Nanoparticles of TiO2 doped with low amount of Fe were synthesized from natural ilmenite obtained from alluvial gold mine wastes. The obtained TiO2 were characterized using X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier-transform infrared spectroscopy (FTIR), UV-Vis diffuse reflectance, thermogravimetric analysis/differential scanning calorimetry (TGA/DSC), N2 adsorption-desorption isotherms, transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The results confirm the formation of mesoporous TiO2 nanoparticles in anatase phase with 0.05 wt.% of iron possibly replacing some titanium places. All the characterizations were performed to the synthesized solid and the reference materials (TiO2 anatase and Degussa P25). The photocatalytic activity of both the synthesized solid and references were evaluated in the photo-oxidation of cyanide in aqueous medium under UV illumination. An experimental design type Box-Behnken was performed choosing three different parameters: the initial concentration of cyanide (50, 150 and 250 ppm) the catalyst load (0.1, 0.5 and 1.0 g L-1) and the oxygen source. The percentage of cyanide conversion was chosen as response in the design obtaining as optimal conditions [CN-]0 = 50 ppm, catalyst load = 0.6 g L-1 and air bubbling. Under these conditions it was reached 32, 32 and 89% of cyanide conversion for Fe-TiO2 synthesized, TiO2 anatase and Degussa P25, respectively. TiO wastes Xray X ray XRD, XRD , (XRD) XRF, XRF (XRF) Fouriertransform Fourier transform FTIR, FTIR (FTIR) UVVis Vis reflectance analysisdifferential analysis differential TGA/DSC, TGADSC TGA/DSC TGA DSC (TGA/DSC) N adsorptiondesorption adsorption desorption isotherms TEM (TEM XPS. XPS . (XPS) 005 0 05 0.0 wt wt. places (TiO P25. P25 P P25) photooxidation photo oxidation illumination BoxBehnken Box Behnken parameters 50, (50 15 25 ppm 0.1, 01 1 (0.1 5 0. 10 1. L1 L source CN0 CN [CN-] 06 6 L- bubbling 3 89 FeTiO2 FeTiO Fe-TiO respectively (XRD (XRF (FTIR (TGA/DSC (XPS 00 P2 (5 2 0.1 (0. [CN- 8 ( (0 [CN

Abstract In Ecuador, Artisanal and Small-Scale Mining, MAPE, is an activity of national relevance. Historically there are three provinces with great potential and mining tradition, which are: El Oro, Zamora Chinchipe and Azuay. In this sense, in the province of El Oro, a large percentage of the economically active population depends directly or indirectly on the exploitation of highly profitable minerals. The key aspects for the development of underground operations of the MAPE regime are the drilling and blasting activities, where there is a great opportunity for improvement, efficiently managing the design of the grid, the execution of the drilling, the amount of explosive and the way it is charged, which are the factors that define the result of the blasting; same that is valued in function of the depth of cut or advance and of the uniformity of the structure of the section. For the development of this research, the baseline survey was carried out through technical visits to the study sector (Zaruma - Portovelo mining district), where traditional work procedures were observed, and then, based on the experimental method, technical variations were made in regarding the firing diagram, specific charge, specific perforation and type of explosive. These traditional (empirical) procedures, based on the driller's field experience, cause, among other things, the inefficiency of the advance, problems to maintain the dimensions of the section, over breaking of the working fronts, and one of the most relevant factors, the insecurity of the personnel who in many cases remain inside the mine for more than 10 hours.The main results show that the best tests were those that used the emulsion/ANFO (Amonium Nitrate Fuel Oil) combination, obtaining an advance percentage of approximately 95%, considered optimal within the operation. It was also evidenced that the Ammonium Nitrate commonly used in ASM needs a specific charge of greater power to meet the objective of the blasting.

Resumen En Ecuador, la Minería Artesanal y de Pequeña Escala, MAPE, es una actividad de relevancia nacional. Históricamente existen tres provincias de amplio potencial y de tradición minera, que son: El Oro, Zamora Chinchipe y Azuay. En este sentido, en la provincia de El Oro, gran porcentaje de la población económicamente activa, depende directa o indirectamente de la explotación de minerales de alta rentabilidad. Uno de los aspectos clave para el desarrollo de las operaciones subterráneas del régimen MAPE, son las actividades de perforación y voladura, en donde existe una gran oportunidad de mejora, gestionando de manera eficiente el diseño de la malla, la ejecución de la perforación, la cantidad de explosivo y la forma de cargado, que son los factores que definen el resultado de la voladura; mismo que es valorado en función de la profundidad de corte o avance y de la uniformidad de la estructura de la sección. Para el desarrollo de esta investigación se realizó el levantamiento de la línea base mediante visitas técnicas al sector de estudio (distrito minero Zaruma - Portovelo), donde se observaron los procedimientos tradicionales de trabajo, para luego, con base al método experimental realizar variaciones técnicas en cuanto al diagrama de disparo, carga específica, perforación específica y tipo de explosivo. Estos procedimientos tradicionales (empíricos), basados en la experiencia de campo del perforista, ocasiona entre otras cosas la ineficiencia del avance, problemas para mantener las dimensiones de la sección, sobre rotura de los frentes de trabajo, y uno de los factores más relevantes, la inseguridad del personal que en muchos casos permanece en el interior de la mina por más de 10 horas. Entre los principales resultados se obtuvo que los mejores ensayos fueron los que se utilizó la combinación emulsión/ANFO (Amonium Nitrate Fuel Oil), obteniendo un porcentaje de avance de aproximadamente 95%, considerado dentro de la operación como óptimo. Así también se evidenció que el Nitrato de Amonio de uso habitual en la MAPE, necesita una carga específica de mayor poder para cumplir con el objetivo de la voladura.

