Résumé La fin de la Seconde Guerre mondiale marque un ensemble de grandes transformations dans la pensée sociale brésilienne. Les théories raciales et eugéniques perdent rapidement leur force face aux interprétations d’ordre culturel et économique. Dans ce travail, une partie de ces transformations est racontée à partir des interprétations sur l’immigration japonaise au Brésil de deux intellectuels ayant une influence marquante au Parlement : le psychiatre-eugéniste Pacheco e Silva et le sociologue Gilberto Freyre. L’immigration japonaise a été au centre d’un débat intense dans les années 1930 et 1940, suscitant même des amendements restrictifs ou prohibitifs dans les Constitutions de 1934 et 1946. Cette étude analyse l’activité parlementaire des deux intellectuels pendant cette période, observe les influences de leurs pensées sociales sur leur activité politique, examine également les transformations qui ont lieu dans les années 1950, avec des changements dans la pensée de Pacheco e Silva, une plus grande influence de la pensée de Freyre et une redéfinition de la place de l’immigration japonaise dans le débat parlementaire. brésilienne dordre d ordre économique travail limmigration l immigration psychiatreeugéniste psychiatre eugéniste Limmigration L dun 193 1940 1946 lactivité période politique 1950 19 194 195 1

Resumen El final de la Segunda Guerra Mundial marcó un conjunto de grandes transformaciones en el pensamiento social brasilero. Las teorías raciales y eugenésicas van perdiendo fuerza rápidamente frente a las interpretaciones de cuño cultural y económico. En este trabajo, se da cuenta de parte de esas transformaciones a partir de las interpretaciones sobre la inmigración japonesa en Brasil de dos intelectuales con un importante desempeño parlamentario: el psiquiatra-eugenista Pacheco e Silva y el sociólogo Gilberto Freyre. La inmigración japonesa fue foco de intenso debate en las décadas de 1930 y 1940, e incluso fue merecedora de enmiendas restrictivas o prohibitivas en las Constituyentes de 1934 y 1946. Este estudio, analiza la acción parlamentaria de los dos intelectuales en ese periodo, observando las influencias de sus pensamientos sociales en su actividad política y examinando, también, las transformaciones que ocurrieron en la década de 1950, con cambios en el pensamiento de Pacheco e Silva, principal influencia del pensamiento de Freyre, y el rediseño del lugar dado a la inmigración japonesa en el debate parlamentario. brasilero económico trabajo parlamentario psiquiatraeugenista psiquiatra eugenista Freyre 193 1940 1946 estudio periodo examinando también 1950 19 194 195 1

Abstract The end of World War II marks a set of major transformations in Brazilian social thought. Racial and eugenic theories rapidly lose ground to interpretations of cultural and economic nature. This article examines part of these transformations through the perspectives on Japanese immigration to Brazil by two intellectuals with important parliamentary roles: the psychiatrist-eugenicist Pacheco e Silva and the sociologist Gilberto Freyre. Japanese immigration was the subject of intense debate in the 1930s and 1940s, even prompting restrictive or prohibitive amendments in the 1934 and 1946 constitutions. This study analyzes the parliamentary activities of both intellectuals over this period and demonstrates the influence of their respective social thoughts on their political endeavors. This article also examines the transformations that took place in the 1950s, including shifts in Pacheco e Silva’s thinking, a greater influence of Freyre’s ideas, and a reconfiguration of the role of Japanese immigration in parliamentary discourse. thought nature roles psychiatristeugenicist psychiatrist eugenicist Freyre s 1940s 193 194 constitutions endeavors 1950s Silvas thinking Freyres ideas discourse 19 1

Resumo O final da Segunda Guerra Mundial marca um conjunto de grandes transformações no pensamento social brasileiro. As teorias raciais e eugênicas vão perdendo rapidamente força frente às interpretações de cunho cultural e econômico. Neste trabalho, conta-se parte dessas transformações a partir das interpretações sobre a imigração japonesa no Brasil em dois intelectuais de marcante atuação parlamentar: o psiquiatra-eugenista Pacheco e Silva e o sociólogo Gilberto Freyre. A imigração japonesa foi foco de intenso debate nas décadas de 1930 e 1940, merecendo até mesmo emendas restritivas ou proibitivas nas Constituintes de 1934 e 1946. Este estudo analisa a atuação parlamentar dos dois intelectuais nesse período, observando as influências de seus pensamentos sociais em sua atividade política. O artigo examina, ainda, as transformações que ocorrem na década de 1950, com mudanças no pensamento de Pacheco e Silva, maior influência do pensamento de Freyre e um redesenho do lugar da imigração japonesa no debate parlamentar. brasileiro econômico trabalho contase conta se psiquiatraeugenista psiquiatra eugenista 193 1940 1946 período política examina ainda 1950 19 194 195 1

