In recent years, the field of coordination chemistry has experienced a surge in interest regarding the synthesis and characterization of coordination complexes for diverse applications. This study is dedicated to investigating coordination compounds resulting from the interaction of nonsteroidal anti-inflammatory drugs (NSAIDs) with metal ions. The study research places significant emphasis on understanding the stability and thermal behavior of these coordination compounds. The utilization of thermoanalytical techniques is crucial in achieving this goal. Thermal analysis and thermokinetics provide valuable insights into the underlying mechanisms, kinetics, and energetics of these reactions, thereby facilitating the optimization of synthesis procedures. The research employs concurrent techniques, namely thermogravimetric analysis (TG) and differential scanning calorimetry (DSC), to explore the thermal stability and decomposition pathways of these coordination compounds. Thermokinetic models and optimization methodologies are subsequently applied to identify key reaction parameters. The primary aim of this research is to unveil the thermal behavior, stability, and reaction kinetics of aceclofenac coordination compounds, thus contributing significantly to the understanding of thermokinetics and thermal analysis in the domain of coordination chemistry. Specifically, this study is focused on aceclofenac coordination complexes involving lanthanum and gadolinium, with the ultimate goal of advancing the field of coordination chemistry. years applications antiinflammatory anti inflammatory NSAIDs (NSAIDs ions mechanisms reactions procedures TG (TG DSC, DSC , (DSC) parameters Specifically gadolinium (DSC

In this work, a miniaturized version of the QuEChERS (quick, easy, cheap, effective, rugged, and safe) method was optimized, validated, and applied for extracting eight pesticide residues in anuran liver tissue samples. The extracts were quantified by high-performance liquid chromatography with diode array detection, and the detected residues in liver tissue samples were identified by tandem mass spectrometry-liquid chromatography. The optimized extraction method entailed the scale reduction of the QuEChERS method twenty times using 500 mg of liver tissue sample, 200 mg Mg2SO4, 50 mg NaCl, 1.5 mL of acetonitrile, and a mixture of 25 mg C18 + 25 mg PSA (primary-secondary amine) as dispersive solid-phase extraction sorbent. The method was validated using liver tissue samples spiked at two levels of pesticide concentrations according to the SANTE/11312/2021 document. Recoveries ranged from 91-110% with a relative standard deviation < 20%. The method robustness assessed by the Steiner and Youden test resulted in recovery rate variations of less than 2% for all pesticides after deliberated changes in seven variables. The validated method was applied to 72 liver tissue samples from two anuran species, registering residues of some pesticides in 31 samples. The proposed method proved to be efficient, precise, and robust for determining pesticide residues in anuran liver tissues. work quick, quick (quick easy cheap effective rugged safe highperformance high performance detection spectrometryliquid spectrometry sample 20 Mg2SO4 MgSO Mg SO 5 NaCl 15 1 1. acetonitrile 2 C C1 primarysecondary primary secondary amine solidphase solid phase sorbent SANTE113122021 SANTE 11312 2021 SANTE/11312/202 document 91110% 91110 91 110% 110 91-110 20% variables 7 species 3 efficient precise tissues Mg2SO SANTE11312202 1131 202 SANTE/11312/20 9111 9 11 91-11 SANTE1131220 113 SANTE/11312/2 911 91-1 SANTE113122 SANTE/11312/ 91- SANTE11312 SANTE/11312 SANTE1131 SANTE/1131 SANTE113 SANTE/113 SANTE11 SANTE/11 SANTE1 SANTE/1 SANTE/

This study offers a comprehensive analysis of how governance capacities in developing countries respond to the challenges that COVID-19 posed. We established a theoretical framework to delve into the multifaceted nature of governance capacities, exploring two distinct aspects of governance: the Weberian one, which focuses on material and organizational capacities, and the Tocquevillian one, which focuses on coordination and associational capacities. We examined these four governance dimensions to illustrate how these distinct skills influence the effectiveness of governance. Our analysis quantifies the impact of the COVID-19 pandemic using such metrics as confirmed cases and deaths. We employ standard and dynamic panel data methodologies to mitigate potential omitted variable bias. Our research findings indicate that countries with robust governance capacities, as assessed by the Bertelsmann Stiftung's Transformation Governance Index, are better equipped to respond effectively to pandemic crises. By applying several models and rigorous robustness tests, we demonstrate efficient resource utilization, the ability to guide and prioritize decision-making within the government, and commitment to cooperation and coordination with other nations and international organizations are the primary drivers of improved outcomes. Our findings remain robust even when controlling for relevant variables and employing estimation techniques that account for potential biases arising from unobservable confounding factors. COVID19 COVID 19 COVID-1 posed one deaths bias Stiftungs Stiftung s Index crises tests utilization decisionmaking decision making government outcomes factors COVID1 1 COVID-

