuse serosanguinous nasal discharge. At necropsy, a large nasal mass was observed, predominantly yellowish-white with blackish-red areas, with an irregular, finely granular, moist, and friable surface. The mass invaded from the mucocutaneous junction of the left nostril to the choanae, infiltrated the frontal sinuses, the cribiform plate, and reached the meninges and the frontal portion of the brain. Microscopy of the surface of the nasal epithelium showed severe destruction of the turbinates and epithelia, evidenced by extensive areas of necrosis with a large amount of cellular debris, ulceration, and secondary bacterial infection. In the central nervous system there was pyogranulomatous meningitis with marked vessel congestion, as well as foci of necrosis and granulomatous inflammation. Immunohistochemistry showed intense staining of numerous intralesional hyphae for antibodies against Conidiobolus lamprauges. The diagnosis of granulomatous rhinitis of mycotic origin associated with the Conidiobolus lamprauges was based on epidemiological, clinical-pathological, and immunohistochemical data. ABSTRACT 3yearold yearold 3 year old Tauá Pará eye discharge months examination score apathy asymmetry necropsy observed yellowishwhite yellowish white blackishred blackish red irregular granular moist choanae sinuses plate brain epithelia debris ulceration infection congestion inflammation epidemiological clinicalpathological, clinicalpathological clinical pathological, pathological clinical-pathological data

RESUMO As atividades de recuperação insustentáveis (URAs) têm sido cada vez mais realizadas para responder à crescente procura global de alimentos, levando a graves repercussões nos ambientes terrestres. Um total de 120 amostras de solo representando 12 locais foram selecionadas aleatoriamente nos três tipos distintos de terra (PMFs, PALs e BHLs) a uma profundidade de 60 cm para avaliar os impactos das URAs na província de Nghe An Mountain, no Vietnã. A análise estatística dos parâmetros do solo foi realizada no software SPSS (versão 26.0) por meio de análise de variância unidirecional (ANOVA). As descobertas indicam diferenças distintas no tamanho das partículas do solo (SPS) entre os diferentes tipos de terreno (DLTs). Florestas virgens e mistas (PMFs) exibiram as menores proporções de areia, variando de 31,4 a 35,2%, enquanto colinas e terras nuas (BHLs) registraram as maiores proporções de areia, variando de 49,7 a 55,1%. Elevado densidade global (BD) foi observado em BHLs (1,36 ± 0,07 kg dm-3) e PMFs (0,89 ± 0,02 a 1,13 ± 0,03 kg dm-3) enquanto terras perenes e anuais (PALs) variaram de 1,17 ± 0,04 a 1,25 ± 0,08 kg dm-3. Os PMFs apresentaram baixos valores de porosidade total do solo (TSP) e teor de água do solo (SWC) com respectivas faixas de 32,97-36,18% e 4,72-6,15% enquanto PALs e BHLs exibiram valores elevados para TSP (39,25-43,19%; 43,97-49,62%). e SWC (7,39-10,07%; 9,98-12,74%). A capacidade de troca catiônica (CEC), Ca2+, K+ e Mg2+ registrou altos valores nos PALs em comparação aos PMFs e PALs, enquanto o conteúdo orgânico total (TOCs) detectou pouca variação entre os DLTs. No geral, as URAs aumentaram os efeitos adversos nas propriedades e funções do solo (SPFs) em toda a área de estudo. (URAs alimentos terrestres 1 PMFs, (PMFs 6 Mountain Vietnã versão 26.0 260 26 0 ANOVA. ANOVA . (ANOVA) SPS (SPS DLTs (DLTs) areia 314 31 4 31, 352 35 2 35,2% (BHLs 497 49 7 49, 551 55 55,1% BD (BD 1,36 136 36 (1,3 007 07 0,0 dm3 dm 3 dm-3 0,89 089 89 (0,8 002 02 113 13 1,1 003 03 (PALs 117 17 004 04 125 25 1,2 008 08 dm3. 3. (TSP (SWC 32,9736,18% 32973618 32,97 36,18% 32 97 18 32,97-36,18 4,726,15% 472615 4,72 6,15% 72 15 4,72-6,15 39,2543,19% 39254319 39,25 43,19% 39 43 19 (39,25-43,19% 43,9749,62%. 43974962 43,97 49,62% 62 43,97-49,62%) 7,3910,07% 7391007 7,39 10,07% 10 (7,39-10,07% 9,9812,74%. 9981274 9,98 12,74% 9 98 74 9,98-12,74%) CEC, CEC , (CEC) Ca2 Ca Ca2+ K Mg2 Mg TOCs (TOCs geral SPFs (SPFs estudo 26. (ANOVA (DLTs 35,2 5 55,1 1,3 (1, 00 0, dm- 0,8 8 (0, 11 1, 9736 32,9736,18 3297361 3297 32,9 3618 36,18 32,97-36,1 726 4,726,15 47261 472 4,7 615 6,15 4,72-6,1 2543 39,2543,19 3925431 3925 39,2 4319 43,19 (39,25-43,19 9749 43,9749,62% 4397496 4397 43,9 4962 49,62 43,97-49,62% 3910 7,3910,07 739100 739 7,3 1007 10,07 (7,39-10,07 9812 9,9812,74% 998127 998 9,9 1274 12,74 9,98-12,74% (CEC 35, 55, (1 (0 973 32,9736,1 329736 329 32, 361 36,1 32,97-36, 4,726,1 4726 47 4, 61 6,1 4,72-6, 254 39,2543,1 392543 392 39, 431 43,1 (39,25-43,1 974 43,9749,62 439749 439 43, 496 49,6 43,97-49,62 391 7,3910,0 73910 73 7, 100 10,0 (7,39-10,0 981 9,9812,74 99812 99 9, 127 12,7 9,98-12,74 ( 32,9736, 32973 36, 32,97-36 4,726, 6, 4,72-6 39,2543, 39254 (39,25-43, 43,9749,6 43974 43,97-49,6 7,3910, 7391 10, (7,39-10, 9,9812,7 9981 12, 9,98-12,7 32,9736 32,97-3 4,726 4,72- 39,2543 (39,25-43 43,9749, 43,97-49, 7,3910 (7,39-10 9,9812, 9,98-12, 32,973 32,97- 39,254 (39,25-4 43,9749 43,97-49 7,391 (7,39-1 9,9812 9,98-12 (39,25- 43,974 43,97-4 (7,39- 9,981 9,98-1 (39,25 43,97- (7,39 9,98- (39,2 (7,3 (39, (7, (39 (7 (3