Résumé Il y a toujours un scepticisme quant à savoir si un membre élu peut exercer une influence au Conseil de Sécurité des Nations Unies (CSNU). Cet article réévalue comment le Brésil, l’Inde et l’Afrique du Sud ont tenté d’influencer le processus de prise de décision du CSNU en tant que membres pendant la période 2010-2012. Il aborde la dynamique et les pratiques du Conseil, la centralité des cinq membres permanents (P5) et les moyens utilisés par les trois pays pour atteindre leurs objectifs de politique étrangère. À travers ces cas spécifiques, cet article montre que bien qu’il y ait de la place pour un membre élu pour influencer le Conseil, il est difficile de défier la prédominance du P5 même en profitant des opportunités et en s’engageant avec les principaux acteurs du CSNU. . (CSNU) Brésil lInde l Inde lAfrique Afrique dinfluencer d 20102012. 20102012 2010 2012. 2012 2010-2012 P (P5 étrangère spécifiques quil qu sengageant s engageant (CSNU 2010201 201 2010-201 (P 201020 20 2010-20 20102 2 2010-2 2010-

Abstract There is always scepticism about the extent to which an elected member of the United Nations Security Council (UNSC) can meaningfully exert influence. This article reassesses how, between 2010 and 2012, Brazil, India, and South Africa tried to leverage their membership to influence UNSC decision-making processes. It addresses the Council’s dynamics and practices, the centrality of its five permanent members (P5), and the ways these countries achieve their foreign policy objectives. Through country-specific cases, this article shows that although there is space for an elected member to influence the Council, challenging the predominance of the P5 remains difficult, even by seizing opportunities and engaging with key UNSC players. (UNSC how 201 2012 Brazil India decisionmaking decision making processes Councils s practices P5, P , (P5) objectives countryspecific country specific cases difficult players 20 (P5 2 (P

Resumen Siempre existe escepticismo sobre si un miembro electo puede ejercer influencia en el Consejo de Seguridad de las Naciones Unidas (CSNU). Este artículo reevalúa cómo Brasil, India y Sudáfrica intentaron influir en el proceso de toma de decisiones del CSNU como miembros en el periodo 2010-2012. Examina la dinámica y las prácticas del Consejo, la centralidad de los cinco miembros permanentes (P5) y las formas en que los tres países alcanzan sus objetivos de política exterior. A través de estos casos concretos, este artículo muestra que, aunque un miembro electo tiene margen para influir en el Consejo, es difícil desafiar el predominio de los P5 incluso aprovechando las oportunidades y comprometiéndose con los actores clave del CSNU. . (CSNU) Brasil 20102012. 20102012 2010 2012. 2012 2010-2012 P (P5 exterior concretos (CSNU 2010201 201 2010-201 (P 201020 20 2010-20 20102 2 2010-2 2010-

Resumo Há sempre ceticismo sobre se um membro eleito pode exercer influência no Conselho de Segurança das Nações Unidas (CSNU). Este artigo reavalia como Brasil, Índia e África do Sul tentaram influenciar o processo de tomada de decisão do CSNU como membros no período 2010-2012. Aborda a dinâmica e as práticas do Conselho, a centralidade dos cinco membros permanentes (P5) e as formas utilizadas pelos três países para atingir seus objetivos de política externa. Por meio desses casos específicos, este artigo mostra que, embora haja espaço para um membro eleito influenciar o Conselho, é difícil desafiar a predominância do P5 mesmo aproveitando oportunidades e engajando-se com os principais atores do CSNU. . (CSNU) Brasil 20102012. 20102012 2010 2012. 2012 2010-2012 P (P5 externa específicos que engajandose engajando (CSNU 2010201 201 2010-201 (P 201020 20 2010-20 20102 2 2010-2 2010-