ABSTRACT Purpose: This prospective, randomized, unmasked, clinical trial aimed to report the visual outcomes of cataract surgery on both eyes versus cataract surgery on one eye in Brazilian patients. Methods: This study included patients with bilateral cataracts and binocular visual acuity worse than or equal to 0.3 logarithm of the minimum angle of resolution. The patients were randomly assigned to undergo surgery on one (Control Group) or both eyes (one eye at a time; Intervention Group). Postoperatively, self-reported visual function using Catquest-9SF (primary outcome measure), binocular visual acuity, stereopsis, and ocular dominance (secondary outcome measures) were compared. Results: A total of 151 patients (77 and 148 eyes in the Control and Intervention Groups, respectively) completed the follow-up. Patients who underwent surgery on both eyes exhibited significantly better self-reported visual function (p=0.036) and stereopsis (p=0.026) than those who underwent surgery on one eye. Binocular visual acuity and ocular dominance did not affect the group comparisons. Conclusions: Surgery on both eyes resulted in significantly better self-reported visual function and stereopsis than surgery on one eye. Purpose prospective randomized unmasked Methods 03 0 3 0. resolution Group time Group. . Postoperatively selfreported self reported Catquest9SF CatquestSF Catquest 9SF SF primary measure, measure , measure) secondary measures compared Results 15 77 (7 14 Groups respectively followup. followup follow up. up follow-up p=0.036 p0036 p 036 (p=0.036 p=0.026 p0026 026 (p=0.026 comparisons Conclusions 1 7 ( p=0.03 p003 (p=0.03 p=0.02 p002 02 (p=0.02 p=0.0 p00 (p=0.0 p=0. p0 (p=0. p=0 (p=0 p= (p= (p

Methods used to determine pesticide residues in teas typically require several laborious steps for sample preparation before analysis. In this study, a simple method based on solid-liquid extraction with low-temperature partitioning (SLE/LTP) and analysis by gas chromatography coupled to mass spectrometry (GC-MS) was optimized and validated for the determination of pesticide residues (pirimiphos-methyl, flutriafol, cyproconazole, and bifenthrin) in dehydrated green tea leaves. After low-temperature partitioning (LTP), the extract in acetonitrile was subjected to a clean-up step using primary secondary amine (PSA) and octadecylsilane (C18) as sorbents for chlorophyll removal. The optimized SLE/LTP-GC-MS method was validated, and it proved to be effective and selective for extracting pesticides from green tea samples, presenting limit of detection (LOD) and limit of quantification (LOQ) of 0.015 and 0.050 mg kg-1, respectively. Recovery ranged between 81-111%, coefficients of variation were less than 16% and coefficients of determination (R2) were greater than 0.990. The optimized and validated method was applied to green tea and 13 other tea varieties sampled in South and Southeast regions of Brazil. The pesticides under study were detected in some of those samples at values higher than the maximum residue limits (MRLs) allowed by the European Union. solidliquid solid liquid lowtemperature low temperature SLE/LTP SLELTP SLE LTP (SLE/LTP GCMS GC MS (GC-MS pirimiphosmethyl, pirimiphosmethyl pirimiphos methyl, methyl (pirimiphos-methyl flutriafol cyproconazole bifenthrin leaves LTP, , (LTP) cleanup clean up PSA (PSA C18 C (C18 removal SLE/LTPGCMS SLELTPGCMS LOD (LOD LOQ (LOQ 0015 0 015 0.01 0050 050 0.05 kg1, kg1 kg 1, 1 kg-1 respectively 81111%, 81111 81 111%, 111 81-111% 16 R2 R (R2 0990 990 0.990 Brazil MRLs (MRLs Union (LTP C1 (C1 LTPGCMS 001 01 0.0 005 05 kg- 81111% 8111 8 111% 11 81-111 (R 099 99 0.99 (C 00 0. 811 81-11 09 9 0.9 81-1 81-

Gas chromatography coupled to mass spectrometry (GC-MS) has been widely used, and along with other methodologies such as derivatization, is a powerful tool to analyze phytocompounds, including cuticular wax components. The loss of structural information upon fragmentation of waxes makes it difficult to interpret and identify the GC-MS mass spectra of these compounds with the traditional methods, as digital libraries. Therefore, as a new complementary alternative to traditional methods of identifying aliphatic acyclic lipids based on mass spectra, we present the new software WaxAlly in this technical note. WaxAlly is a new software created based on simple algorithms, enabling the rapid recognition by the user of eight aliphatic acyclic lipid classes, including alkanes, alkenes, aldehydes, ketones, esters, and TMS derivatives of free fatty acids, primary and secondary alcohols, and their homologues with carbon chains varying between 10 and 100 carbons. Additionally, the WaxAlly software provides a section for data organization, internet comparison to NIST and PubChem databases, and academic information about mass fragmentation of acyclic lipids. The software has proven to be a very useful complementary technique in identifying plant wax lipid homologues, and new fragmentation patterns of lipid classes can be added in the future to improve the program. GCMS GC MS (GC-MS used derivatization phytocompounds components libraries Therefore note algorithms alkanes alkenes aldehydes ketones esters acids alcohols 1 carbons Additionally organization databases program

