EFFECT OF LIQUID SWINE WASTEWATER DOSES ON PHYSICAL, CHEMICAL AND ELECTROCHEMICAL ATTRIBUTES IN A CERRADO OXISOL. The addition of organic residues enhances soil and plant organic matter and nutrient content. To gauge the impact of varying liquid swine waste (LSW) levels on soil, we studied changes in a clayey Oxisol’s physical, chemical, and electrochemical traits from the Cerrado. LSW doses (0, 50, 150, 450, 600 m3 ha−1) were applied to the 0-0.20 m layer in a randomized design with three replicates. Post a 30-day incubation at 60% field capacity, the soil underwent mineralogical, physical (clay dispersed in water - CDW), chemical (sodium adsorption ratio - SAR, cation exchange capacity - CEC, base saturation - V%), and electrochemical (pH in H2O and KCl, ApH, point of zero charge - PZC, point of zero salt effect - PZSE, surface electric potential - iµo, and electrical conductivity - EC) analyses. The levels of exchangeable Ca, K, Mg, Na, and available P increased with increasing LSW doses. Increasing LSW doses in the soil led to an increase in EC, but soil salinization was not observed at the highest dose. With the application of LSW doses, there was a decrease in pH, ApH, PZSE, and an increase in CEC, PZC and ψo. Despite the increase in ψo, low clay dispersibility was observed. PHYSICAL OXISOL content (LSW Oxisols Oxisol s Cerrado 0, 0 (0 50 150 450 60 ha−1 ha1 ha 1 00.20 0020 0.20 20 0-0.2 replicates 30day day 30 mineralogical CDW, CDW , CDW) sodium SAR CEC V%, V V% V%) pH HO H O KCl ApH PZSE iµo EC analyses Ca K Mg Na dose ψo ( 5 15 45 6 ha− 00 00.2 002 020 0.2 2 0-0. 3 4 00. 02 0. 0-0 0-

Chitosan (CS) blends with collagen (CL) and Aloe vera (AV) have gained significant attention in the biomedical field due to their biocompatibility, biodegradability, and potential for wound healing applications. In this study, we investigated the preparation and characterization of CS/CL and CS/AV blends using selective precipitation and co-precipitation techniques. The synthesis processes were analyzed for yield and 4-hydroxyproline content (in CS/CL blends). The materials were characterized using bromatological analyses, viscosity measurements, Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). These eco-friendly methods effectively promoted interactions between the biopolymers, resulting in homogeneous blends with tunable properties. Besides, they are simple, fast, safe, and require minimal infrastructure. This study demonstrated that selective precipitation and co-precipitation are effective methods for producing chitosan/collagen and chitosan/Aloe vera blends. These methods foster interactions and miscibility between the biopolymers, as confirmed by FTIR, XRD, viscosity, and 4-Hy content analyses. They also align with green chemistry principles by avoiding organic solvents, reducing environmental risks, and minimizing waste. The high yields achieved, especially for CS/AV blends (exceeding 96%), make these materials compatible with lyophilization procedures. The absence of segregated phases after appropriate washing underscores their suitability for pharmaceutical formulations and other applications. CS (CS CL (CL AV (AV biocompatibility biodegradability applications CSCL CSAV coprecipitation co techniques 4hydroxyproline hydroxyproline 4 . blends) analyses measurements Fouriertransform Fourier transform FTIR , (FTIR) Xray X ray XRD (XRD) SEM. SEM (SEM) ecofriendly eco friendly biopolymers properties Besides simple fast safe infrastructure chitosancollagen chitosan chitosanAloe 4Hy Hy solvents risks waste achieved exceeding 96%, 96 96% 96%) procedures (FTIR (XRD (SEM 9

ABSTRACT Biochar can promote crop production and soil quality. However, its characteristics depend on the waste used in its production and its effects may vary according to the species being cultivated and the management adopted. The aim of this study was to evaluate the application of biochar from animal waste on soil quality and the agronomic characteristics of the cowpea. An experiment was set up to test three types of biochar (bovine-BB, swine-SB and poultry-BP), with added fertiliser (BBF, SBF and BPF) and two control treatments, including the addition of calcium magnesium oxide (CT) and calcium magnesium oxide with fertiliser (CTF), giving a total of eight treatments with four replications. There was a respective increase of up to 102.94%, 1048%, 1560% and 360.22% in stem diameter, number of pods, number of grains per pod and stem dry matter from adding the biochar. The poultry biochar increased each of the above parameters even with no added fertiliser. There was no difference in basal soil respiration or β-glucosidase enzyme activity, whereas organic carbon (TOC), total nitrogen (TN), microbial carbon and soil labile carbon were greater with biochar. BBF gave the highest TOC content (24.40 g kg-1), while BP and BPF increased TN by around 61%. The application of biochar + fertiliser contributed to an average reduction of 56% in the soil metabolic quotient. Poultry biochar favoured both the agronomic characteristics of the cowpea and soil quality, while bovine biochar showed more marked results with the addition of fertiliser. However adopted bovineBB, bovineBB BB, BB (bovine-BB swineSB swine SB poultryBP, poultryBP , poultry-BP) BBF, (BBF CT (CT CTF, CTF (CTF) replications 10294 102 94 102.94% 1048 1048% 1560 36022 360 22 360.22 diameter pods βglucosidase β glucosidase activity TOC, (TOC) TN, (TN) 24.40 2440 24 40 (24.4 kg1, kg1 kg 1 kg-1) 61 61% 56 quotient poultry-BP (CTF 1029 10 9 102.94 104 156 3602 36 2 360.2 (TOC (TN 24.4 244 4 (24. kg-1 6 5 102.9 15 3 360. 24. (24 kg- 102. (2 (