Probability-based empirical methods were employed as an alternative approach to predicting uncertainties associated with rock mass properties. The focus was on developing probabilistic spreadsheets to forecast rock mass classification indexes. Histograms were constructed to describe the best distribution in predicting rock mass properties. The developed models also offer utility in predicting the impact of discontinuities within the rock mass on rock strength and rock mass classification systems. Statistical analyses identified volumetric joint count, joint spacing, joint frequency, and rock strength as the most influential parameters. Moreover, the statistical analysis revealed varying degrees of correlation among different rock mass properties. While some properties demonstrated significant correlations suitable for modelling, others did not align well with any correlation model. The results highlight the need for a comprehensive approach to rock mass characterization, considering multiple factors beyond volumetric joint count. Geological complexities, including tectonic activity and weathering processes, may obscure direct correlations. These results emphasize the importance of empirical modelling and detailed site investigations for accurate assessment of rock mass quality and stability in the Himalaya.

RESUMEN En la Amazonía ecuatoriana, cada día son mayores los desafíos para la identificación de especies fitorremediadoras que disminuyan la contaminación por metales pesados producto de la actividad minera. El objetivo de este trabajo fue evaluar el potencial bioacumulador de metales pesados de tres especies forestales de rápido crecimiento (Ochroma pyramidale, Piptocoma discolor y Bambusa vulgaris) en un área de extracción minera, en la comunidad Yutzupino, Napo para la restauración. Se recolectaron muestras de hoja y suelo para determinar la concentración de metales pesados (Cd, Pb, Fe y Ni), mediante espectrometría de absorción atómica y se calculó el factor de bioconcentración (FBC). Los análisis foliares mostraron que B. vulgaris presentó mayor concentración de Ni (6,89 mg kg-1) y Fe (156,33 mg kg-1) y P. discolor contenía Cd (0,35 mg kg-1) y Pb (55,67 mg kg -1). Los análisis de suelos mostraron un patrón de variación en B. vulgaris superior en Cd, Ni y Pb y en O. pyramidale para Fe. El factor de bioconcentración permitió identificar la capacidad acumuladora de las especies, lo que sugiere que P. discolor puede ser utilizada como especie fitorremediadora para sitios contaminadas por Cd y Pb, O. pyramidale para Ni y B. vulgaris para Fe.

RESUMO Na Amazônia equatoriana, os desafios para a identificação de espécies de fitorremediação para reduzir a contaminação por metais pesados provenientes de atividades de mineração aumentam a cada dia. O objetivo deste trabalho foi avaliar o potencial bioacumulativo de metais pesados de três espécies florestais de crescimento rápido (Ochroma pyramidale, Piptocoma discolor e Bambusa vulgaris) em uma área de extração de mineração na comunidade de Yutzupino, Napo, para restauração. Amostras de folhas e de solo foram coletadas para determinar a concentração de metais pesados (Cd, Pb, Fe e Ni) por espectrometria de absorção atômica e o fator de bioconcentração (BCF) foi calculado. A análise das folhas mostrou que a B. vulgaris tinha concentrações mais altas de Ni (6,89 mg kg-1) e Fe (156,33 mg kg-1) e a P. discolor continha Cd (0,35 mg kg-1) e Pb (55,67 mg kg -1). As análises do solo mostraram um padrão de variação em B. vulgaris maior em Cd, Ni e Pb e em O. pyramidale para Fe. O fator de bioconcentração identificou a capacidade de acumulação das espécies, sugerindo que P. discolor pode ser usada como uma espécie de fitorremediação para locais contaminados com Cd e Pb, O. pyramidale para Ni e B. vulgaris para Fe.

ABSTRACT In the Ecuadorian Amazon, the challenges for identifying, phytoremediation species that reduce heavy metal contamination resulting from mining activity are increasing every day. The objective of this work was to evaluate the bioaccumulator potential of heavy metals of three fast-growing forest species (Ochroma pyramidale, Piptocoma discolor and Bambusa vulgaris) in a mining extraction area, in the Yutzupino community, Napo for restoration. Leaf and soil samples were collected to determine the concentration of heavy metals (Cd, Pb, Fe and Ni) using atomic absorption spectrometry and the bioconcentration factor (BCF) was calculated. Leaf analyzes showed that B. vulgaris presented a higher concentration of Ni (6.89 mg kg-1 ) and Fe (156.33 mg kg-1 ) and P. discolor contained Cd (0.35 mg kg-1 ) and Pb (55.67 mg kg -1 ). Soil analyzes showed a pattern of variation in B. vulgaris superior in Cd, Ni and Pb and in O. pyramidale for Fe. The bioconcentration factor allowed identifying the accumulating capacity of the species, which suggests that P. discolor may be used as a phytoremediation species for sites contaminated by Cd and Pb, O. pyramidale for Ni and B. vulgaris for Fe.