ABSTRACT Purpose: This study aimed to compare the safety and effectiveness of intraocular pressure reduction between micropulse transscleral cyclophotocoagulation and “slow cook” transscleral cyclophotocoagulation in patients with refractory primary open-angle glaucoma. Methods: We included patients with primary open angle glaucoma with at least 12 months of follow-up. We collected and analyzed data on the preoperative characteristics and postoperative outcomes. The primary outcomes were a reduction of ≥20% of the baseline value (criterion A) and/or intraocular pressure between 6 and 21 mmHg (criterion B). Results: We included 128 eyes with primary open-angle glaucoma. The preoperative mean intraocular pressure was 25.53 ± 6.40 and 35.02 ± 12.57 mmHg in the micropulse- and “slow cook” transscleral cyclophotocoagulation groups, respectively (p<0.001). The mean intraocular pressure was reduced significantly to 14.33 ± 3.40 and 15.37 ± 5.85 mmHg in the micropulse- and “slow cook” transscleral cyclophotocoagulation groups at the last follow-up, respectively (p=0.110). The mean intraocular pressure reduction at 12 months was 11.20 ± 11.46 and 19.65 ± 13.22 mmHg in the micropulse- and “slow cook” transscleral cyclophotocoagulation groups, respectively (p<0.001). The median preoperative logMAR visual acuity was 0.52 ± 0.69 and 1.75 ± 1.04 in the micropulse- and “slow cook” transscleral cyclophotocoagulation groups, respectively (p<0.001). The mean visual acuity variation was −0.10 ± 0.35 and −0.074 ± 0.16 in the micropulse- and “slow cook” transscleral cyclophotocoagulation, respectively (p=0.510). Preoperatively, the mean eye drops were 3.44 ± 1.38 and 2.89 ± 0.68 drugs in the micropulse- and “slow cook” transscleral cyclophotocoagulation groups, respectively (p=0.017), but those were 2.06 ± 1.42 and 1.02 ± 1.46 at the end of the study in the “slow cook” and micropulse transscleral cyclophotocoagulation groups, respectively (p<0.001). The success of criterion A was not significant between both groups. Compared with 11 eyes (17.74%) in the “slow cook” transscleral cyclophotocoagulation group, 19 eyes (28.78%) in the micropulse transscleral cyclophotocoagulation group showed complete success (p=0.171). For criterion B, 28 (42.42%) and 2 eyes (3.22%) showed complete success after micropulse- and “slow cook” transscleral cyclophotocoagulation, respectively (p<0.001). Conclusion: Both techniques reduced intraocular pressure effectively. Purpose slow cook openangle Methods 1 followup. followup follow up. up follow-up 20 ≥20 andor or B. B . B) Results 2553 25 53 25.5 640 40 6.4 3502 35 02 35.0 1257 57 12.5 p<0.001. p0001 p p<0.001 0 001 (p<0.001) 1433 14 33 14.3 340 3 3.4 1537 15 37 15.3 585 5 85 5.8 followup, up, p=0.110. p0110 p=0.110 110 (p=0.110) 1120 11.2 1146 46 11.4 1965 65 19.6 1322 13 22 13.2 052 52 0.5 069 69 0.6 175 75 1.7 104 04 1.0 010 10 −0.1 035 0.3 0074 074 −0.07 016 16 0.1 p=0.510. p0510 p=0.510 510 (p=0.510) Preoperatively 344 44 138 38 1.3 289 89 2.8 068 68 p=0.017, p0017 p=0.017 , 017 (p=0.017) 206 06 2.0 142 42 1.4 102 146 17.74% 1774 17 74 (17.74% 28.78% 2878 78 (28.78% p=0.171. p0171 p=0.171 171 (p=0.171) 42.42% 4242 (42.42% 3.22% 322 (3.22% Conclusion effectively ≥2 255 25. 64 4 6. 350 35. 125 12. p000 p<0.00 00 (p<0.001 143 14. 34 3. 153 15. 58 8 5. p011 p=0.11 (p=0.110 112 11. 114 196 19. 132 13. 05 0. 7 1. 01 −0. 03 007 07 −0.0 p051 p=0.51 51 (p=0.510 2. p001 p=0.01 (p=0.017 17.74 177 (17.74 28.78 287 (28.78 p017 p=0.17 (p=0.171 42.42 424 (42.42 3.22 32 (3.22 ≥ p00 p<0.0 (p<0.00 p01 p=0.1 (p=0.11 −0 p05 p=0.5 (p=0.51 p=0.0 (p=0.01 17.7 (17.7 28.7 (28.7 (p=0.17 42.4 (42.4 3.2 (3.2 p0 p<0. (p<0.0 p=0. (p=0.1 − (p=0.5 (p=0.0 17. (17. 28. (28. 42. (42. (3. p<0 (p<0. p=0 (p=0. (17 (28 (42 (3 p< (p<0 p= (p=0 (1 (2 (4 ( (p< (p= (p