ABSTRACT Unsustainable reclamation activities (URAs) have been increasingly conducted to respond to the rising global food demand, leading to severe repercussions on land environments. A total of 120 soil samples representing 12 sites were randomly selected in the three distinct land types (PMFs, PALs, and BHLs) to a depth of 60 cm. The impacts of URAs on soil properties and functions (SPFs) across the Nghe An mountainous province, Vietnam were assessed using the SPSS software (version 26.0) through a one-way analysis of variance (ANOVA). The findings indicated the distinct differences in soil particle size (SPS) among different land types (DLTs). Pristine and mixed forests (PMFs) exhibited the lowest sand ratios, ranging from 31.4 to 35.2%, while bare hills and lands (BHLs) recorded the highest sand ratios, ranging from 49.7 to 55.1%. High bulk density (BD) was observed in BHLs (1.36 ± 0.07 kg dm-3) and PMFs (0.89 ± 0.02 to 1.13 ± 0.03 kg dm-3) while perennial and annual lands (PALs) varied from 1.17 ± 0.04 to 1.25 ± 0.08 kg dm-3. PMFs showed low values for total soil porosity (TSP), and soil water content (SWC) with respective ranges of 32.97-36.18% and 4.72-6.15% while PALs and BHLs exhibited high values for TSP (39.25-43.19%; 43.97-49.62%), and SWC (7.39-10.07%; 9.98-12.74%). Cation exchange capacity (CEC), Ca2+, K+, and Mg2+ were recorded higher in PALs compared to PMFs and PALs while total organic contents (TOCs) detected little variation among DLTs. Overall, the URAs enhanced the adverse effects on the SPFs across the study area. (URAs demand environments 1 PMFs, (PMFs 6 cm (SPFs province version 26.0 260 26 0 oneway one way ANOVA. ANOVA . (ANOVA) SPS (SPS DLTs (DLTs) ratios 314 31 4 31. 352 35 2 35.2% (BHLs 497 49 7 49. 551 55 55.1% BD (BD 1.36 136 36 (1.3 007 07 0.0 dm3 dm 3 dm-3 0.89 089 89 (0.8 002 02 113 13 1.1 003 03 (PALs 117 17 004 04 125 25 1.2 008 08 dm3. 3. TSP, , (TSP) (SWC 32.9736.18% 32973618 32.97 36.18% 32 97 18 32.97-36.18 4.726.15% 472615 4.72 6.15% 72 15 4.72-6.15 39.2543.19% 39254319 39.25 43.19% 39 43 19 (39.25-43.19% 43.9749.62%, 43974962 43.97 49.62% 62 43.97-49.62%) 7.3910.07% 7391007 7.39 10.07% 10 (7.39-10.07% 9.9812.74%. 9981274 9.98 12.74% 9 98 74 9.98-12.74%) CEC, CEC (CEC) Ca2 Ca Ca2+ K K+ Mg2 Mg TOCs (TOCs Overall area 26. (ANOVA (DLTs 35.2 5 55.1 1.3 (1. 00 0. dm- 0.8 8 (0. 11 1. (TSP 9736 32.9736.18 3297361 3297 32.9 3618 36.18 32.97-36.1 726 4.726.15 47261 472 4.7 615 6.15 4.72-6.1 2543 39.2543.19 3925431 3925 39.2 4319 43.19 (39.25-43.19 9749 43.9749.62% 4397496 4397 43.9 4962 49.62 43.97-49.62% 3910 7.3910.07 739100 739 7.3 1007 10.07 (7.39-10.07 9812 9.9812.74% 998127 998 9.9 1274 12.74 9.98-12.74% (CEC 35. 55. (1 (0 973 32.9736.1 329736 329 32. 361 36.1 32.97-36. 4.726.1 4726 47 4. 61 6.1 4.72-6. 254 39.2543.1 392543 392 39. 431 43.1 (39.25-43.1 974 43.9749.62 439749 439 43. 496 49.6 43.97-49.62 391 7.3910.0 73910 73 7. 100 10.0 (7.39-10.0 981 9.9812.74 99812 99 9. 127 12.7 9.98-12.74 ( 32.9736. 32973 36. 32.97-36 4.726. 6. 4.72-6 39.2543. 39254 (39.25-43. 43.9749.6 43974 43.97-49.6 7.3910. 7391 10. (7.39-10. 9.9812.7 9981 12. 9.98-12.7 32.9736 32.97-3 4.726 4.72- 39.2543 (39.25-43 43.9749. 43.97-49. 7.3910 (7.39-10 9.9812. 9.98-12. 32.973 32.97- 39.254 (39.25-4 43.9749 43.97-49 7.391 (7.39-1 9.9812 9.98-12 (39.25- 43.974 43.97-4 (7.39- 9.981 9.98-1 (39.25 43.97- (7.39 9.98- (39.2 (7.3 (39. (7. (39 (7 (3