Abstract Mining is the largest economic activity in Peru, contributing a considerable percentage of the country's Gross Domestic Product. However, the process of this activity evidences several socio-environmental conflicts. The generation of mining waste or expressed as mining tailings from the various processes is a latent threat that affects the spheres of sustainable development. The objective of this study was to propose the valorization of mining tailings as aggregates for road construction in the Andean region of Peru under a circular economy approach. Consequently, several analyses were carried out to evaluate its viability, such as the meteorological factor of precipitation, acidity or alkalinity, elements present in the sample, granulometry, California Bearing Ratio (CBR) and Marshall test. The results have shown that the proposal complies with the parameters established at the national level with a stability of 877.67 kg and a 25% utilization of mine tailings. In conclusion, the use of mine tailings as aggregates for construction is a viable proposal for road construction under a circular economy approach. Finally, the analysis of the valorization of mining waste in other elements of the construction sector is recommended to continue promoting the circular economy and sustainable development.

Resumen La minería en el Perú es la más grande actividad económica aportando un porcentaje considerable al Producto Bruto Interno nacional. Sin embargo, el proceso de esta actividad evidencia diversos conflictos socio-ambientales. La generación de residuos mineros o expresados como relaves mineros provenientes de los diversos procesos es una amenaza latente que afecta las esferas del desarrollo sostenible. Este estudio tuvo como objetivo la propuesta de valorización de relaves mineros como áridos para la construcción de carreteras en la región andina del Perú bajo un enfoque de economía circular. En consecuencia, se realizó diversos análisis para evaluar su viabilidad como el factor meteorológico de precipitación, acidez o alcalinidad, elementos presentes en la muestra, granulometría, California Bearing Ratio (CBR) y prueba Marshall. Los resultados han demostrado que la propuesta cumple con los parámetros establecidos a nivel nacional con una estabilidad de 877,67 kg y un aprovechamiento del 25% de los relaves mineros. En conclusión, el uso de relaves mineros como áridos para la construcción es una propuesta viable para la construcción de carreteras bajo un enfoque de economía circular. Finalmente, se recomienda el análisis de valorización de residuos mineros en otros elementos del sector construcción para continuar promoviendo la economía circular y desarrollo sostenible.

Resumo Los usuarios de internet en todo el mundo pasan un promedio de 2 horas y 25 minutos al día en las redes sociales, por lo que técnicas como el análisis del sentimiento son aplicadas a sus redes sociales, la cual es utilizada para la identificación y clasificación de las emociones empleadas en actividades como investigación de mercados, monitoreo de la reputación de marca, medición de la satisfacción del cliente, entre otros. Esta comunicación pretende determinar la importancia y utilidad del análisis de sentimiento a través de la minería de datos como una herramienta relevante para conocer tendencias de opinión y sentimiento de referentes comunicacionales. La metodología utilizada es de corte cualitativo bajo el método del estudio de caso. Se utilizó Twitter como fuente para la recopilación de información y para su análisis se empleó el software de minería de datos RapidMiner con el operador para análisis de sentimiento. Como parte de las conclusiones, se observa que es posible afirmar que el análisis del sentimiento a través de la minería de datos es una herramienta útil y valiosa para la toma de decisiones sobre las estrategias comunicacionales que pueden llevarse a cabo, no solo en el turismo sino en cualquier actividad que busque posicionarse en la mente del consumidor.

Abstract Internet users around the world spend an average of 2 hours and 25 minutes a day on social networks, so techniques such as sentiment analysis are applied to their social networks, which is used for the identification and classification of the emotions used in activities such as market research, brand reputation monitoring, customer satisfaction measurement, among others. This communication aims to determine the importance and usefulness of sentiment analysis through data mining as a relevant tool to know opinion trends and sentiment of communication referents.The methodology used is qualitative under the case study method. Twitter was used as a source for the collection of information and for its analysis the data mining software RapidMiner was used with the operator for sentiment analysis. As part of the conclusions, it is observed that it is possible to affirm that the analysis of sentiment through data mining is a useful and valuable tool for decision-making on communication strategies that can be carried out, not only in tourism, but in any activity that seeks to position itself in the mind of the consumer.

ABSTRACT Vermiculite mining residues, although of low solubility, contain nutrients such as calcium, magnesium, and potassium at concentrations that allow their agricultural use. Beneficial bacteria can increase the solubility of this waste and its efficiency. The objective of the present study was to evaluate the influence of bio-inoculation of vermiculite residue, associated with cattle manure, on the release of nutrients and initial growth of maize. A completely randomized design was performed in a greenhouse with seven treatments and four replications. The treatments were: T1 - soil without fertilization; T2 - soil fertilized with soluble sources of nutrients (conventional fertilization); T3 - application of vermiculite residue (VR); T4 - VR enriched with cattle manure (CM); T5 - VR + CM with Bacillus subtilis; T6 - VR + CM + B. amyloliquefaciens, and T7 - VR + CM +B. subtilis + B. amyloliquefaciens). Regardless of the use of cattle manure or beneficial microorganisms, vermiculite mining waste increased the availability of Ca and K in the soil, but was not able to match the soluble sources of nutrients. Mining waste associated with cattle manure and beneficial microorganisms (B. subtilis and B. amyloliquefaciens) increased microbial activity and enhanced the release of available calcium for maize. VR increased the growth and the dry mass production of maize compared to the non-fertilized soil, but was consistently inferior to conventional fertilizer. residues magnesium efficiency bioinoculation bio inoculation replications were T fertilization fertilization) (VR) (CM) B amyloliquefaciens +B amyloliquefaciens. . (B nonfertilized non fertilizer (VR (CM