ABSTRACT Moringa oleifera Lam. is an arboreal forest species of great economic potential, adapted to the climatic conditions of the Brazilian semi-arid region, whose multiplication is mainly by seeds. Rapid viability and vigor tests help in the choice of lots. Thus, the objective of this study was to assess the efficiency of the pH of exudate and primary root protrusion tests in the evaluation of viability and vigor, respectively. Two seed lots were initially evaluated for moisture content, germination, first count, germination speed index, seedling length, seedling dry mass and electrical conductivity. For the pH of exudate test, phenolphthalein (1%) and sodium carbonate (2 and 4 g L-1) solutions were prepared, with three soaking periods (1, 3 and 5 h) and three temperatures (25, 30 and 35 °C). Exudate solution in strong to light pink color indicated viable seeds, whereas very light pink color to colorless indicated non-viable seeds. The primary root protrusion test was performed under 25, 30 and 35 °C, evaluating the primary root protrusion of at least 2 mm, every 12 h until 196 h. The experimental design was completely randomized, with four replicates. pH of exudate test with 1 h of soaking at 25 or 30 °C with 2 g L-1 sodium carbonate solution was promising, but further studies are needed before it is indicated as routine use for the species. Primary root protrusion test is efficient and can be conducted at 35 °C with evaluation after 48 h. Lam potential semiarid semi arid region seeds Thus respectively content count index length conductivity 1% (1% ( L1 L prepared 1, (1 (25 °C. C . °C) nonviable non mm 19 randomized replicates L- promising

Seeking a viable alternative to fossil fuels as the primary energy source, bioethanol has emerged as a promising second-generation fuel derived from lignocellulosic biomass. With Brazil ranking pineapple as the third most produced fruit in temporary crops, this study aims to assess the impact of chemical pretreatment techniques, specifically organosolv and diluted acid, on the residual biomass of Pérola pineapple peel to enhance bioethanol production. Employing an experimental design that incorporates temperature, reaction time, and varying concentrations of organic solvent, the study examines their effects on the susceptibility of the substrate to saccharification for future bioethanol generation. Factors such as alphacellulose, hemicellulose, and lignin were evaluated in triplicate and subjected to statistical analysis using the Tukey test with a confidence level of 95%. Upon application of the pretreatment methods, it was observed that the organosolv solvent approach (utilizing water and ethanol) with sulfuric acid exhibited superior sugar conversion, yielding the highest concentration of xylose at 9.13 g L-1. Additionally, the pretreated biomass contained 1.38 g L 1 of cellobiose, 3.11 g L-1 of arabinose, and 3.76 g L-1 of glucose. This technique demonstrates promising potential for obtaining fermentable sugars crucial for bioethanol production. source secondgeneration second generation crops techniques production temperature time alphacellulose hemicellulose 95 95% methods utilizing ethanol conversion 913 9 13 9.1 L1. L1 1. Additionally 138 38 1.3 cellobiose 311 3 11 3.1 L- arabinose 376 76 3.7 glucose 91 9. 31 3. 37 7

Two novel alkyl thiophene-modified pyrene derivatives (1)-(2) were created and synthesized using palladium-catalyzed Stille coupling processes and Friedel-Crafts reaction of pyrene. The polycyclic aromatic groups of the thiophene-modified pyrene were oxidized with Ag[Al(OC(CF3)3)4] to provide the insensitive radical cations 1•+-2•+ based on the alkyl thiophene-modified pyrene derivatives. Nuclear magnetic resonance (NMR), electron paramagnetic resonance (EPR), UV-Vis spectroscopy, and density functional theory (DFT) calculations, were used to investigate their structures and properties. The pyrene moieties were the primary location of the electron spin distribution, with a little overflow onto the outer thiophene moieties. Due to the different substituent groups, free radicals 1•+ 2•+ exhibit some different properties. Compound 1•+ is the most extensive thiophene-modified pyrene radical cation that has been reported. These species are anticipated to have wide-ranging potential in the areas of optoelectronic materials and semiconductors. thiophenemodified modified 12 1 2 (1)-(2 palladiumcatalyzed palladium catalyzed FriedelCrafts Friedel Crafts AgAlOCCF334 AgAlOCCF Ag Al OC CF3 3 4 CF Ag[Al(OC(CF3)3)4 1•+2•+ 1•+-2• NMR, NMR , (NMR) EPR, EPR (EPR) UVVis UV Vis spectroscopy DFT (DFT calculations properties distribution 1• 2• reported wideranging wide ranging semiconductors (1)-( AgAlOCCF33 Ag[Al(OC(CF3)3) 1•+2• 1•+-2 (NMR (EPR (1)- AgAlOCCF3 Ag[Al(OC(CF3)3 1•+2 1•+- (1) Ag[Al(OC(CF3) (1 Ag[Al(OC(CF3 ( Ag[Al(OC(CF