Résumé Ce commentaire critique la reproduction de la croyance erronée selon laquelle l’économie mainstream est identique à l’économie néoclassique et celle-ci, à son tour, est identique à l’économie (néo)libérale. Le rejet de ces égalités complique les relations entre l’économie mainstream, orthodoxe et hétérodoxe. Le commentaire soutient également que le cas du Brésil diffère de celui des États-Unis, car plusieurs idées économiques marginalisées aux États-Unis jouissent de prestige et d’influence dans le milieu académique brésilien, ce qui rend le concept même d’économie mainstream plus ambigu. Tout cela implique plusieurs divergences par rapport à l’article récent de Francisco Marques (2024). D’autres différences sont soulignées en ce qui concerne l’utilisation des mathématiques, de la statistique et de l’économétrie, ainsi que l’interdisciplinarité. Le résultat est une vision plus complexe de l’académie économique aux États-Unis et surtout au Brésil. Le commentaire identifie également et corrige les principales distorsions dans la traduction que Marques fait d’un passage relativement long de Dequech (2018). léconomie l économie celleci, celleci celle ci, ci celle-ci tour néolibérale. néolibérale néo libérale. libérale (néo)libérale hétérodoxe ÉtatsUnis, ÉtatsUnis États Unis, Unis dinfluence d influence brésilien déconomie ambigu larticle article 2024. 2024 . (2024) Dautres D autres lutilisation utilisation mathématiques léconométrie, léconométrie économétrie, économétrie l’économétrie linterdisciplinarité. linterdisciplinarité interdisciplinarité. interdisciplinarité l’interdisciplinarité lacadémie académie dun un 2018. 2018 (2018) 202 (2024 201 (2018 20 (202 (201 2 (20 (2 (

Abstract This comment criticizes the reproduction of the mistaken belief that mainstream economics is equal to neoclassical economics and that the latter, in turn, is equal to (neo)liberal economics. The rejection of those equalities turns the relations among mainstream, orthodox and heterodox economics more difficult. The comment also claims that the Brazilian case is different from the American one, since several economic ideas marginalized in the United States have both prestige and influence in the Brazilian academy, which makes the concept of mainstream economics itself more ambiguous. All that implies many divergences regarding the recent article by Francisco Marques (2024). Other differences are pointed out regarding the use of math, statistics and econometry, as well as interdisciplinarity. The result is a more complex view of the economics academy in the United States and mainly in Brazil. The comment also identifies and corrects the main distortions in the translation that Marques made of a relatively long excerpt of Dequech (2018). latter turn neoliberal neo liberal difficult one ambiguous 2024. 2024 . (2024) math econometry interdisciplinarity Brazil 2018. 2018 (2018) 202 (2024 201 (2018 20 (202 (201 2 (20 (2 (

Resumen Este comentario critica la reproducción de la creencia errónea de que la economía mainstream es igual a la economía neoclásica y que la economía neoclásica es igual a la economía (neo)liberal. El rechazo de estas igualdades complica las relaciones entre la economía mainstream, ortodoxa y heterodoxa. El comentario también argumenta que el caso de Brasil es diferente al de EE.UU., ya que varias ideas económicas marginadas en EE.UU. tienen prestigio e influencia en el mundo académico brasileño, lo que hace que el propio concepto de economía mainstream sea más ambiguo. Todo ello implica varias divergencias con respecto al reciente artículo de Francisco Marques (2024). Otras diferencias son señaladas acerca del uso de las matemáticas, la estadística y la econometría, así como de la interdisciplinaridad. El resultado es una visión más compleja del mundo académico económico en Estados Unidos y, sobre todo, en Brasil. El comentario también identifica y corrige las principales distorsiones en la traducción de Marques de un extracto relativamente largo de Dequech (2018). neoliberal. neoliberal neo liberal. liberal (neo)liberal heterodoxa EEUU EE UU EE.UU brasileño ambiguo 2024. 2024 . (2024) matemáticas econometría interdisciplinaridad todo 2018. 2018 (2018) 202 (2024 201 (2018 20 (202 (201 2 (20 (2 (

Resumo Este comentário critica a reprodução da crença equivocada de que a economia mainstream é igual à economia neoclássica e de que esta, por sua vez, é igual à economia (neo)liberal. A rejeição dessas igualdades complica as relações entre economia mainstream, ortodoxa e heterodoxa. O comentário argumenta também que o caso do Brasil é diferente do americano, pois várias ideias econômicas que são marginalizadas nos Estados Unidos têm prestígio e influência na academia brasileira, o que torna o próprio conceito de economia mainstream mais ambíguo. Tudo isso implica várias divergências em relação ao artigo recente de Francisco Marques (2024). Outras diferenças são apontadas no que se refere ao uso de matemática, estatística e econometria e à interdisciplinaridade. O resultado é uma visão mais complexa da academia de economia nos Estados Unidos e sobretudo no Brasil. O comentário também identifica e corrige as principais distorções na tradução que Marques faz de um trecho relativamente longo de Dequech (2018). esta vez neoliberal. neoliberal neo liberal. liberal (neo)liberal heterodoxa americano brasileira ambíguo 2024. 2024 . (2024) matemática interdisciplinaridade 2018. 2018 (2018) 202 (2024 201 (2018 20 (202 (201 2 (20 (2 (