Seeking a viable alternative to fossil fuels as the primary energy source, bioethanol has emerged as a promising second-generation fuel derived from lignocellulosic biomass. With Brazil ranking pineapple as the third most produced fruit in temporary crops, this study aims to assess the impact of chemical pretreatment techniques, specifically organosolv and diluted acid, on the residual biomass of Pérola pineapple peel to enhance bioethanol production. Employing an experimental design that incorporates temperature, reaction time, and varying concentrations of organic solvent, the study examines their effects on the susceptibility of the substrate to saccharification for future bioethanol generation. Factors such as alphacellulose, hemicellulose, and lignin were evaluated in triplicate and subjected to statistical analysis using the Tukey test with a confidence level of 95%. Upon application of the pretreatment methods, it was observed that the organosolv solvent approach (utilizing water and ethanol) with sulfuric acid exhibited superior sugar conversion, yielding the highest concentration of xylose at 9.13 g L-1. Additionally, the pretreated biomass contained 1.38 g L 1 of cellobiose, 3.11 g L-1 of arabinose, and 3.76 g L-1 of glucose. This technique demonstrates promising potential for obtaining fermentable sugars crucial for bioethanol production. source secondgeneration second generation crops techniques production temperature time alphacellulose hemicellulose 95 95% methods utilizing ethanol conversion 913 9 13 9.1 L1. L1 1. Additionally 138 38 1.3 cellobiose 311 3 11 3.1 L- arabinose 376 76 3.7 glucose 91 9. 31 3. 37 7

Acetylsalicylic acid (ASA) synthesized in the practical classes of experimental organic chemistry is generally discarded after the classes. Thus, the objective of this work is to find an alternative application for ASA and to promote awareness about the recycling of chemicals in educational and research environments. In addition, it explores the subsequent application of this synthesized ASA in the creation of powdered developers for latent fingerprints. The adopted methodology included the recrystallization of the previously synthesized ASA, followed by the development of three distinct formulations of powdered developers, which include ASA, lignin, and methylene blue. Subsequently, these powders were used to identify latent fingerprints, demonstrating that they are promising substances for such applications. (ASA Thus environments addition fingerprints lignin blue Subsequently applications

Abstract Textile sludge is a waste from the effluent treatment of textile laundries and its incorporation into alternative materials has been proposed as a possibility for its disposal. A systematic search was carried out in literature from this perspective, aiming to observe concentrations of waste material and its preparation, matrices used, technological performance and immobilization of textile waste. The matrices used were mortars, concretes and ceramic bricks, in general, deleterious effects were observed on mechanical characteristics of the materials produced. In concrete and mortars, the fineness had an impact on increase in water demand, which increased mixtures porosity; and organic matter and heavy metals, in cement hydration. Recent studies therefore proposed waste material pre-treatment as a favorable alternative. Increases in porosity also occurred in ceramic bricks, however, due to high organic matter content. Regarding waste immobilization, cementitious materials showed satisfactory performance; ceramic bricks, on the other hand, obtained some results outside the normative limits. Therefore, it is necessary to expand discussions regarding the pre-treatment carried out on textile sludge, as well as its impacts on mechanical and environmental performance. disposal perspective preparation mortars bricks general produced demand metals hydration pretreatment pre however content hand limits Therefore