Résumé Cet article analyse la Banque Mondiale comme un acteur de la néo-libéralisation du capitalisme mondial, mettant l’accent sur ses fonctions de prêteur, conseiller et conseiller technique des gouvernements, agent de la société civile et producteur de recherches économiques pendant la période 1980-2023. En s’appuyant sur des sources primaires de l’institution elle-même et d’une vaste littérature spécialisée, l’étude montre comment l’action de la Banque Mondiale est devenue de plus en plus complète, politisée et intrusive, bien que présentant des variations dans la forme, le contenu et l’intensité de votre agenda politique et de vos pratiques opérationnelles. Larticle conclut que, dans un context mondial marqué par de grands changements économiques et politiques, une plus grande contestation des revenus économiques supposés universels et des incertitudes quant à l’avenir, la Banque mondiale est restée fidèle au paradigme politique néolibéral, cependant, elle a adopté une approche plus pragmatique, flexible, discrète et dépendante des circonstances et des priorités des emprunteurs (notamment ceux de grande envergure). néolibéralisation néo libéralisation laccent l accent prêteur gouvernements 19802023. 19802023 1980 2023. 2023 1980-2023 sappuyant s appuyant linstitution institution ellemême même dune d spécialisée létude étude laction action complète intrusive forme lintensité intensité opérationnelles politiques lavenir, lavenir avenir, avenir l’avenir néolibéral cependant pragmatique flexible notamment envergure. envergure . envergure) 1980202 198 202 1980-202 198020 19 20 1980-20 19802 1 2 1980-2 1980-

Abstract This article analyses the World Bank as an agent of the neoliberalization of global capitalism, with an emphasis on its functions as a lender, adviser and technical advisor to governments, civil society agent, and producer of economic research during the period from 1980 to 2023. Based on primary sources from the institution itself and extensive specialized literature, the article shows how the World Bank’s activities have become increasingly comprehensive, politicized, and intrusive, but with variations in form, content, and intensity in its political agenda and operational practices. It concludes that, in a global environment marked by major economic and political changes, greater contestation of supposedly universal economic recipes, and uncertainties about the future, the World Bank has remained faithful to the neoliberal political paradigm, but it has started to act in a more pragmatic, flexible, discreet way that depends on the circumstances and priorities of the borrowers (especially the larger ones). capitalism lender governments 198 2023 literature Banks s comprehensive politicized intrusive form content practices changes recipes future paradigm pragmatic flexible especially ones. ones . ones) 19 202 1 20 2

Resumo Este artigo analisa o Banco Mundial como agente de neoliberalização do capitalismo global, dando ênfase às suas funções de emprestador, conselheiro e assessor técnico de governos, agente da sociedade civil e produtor de pesquisas econômicas durante o período de 1980 a 2023. Com base em fontes primárias da própria instituição e ampla literatura especializada, o trabalho mostra como a atuação do Banco Mundial se tornou cada vez mais abrangente, politizada e intrusiva, porém com variações de forma, conteúdo e intensidade em sua agenda política e suas práticas operacionais. Conclui que, em um ambiente global marcado por grandes mudanças econômicas e políticas, maior contestação a receitas econômicas supostamente universais e incertezas quanto ao futuro, o Banco Mundial se manteve fiel ao paradigma político neoliberal, porém, passou a atuar de forma mais pragmática, flexível, discreta e dependente das circunstâncias e prioridades dos mutuários (especialmente os de maior volume). emprestador governos 198 2023 especializada abrangente intrusiva operacionais que políticas futuro neoliberal pragmática flexível especialmente volume. volume . volume) 19 202 1 20 2

Resumen Este artículo analiza el Banco Mundial como agente de la neoliberalización del capitalismo global, haciendo hincapié en sus funciones como prestamista, asesor y consejero técnico de los gobiernos, agente de la sociedad civil y productor de investigación económica durante el periodo comprendido entre 1980 y 2023. Basándose en fuentes primarias de la propia institución y en una amplia bibliografía especializada, el artículo muestra cómo las actividades del Banco Mundial se han vuelto cada vez más amplias, politizadas e intrusivas, pero con variaciones de forma, contenido e intensidad en su agenda política y sus prácticas operativas. Concluye que, en un entorno global marcado por grandes cambios económicos y políticos, una mayor contestación de las recetas económicas supuestamente universales y la incertidumbre sobre el futuro, el Banco Mundial se ha mantenido fiel al paradigma político neoliberal, pero ha empezado a actuar de una forma más pragmática, flexible y discreta que depende de las circunstancias y prioridades de los prestatarios (especialmente de los más grandes). prestamista gobiernos 198 2023 especializada amplias intrusivas operativas políticos futuro neoliberal pragmática especialmente grandes. . grandes) 19 202 1 20 2