RESUMO: A regularização ambiental da piscicultura continental no Brasil está intimamente ligada à ocupação e uso do solo, as áreas utilizadas para a atividade estão em sua maioria inseridas em áreas de preservação permanente (APP), próximas a rios e nascentes. Esse cenário demonstra a relação entre a atividade e o cumprimento da lei, referente às questões florestais no país. Santa Catarina é um dos estados líderes na piscicultura e um dos primeiros a regulamentar o uso de áreas de preservação permanente (APPs). Assim, foi avaliada a viabilidade de uma proposta de compensação ambiental para regularizar o uso de APPs em Santa Catarina para a piscicultura. Os resultados mostraram que 74% das pisciculturas analisadas precisam regularizar a ocupação das estruturas de produção em APPs. Com relação ao índice proposto de compensação pelo uso em APP, o fator de compensação ambiental (FCA), por meio da avaliação dos mapas individuais e posterior avaliação integrada, todas as pisciculturas identificadas com passivos ambientais em ocupação apresentavam relações de 1:2 e 1:3, sendo este índice uma alternativa viável para a regularização ambiental da atividade. No entanto, propõe-se que o ECF seja aplicado a pequenas pisciculturas, de até quatro módulos fiscais e que tenham um perfil de ocupação mínima padrão em relação à área total da propriedade, conforme avaliado no presente estudo. RESUMO solo APP , (APP) nascentes lei país . (APPs) Assim 74 FCA, FCA (FCA) integrada 12 1 2 1: 13, 13 3, 3 1:3 entanto propõese propõe se propriedade estudo (APP (APPs 7 (FCA