RESUMO Os resíduos da mineração de vermiculita, embora de baixa solubilidade, contêm nutrientes como cálcio, magnésio e potássio em concentrações que permitem seu uso agrícola. Bactérias benéficas podem aumentar a solubilidade deste resíduo e sua eficiência. Objetivou-se avaliar a influência da bioinoculação do resíduo de vermiculita, associado ao esterco bovino, na liberação de nutrientes e no crescimento inicial do milho. Foi realizado delineamento inteiramente casualizado em casa de vegetação com sete tratamentos e quatro repetições. Os tratamentos foram: T1 - solo sem adubação; T2 - solo adubado com fontes solúveis de nutrientes (fertilização convencional); T3 - aplicação de resíduo de vermiculita (VR); T4 - VR enriquecido com esterco bovino (CM); T5 -VR+CM com Bacillus subtilis; T6 - VR + CM + B. amyloliquefaciens e T7 - VR + CM + B. subtilis + B. amyloliquefaciens). O VR aumentou a disponibilidade de Ca e K no solo, porém seu desempenho foi inferior às fontes solúveis. Independentemente da utilização de esterco bovino ou de microrganismos benéficos, os resíduos da mineração de vermiculita aumentaram a disponibilidade de Ca e K no solo, mas não foram capazes de igualar as fontes solúveis de nutrientes. Os resíduos de mineração associados ao esterco bovino e aos microrganismos benéficos (B. subtilis e B. amyloliquefaciens) aumentaram a atividade microbiana e aumentaram a liberação de cálcio disponível para o milho. Os resíduos da mineração de vermiculita aumentaram o crescimento e a produção de massa seca do milho em comparação ao solo não fertilizado, mas foram consistentemente inferiores ao fertilizante convencional. agrícola eficiência Objetivouse Objetivou se repetições T adubação fertilização convencional convencional) (VR) (CM) VR+CM VRCM B amyloliquefaciens. . (B fertilizado (VR (CM

Over the years the study of the quantitative structure-activity relationship (QSAR) has transformed from a simple regression analysis to the implementation of machine learning (ML) with multiple statistics. Today ML-based QSAR models are quite important and play a notable role in drug design and screening, property prediction, biological activity, etc. ML methods applied to QSAR build classification or regression models to describe/predict the complex relationships between the chemical structure of molecules and biological activity. Even with the increase in scientific publications addressing this topic written in Portuguese, there is still a shortage of scientific articles explaining ML techniques applied to QSAR, how to build models, the types of models, algorithms, for the Brazilian scientific community. And to fill this need, we intend to approach the subject in a simple and didactic way for students and researchers who are starting in this very promising and important area. We will describe the fully explained theory of machine learning by applying QSAR, abstracting the complexity, and well-illustrated. structureactivity activity (QSAR (ML statistics MLbased based screening prediction etc describepredict predict Portuguese algorithms community need area complexity wellillustrated. wellillustrated well illustrated. illustrated well-illustrated

ABSTRACT Tropical forests have the highest rates of net primary productivity (NPP) in terrestrial ecosystems and, therefore, may contribute significantly to the mitigation of global climate change. Although NPP is influenced by soil fertility, and recently, in some regions, mining activity in forest ecosystems has intensified. Little is known about how soils determine the restoration of NPP in forests degraded by mining. We evaluated the influence of soil nutrients on wood NPP of post-mining forests in the biogeographic Chocó region (Colombia), with emphasis on the effects of nitrogen (N) and phosphorus (P) limitations in post-mining forests under successional stages of 12-15 or 30-35 years. For this, permanent plots were established in secondary post-mining forests in Jigualito (Colombian Pacific), the wood NPP (accumulated and current) was evaluated, and it was related to soil properties such as organic matter (OM), acidity, Al, total N, available P, magnesium (Mg), potassium (K), calcium (Ca), and texture. An accumulated wood NPP of 0.72 t ha-1 yr-1 was recorded in post-mining forests 12-15 years old. Meanwhile, in post-mining forests of 30-35 years, the accumulated wood NPP was 6.52 t ha-1 yr-1. The current wood NPP was 4.25 t ha-1 yr-1 in post-mining forests with 30-35 years of recovery. Accumulated NPP positively correlated with soil OM, total N, Ca, Mg, and effective cation exchange capacity–ECEC in post-mining forests. In post-mining forests, a slow recovery of the wood NPP was denoted in the first years. Soil nutrients determined the wood NPP, and a multiple limitation of nutrients with the succession was observed, which corroborates the need to restore the degraded ecosystem in the region. (NPP therefore change fertility recently regions intensified postmining post Colombia, Colombia , (Colombia) N (N P (P 1215 12 15 12-1 3035 30 35 30-3 this Colombian Pacific, Pacific Pacific) OM (OM) acidity Al Mg (Mg) K, K (K) Ca (Ca) texture 072 0 72 0.7 ha1 ha 1 ha- yr1 yr yr- old Meanwhile 652 6 52 6.5 yr1. 1. 425 4 25 4.2 capacityECEC capacity ECEC observed (Colombia 121 12- 303 3 30- (OM (Mg (K (Ca 07 7 0. 65 5 6. 42 2 4.