Abstract This paper deals with the political repression carried out at the National Council for Scientific and Technical Research (CONICET) during the last military dictatorship in Argentina and the first experience to repair the files of murdered and/or disappeared people that CONICET began recently. In addition to the bibliographic and documental review, we interviewed key informants and built a matrix with primary data on the repression victims in the organization based on a detailed review of over 8,000 institutional resolutions between 1973 and 1983. The matrix arrived at a total of 2,843 cases, 78% of which corresponded to forced evictions (mass layoffs and license requests) and 21% to dismissals by the organization (dismissals, layoffs and other measures). The results obtained allow us to measure the impact of the dictatorship on Argentina’s main scientific organization, which had not been studied before. (CONICET andor or recently 8000 8 000 8,00 197 1983 2843 2 843 2,84 cases 78 mass requests 21 dismissals, (dismissals measures. measures . measures) Argentinas s before 800 00 8,0 19 198 284 84 2,8 7 80 0 8, 1 28 2,

Résumé Cet article traite de la répression politique exercée au Conseil national de la recherche scientifique et technique (CONICET) lors de la dernière dictature militaire en Argentine et de la première expérience de réparation des archives du personnel assassiné et/ou disparu que le CONICET a récemment entamée. En plus de la révision bibliographique et documentaire, nous avons mené des entretiens avec des informateurs clés et construit une matrice avec des données primaires sur les victimes de la répression dans l’organisation sur la base d’une révision détaillée de plus de 8000 résolutions institutionnelles entre 1973 et 1983. La matrice a atteint un total de 2.843 cas, dont 78% ont été des expulsions forcées (licenciements massifs et demandes de congé) et 21% d’exemptions par l’organisation (révocation, licenciements et autres mesures). Les résultats obtenus nous permettent de mesurer l’impact de la dictature sur la principale organisation scientifique en Argentine, ce qui n’avait pas été étudié auparavant. (CONICET etou ou entamée documentaire lorganisation l dune d 800 197 1983 2843 2 843 2.84 cas 78 congé 21 dexemptions exemptions révocation, révocation (révocation mesures. mesures . mesures) limpact impact navait n avait auparavant 80 19 198 284 84 2.8 7 8 1 28 2.

Resumo Este artigo trata da repressão política exercida no Conselho Nacional de Pesquisas Científicas e Técnicas (CONICET) durante a última ditadura militar na Argentina e da primeira experiência de reparação dos arquivos de pessoal assassinado e/ou desaparecido que o CONICET iniciou recentemente. Além da revisão bibliográfica e documental, realizamos entrevistas com informantes-chave e construímos uma matriz com dados primários sobre as vítimas da repressão na organização com base em uma revisão detalhada de mais de 8.000 resoluções institucionais entre 1973 e 1983. A matriz chegou a um total de 2.843 casos, 78% dos quais corresponderam a expulsões forçadas (demissões em massa e pedidos de licença) e 21% a exonerações pela organização (exonerações, demissões e outras medidas). Os resultados obtidos nos permitem medir o impacto da ditadura na principal organização científica da Argentina, algo que não havia sido estudado anteriormente. (CONICET eou ou recentemente documental informanteschave informantes chave 8000 8 000 8.00 197 1983 2843 2 843 2.84 casos 78 licença 21 exonerações, (exonerações medidas. medidas . medidas) anteriormente 800 00 8.0 19 198 284 84 2.8 7 80 0 8. 1 28 2.

Resumen Este trabajo aborda la represión política ejercida en el Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) durante la última Dictadura militar argentina y la primera experiencia de reparación de legajos del personal asesinado y/o desaparecido que el CONICET inició recientemente. Además de la revisión bibliográfica y documental; realizamos entrevistas a informantes claves y construimos una matriz con datos primarios sobre las víctimas de la represión en el organismo a partir de la revisión pormenorizada de más de 8000 resoluciones institucionales entre 1973 y 1983. La matriz alcanzó un total de 2843 casos, de los cuales el 78% corresponde a expulsiones forzadas (renuncias masivas y pedidos de licencias) y el 21% a exoneraciones por parte del organismo (bajas, cesantías y otras medidas). Los resultados obtenidos permiten dimensionar el impacto de la dictadura en el principal organismo científico argentino, algo que no había sido estudiado previamente. (CONICET yo o recientemente documental 800 197 1983 284 casos 78 renuncias licencias 21 bajas, bajas (bajas medidas. medidas . medidas) argentino previamente 80 19 198 28 7 2 8 1