ABSTRACT: The environmental regulation of continental fish farming in Brazil is closely linked to land occupation and use. Areas used for this activity are mostly located in permanent preservation areas (PPA), close to rivers and springs, demonstrating the necessity of regulating this activity for its compliance with public policy. Santa Catarina is a leading state in fish farming and one of the first to regulate the use of PPAs. The feasibility of a proposal for environmental compensation to regularize the use of PPAs in Santa Catarina for fish farming; was therefore, assessed. The results showed that 74% of the fish farms analyzed need to regularize the occupation of production structures in PPAs. Regarding the proposed index of compensation for use in PPAs, the environmental compensation factor (ECF), through evaluation of the individual maps and subsequent integrated evaluation, all the fish farms identified with environmental liabilities in occupation had ratios of 1:2 and 1:3, and this index is a viable alternative for environmental regularization of the activity. It was further proposed that ECF be applied to small fish farms of up to four fiscal modules and that they have a standard minimum occupancy profile in relation to the total area of the property, as assessed in the present study. ABSTRACT PPA, PPA , (PPA) springs policy therefore 74 ECF, (ECF) 12 1 2 1: 13, 13 3, 3 1:3 property study (PPA 7 (ECF

Die prosesse wat gebruik word om onroerende eiendom van verkoper na koper in Suid-Afrika oor te dra, is verouderd en nie outomaties nie. Dokumente in papierformaat verhoog die risiko vir bedrog en wanvoorstellings. Hierdie artikel oorweeg die implementering van 'n wolkgebaseerde, gesentraliseerde databasis met eiendomsaanvoerkettingvennote, om deursigtigheid, omkeertyd en sekuriteit te verbeter, terwyl die risiko en koste geminimaliseer word. Die digitalisering van eiendomsprosesse sou lei tot die dematerialisering van die titelbewys, en nie bloot outomatisering van die papiergebaseerde stelsel nie. Die kwalitatiewe navorsing was verkennend, en halfgestruktureerde onderhoude is gevoer met rolspelers betrokke by eiendomsoordragte in Suid-Afrika. Dit het die Suid-Afrikaanse Reserwebank, die Departement van Landbou, Grondhervorming en Landelike Ontwikkeling, die Prokureursorde van Suid-Afrika, verbandopstellers, Die Bankvereniging, die Departement van Binnelandse Sake, die registrateur van die aktekantoor, die landmeter-generaal, munisipaliteite, sagtewaremaatskappye, die Nasionale Tesourie, Suid-Afrika se Sentrale Sekuriteitebewaarplek, sowel as die Tshwane Munisipaliteit se Raad, ingesluit.

The processes used to transfer immovable property from a seller to a buyer in South Africa are outdated and not digitised. Paper-based documents increase the risk of fraud and misrepresentation. This study considered the implementation of a cloud-based centralised database for property supply chain partners to enhance transparency, turnaround times, and security while minimising risks and costs. Digitalised property processes would result in title deeds' dematerialisation and not merely the automation of the paper-based system. This qualitative study was exploratory, and semi-structured interviews were conducted with role-players involved with property transfers in South Africa. These included the South African Reserve Bank, the Department of Agriculture, Land Reform and Rural Development, the Law Society of South Africa, mortgage originators, The Banking Association, the Department of Home Affairs, the Registrar of each Deeds Office, the Surveyor General's office, municipalities, software companies, National Treasury, South Africa's Central Securities Depository (Strate Ltd), and the Tshwane Mettropolitan Municipal Council.