This study highlights the synthesis of innovative polyurethane materials derived from Moringa oleifera oils extracted from two distinct sources. The oils were converted into their respective polyols through the in situ generated performic acid method. Diverse material characteristics were observed due to different agroclimatic and cultivation conditions for the sources. Extraction yields were 45.21% (source 1) and 40.32% (source 2), with acid values of 28.70 and 26.00 mg KOH per g of oil, respectively. Oleic acid constituted 79.87 and 67.11% of the oils composition, respectively. Nuclear magnetic resonance and Fourier transform infrared spectroscopy (FTIR) confirmed the hydroxylation of the oils. FTIR also identified the isocyanate structures in the synthesized polyurethane materials. Gel permeation chromatography analysis revealed a higher oligomer content in the polyol synthesized from the oil extracted from source 2. Thermogravimetric analysis demonstrated enhanced thermal stability post-oil conversion, highlighting decomposition stages for rigid and flexible segments. Differential scanning calorimetry indicated higher unsaturation in the oil extracted from source 1, resulting in an elevated crystallization temperature. Tensile testing showed increased elasticity as the [NCO]/[OH] ratio decreased in the material, emphasizing the influence of polyol and crosslinking agent concentrations on mechanical resistance of polyurethane materials. sources method 4521 45 21 45.21 1 4032 40 32 40.32 2, 2 , 2) 2870 28 70 28.7 2600 26 00 26.0 respectively 7987 79 87 79.8 6711 67 11 67.11 composition (FTIR postoil post conversion segments temperature NCO/OH NCOOH NCO / OH [NCO]/[OH 452 4 45.2 403 3 40.3 287 7 28. 260 0 26. 798 8 79. 671 6 67.1 45. 40. 67.

The objective of this work was to evaluate the total concentration and bioaccessible fractions of Ba, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Pb, V and Zn in berry fruits and analyze the influence of different cultivars and growing conditions on the obtained results. The variations in bioaccessible concentrations were from 7.7-30, 17-29, 22-50, 1.8-96, 22-33 and 20-51% of the total concentration, for Ba, Cu, Fe, Mn, Pb and Zn, respectively. Copper showed greater bioaccessibility in blackberry and blueberry. For Fe, bioaccessibility was observed in all strawberries and blueberries and in some blackberries. Zinc presented higher bioaccessible fractions in strawberries. For V, only the sample Blackberry 124 showed bioaccessible concentration, (11% of the total concentration). Regarding the different forms of cultivation, the strawberries that received radiation from the red and white lamps presented a higher production of fruit compared to the other systems, however, in relation to the absorption of nutrients, a small variation was observed between the fruits. Ba Ca Cd Cr Cu Fe K Mg Mn results 7.730, 7730 7.7 30, 7 30 7.7-30 1729, 1729 17 29, 29 17-29 2250, 2250 22 50, 50 22-50 1.896, 1896 1.8 96, 1 8 96 1.8-96 2233 33 22-3 2051% 2051 20 51% 51 20-51 respectively blueberry blackberries 12 11% 11 (11 concentration. . concentration) cultivation systems however nutrients 730 7.730 773 77 7. 3 7.7-3 172 2 17-2 225 5 22-5 896 1.896 189 18 1. 9 1.8-9 223 22- 205 20-5 (1 73 7.73 7.7- 17- 89 1.89 1.8- 20- (

Assessing the dynamics of pollutants in the environment is a very complex challenge, primarily because of the large number of variables involved. Thus, in addition to processes that depend on the physicochemical properties of the pollutant and the main characteristics of the contaminated environment, there are less obvious phenomena that also influence the dynamics of pollutants, such as colloid-mediated transport. The objective of this work is to elucidate the main characteristics of this process and its influence on the transport of pollutants through the soil, taking glyphosate as an example. Although this pollutant is strongly retained by soil components, its presence in groundwater is quite frequent, often due to this facilitated transport by colloids. challenge involved Thus colloidmediated colloid mediated example components frequent colloids