Abstract We investigated how the FBI persecuted the Black Panther Party of the United States through the COINTELPRO program between 1968 and 1971, and verified that such practices follow a pattern similar to that of other counterintelligence activities mobilized in the repression of political organizations of the left and the black movement in the 20th Century, repeating a consolidated modus operandi at the time. In terms of methodology, we proposed a content analysis of primary sources little studied in Brazil – internal FBI memos and the final report of the US Senate Committee (“Church Committee”) dedicated to investigating government intelligence activities – and a systematization of secondary sources that have already analyzed the material in the United States. The relevance of the paper is to highlight the role of repression in studies of sociopolitical movements and mobilizations, mainly in the case of the Black Panthers – in which it occupies a specific importance to understand obstacles to develop the organization and its own dissolution process. 196 1971 th Century time methodology Church Committee” mobilizations process 19 197 1

Résumé Les recherches montrent comment le Black Panther Party des États-Unis a été persécuté par le FBI à travers le programme COINTELPRO entre 1968 et 1971. Ainsi, ces pratiques suivent un schéma similaire à celui d’autres activités de contre- renseignement mobilisées dans la répression des organisations politiques de gauche et du mouvement noir au XXe siècle, en répétant un modus operandi consolidé à l’époque. Méthodologiquement, il est proposé une analyse de contenu sur des sources primaires peu étudiées au Brésil - mémos internes du FBI et le rapport final du comité du Sénat américain (“Church Committee”) consacré à enquêter sur les activités de renseignement du gouvernement - et une systématisation des sources secondaires qui ont déjà analysé le matériel aux États-Unis. La pertinence de cet article est de souligner la place de la répression dans les études de mouvements et les mobilisations sociopolitiques, surtout dans le cas des Black Panthers - où elle revêt une importance particulière pour comprendre les obstacles au développement de l’organisation et son propre processus de dissolution. ÉtatsUnis États Unis 196 1971 Ainsi dautres d autres contre siècle lépoque. lépoque l époque. époque l’époque Méthodologiquement Church Committee Committee” ÉtatsUnis. Unis. sociopolitiques lorganisation organisation dissolution 19 197 1

Resumo Pesquisa-se como o Partido Pantera Negra dos Estados Unidos foi perseguido pelo FBI por meio do programa COINTELPRO entre os anos 1968 e 1971. Verifica-se, então, que tais práticas seguem um padrão similar ao de outras atividades de contrainteligência mobilizadas na repressão a organizações políticas da esquerda e do movimento negro no século XX, repetindo um modus operandi consolidado à época. Metodologicamente, propõe-se uma análise de conteúdo sobre fontes primárias pouco estudadas no Brasil – memorandos internos do FBI e o relatório final do comitê do Senado estadunidense (“Church Committee”) dedicado a investigar atividades de inteligência do governo – e uma sistematização de fontes secundárias que já analisaram o material nos Estados Unidos. A relevância do artigo consiste em destacar o lugar da repressão em estudos de movimentos e mobilizações sociopolíticas, sobretudo no caso dos Panteras Negras – no qual ela ocupa uma importância particular para compreender obstáculos ao desenvolvimento da organização e seu próprio processo de dissolução. Pesquisase Pesquisa se 196 1971 Verificase, Verificase Verifica se, Verifica-se então XX época Metodologicamente propõese propõe Church Committee Committee” sociopolíticas dissolução 19 197 1

Resumen Se investiga cómo el Partido de las Panteras Negras de Estados Unidos fue perseguido por el FBI a través del programa COINTELPRO entre 1968 y 1971. Puede verse, pues, que estas prácticas siguen un patrón similar al de otras actividades de contrainteligencia movilizadas en la represión de las organizaciones políticas de izquierda y del movimiento negro en el siglo XX, repitiendo un modus operandi consolidado en la época. Metodológicamente, proponemos un análisis de contenido de fuentes primarias poco estudiadas en Brasil – memorandos internos del FBI y el informe final del comité del Senado estadounidense (“Church Committee”) dedicado a investigar las actividades de inteligencia del gobierno – y una sistematización de fuentes secundarias que ya han analizado el material en Estados Unidos. La pertinencia del artículo radica en destacar el lugar que ocupa la represión en los estudios sobre los movimientos y movilizaciones sociopolíticos, especialmente en el caso de los Panteras Negras, donde es particularmente importante comprender los obstáculos al desarrollo de la organización y su propio proceso de disolución. 196 1971 verse pues XX época Metodológicamente Church Committee Committee” sociopolíticos disolución 19 197 1