Resumen: Este artículo tiene como objetivo analizar los cambios en la dinámica residencial y comercial de un barrio del sur de Belo Horizonte. Utilizando el registro del Impuesto sobre Bienes Urbanos y Territoriales y el registro del Impuesto sobre Transmisiones Inmobiliarias, fue posible, no sólo identificar y mapear las nuevas propiedades residenciales y comerciales construidas en el barrio en la última década, sino delinear el perfil de sus nuevas residentes y consumidores. Se tiene en cuenta el concepto de gentrificación como un proceso de sustitución de una clase social de menor estatus por otra de mayor estatus, para examinar los resultados encontrados. Los datos apuntan a un proceso de cambio físico, marcado por la mayor oferta de edificios con alto nivel de acabado y alto valor, dirigidos a un grupo social de mayor estatus que los residentes anteriores. El principal actor detrás de estos cambios es el mercado inmobiliario. Resumen Horizonte Inmobiliarias posible década consumidores encontrados físico valor anteriores inmobiliario

Abstract: This article aims to analyze changes in the residential and commercial dynamics of a neighborhood in the south of Belo Horizonte. Using the Urban Property and Territorial Property Tax register and the Real Estate Transfer Tax register, it was possible, not only to identify and map the new residential and commercial properties built in the neighborhood in the last decade, but to outline the profile of its new residents and consumers. The concept of gentrification is taken into account as a process of replacing a social class with a lower status by another with a higher status, to examine the results found. The data point to a process of physical change, marked by the greater supply of buildings with a high standard of finishing and high value, aimed at a social group with a higher status than the previous residents. The main actor behind these changes is the real estate market. Abstract Horizonte possible decade consumers found change value market

Resumo: Este artigo tem como objetivo analisar as mudanças nas dinâmicas residenciais e comerciais de um bairro da Zona Sul de Belo Horizonte. Utilizando o cadastro do Imposto sobre a Propriedade Predial e Territorial Urbana e o cadastro do Imposto sobre a Transmissão de Bens Imóveis, foi possível, não apenas identificar e mapear os novos imóveis residenciais e comerciais construídos no bairro na última década, mas esboçar o perfil de seus novos moradores e consumidores. Leva-se em conta o conceito de gentrificação enquanto um processo de substituição de uma classe social com status inferior por outra com status superior, para examinar os resultados encontrados. Os dados apontam para um processo de mudança física, marcada pela maior oferta de edifícios com alto padrão de acabamento e alto valor, voltados para um grupo social com status superior ao dos antigos moradores. Tais mudanças têm como principal ator o mercado imobiliário. Resumo Horizonte Imóveis possível década consumidores Levase Leva se encontrados física valor imobiliário

Resumo O concreto quando exposto a elevadas temperaturas tem suas propriedades alteradas e os processos de recuperação são dependentes da intensidade destas modificações. O objetivo deste artigo foi avaliar a influência das altas temperaturas nas propriedades do concreto, em uma faixa na qual a estrutura ainda pode ser recuperada, e a verificação dos efeitos gerados no material quando submetidos a resfriamento natural e resfriamento rápido. Para isto se desenvolveu o programa experimental com três traços de concreto, os quais foram expostos a temperaturas de 100 ºC, 300 ºC, 450 ºC e 600 ºC; subdivididos em grupos de resfriamento lento e rápido. Com a elevação da temperatura, intensificam-se os processos de fissuração e alterações microestruturais, as quais geram redução nas resistências mecânicas e o aumento da absorção. Verificou-se que o módulo de elasticidade foi a propriedade mais afetada por estas alterações. As correlações entre o módulo de elasticidade e as demais propriedades foram acompanhadas pelo aumento da microfissuração do concreto, perda de água e decomposição das fases da pasta, sendo observada posterior reidratação da etringita durante o resfriamento do concreto. modificações recuperada rápido 10 30 45 60 temperatura intensificamse intensificam microestruturais absorção Verificouse Verificou pasta 1 3 4 6