Resumo Olodo têxtil é um resíduo do tratamento do efluente das lavanderias têxteis e sua incorporação em materiais alternativos tem sido proposta como possibilidade para sua destinação. Foi realizada uma busca sistemática na literatura nesta perspectiva, visando observar as concentrações de material residual e seu preparo, as matrizes utilizadas, o desempenho tecnológico e imobilização do resíduo têxtil. As matrizes empregadas foram argamassas, concretos e tijolos cerâmicos, sendo observados, de maneira geral, efeitos deletérios nas características mecânicas dos materiais produzidos. Em concretos e argamassas, a finura impactou no aumento da demanda de água, o que elevou a porosidade das misturas; e a matéria orgânica e metais pesados, na hidratação do cimento. Estudos recentes propuseram, então, o pré-tratamento do material residual como uma alternativa favorável. Incrementos na porosidade também ocorreram nos tijolos cerâmicos, porém, devido ao elevado teor de matéria orgânica. Quanto a imobilização do resíduo, os materiais cimentícios apresentaram desempenho satisfatório; já os tijolos cerâmicos, obtiveram alguns resultados fora dos limites normativos. Portanto, é necessário ampliar as discussões quanto ao pré-tratamento realizado no lodo têxtil, bem como seus impactos no desempenho mecânico e ambiental. destinação perspectiva preparo utilizadas argamassas cerâmicos observados geral produzidos água misturas pesados cimento propuseram então prétratamento pré favorável porém satisfatório normativos Portanto ambiental

Abstract The organic composition of 65 °% of urban solid waste of the Metropolitan District of Quito originates from food waste, which has negative environmental effects. The purpose of this study was to evaluate the factors related to food waste in homes in the capital and characterize urban solid waste management. The study is quantitative and exploratory. An association analysis was performed for the main categorical variables through calculation of statistical chi squared and an assessment of polychoric relation. A descriptive and multi-scale statistical analyses were performed for focus of the social metabolism to characterize waste management. A noteworthy element was the relation between expenses for purchase of food and non-alcoholic beverages in the last month-household income in the last month (p value < 5 %). Between 2012-2021, the most representative median for waste generation corresponded to the Eugenio Espejo administration, with 141470 t/ year, with a metabolic waste rate of 2.45E-05 (t/year). On the other hand, the Tumbaco administration obtained 30217 t/year and 1.22E-05 t/year, respectively.

Resumen La composición orgánica del 65 % de residuos sólidos urbanos del Distrito Metropolitano de Quito proviene de restos de alimentos, lo que provoca efectos medioambientales negativos. El propósito de esta investigación es evaluar los factores que inciden en el desperdicio de alimentos en los hogares capitalinos y caracterizar la gestión de sus residuos sólidos urbanos. La investigación es cuantitativa de tipo exploratoria. Se realizó un análisis de asociación entre las principales variables categóricas mediante el cálculo del estadístico chi-cuadrado y una evaluación de correlación policórica. Se aplicaron análisis estadístico descriptivo y multiescala del enfoque del metabolismo social para caracterizar la gestión de residuos. Destaca la relación entre el gasto en compra de alimentos y bebidas no alcohólicas en el último mes -ingreso del hogar en el último mes (p valor < 5 %). Entre 2012-2021, la mediana más representativa de generación de residuos corresponde a la administración Eugenio Espejo, con 141 470 t/año, y su tasa metabólica de residuos de 2,45E-05 t/año. En contraste, la administración Tumbaco obtuvo 30 217 t/año y 1,22E-05 t/año, respectivamente.

Resumo A composição orgânica do 65 °% dos resíduos sólidos urbanos do Distrito Metropolitano de Quito provém de restos de alimentos, o qual provoca efeitos negativos ao meio ambiente. O objetivo dessa investigação foi avaliar os fatores incidentes no desperdício de alimentos nos lares da capital e caracterizar a gestão dos resíduos sólidos urbanos. A pesquisa foi quantitativa e exploratória. Fez-se uma análise de associação das variáveis principais com o cálculo do chi-quadrado estatístico e uma avaliação da correlação policórica. Usaram-se análises estadísticos descritivos e multiescala do foco do metabolismo social para caracterizar a gestão dos resíduos. Destacou-se a relação do gasto para a compra de alimentos e bebidas não alcoólicas no último mês -rendas do lar no último mês (p valor < 5 %). Entre os anos 2012-2021, a mediana mais representativa de geração de resíduos foi da administração Eugenio Espejo, com 141 470 t/ano, e uma taxa metabólica de resíduos de 2,45E-05 t/ano. Em contraste, a administração Tumbaco teve 30 217 t/ano e 1,22E-05 t/ano, respetivamente.

Abstract Introduction: Spills of flammable liquids can lead to serious accidents, mainly in industrial plants and on roads. To prevent the spread of spills, various forms of collection are used, such as absorption with porous solids. Agroindustrial waste can be used as sorbent materials for flammable liquids. Objective: To determine the sorption capacity of the residual empty-fruit bunch of oil-palm (Elaeis guineensis) and the macaw palm (Acrocomia sp.) nutshell for four organic flammable liquids. Methods: The residual biomasses of E. guineensis and Acrocomia sp. were assessed as sorbents for spilled fuels (diesel, jet fuel, commercial kerosene, and gasoline). Volumetric measurement of liquid-fuel absorption at 24 ºC was taken during a week. Desorption was measured at 50 ºC as the drying kinetics, by using moisture scales. Results: The sorption capacity of the Acrocomia sp. material was not satisfactory, compared to the E. guineensis residual material, due to differences in the residual architecture of the organic material. This last can absorb 2.4 ± 0.2 cm3 g-1 at 24 ºC, during a one-week period. Diatomite absorbs greater quantities of the organic liquids but, the fluids diffusion at 50 ºC is 0.26 ± 0.09 times more slowly in the mineral matrix, because of the greater pore tortuosity in this mineral matrix. Conclusions: The oil-palm empty fruit bunch of E. guineensis, showed lesser but adequate performance than the sorbing behavior for fire hazard mitigation of diatomite. The nutshell of macaw palm (Acrocomia sp.) did not prove to be useful for this recovery operation.