Abstract Artisanal and small-scale gold mining can occur on land or in riverbeds. However, the activity needs to be supported by a Mining Permit, issued by the Agência Nacional de Mineração, which is the Brazilian institution responsible for mining management, and the appropriate environmental license from the competent environmental agency. The use of images from Sentinel-2 satellites presents itself as a potential tool for identifying gold mining vessels due to the temporal resolution, free imagery, global coverage, and more refined spatial resolution. So, this study aimed to identify gold mining vessels on the Madeira River near Porto Velho city, Rondônia state, located at Brazilian Amazon, in 13 Sentinel-2 images from 2018 to 2021 using the classifiers: Support Vector Machine (SVM), K-Nearest Neighbors (KNN) Random Forest (RF) and Spectral Angle Mapper (SAM). The results showed that machine learning classifiers obtained the best performance, especially the object-oriented SVM classifier, which had the best average F1 score (0.91). In addition, the detection percentage of gold mining vessels originated by this classifier was satisfactory, with only 0 to 4 active gold mining vessels with sediment plumes being omitted per image. Therefore, based on the results obtained, it was concluded that the use of machine learning classifiers proved to be effective in identifying gold mining vessels. smallscale small scale riverbeds However Permit Mineração management agency Sentinel2 Sentinel 2 Sentinel- resolution imagery coverage So city state Amazon 1 201 202 SVM, , (SVM) KNearest K Nearest KNN (KNN RF (RF SAM. SAM . (SAM) performance objectoriented object oriented F 0.91. 091 0.91 91 (0.91) addition satisfactory image Therefore 20 (SVM (SAM 09 0.9 9 (0.91 0. (0.9 (0. (0 (

Resumo Garimpos de ouro podem ocorrer em terra firme ou em leitos de rios na forma de embarcações. Porém, a atividade precisa estar amparada com uma Permissão de Lavra Garimpeira (PLG), expedida pela Agência Nacional de Mineração, e com a devida licença ambiental do órgão ambiental competente. Nesse sentido, o uso de imagens dos satélites Sentinel-2 se apresenta como ferramenta potencial para identificação de garimpos de ouro embarcados devido à resolução temporal, gratuidade de imagens, cobertura global e resolução espacial mais refinada. Este estudo objetivou identificar garimpos de ouro embarcados no Rio Madeira, próximo à cidade Porto Velho, estado de Rondônia, em 13 imagens Sentinel-2 de 2018 a 2021, a partir dos seguintes classificadores: Support Vector Machine (SVM); K-Nearest Neighbor (KNN); Random Forest (RF); e Spectral Angle Mapper (SAM). Os resultados demonstraram que os classificadores do tipo machine learning obtiveram melhor performance, com destaque para o classificador SVM orientado a objeto que apresentou melhor score F1 médio (0,91). Além disso, o percentual de detecção obtido foi satisfatório com omissão variando de 0 a 4 garimpos ativos por imagem. Assim, a partir dos resultados obtidos, conclui-se que o uso de classificadores machine learning se mostrou eficaz para identificar garimpos de ouro embarcados. embarcações Porém PLG, PLG , (PLG) Mineração competente sentido Sentinel2 Sentinel 2 Sentinel- temporal refinada Madeira Velho Rondônia 1 201 2021 (SVM) KNearest K Nearest KNN (KNN) RF (RF) SAM. SAM . (SAM) performance F 0,91. 091 0,91 91 (0,91) disso imagem Assim obtidos concluise conclui (PLG 20 202 (SVM (KNN (RF (SAM 09 0,9 9 (0,91 0, (0,9 (0, (0 (

Abstract In the past decade, machine learning techniques were responsible for a revolution in classification and regression tasks, making it possible to automate some laborious activities, saving time and reducing errors. It is known that the geological logging process is one of the most time-consuming activities accomplished by mining companies. Additionally, it is a subjective activity, and changes in the staff directly affect the geological databases due to different human log interpretation. By developing an automatic log classifier, a company can avoid problems related to the turnover of the staff by standardizing the criteria used to label an interval and can save time by avoiding manual log description. The proposed solution is: given the well log data containing the coordinates, resistivity and natural gamma, the model will be able to predict the presence or absence of coal, and its lithology. The innovation of the methodology proposed, considers not only the geophysical logging values, but additionally inserts the neighbourhood of a given depth as valuable input information, using Fully Convolutional Network. It performs a semantic segmentation using the well log data, which means that model´s input is the complete well log data curve and the trained model will return an output curve giving the probability of the presence of coal, by interval. The results showed good prediction for the binary problem (F1-score 0.79). The multi-class modelling suffers from the lack of data for each class, resulting in a F1-score from 0.38 for the worst result to 0.76 for the best. decade tasks errors timeconsuming consuming companies Additionally activity interpretation classifier description coordinates gamma coal lithology values information Network models s F1score Fscore F1 score F 0.79. 079 0.79 . 0 79 0.79) multiclass multi class 038 38 0.3 076 76 0.7 best 07 7 03 3 0.