Abstract Concrete, when exposed to high temperatures, has its properties changed, and the recovery processes depend on the intensity of these changes. This paper aimed to evaluate the influence of high temperatures on concrete properties and verify the effects generated in the material when submitted to natural and fast cooling. Three different concrete mixes were exposed to temperatures of 100 °C, 300 ºC, 450 ºC, and 600 ºC, subdivided into slow and fast cooling groups. With the increase in temperature, cracking processes and microstructural alterations intensified, generating reductions in mechanical strength and increases in absorptions. This study has identified that the elastic modulus was the property most affected by these changes. The correlations between the elastic modulus and the other properties were accompanied by increased concrete micro-cracking, water loss, and decomposition of paste phases. Also, it was found an effect of ettringite rehydration during concrete cooling. Concrete changed changes 10 C °C 30 ºC 45 60 groups temperature intensified absorptions microcracking, microcracking micro cracking, micro-cracking loss phases Also 1 3 4 6

Abstract Solar Heat Gain Coefficient (SHGC) is a thermal property of glass and transparent elements, defined as the ratio between the amount of solar energy that passes through the glass and the amount of solar energy that reaches it. SHGC can be determined using mathematical models, computer simulations, or field and laboratory measurements. This paper compares the methods for obtaining the SHGC, which include laboratory measurements using a portable calorimeter, computer simulation using the WINDOW software and calculated according to ISO 9050 standard. Two solar control glasses and one clear glass, used as a reference, were selected. The SHGCs obtained using laboratory measurements were lower than those obtained using the other methods due to the solar simulator and equipment limitations. Despite this, there was a good approximation of the behaviour of the glasses regarding the increase in air velocity. The heat transfer coefficient on the exterior surface was fixed, so the SHGC obtained for each glass based on ISO 9050 remains the same, regardless of the air velocity. The SHGC results based on ISO 9050 were similar to those measured by means of a portable calorimeter under conditions of higher air velocities. (SHGC elements it models simulations 905 standard reference selected limitations this velocity fixed same velocities 90 9

Resumo O fator solar é uma propriedade térmica de vidros e elementos transparentes, definida como a razão entre a quantidade de energia solar que atravessa o vidro e a quantidade de energia solar que nele incide. O fator solar pode ser determinado por meio de modelos de cálculo, simulações computacionais ou medições em campo ou laboratório. Este artigo compara métodos de obtenção do fator solar, que incluem medições em laboratório com um calorímetro portátil, simulação computacional no software WINDOW e cálculo conforme procedimentos da norma ISO 9050. Foram selecionados dois vidros de controle solar e um vidro comum como referência. Devido a limitações do simulador solar e do equipamento, os valores de fator solar obtidos nas medições em laboratório foram menores que os calculados pelos outros dois métodos. Apesar disso, houve boa aproximação do comportamento dos vidros quanto ao aumento da velocidade do ar. Os valores calculados por meio da ISO 9050 permaneceram iguais para cada tipo de vidro, independentemente da velocidade do ar, devido ao coeficiente de transferência de calor superficial externo ser fixo. Os valores de fator solar calculados pela norma apresentaram maior proximidade com os valores medidos pelo calorímetro portátil em condições de velocidades do ar mais elevadas. transparentes incide referência equipamento disso 905 fixo elevadas 90 9

Abstract Mortars’ workability results from other properties, such as consistency, plasticity, cohesion, water retention, exudation, initial adhesion and density. A workable mortar distributes itself in application, doesn’t segregate during transport, and remains plastic during the application time. This property depends on several application factors, together with the constituent materials. Therefore, this study aims to assess the influence of the formulation, aggregate type and water content on rheological behavior of rendering mortars, combined with particle packing studies. For this purpose, three usual mortar formulations were chosen. The minimum water content was calculated through the concepts of particle packing and the squeeze flow test. As a result, the influence of each constituent on the workability of the mortar was determined, together with the formulations optimized by the aggregate type. The water content analysis revealed the wet packing density and minimum value required for the formation of the water film around the particles. Mortars properties consistency plasticity cohesion retention exudation doesnt doesn t transport time factors materials Therefore formulation mortars studies purpose chosen test result determined particles