Resumen Introducción: Los vertidos de líquidos inflamables pueden producir accidentes graves, principalmente en plantas industriales y en carretera. Para prevenir la dispersión de derrames, se utilizan diversas formas de recolecta, como la absorción con sólidos porosos. Residuos agroindustriales pueden ser aprovechados como materiales sorbentes de líquidos inflamables. Objetivo: Determinar la capacidad de absorción de las biomasas residuales del pedúnculo de la palma aceitera (Elaeis guineensis) y del endocarpio del fruto de coyol (Acrocomia sp.) para cuatro líquidos orgánicos inflamables. Métodos: Las biomasas residuales de E. guineensis y de Acrocomia sp. se evaluaron como sorbentes para combustibles derramados (diésel, queroseno de aviación, queroseno comercial y gasolina). Se midió la cantidad de líquido absorbida por las biomasas a 24 ºC durante una semana, y su cinética de desorción a 50 ºC, usando balanzas de secado. Resultados: La propiedad sorbente del material de Acrocomia sp. no fue satisfactoria, comparada con el pedúnculo de E. guineensis, debido a diferencias en arquitectura residual del material orgánico. Esta última biomasa muestra una capacidad de absorción para los combustibles de 2.4 ± 0.2 cm3 g-1 a 24 ºC. La diatomita absorbe mayor cantidad de los combustibles estudiados, pero la difusión de estos fluidos a 50 ºC por la matriz mineral es solo 0.26 ± 0.09 veces lo observado para el material de E. guineensis, como resultado del mayor grado de tortuosidad de los poros de la diatomita. Conclusiones: El pedúnculo de palma aceitera (E. guineensis) mostró un adecuado potencial desempeño para la aplicación pasiva en la mitigación de los riesgos de incendio, con respecto a la diatomita. El endocarpio del fruto de Acrocomia sp. no resultó útil para esta operación de recuperación.

Abstract The soil-crop systems of the peri-urban area allow the recovery of chemical elements from the manure generated in intensive livestock production, reducing the risk of contamination of groundwater. This study evaluated the effect of the application of different doses of feedlot waste compost on the lettuce crop (Lactuca sativa L.) and on the chemical, physicochemical, and biological properties of the soil. In two consecutive years, greenhouse experiments were carried out applying doses equivalent to 128 and 500 kg ha-1 of nitrogen, determining fresh weight and apparent efficiency of nitrogen recovery in the crop, and in the soil, nitrate content, organic matter, activity overall biological, electrical conductivity, and pH. The yield of the lettuce crop increased between 29 and 55%, with apparent N recovery efficiencies of less than 5%. In the soil, the effects were mainly manifested in the first centimeters, with increases in the contents of organic matter, global biological activity, and electrical conductivity. On the other hand, there were no significant changes in the pH or nitrate content at depths greater than those reached by the roots of the crop.

Resumen Los sistemas suelo-cultivo del periurbano permiten recuperar elementos químicos del estiércol generado en la producción pecuaria intensiva, disminuyendo el riesgo de contaminación de aguas subterráneas. Este estudio evaluó el efecto de la aplicación de diferentes dosis de compost de residuos de feedlot en el cultivo de lechuga (Lactuca sativa L.) y en propiedades químicas, fisicoquímicas y biológicas del suelo. En dos años consecutivos se realizaron experimentos en invernadero, aplicando dosis equivalentes a 128 y 500 kg ha-1 de nitrógeno, determinando peso fresco y eficiencia aparente de recuperación de N en el cultivo, y en el suelo, contenido de nitratos, materia orgánica, actividad biológica global, conductividad eléctrica y pH. El rendimiento del cultivo de lechuga se incrementó entre el 29 y 55%, con eficiencias de recuperación aparente de nitrógeno menores al 5%. En el suelo, los efectos se manifestaron principalmente en los primeros centímetros, con aumentos en los contenidos de materia orgánica, actividad biológica global y conductividad eléctrica. Por otro lado, no hubo cambios significativos en el pH ni en el contenido de nitratos a profundidades mayores a la alcanzada por las raíces del cultivo.