Resumen: La malaria es un problema de salud pública y los casos diagnosticados en la capital de Roraima, Brasil, tienen el potencial de caracterizar la carga de la enfermedad en todo el estado. El objetivo de este estudio fue describir los aspectos epidemiológicos, clínicos y de laboratorio de los casos de malaria diagnosticados en Boa Vista. Para ello, se realizó un estudio descriptivo y transversal en dos unidades de salud del municipio, con personas diagnosticadas con malaria y que aceptaron responder el cuestionario. De 206 participantes, caracterizados como hombres, pardos y jóvenes, el 96% (198) reportó actividad minera ilegal. Entre los mineros, el 66% (131) procedían de otros estados de Brasil o de otros países. Las minas estaban ubicadas principalmente en el territorio Yanomami, en Roraima. La infección por Plasmodium vivax se produjo en el 74% (153) de los participantes. Entre los mineros, hubo relatos de hospitalizaciones por malaria grave, ataques previos de malaria y retrasos en el tratamiento tras de la aparición de los síntomas. Aunque el 73% (145) de los mineros informó saber cómo se transmitía la malaria, solo el 54% (107) usaba mosquiteros o repelentes. El uso de Artecom y cloroquina por parte de los mineros no está destinado a un tratamiento completo, sino al alivio de los síntomas para permitir el regreso a las minas de oro. Esto resalta la importancia de la vigilancia molecular para detectar la resistencia a los antipalúdicos. Los indígenas son considerados una población vulnerable a la malaria, y los mineros promueven el aumento de la malaria en las Tierras Indígenas de Roraima. Por lo tanto, el acceso al diagnóstico y tratamiento en zonas indígenas invadidas por mineros es imperativo para combatir esta enfermedad que asola a las comunidades indígenas y amenaza la salud pública a gran escala en el objetivo de erradicar la malaria en el estado. Resumen Roraima estado epidemiológicos Vista ello municipio cuestionario 20 participantes hombres jóvenes 96 198 (198 ilegal 66 131 (131 países Yanomami 74 153 (153 grave 73 145 (145 54 107 (107 repelentes completo oro antipalúdicos tanto 2 9 19 (19 6 13 (13 7 15 (15 14 (14 5 10 (10 1 (1 (

Resumo: A malária é um problema de saúde pública e os casos diagnosticados na capital de Roraima, Brasil, têm potencial para caracterizar a carga da doença em todo o estado. O objetivo deste estudo foi descrever os aspectos epidemiológicos, clínicos e laboratoriais dos casos de malária diagnosticados em Boa Vista. Para tanto, foi realizado um estudo descritivo e transversal em duas unidades de saúde do município, com indivíduos diagnosticados com malária e que concordaram em responder ao questionário. De 206 participantes, caracterizados como homens, pardos e jovens, 96% (198) relataram atividade de garimpo ilegal. Entre garimpeiros, 66% (131) vieram de outros estados do Brasil ou de outros países. As minas estavam localizadas principalmente no território Yanomami, em Roraima. A infecção por Plasmodium vivax ocorreu em 74% (153) dos participantes. Entre garimpeiros, houve relatos de internações por malária grave, ataques prévios de malária e atrasos no tratamento após o início dos sintomas. Embora 73% (145) dos garimpeiros tenham relatado saber como a malária era transmitida, apenas 54% (107) usavam mosquiteiros ou repelentes. O uso de Artecom e cloroquina pelos garimpeiros não se destina ao tratamento completo, mas apenas ao alívio dos sintomas, permitindo o retorno às minas de ouro. Isso ressalta a importância da vigilância molecular para detectar a resistência antimalárica. Os indígenas são considerados uma população vulnerável à malária, e os garimpeiros promovem o aumento da malária nas Terras Indígenas de Roraima. Portanto, o acesso ao diagnóstico e tratamento em áreas indígenas invadidas por garimpeiros é imperativo para o enfrentamento dessa doença que assola as comunidades indígenas e ameaça a saúde pública em larga escala na meta de erradicar a malária no estado. Resumo Roraima estado epidemiológicos Vista tanto município questionário 20 participantes homens jovens 96 198 (198 ilegal 66 131 (131 países Yanomami 74 153 (153 grave sintomas 73 145 (145 transmitida 54 107 (107 repelentes completo ouro antimalárica Portanto 2 9 19 (19 6 13 (13 7 15 (15 14 (14 5 10 (10 1 (1 (