Resumo A trabalhabilidade das argamassas resulta de outras propriedades, como consistência, plasticidade, coesão, retenção de água, exsudação, adesão inicial e densidade. Uma argamassa trabalhável distribui-se durante a aplicação, não segrega durante o transporte e permanece plástica durante o tempo de aplicação. Esta propriedade depende de vários fatores de aplicação, juntamente com os materiais constituintes. Portanto, este estudo tem como objetivo avaliar a influência da formulação, do tipo de agregado e do teor de água no comportamento reológico de argamassas de reboco, aliado a estudos de empacotamento de partículas. Para tanto, foram escolhidas três formulações de argamassas usuais. O teor mínimo de água foi calculado através dos conceitos de empacotamento de partículas e teste de squeeze flow. Como resultado, foi determinada a influência de cada constituinte na trabalhabilidade da argamassa, juntamente com as formulações otimizadas pelo tipo de agregado. A análise do teor de água revelou a densidade de empacotamento úmido e o valor mínimo necessário para a formação do filme de água ao redor das partículas. propriedades consistência plasticidade coesão exsudação distribuise distribui se aplicação constituintes Portanto formulação reboco tanto usuais flow resultado

ABSTRACT This article addresses the study of economic abuse in the context of intimate heterosexual partnerships as a form of violence against women. In particular, it analyzes how the simulated contract has been used as a tool for this purpose. Thus, this research contributes to the determination of the interface between contract law and gender violence. Its methodology is based on the analysis of relevant jurisprudence of the Colombian Supreme Court of Justice. This examination allows the conclusion that the simulated contract could be one of many strategies to abuse women's property rights. In this sense, the simulation scheme has been an instrument to keep in force de facto the property-related dimensions of the marital power institution that was abolished almost a century ago in the country.

RESUMEN Este artículo aborda el estudio del abuso económico en el contexto de las parejas heterosexuales como una forma de violencia en contra de las mujeres. En particular, analiza la manera en que el contrato simulado ha sido utilizado como una herramienta para este fin. Así, esta investigación contribuye a la determinación de la intersección entre derecho privado de contratos y violencia de género. Su metodología se basa en el análisis de jurisprudencia pertinente de la Corte Suprema de Justicia colombiana. Este examen permite concluir que el negocio simulado puede ser una de tantas estrategias para abusar de los derechos patrimoniales de las mujeres. En este sentido, la maniobra simulatoria ha sido un expediente para mantener vigente de facto la dimensión patrimonial de la potestad marital que fuera derogada hace casi un siglo en el país.

Abstract: This article aims to analyze the relative cost of housing in Chile between 1966 and 2022. Specialized literature in this field focuses on four main themes: the impact of the neoliberal model on housing policies, the issue of property and renting, the maintenance of shantytowns, and issues of space and architecture. While there is consensus on the positive impact of social policies on access to housing for low-income families, debates persist regarding poverty and marginality. The research employs the Occupational and Unemployment Survey of Gran Santiago conducted by the Microdata Center of the University of Chile, administered quarterly since 1957 in all districts of Gran Santiago, with an annual survived population of around 10 000 individuals and 2 000 to 3 000 family groups. The findings reveal that: 1) the reduction in the relative cost of housing is more significant in non-poor households than in poor households; 2) in comparison to the international average, there is a decrease in the relative cost from 2000 to 2010, followed by an increase between 2011 and 2017; 3) the relative cost rises in impoverished sectors, particularly in the bottom 10% of income earners; 4) the reduction in relative cost is more pronounced in rented homes than in owned ones.

Resumen: El artículo tiene como objetivo analizar el costo relativo de la vivienda en Chile entre 1966 y 2022. La literatura especializada en esta área se centra en cuatro temas principales: el impacto del modelo neoliberal en las políticas de vivienda, el tema de la propiedad y el arriendo, el mantenimiento de campamentos y aspectos relacionados con el espacio y la arquitectura. Aunque hay consenso sobre el impacto positivo de las políticas sociales en el acceso a viviendas para familias de bajos ingresos, persisten debates en torno a la pobreza y la marginalidad. Se utiliza la Encuesta de Ocupación y Desocupación del Gran Santiago del Centro de Microdatos de la Universidad de Chile, aplicada trimestralmente desde 1957 en todas las comunas del Gran Santiago, con una población encuestada anual de alrededor de 10 000 individuos y 2 000 a 3 000 grupos familiares. Los resultados revelan que: 1) la reducción del costo relativo de la vivienda es mayor en hogares no-pobres que en hogares pobres; 2) en comparación con el promedio internacional, hay una disminución en el costo relativo del 2000 hasta el 2010, seguida de un aumento entre 2011 y 2017; 3) el costo relativo aumenta en sectores empobrecidos, especialmente en el 10% de menores ingresos; 4) la reducción del costo relativo es más marcada en casas arrendadas que en propias.