Resumen Os sistemas solo-cultivo do periurbano permitem recuperar elementos químicos do estrume gerado na produção pecuária intensiva, disminuindo o risco de contaminação de águas subterrâneas. Este estudo avaliou o efeto da aplicação de diferentes doses de compost de resíduos de feedlot no cultivo de alface (Lactuca sativa L.) e nas propiedades químicas, fisicoquímicas e biológicas do solo. Em dois anos consecutivos realizaram-se experimentos em estufa, aplicando doses equivalentes a 128 e 500 kg ha-1 de nitrogênio, determinando peso fresco e eficiência aparente de recuperação de N no cultivo, e no solo, conteúdo de nitratos, matéria orgânica, atividade biológica global, condutividade elétrica e pH. O rendimento do cultivo de alface incrementou-se entre o 29 e 55%, com eficiências de recuperação aparente de nitrogênio menores ao 5%. No solo, os efeitos manifestaram-se principalmente nos primeiros centímetros, com aumentos nos conteúdos de matéria orgânica, atividade biológica global e condutividade elétrica. Por outro lado, não teve câmbios significativos no pH nem no conteúdo de nitratos em profundidades maiores à conseguida pelas raizes do cultivo.

Abstract: Plastic is widely used and responsible for negative environmental impacts. Such is the case of expanded polystyrene (EPS), a material that presents revaluation challenges due to its low density. The ability of certain insects larvae, such as Tenebrio molitor, to mineralize plastic has been demonstrated, although its insect farming still focuses on obtaining sustainable protein and biofertilizer. This study investigates the influence of an EPS diet on the larval development of T. molitor for 6 months and examines how the diet affects the volume of biofertilizer collected in this period. Trials were developed with three diets, performing periodic measurements and collection of material. The results indicate that larvae fed a combined substrate, as well as those fed an organic diet, demonstrate survival rates of up to 66%. The final length is lower in the inorganic diet (112 mm), and in the other diets it exceeds 162 mm. Larvae on an inorganic diet did not progress to pupal stage, demonstrated a disappointing lowest Feed Conversion Ratio (3.87) and produced less frass (1.28g), compared to the combined diet which recorded 5.11g. The data suggest that plastic entomoremediation works optimally if larvae are raised on a combined diet substrate of EPS and organic elements. This condition not only produces positive results, but also is aligned well with the principles of the circular economy. Therefore, a combined diet proves to be an ideal candidate for tackling EPS waste.

Resumen: El plástico es ampliamente utilizado y responsable de impactos ambientales negativos. Tal es el caso del poliestireno expandido (EPS), que presenta desafíos de revalorización por su baja densidad. Aunque ciertas larvas de insecto, como tenebrio molitor, han demostrado la capacidad de mineralizar plásticos, la insecticultura de estos aún se enfoca en obtener proteína sostenible y biofertilizante. En este estudio, se investiga la influencia de una dieta de EPS en el desarrollo larval de T. molitor durante 6 meses, y se examina cómo la dieta afecta el volumen de biofertilizante recolectado en este lapso. Se desarrollaron ensayos con tres dietas, realizando mediciones y recolección de material de manera periódica. Los resultados indican que las larvas alimentadas con un sustrato combinado, así como aquellas con una dieta orgánica, demuestran tasas de supervivencia de hasta 66%. La longitud final es inferior en la dieta inorgánica (112mm), y en las otras dietas superan los 162 mm. Las larvas de una dieta inorgánica no progresaron a pupa, demostraron un Factor de Conversión de Alimento desalentador (3,87) y produjeron menor cantidad de frass/biofertilizante (1,28g), en comparación con la dieta combinada que registró 5,11g. Los datos sugieren que la entomoremediación plástica funciona óptimamente si se cría larvas en un sustrato combinado de EPS y elementos orgánicos. Dicha condición no solo produce resultados positivos, sino que se alinea con los principios de economía circular. En consecuencia, se demuestra que una dieta combinada es ideal para abordarla como opción en el tratamiento de residuos de EPS.