The present work reports the in situ fabrication of Ag nanoparticles (AgNPs) in polystyrene-b-poly(2-vinylpyridine) (PS-b-P2VP) over pre-patterned hydrophobic stripes on a hydrophilic glass surface. Microcontact printing (μCP) using octadecyltrichlorosilane (OTS) as “ink” was used to obtain these chemically modified substrates. A comparison of the results of the PS-b-P2VP self-assembly over a bare glass substrate and a pre-patterned glass substrate demonstrated the influence of the pattern on the film morphology. Polymeric films of Ag+ and PS-b-P2VP were prepared on a pre-patterned substrate and heated at 150 °C to enable the self-reconstruction of the polymeric matrix and the in situ formation of AgNPs (average particle size of approximately 100 nm). The AgNP/PS-b-P2VP thin films were characterized using UV-Vis spectroscopy and atomic force microscopy. The results demonstrate that the concentration of the solutions of Ag+/PS-b-P2VP used to prepare the films strongly influences the morphologies and dispersion of AgNPs. Moreover, the surface-enhanced Raman spectroscopy (SERS) activity of the fabricated polymer nanocomposites using Nile Blue as a molecular probe shows the importance of the chemical modification of the substrate in the enhancement of the SERS signal. (AgNPs polystyrenebpoly2vinylpyridine polystyrenebpolyvinylpyridine polystyrene b poly 2 vinylpyridine polystyrene-b-poly(2-vinylpyridine PSbP2VP PSbPVP PS P2VP P VP (PS-b-P2VP prepatterned pre patterned surface μCP (μCP OTS (OTS ink “ink substrates selfassembly self assembly morphology 15 C selfreconstruction reconstruction average 10 nm. nm . nm) AgNP/PSbP2VP AgNPPSbP2VP AgNPPSbPVP AgNP/PS AgNP UVVis UV Vis microscopy Ag+/PSbP2VP AgPSbP2VP AgPSbPVP Ag+/PS Moreover surfaceenhanced enhanced (SERS signal polystyrenebpoly PSbP PVP 1 AgNPPSbP AgNPPS AgPSbP AgPS

The acetalization or transacetalization reactions produce acetals or ketals used in cosmetics, food, pharmaceuticals, and fuel additives. Besides synthesizing several products, the acetalization or transacetalization reactions can protect carbonyl groups, 1,2 and 1,3-diols in multi-step synthesis. This work studies the transacetalization of glycerol with 2,2-dimethoxypropane (2,2-DMP) to yield 2,2-dimethyl-4-hydroxymethyl-1,3-dioxolane (solketal) by catalyzing with USY, HBeta, and HZSM-5 zeolites under cleaner and mild reaction conditions (reaction temperature: 25 °C; 2,2-DMP/glycerol molar ratio: 1; reaction time: 1 h; and catalyst concentration: 0.05-5 wt.%). For catalyst concentration equal to or greater than 2,5 wt.%, glycerol conversion stabilized near 96-97% for the three zeolites tested. The product selectivities also assume a constant value, close to 97% for solketal. For the lowest concentration of catalyst, the influence of the zeolite properties on the glycerol conversion, such as acidity and the strong/weak acid site ratio, was observed. Concerning the selectivity of the products, the results suggested that it can be based on zeolite topology, active sites at the particle surface, and the relative amount of micro and mesoporous HBeta, the most selective catalyst for acetals production, was reused at least once without loss of activity and selectivity. cosmetics food pharmaceuticals additives products groups 12 2 1, 1,3diols 13diols diols 1,3 3 multistep multi step synthesis 2,2dimethoxypropane 22dimethoxypropane dimethoxypropane 2,2 2,2DMP 22DMP DMP (2,2-DMP 2,2dimethyl4hydroxymethyl1,3dioxolane 22dimethyl4hydroxymethyl13dioxolane dimethylhydroxymethyldioxolane dimethyl 4 hydroxymethyl dioxolane solketal (solketal USY HBeta HZSM5 HZSM 5 HZSM- temperature °C C 2,2DMP/glycerol 22DMPglycerol DMPglycerol DMP/glycerol ratio time h 0.055 0055 0.05 0 05 0.05- wt.%. wt wt.% . wt.%) 2, 9697% 9697 96 97 96-97 tested value strongweak strong weak observed topology surface production 3diols 13 2dimethoxypropane 22 2DMP 2dimethyl4hydroxymethyl1 3dioxolane 055 005 0.0 wt. 969 9 96-9 dimethylhydroxymethyl 2dimethyl4hydroxymethyl 00 0. 96-