Abstract: Malaria is a public health problem and the cases diagnosed in the capital of Roraima, Brazil, show potential to characterize the burden of the disease in the state. This study aimed to describe the epidemiological, clinical, and laboratory aspects of malaria cases diagnosed in Boa Vista. For this purpose, a descriptive, cross-sectional study was conducted in two health units in the city, with individuals diagnosed and who agreed to respond the questionnaire. Of the total of 206 participants, characterized as men, mixed-race, and young, 96% (198) reported participating in illegal mining activity. Among the group of miners, 66% (131) came from other states of Brazil or other countries. The mines were mainly located in the Yanomami territory in Roraima. Plasmodium vivax infection occurred in 74% (153) of participants. In the miner’s group, hospitalizations for severe malaria, previous malaria attacks, and delays in treatment after the onset of symptoms were reported. Although 73% (145) of miners reported knowing how malaria was transmitted, only 54% (107) used mosquito nets or repellents. The use of Artecom and chloroquine by miners is not for the complete treatment but only to relieve symptoms for returning to gold mines, highlighting the importance of molecular surveillance to antimalarial resistance. Indigenous peoples are considered vulnerable to malaria and miners promotes the increase of malaria in Roraima Indigenous Lands. Therefore, access to diagnosis and treatment in Indigenous areas invaded by miners is imperative to confront this disease that ravages Indigenous communities and threatens public health on a large scale to achieve the goal of eliminating malaria in the state. Abstract state epidemiological clinical Vista purpose descriptive crosssectional cross sectional city questionnaire 20 participants men mixedrace, mixedrace mixed race, race mixed-race young 96 198 (198 activity 66 131 (131 countries 74 153 (153 miner s attacks 73 145 (145 transmitted 54 107 (107 repellents resistance Lands Therefore 2 9 19 (19 6 13 (13 7 15 (15 14 (14 5 10 (10 1 (1 (

Resumo: A malária é um problema de saúde pública e os casos diagnosticados na capital de Roraima, Brasil, têm potencial para caracterizar a carga da doença em todo o estado. O objetivo deste estudo foi descrever os aspectos epidemiológicos, clínicos e laboratoriais dos casos de malária diagnosticados em Boa Vista. Para tanto, foi realizado um estudo descritivo e transversal em duas unidades de saúde do município, com indivíduos diagnosticados com malária e que concordaram em responder ao questionário. De 206 participantes, caracterizados como homens, pardos e jovens, 96% (198) relataram atividade de garimpo ilegal. Entre garimpeiros, 66% (131) vieram de outros estados do Brasil ou de outros países. As minas estavam localizadas principalmente no território Yanomami, em Roraima. A infecção por Plasmodium vivax ocorreu em 74% (153) dos participantes. Entre garimpeiros, houve relatos de internações por malária grave, ataques prévios de malária e atrasos no tratamento após o início dos sintomas. Embora 73% (145) dos garimpeiros tenham relatado saber como a malária era transmitida, apenas 54% (107) usavam mosquiteiros ou repelentes. O uso de Artecom e cloroquina pelos garimpeiros não se destina ao tratamento completo, mas apenas ao alívio dos sintomas, permitindo o retorno às minas de ouro. Isso ressalta a importância da vigilância molecular para detectar a resistência antimalárica. Os indígenas são considerados uma população vulnerável à malária, e os garimpeiros promovem o aumento da malária nas Terras Indígenas de Roraima. Portanto, o acesso ao diagnóstico e tratamento em áreas indígenas invadidas por garimpeiros é imperativo para o enfrentamento dessa doença que assola as comunidades indígenas e ameaça a saúde pública em larga escala na meta de erradicar a malária no estado.

Resumen: La malaria es un problema de salud pública y los casos diagnosticados en la capital de Roraima, Brasil, tienen el potencial de caracterizar la carga de la enfermedad en todo el estado. El objetivo de este estudio fue describir los aspectos epidemiológicos, clínicos y de laboratorio de los casos de malaria diagnosticados en Boa Vista. Para ello, se realizó un estudio descriptivo y transversal en dos unidades de salud del municipio, con personas diagnosticadas con malaria y que aceptaron responder el cuestionario. De 206 participantes, caracterizados como hombres, pardos y jóvenes, el 96% (198) reportó actividad minera ilegal. Entre los mineros, el 66% (131) procedían de otros estados de Brasil o de otros países. Las minas estaban ubicadas principalmente en el territorio Yanomami, en Roraima. La infección por Plasmodium vivax se produjo en el 74% (153) de los participantes. Entre los mineros, hubo relatos de hospitalizaciones por malaria grave, ataques previos de malaria y retrasos en el tratamiento tras de la aparición de los síntomas. Aunque el 73% (145) de los mineros informó saber cómo se transmitía la malaria, solo el 54% (107) usaba mosquiteros o repelentes. El uso de Artecom y cloroquina por parte de los mineros no está destinado a un tratamiento completo, sino al alivio de los síntomas para permitir el regreso a las minas de oro. Esto resalta la importancia de la vigilancia molecular para detectar la resistencia a los antipalúdicos. Los indígenas son considerados una población vulnerable a la malaria, y los mineros promueven el aumento de la malaria en las Tierras Indígenas de Roraima. Por lo tanto, el acceso al diagnóstico y tratamiento en zonas indígenas invadidas por mineros es imperativo para combatir esta enfermedad que asola a las comunidades indígenas y amenaza la salud pública a gran escala en el objetivo de erradicar la malaria en el estado.