ABSTRACT Species of the genus Capsicum, especially peppers, are economically important and widely consumed worldwide. The application of animal waste as organic fertilizer is a simple and cost-effective technique for applying nutrients to the soil. Combining cattle manure with humic substances can stimulate plant metabolism, resulting in increased nutrient absorption and assimilation. Therefore, the objective in this study was to evaluate doses of cattle manure combined with humic substances for stimulating plant metabolism and morphophysiological and nutritional processes in pepper plants. A randomized block design with four replicates was used, in a 4×3 factorial arrangement consisting of four cattle manure doses (8, 18, 28, and 38 Mg ha-1) and three humic substance doses (0, 8, and 12 kg ha-1). Humic substances (12 kg ha-1) enhanced gas exchange, increasing net photosynthesis (34.2%), stomatal conductance (12.7%), instantaneous water use efficiency (15.87%), instantaneous carboxylation efficiency (37.37%), and absorbed energy conversion efficiency (23.53%). Cattle manure adequately met the crop’s nutritional requirements, while humic substances increased the number and thickness of plant root hairs. The most effective combination to increase photosynthetic activity in pepper plants was 38 Mg ha-1 of cattle manure combined with 8 kg ha-1 of humic substances. Humic substances stimulated positive morphophysiological responses in organic pepper crops, which resulted in increased production. Capsicum peppers worldwide costeffective cost soil assimilation Therefore used 43 4 3 4× (8 18 28 ha1 ha 1 0, 0 (0 ha1. . (1 exchange 34.2%, 342 34.2% , 34 2 (34.2%) 12.7%, 127 12.7% 7 (12.7%) 15.87%, 1587 15.87% 15 87 (15.87%) 37.37%, 3737 37.37% 37 (37.37%) 23.53%. 2353 23.53% 23 53 (23.53%) crops crop s requirements hairs ha- production ( 34.2 (34.2% 12.7 (12.7% 158 15.87 (15.87% 373 37.37 (37.37% 235 23.53 5 (23.53% 34. (34.2 12. (12.7 15.8 (15.87 37.3 (37.37 23.5 (23.53 (34. (12. 15. (15.8 37. (37.3 23. (23.5 (34 (15. (37. (23. (3 (15 (37 (23 (2

RESUMO As espécies do gênero Capsicum, principalmente pimentão, possuem grande relevância econômica e são amplamente consumidas em todo o mundo. A aplicação de dejetos animais como fertilizante orgânico é uma técnica simples e barata de distribuição de nutrientes ao solo. O esterco bovino em associação com substâncias húmicas pode estimular o metabolismo das plantas, resultando no aumento da absorção e assimilação de nutrientes. Portanto, o objetivo neste estudo foi avaliar doses de esterco bovino associado a substâncias húmicas para estimular o metabolismo vegetal, a morfofisiologia e a nutrição em pimentões. O delineamento utilizado foi em blocos casualizados, distribuídos em arranjo fatorial 4 x 3, referente a quatro doses de esterco bovino (8, 18, 28 e 38 t ha-1) e três doses de substâncias húmicas (0, 8 e 12 kg ha-1), com quatro repetições. Substâncias húmicas (12 kg ha-1) estimularam as trocas gasosas, aumentando a fotossíntese líquida (34,2%), a condutância estomática (12,7%), a eficiência instantânea do uso da água (15,87%), a eficiência instantânea de carboxilação (37,37%) e a eficiência efetiva da absorção conversão de energia (23,53%). O esterco bovino supriu adequadamente as necessidades nutricionais da cultura, enquanto as substâncias húmicas aumentaram o número e a espessura dos pelos radiculares do pimentão. A combinação de manejo mais eficaz para aumentar a atividade fotossintética em pimentões é 38 t ha-1 de esterco combinado com 8 kg ha-1 de substâncias húmicas. As substâncias húmicas estimularam respostas morfofisiológicas positivas no cultivo de pimentão orgânico, o que resultou no aumento da produção. Capsicum mundo solo plantas Portanto vegetal casualizados 3 8, (8 18 2 ha1 ha 1 0, 0 (0 ha1, , repetições (1 gasosas 34,2%, 342 34,2% 34 (34,2%) 12,7%, 127 12,7% 7 (12,7%) 15,87%, 1587 15,87% 15 87 (15,87%) 37,37% 3737 37 (37,37% 23,53%. 2353 23,53% . 23 53 (23,53%) cultura ha- produção ( 34,2 (34,2% 12,7 (12,7% 158 15,87 (15,87% 37,37 373 (37,37 235 23,53 5 (23,53% 34, (34,2 12, (12,7 15,8 (15,87 37,3 (37,3 23,5 (23,53 (34, (12, 15, (15,8 37, (37, 23, (23,5 (34 (15, (37 (23, (3 (15 (23 (2

Abstract The aim of the present study was to assess the agronomic performance and chemical composition of soil cultivated with palisade grass (Urochloa brizantha cv. Marandu) subjected to growing doses of liquid blood waste. The experiment followed the completely randomized blocks design with six treatments and four repetitions. The following doses of processed liquid blood waste were applied to test palisade grass’ yield: 0, 150, 300, 450 and 600 m3 ha-1. In addition, it was used in conjunction with chemical fertilization at a rate of 50 kg ha-1 of P2O5 and 100 kg ha-1 of N (this treatment was not managed with liquid blood residue). Palisade grass forage yield was influenced by the fertilization strategy (P<0.001) - the highest values observed for this variable were recorded under blood waste doses of 450 m3 ha-1 and 600 m3 ha-1. The 0.0 - 0.20 m soil layer affect the organic matter fraction. On the other hand, phosphorus (P) content presented differences between fertilization strategies; thus, it was possible observing that the waste dose of 450 m3 ha-1 accounted for the highest availability of nutrients. The application of blood liquid waste as alternative source of organic fertilizers can be feasible, because it promotes significant increase in forage mass.