RESUMO Objetivo: Avaliar a sazonalidade da bronquiolite aguda no Brasil durante a temporada 2020–2022 e compará-la com a das temporadas anteriores. Métodos: Os dados de incidência de internações por bronquiolite aguda em lactentes <1 ano de idade foram obtidos do Departamento de Informática da base de dados da Saúde Pública Brasileira para o período entre 2016 e 2022. Esses dados também foram analisados por macrorregiões do Brasil (Norte, Nordeste, Sudeste, Sul e Centro-Oeste). Para descrever características sazonais e de tendência ao longo do tempo, utilizamos o Modelo de Médias Móveis Integradas Autorregressivas Sazonais. Resultados: Em comparação com o período pré-COVID-19, a incidência de hospitalizações relacionadas com bronquiolite aguda diminuiu 97% durante as intervenções não farmacológicas (março de 2020 – agosto de 2021), mas aumentou 95% após a flexibilização das intervenções não farmacológicas (setembro de 2021 – dezembro de 2022), resultando no aumento geral de 16%. Durante o período pré-COVID-19, as hospitalizações por bronquiolite aguda seguiram um padrão sazonal, que foi interrompido em 2020–2021, mas recuperaram-se em 2022, com um pico ocorrido em maio, aproximadamente 4% superior ao pico pré-COVID-19. Conclusões: Este estudo ressalta a influência significativa das intervenções contra a COVID-19 nas hospitalizações por bronquiolite aguda no Brasil. A restauração de um padrão sazonal em 2022 sublinha a interação entre as medidas de saúde pública e a dinâmica das doenças respiratórias em crianças pequenas. Objetivo 20202022 2020–202 comparála compará la anteriores Métodos 1 < 201 Norte, Norte (Norte Nordeste Sudeste CentroOeste. CentroOeste Centro Oeste . Centro-Oeste) tempo Sazonais Resultados préCOVID19, préCOVID19 préCOVID pré COVID 19, 19 pré-COVID-19 97 março 202 2021, , 2021) 95 setembro 2022) 16 16% 20202021 2020–2021 recuperaramse recuperaram se maio 4 préCOVID19. 19. Conclusões COVID19 COVID-1 pequenas 2020202 2020–20 20 Centro-Oeste préCOVID1 pré-COVID-1 9 COVID1 COVID- 202020 2020–2 2 pré-COVID- 20202 2020– pré-COVID

ABSTRACT Objective: To evaluate the seasonality of acute bronchiolitis in Brazil during the 2020–2022 season and compare it with the previous seasons. Methods: Data from the incidence of hospitalizations due to acute bronchiolitis in infants <1 year of age were obtained from the Department of Informatics of the Brazilian Public Health database for the period between 2016 and 2022. These data were also analyzed by macro-regions of Brazil (North, Northeast, Southeast, South, and Midwest). To describe seasonal and trend characteristics over time, we used the Seasonal Autoregressive Integrated Moving Averages Model. Results: Compared to the pre-COVID-19 period, the incidence of hospitalizations related to acute bronchiolitis decreased by 97% during non-pharmacological interventions (March 2020 – August 2021) but increased by 95% after non-pharmacological interventions relaxation (September 2021 – December 2022), resulting in a 16% overall increase. During the pre-COVID-19 period, hospitalizations for acute bronchiolitis followed a seasonal pattern, which was disrupted in 2020–2021 but recovered in 2022, with a peak occurring in May, approximately 4% higher than the pre-COVID-19 peak. Conclusions: This study underscores the significant influence of COVID-19 interventions on acute bronchiolitis hospitalizations in Brazil. The restoration of a seasonal pattern in 2022 highlights the interplay between public health measures and respiratory illness dynamics in young children. Objective 20202022 2020–202 seasons Methods 1 < 201 macroregions macro regions North, North (North Northeast Southeast South Midwest. Midwest . Midwest) time Model Results preCOVID19 preCOVID pre COVID 19 pre-COVID-1 97 nonpharmacological non pharmacological March 202 95 September , 2022) 16 increase 20202021 May 4 Conclusions COVID19 COVID-1 children 2020202 2020–20 20 preCOVID1 pre-COVID- 9 COVID1 COVID- 202020 2020–2 2 pre-COVID 20202 2020–

Cupuaçu (Theobroma grandiflorum Schum.) is an Amazonian fruit rich in antioxidants potential due to its phenolic compounds. Its seeds produce cupulate, a chocolate-like product, and the residue remains rich in biocompounds. This study aimed to optimize and compare microwave-assisted (MAE) and high pressure/temperature extraction (HPTE) of polyphenolic and flavonoid compounds from cupuaçu seed by-products. A Box-Behnken 33 factorial design assessed the influence of extraction time, solid/liquid ratio, and ethanol concentration. Responses included total polyphenol content, total flavonoid content, and anti-radical power via the ABTS (2,2-azino-bis-3-ethylbenzothiazoline-6-sulphonic acid) method. In optimum conditions, MAE had the highest total polyphenol content and HPTE for flavonoids. Optimal conditions for both methods were 65% (m/v) ethanol concentration, 45 min extraction time, and 0.03 g mL−1 solid/liquid ratio. MAE and HPTE achieved greater recovery of (−)-epicatechin and (−)-epigallocatechin-3-gallate compared to percolation. Both techniques proved viable for recovering polyphenols from cupuaçu seed by-products, in less time and with less solvent. Thus, cupuaçu by-products can be a sustainable and functional food source, with MAE and HPTE providing high yields and quality extracts rich in polyphenols. Theobroma Schum. Schum cupulate chocolatelike chocolate like product biocompounds microwaveassisted microwave assisted (MAE pressuretemperature pressure temperature (HPTE byproducts. byproducts by products. products BoxBehnken Box Behnken 3 solidliquid solid liquid ratio concentration antiradical anti radical 2,2azinobis3ethylbenzothiazoline6sulphonic 22azinobis3ethylbenzothiazoline6sulphonic azinobisethylbenzothiazolinesulphonic 2,2 azino bis ethylbenzothiazoline 6 sulphonic 2 acid method flavonoids 65 m/v mv m v (m/v 4 003 0 03 0.0 mL1 mL 1 mL− −epicatechin epicatechin − −epigallocatechin3gallate epigallocatechin3gallate epigallocatechingallate epigallocatechin gallate percolation byproducts, products, solvent Thus source 2azinobis3ethylbenzothiazoline6sulphonic azinobis 22 2, 00 0.