Resumen Los planes de ordenamiento social de la propiedad rural (POSPR) en Colombia permitirían la implementación de la reforma rural integral (RRI), componente esencial del Acuerdo de Paz. De manera puntual, se argumenta que el diseño institucional del POSPR de Ovejas, municipio del Departamento de Sucre, posibilitaría la ejecución de la RRI. La información de entrevistas a actores clave, la revisión de legislación nacional y la elaboración de matrices en un software muestran que, en esta localidad, los planes de incorporación de hectáreas al Fondo de Tierras y de entrega de títulos de propiedad fortalecen la participación comunitaria con equidad de género y garantiza el ordenamiento del territorio. No obstante, la suspensión paulatina a escala nacional de estos planes ha detenido el avance de la reforma rural. Ovejas sería el único municipio que estaría cumpliendo con este punto del Acuerdo de Paz.

Abstract The Plans for the Social Organization of Rural Property (POSPR) in Colombia would allow the implementation of the Integral Rural Reform (RRI), an essential component of the Peace Agreements. Specifically, POSPR’s institutional design in Ovejas (a municipality in the Department of Sucre) would enable the implementation of the RRI. Information from interviews with key actors, the review of national legislation, and the use of software to elaborate databases show that, in this locality, plans to incorporate hectares into the Land Fund and the delivery of land titles strengthen community participation with gender equity and guarantee territorial planning. However, the gradual suspension of these plans at the national level has halted the progress of rural reform. Ovejas would be the only municipality complying with this point of the Peace Agreements.

Resumen El alquiler de vivienda es una práctica en crecimiento en gran parte de Argentina. Este trabajo analiza el proceso de inquilinización y las iniciativas de regulación del mercado de alquileres en Rosario, tercera ciudad con mayor número de inquilinos del país entre 2003-2023. Los datos que arrojan los documentos oficiales, no oficiales y notas de prensa, muestran que la legislación nacional favorece la desregulación del mercado habitacional. La escasez de políticas habitacionales para inquilinos contrasta con la disponibilidad de viviendas que no se alquilan debido a conflictos y falta de control estatal respecto de precios, regulación y mediación contratos. La elaboración de una política pública para este mercado debería incluir una propuesta de impuestos a la vivienda desocupada, alquiler social e incentivos para la construcción de nuevas viviendas para atender la demanda de alquiler.

Abstract Renting property is a widespread practice in much of Argentina. This paper analyses the mechanisms of renting and initiatives to regulate the rental market in Rosario, the third city with the highest number of tenants in the country (2003-2023). Data from official and unofficial documents and press releases show that national legislation favors the deregulation of the housing market. The scarcity of housing policies for tenants contrasts with the availability of unrented housing due to conflicts and lack of state control over prices, regulation and mediation of contracts. The development of a public policy for this market should include a proposal for taxation of unoccupied housing, social renting and incentives for building new housing to meet rental demand.

ABSTRACT: The aim of this article is to present different legal strategies for the financial sustainability of Colombian biobanks. For that purpose, this work criticizes the sale of human biological samples as a means for sustainability, and proposes different legal alternatives based on, among others, the compensation for the costs associated with the maintenance of the biobank, services of sample collection for third parties or political commitment on the part of the State.

RESUMEN. El objetivo de este artículo es presentar posibles estrategias jurídicas para la sostenibilidad financiera de los biobancos en Colombia. Para tal propósito, critica la posibilidad de comercializar muestras biológicas humanas mediante contratos onerosos y estudia algunas alternativas de sostenimiento basadas, por ejemplo, en la compensación económica por los costos asociados al mantenimiento, el servicio de colección de muestras a terceros o el compromiso político por parte del Estado.