Resumen El objetivo fue evaluar el comportamiento agronómico y la composición química de suelos cultivados con pasto insurgente (Urochloa brizantha cv. Marandu) sometido a dosis crecientes de residuos sanguíneos líquidos. El experimento siguió el diseño de bloques completamente al azar con seis tratamientos y cuatro repeticiones. Las siguientes dosis de residuos sanguíneos líquidos procesados se aplicaron para analizar el rendimiento del pasto insurgente: 0, 150, 300, 450 y 600 m3 ha-1. Además, se utilizó en conjunto con la fertilización química a razón de 50 kg ha-1 de P2O5 y 100 kg ha-1 de N (este tratamiento no se manejó con residuos sanguíneos líquidos). El rendimiento de forraje de pasto insurgente estuvo influenciado por la estrategia de fertilización (P<0.001) - los valores más altos observados para esta variable se registraron bajo dosis de residuos sanguíneos de 450 m3 ha-1 y 600 m3 ha-1. La capa de suelo de 0.0 a 0.20 m afecta a la fracción de materia orgánica. Por otro lado, el contenido de fósforo (P) presentó diferencias entre las estrategias de fertilización; así, fue posible observar que la dosis de residuos de 450 m3 ha-1 resultó en la mayor disponibilidad de nutrientes. La aplicación de residuos sanguíneos líquidos como fuente alternativa de fertilizantes orgánicos puede ser factible, ya que promueve un aumento significativo de la masa forrajera.

ABSTRACT Introduction: An opportunity for the local development of Placetas, a municipality in the central region of Cuba, is the use of biogas generated from the swine waste from its Genetic Center as an energy alternative for the drying of different materials available in the area. Objective: To present a technological proposal for a multipurpose dryer for grains, tubers, protein plants and organic fertilizer, using biogas generated from swine waste as an energy source. Materials and Methods: The physicochemical parameters of the streams involved were identified, appropriate technologies were selected, process demands were estimated, and a rotary dryer was designed using the high-temperature method. Results and Discussion: A direct drying scheme was selected in a rotary equipment, ensuring ease in the handling of non-adherent granular solids and using mixtures of air and gases from biogas combustion as an energetic alternative. The technological proposal allows the treatment of 300 kg/h of wet material. It satisfies the drying service provided to productive forms of the area and their own productive needs. For tubers and protein plants, according to their initial humidity, a semi-continuous drying scheme was proposed with two passes and a hopper for storage and recycling of the material. The rotary dryer requires 0.7 m in diameter and 3.0 m in length. Conclusions: The developed proposal satisfies the productive demands with safety, energy efficiency, productivity and sustainability, contributing to the reduction of environmental impact and to the increase of the technical-economic effectiveness.

RESUMEN Introducción: Una oportunidad para el desarrollo local de Placetas, un municipio en la región central de Cuba, es el aprovechamiento del biogás generado con los residuales porcinos de su Centro Genético como alternativa energética para el secado de diferentes materiales disponibles en la zona. Objetivo: Presentar una propuesta tecnológica de secadero multipropósito para granos, tubérculos, plantas proteicas y fertilizante orgánico, que utiliza biogás generado con residuales porcinos como fuente energética. Materiales y Métodos: Se identificaron los parámetros físico-químicos de las corrientes involucradas, se seleccionaron las tecnologías adecuadas, se estimaron las demandas del proceso y se diseñó un secador rotatorio por el método de alta temperatura. Resultados y Discusión: Se seleccionó un esquema de secado directo en un equipo rotatorio, garantizando facilidad en el manejo de los sólidos granulares no adherentes y utilizando mezclas de aire y gases de la combustión del biogás como alternativa energética. La propuesta tecnológica permite tratar 300 kg/h de material húmedo. Se satisface la prestación del servicio de secado a formas productivas de la zona y las necesidades productivas propias. Para tubérculos y plantas proteicas, atendiendo a su humedad inicial, se propuso un esquema de secado semicontinuo con dos pases y una tolva para el almacenamiento y reciclo del material. El secador rotatorio requiere 0,7 m de diámetro y de 3,0 m de longitud. Conclusiones: La propuesta desarrollada satisface las demandas productivas con seguridad, eficiencia energética, productividad y sostenibilidad, contribuyendo a la reducción del impacto ambiental y al incremento de la efectividad técnico económica.