ABSTRACT Objective: The aim of this study was to evaluate the functioning and associated factors in children and adolescents with osteogenesis imperfecta (OI). Methods: This is a cross-sectional study conducted on 30 children and adolescents with OI. Medical records, use of bisphosphonates, socioeconomic status, handgrip strength, balance, joint hypermobility, ambulatory level, and the Pediatric Evaluation of Disability Inventory—Computer Adaptative Test (PEDI-CAT) scores were assessed. Data is presented as mean and standard deviation and Student’s t-test or Mann–Whitney U test. Categorical data is presented as frequency and analyzed using Fisher’s exact test. Within-group analyses were conducted using ANCOVA or Wilcoxon signed-rank test. Correlations used Kendall’s Tau-b test. Results: The participants involved in this study were 6–18 years old. The sample was separated into two groups according to disease severity. The moderate/severe OI group (n=10) presented a lower height and muscular strength than the mild group (n=20). Muscle weakness was observed in all participants with OI when compared with the normal population. No differences were observed between the groups in the PEDI-CAT scores except for the mobility domain. There were correlations between the PEDI-CAT mobility domain and the number of fractures, OI type, weight, and balance; there was also a correlation between the PEDI-CAT daily activities, mobility, responsibility, and social/cognitive domains. Conclusions: The findings suggest that children with moderate/severe forms of OI can achieve the same function levels as children with mild OI. Fractures can have a major influence on the functional level, and treatment should focus on the prevention and rehabilitation of these events when they occur. Objective . (OI) Methods crosssectional cross sectional 3 records bisphosphonates status balance hypermobility level InventoryComputer Inventory Computer PEDICAT PEDI CAT (PEDI-CAT assessed Students Student s ttest t test MannWhitney Mann Whitney Fishers Fisher Withingroup Within signedrank signed rank Kendalls Kendall Taub Tau b Results 618 6 18 6–1 old severity moderatesevere moderate severe n=10 n10 n 10 (n=10 n=20. n20 n=20 20 (n=20) population fractures type weight activities responsibility socialcognitive social cognitive domains Conclusions occur (OI 61 1 6– n=1 n1 (n=1 n2 n=2 2 (n=20 n= (n= (n=2 (n

RESUMO Objetivo: Avaliar a funcionalidade e fatores associados em crianças e adolescentes com osteogênese imperfeita (OI). Métodos: Estudo transversal com 30 crianças e adolescentes com OI. Foram avaliados prontuários médicos, uso de bisfosfonatos, características socioeconômicas, dinamometria de preensão palmar, equilíbrio, hipermobilidade articular, nível de deambulação e escores do Pediatric Evaluation of Disability Inventory - Computer Adaptative Test (PEDI-CAT). Os dados foram apresentados em média e desvio padrão e comparados por teste t por Mann-Whitney, enquanto os categóricos foram apresentados em frequência e comparados pelo teste exato de Fisher. Análises intragrupos foram realizadas por análise de covariância (ANCOVA) ou Teste de Wilcoxon para postos sinalizados. O teste Tau-b de Kendall foi usado para correlações. Resultados: A idade variou de 6 a 18 anos. A amostra foi dividida em dois grupos de acordo com a gravidade da doença. Casos moderados/graves (n=10) apresentaram menor estatura e força muscular comparadas às dos leves (n=20). Fraqueza muscular foi observada em todos os casos de OI quando comparados à população normal. Não houve diferença nos domínios do PEDI-CAT com exceção do domínio mobilidade. Houve correlação entre o número de fraturas, tipo de OI, peso e equilíbrio e o domínio mobilidade; e entre os domínios Atividades Diárias e Mobilidade e Responsabilidade e Social/cognitivo do PEDI-CAT. Conclusões: Nossos achados sugerem que crianças com OI moderada/severa podem atingir o mesmo nível de funcionalidade que crianças com a forma leve. Fraturas podem ter grande influência no nível de funcionalidade e o tratamento deve enfocar a prevenção e a reabilitação desses eventos. Objetivo . (OI) Métodos 3 médicos bisfosfonatos socioeconômicas palmar articular PEDICAT. PEDICAT PEDI CAT (PEDI-CAT) MannWhitney, MannWhitney Mann Whitney, Whitney Mann-Whitney Fisher ANCOVA (ANCOVA sinalizados Taub Tau b correlações Resultados 1 anos doença moderadosgraves moderados graves n=10 n10 n 10 (n=10 n=20. n20 n=20 20 (n=20) normal mobilidade fraturas Socialcognitivo Social cognitivo CAT. Conclusões moderadasevera moderada severa leve eventos (OI (PEDI-CAT n=1 n1 (n=1 n2 n=2 2 (n=20 n= (n= (n=2 (n