Abstract: Malaria is a public health problem and the cases diagnosed in the capital of Roraima, Brazil, show potential to characterize the burden of the disease in the state. This study aimed to describe the epidemiological, clinical, and laboratory aspects of malaria cases diagnosed in Boa Vista. For this purpose, a descriptive, cross-sectional study was conducted in two health units in the city, with individuals diagnosed and who agreed to respond the questionnaire. Of the total of 206 participants, characterized as men, mixed-race, and young, 96% (198) reported participating in illegal mining activity. Among the group of miners, 66% (131) came from other states of Brazil or other countries. The mines were mainly located in the Yanomami territory in Roraima. Plasmodium vivax infection occurred in 74% (153) of participants. In the miner’s group, hospitalizations for severe malaria, previous malaria attacks, and delays in treatment after the onset of symptoms were reported. Although 73% (145) of miners reported knowing how malaria was transmitted, only 54% (107) used mosquito nets or repellents. The use of Artecom and chloroquine by miners is not for the complete treatment but only to relieve symptoms for returning to gold mines, highlighting the importance of molecular surveillance to antimalarial resistance. Indigenous peoples are considered vulnerable to malaria and miners promotes the increase of malaria in Roraima Indigenous Lands. Therefore, access to diagnosis and treatment in Indigenous areas invaded by miners is imperative to confront this disease that ravages Indigenous communities and threatens public health on a large scale to achieve the goal of eliminating malaria in the state.

ABSTRACT Deforestation and high human mobility due to mining activities have been key to the increase in malaria cases in the Americas. Here, we review the epidemiological and control aspects of malaria in the Amazon mining areas. Epidemiological evidence shows: 1) a positive correlation between illegal mining activity and malaria incidence, mostly in the Amazon region; 2) most Brazilian miners are males aged 15-29 years who move between states and even countries; 3) miners do not fear the disease and rely on medical care, diagnosis, and medication when they become ill; 4) illegal mining has emerged as the most reported anthropogenic activity within indigenous lands and is identified as a major cause of malaria outbreaks among indigenous people in the Amazon; and 5) because mining is largely illegal, most areas are not covered by any healthcare facilities or activities, leading to little assistance in the diagnosis and treatment of malaria. Our review identified five strategies for reducing the malaria incidence in areas with mining activities: 1) reviewing legislation to control deforestation and mining expansion, particularly in indigenous lands; 2) strengthening malaria surveillance by expanding the network of community health agents to support rapid diagnosis and treatment; 3) reinforcing vector control strategies, such as the use of insecticide-treated nets; 4) integrating deforestation alerts into the national malaria control program; and 5) implementing multi-sectoral activities and providing prompt assistance to indigenous populations. With this roadmap, we can expect a decrease in malaria incidence in the Amazonian mining areas in the future. Americas Here shows 1 region 2 1529 15 29 15-2 countries 3 care ill 4 5 expansion insecticidetreated insecticide treated nets program multisectoral multi sectoral populations roadmap future 152 15-

RESUMEN En los primeros años del siglo XIX, la abertura de una carretera entra la parte central de la zona de Mata de Minas Gerais y la ciudad de Campos dos Goytacazes sirvió como catalizador del proceso de ocupación de las tierras que la atravesaban. Del mismo modo, se percibió el aumento del comercio entre estas dos áreas, llevándolos a la formación de un espacio económico particular, correspondiente en gran medida a la cuenca del río Pomba. Este artículo tiene por objetivo analizar la producción rural y la circulación de mercancías de esta región a lo largo de las primeras décadas del siglo XIX con base en los datos de los décimos de importación y exportación del registro de la Barra de Pombo, así como cuestionar la veracidad del concepto de espacio económico para el período posterior a la decadencia de la actividad minera. atravesaban modo áreas particular Pomba Pombo minera

ABSTRACT In the early years of the nineteenth century, the opening of a road between the central part of the so-called “Zona da Mata” (Forest Belt) of Minas Gerais and the city of Campos dos Goytacazes acted as a catalyst for a process of land occupation in the region. The process was accompanied by an increase in trade between the two areas, signaling the formation of a particular economic space. This article analyzes the rural production and the circulation of goods in the central area of the Zona da Mata during the first decades of the nineteenth century, based on records of tithes and on import and export data from the Barra do Pomba customs house. It also questions the validity of the concept of economic space for the period after the decline of mining activity. century socalled so called Forest Belt region areas house activity

RESUMO Nos primeiros anos do século XIX, a abertura de uma estrada entre a parte central da Zona da Mata de Minas Gerais e a cidade de Campos dos Goytacazes atuou como catalisador do processo de ocupação das terras por ela atravessadas. Do mesmo modo, assistiu-se ao incremento do comércio entre as duas áreas, sinalizando para a formação de um espaço econômico particular, em grande medida correspondente à bacia hidrográfica do rio Pomba. Este artigo tem por objetivo analisar a produção rural e a circulação de mercadorias nessa região ao longo das primeiras décadas do século XIX com base nos dados dos dízimos e de importação e exportação pelo registro da Barra do Pomba, bem como questionar a validade do conceito de espaço econômico para o período posterior ao declínio da atividade mineradora. atravessadas modo assistiuse assistiu se áreas particular Pomba mineradora