ABSTRACT Municipal biowaste has a high potential for agricultural use. However, it requires an additional amendment to increase the nutritional content used during the composting process. The purpose of this study was to investigate the selection of compost-enhancing amendments from municipal biowaste using bibliometric and multicriteria analysis. The municipality of Yopal (Casanare, Colombia) was chosen as a case study. Using a search equation in the Scopus and Web of Science databases over five years (2018-2022), 53 publications were discovered, from which 25 were chosen for a full review to identify alternatives for amendment. Ashes, rice husks, sawdust, sugarcane bagasse, tree pruning waste, and alfalfa hay were assessed as amendment substitutes. Criteria such as financial cost, accessibility to acquire the amendment, nitrogen, phosphorus, and carbon contribution were used in the analysis of hierarchical processes. Tree pruning waste was the best option based on the criteria chosen because it is easily accessible and contributes with carbon and nitrogen (C/N: 13) to composting. Factors such as cost and affordability influence the physical and chemical characteristics that an amendment brings to the composting of municipal biowaste. use However process compostenhancing compost enhancing Casanare, Casanare (Casanare Colombia 20182022, 20182022 2018 2022 , (2018-2022) 5 discovered 2 Ashes husks sawdust bagasse substitutes phosphorus processes C/N CN C N (C/N 13 2018202 201 202 (2018-2022 1 201820 20 (2018-202 20182 (2018-20 (2018-2 (2018- (2018 (201 (20 (2 (

RESUMO Os biorresíduos municipais têm um elevado potencial para utilização agrícola. No entanto, requer uma alteração adicional para aumentar o conteúdo nutricional utilizado durante o processo de compostagem. O objetivo deste estudo foi investigar a seleção de aditivos melhoradores de compostagem a partir de resíduos biológicos municipais, utilizando análise bibliométrica e multicritério. O município de Yopal (Casanare, Colômbia) foi escolhido como estudo de caso. Utilizando uma equação de busca nas bases de dados Scopus e Web of Science ao longo de cinco anos (2018-2022), foram descobertas 53 publicações, das quais 25 foram escolhidas para uma revisão completa para identificar alternativas de alteração. Cinzas, cascas de arroz, serragem, bagaço de cana-de-açúcar, podas de árvores e feno de alfafa foram testados como substitutos de emendas. Critérios como custo financeiro, acessibilidade para aquisição do aditivo, aporte de nitrogênio, fósforo e carbono foram utilizados na análise dos processos hierárquicos. A poda de árvores foi a melhor opção pelos critérios escolhidos por ser de fácil acesso e contribuir com carbono e nitrogênio (C/N: 13) para a compostagem. Fatores como custo e acessibilidade influenciam as características físicas e químicas que uma alteração traz para a compostagem de biorresíduos municipais. agrícola entanto multicritério Casanare, Casanare (Casanare Colômbia caso 20182022, 20182022 2018 2022 , (2018-2022) 5 publicações 2 Cinzas arroz serragem canadeaçúcar, canadeaçúcar cana açúcar, açúcar cana-de-açúcar emendas financeiro aditivo hierárquicos C/N CN C N (C/N 13 2018202 201 202 (2018-2022 1 201820 20 (2018-202 20182 (2018-20 (2018-2 (2018- (2018 (201 (20 (2 (

ABSTRACT: Persistent organic pollutants (POPs) represent a significant environmental problem due to their toxicity, with a high capacity to persist in the environment, resistance to conventional degradation methods, the ability to accumulate in living organisms and their magnification in food chains or food. In this review article, the impacts on health and environmental components are examined. Strategies and measures for control, mitigation and/or minimization of POPs are also addressed. Agricultural and industrial activities, inadequate final disposal of solid waste and lack of wastewater treatment are identified as the main sources of POP emissions. In addition, innovative and promising technologies are analyzed, such as nanotechnology, bioremediation, rhizoremediation, biochar, chromatography techniques, ultrasound, among others, for the adequate treatment of POPs. The review highlights both the advantages and limitations of these technologies, pointing out areas that still require developments to achieve effective treatments. More economical and ecological alternatives are also mentioned to counteract the impacts of POPs.

RESUMEN: Los contaminantes orgánicos persistentes (COP) representan un problema ambiental significativo debido a su toxicidad, con una alta capacidad para persistir en el entorno, resistencia a los métodos de degradación convencionales, la capacidad de acumulación en organismos vivos y su magnificación en las cadenas tróficas o alimentarias. En este artículo de revisión, se examinan los impactos en la salud y en los componentes medio ambientales. También se abordan las estrategias y medidas de control, mitigación y/o minimización de los COP. Se identifica a las actividades agrícolas, industriales, la inadecuada disposición final de los residuos sólidos y la falta de tratamiento de las aguas residuales como las principales fuentes de emisión de COP. Además, se analizan tecnologías innovadoras y prometedoras, como la nanotecnología, biorremediación, rizorremediación, biocarbón, técnicas de cromatografía, ultrasonido, entre otras, para el tratamiento adecuado de los COP. La revisión destaca tanto las ventajas como las limitaciones de estas tecnologías, señalando áreas que aún requieren desarrollos para lograr tratamientos eficaces. También se mencionan alternativas más económicas y ecológicas, para contrarrestar los impactos de los COP.