Abstract Several structural models aim to predict the behavior of masonry walls. Those are included in technical standards strive to ensure the anticipation of the structural capacity, thereby assuring its safety. Different regions of the world encompass diverse parameters for predicting the lateral capacity of masonry members. This study sought to compare the Brazilian, Canadian, American, Australian, and European masonry standards regarding the shear and flexural capacity specification of walls. Equations derived from the standards were contrasted against finite element modeling results and to reliable formulation from the literature for predicting wall shear behavior. Additionally, an actualization is proposed to the Brazilian standard. The results revealed that while flexural capacity specifications result in comparable values across all standards, the Brazilian standard exhibited the least conservatism in the shear capacity, followed by the Australian, American, Canadian, and European standards. The diagonal shear was the primary mode of panel failure of the walls from the FE (Finite Element) modeling. The suggested adjustments to the Brazilian code, including considering the net area and correction of the initial shear strength (fvk0), result values close to the modeling results. safety members Canadian American Australian Additionally Finite Element code fvk0, fvk0 fvk , (fvk0) (fvk0 (fvk

Resumo Enquanto diversos modelos estruturais buscam prever o comportamento de paredes em alvenaria, as normas técnicas buscam promover a previsão das cargas resistentes, de modo a trazer segurança para as estruturas. Diferentes regiões do mundo possuem parâmetros diversos para previsão da capacidade lateral das estruturas em alvenaria. O presente trabalho buscou realizar a comparação entre as normas de alvenaria estrutural brasileira, americana, australiana e europeia no que tange à resistência ao cisalhamento das mesmas e à flexocompressão que estão submetidas. Os equacionamentos indicados nas normas foram comparados com modelagem por elementos finitos e com a equação da literatura (2022), consideradas fidedignas para previsão do comportamento das paredes submetidas a forças laterais no plano. É proposta uma atualização para a norma brasileira. Os resultados mostraram que enquanto os resultados dos modelos para flexocompressão têm valores similares em todas as normas, para cisalhamento, a norma brasileira se mostrou como sendo a menos conservadora, seguida pela australiana, americana, canadense e europeia. Foi identificado ainda, por meio da modelagem em EF (Elementos Finitos), que o principal modo de ruptura dos painéis é a compressão diagonal. A proposta de modificação na norma brasileira, com consideração de área líquida e a correção da resistência ao cisalhamento inicial (fvk0), resultam valores muito mais próximos aos resultados do modelo. resistentes americana 2022, 2022 , (2022) plano conservadora ainda Elementos Finitos, Finitos Finitos) diagonal fvk0, fvk0 fvk (fvk0) modelo 202 (2022 (fvk0 20 (202 (fvk 2 (20 (2 (

The way Family Health teams work can encourage sharing between different fields of knowledge and the development of interprofessional collaborative practices. The objective was to understand how interprofessional collaborative practices are built in the work process in Family Health units. Exploratory, descriptive research, with quantitative and qualitative approaches, carried out with Family Health teams from 26 municipalities in the countryside of the state of São Paulo, using secondary data and semi-structured interviews. From the analysis, two thematic categories emerged: the development of interprofessional work and aspects related to the team. The construction of interprofessional collaborative practices permeates collective spaces in moments of professional integration. However, there are weaknesses arising from the fragmentation of professional practices and the lack of user-centeredness.

O modo de trabalhar das equipes de Saúde da Família pode favorecer o compartilhamento entre diferentes campos de saberes e o desenvolvimento de práticas colaborativas interprofissionais. Objetivou-se compreender como se dá a construção de práticas colaborativas interprofissionais no processo de trabalho em unidades de Saúde da Família (USF). Investigação exploratória, descritiva, com abordagens quantitativa e qualitativa, realizada com equipes de Saúde da Família de 26 municípios do interior paulista, utilizando dados secundários e entrevistas semiestruturadas. Da análise, emergiram duas categorias temáticas: o desenvolvimento do trabalho interprofissional e aspectos relacionados com a equipe. A construção das práticas colaborativas interprofissionais perpassa os espaços coletivos em momentos de integração dos profissionais. Porém, existem fragilidades decorrentes da fragmentação das práticas profissionais e da não centralidade no usuário.

El modo de trabajar de los equipos de Salud de la Familia puede favorecer la compartición entre diferentes campos de saberes y el desarrollo de prácticas colaborativas interprofesionales. El objetivo fue comprender cómo se realiza la construcción de prácticas colaborativas interprofesionales en el proceso de trabajo en unidades de Salud de la Familia. Una investigación exploratoria, descriptiva, con abordajes cuantitativo y cualitativo, realizada con equipos de Salud de la Familia de 26 municipios del interior del Estado de São Paulo, utilizando datos secundarios y entrevistas semiestructuradas. Del análisis surgieron dos categorías temáticas: el desarrollo del trabajo interprofesional y aspectos relacionados con el equipo. La construcción de las prácticas colaborativas interprofesionales atraviesa los espacios colectivos, en momentos de integración de los profesionales. No obstante, hay fragilidades provenientes de la fragmentación de las prácticas profesionales y de la no centralidad en el usuario.