ABSTRACT Bell pepper, a crop of nutritional importance, stands out for its vitamin C content. Given the need for sustainable agricultural practices, the present study explored the use of biochars derived from regional waste as an alternative in bell pepper cultivation. In this context, the present study aimed to evaluate the effect of biochars from poultry litter, coconut fiber, and rice straw on the biometric and physicochemical characteristics of bell pepper fruits, on fruit production per plant and on fruit yield. The experiment was performed in the field in a randomized block design, in a 5 × 3 + 1 factorial scheme, referring to five doses of biochar (0, 3, 6, 9, and 12 t ha-1) and three types of biochar (coconut fiber, poultry litter, and rice straw) with four repetitions, plus an additional treatment (mineral fertilization). Biometric variables (fruit length and diameter, skin thickness, number of fruits, fruit mass) and physicochemical variables of the fruits (soluble solids, titratable acidity, pH, vitamin C, and ash content), production and yield of the fruits were evaluated. The production of bell pepper fruits was not influenced by biochars, but the doses of biochars influenced all variables analyzed with the exception of skin thickness. Vitamin C and soluble solids contents were higher in treatments with biochar and lower with mineral fertilizer. Biochar produced from rice straw had the greatest influence on fruit acidification. importance content practices cultivation context litter fiber design scheme 0, 0 (0 6 9 ha1 ha ha-1 repetitions fertilization. fertilization . fertilization) diameter thickness mass acidity pH content, , content) evaluated fertilizer acidification ( ha-

RESUMO O pimentão, cultura de importância nutricional, destaca-se por seu valor de vitamina C. Diante da necessidade de práticas agrícolas sustentáveis, o estudo explorou o uso de biocarvões derivados de resíduos regionais como alternativa na cultura de pimentão. Nesse contexto, objetivou-se avaliar o efeito de biocarvões provenientes de cama de frango, fibra de coco e palha de arroz, nas características biométricas e físico-químicas de frutos de pimentão verde, na produção de frutos por planta e na produtividade. A pesquisa foi conduzida em campo no delineamento em blocos casualizados, em esquema fatorial 5 × 3 + 1, referentes a cinco doses de biocarvão (0, 3, 6, 9 e 12 t ha-1) e três tipos de biocarvão (fibra de coco, cama de aviário e palha de arroz) com quatro repetições, mais um tratamento adicional (adubação mineral). Foram avaliadas variáveis biométricas (comprimento e diâmetro dos frutos, espessura da casca, número de frutos, massa do fruto) e físico-químicas dos frutos (sólidos solúveis, acidez titulável, pH, vitamina C e teor de cinzas), produção e produtividade dos frutos. A produção de frutos de pimentão verde não foi influenciada pelos biocarvões, porém as doses de biocarvões influenciaram todas as variáveis analisadas com exceção da espessura da casca. Os teores de vitamina C e de sólidos solúveis foram maiores nos tratamentos com biocarvões e menores com adubação mineral. A maior influência na acidificação dos frutos foi com o biocarvão produzido com palha de arroz. nutricional destacase destaca se sustentáveis contexto objetivouse objetivou frango arroz físicoquímicas físico químicas casualizados 1 0, 0 (0 6 ha1 ha ha-1 repetições mineral . mineral) comprimento casca fruto titulável pH cinzas, cinzas , cinzas) ( ha-

Asphaltenes are complex molecules with a tendency to aggregate. This property can be an issue for the oil industry due to CO2 reinjection into reservoirs to mitigate these gas emissions. The present theoretical study aimed to study the CO2 interaction with no-substitute and substituted coronene as an asphaltene model compound at CAM-B3LYP-D3/6-311G(d,p) level. The electronic properties were evaluated using harmonic oscillator model of aromaticity (HOMA), quantum theory of atoms in molecules (QTAIM), and reduced density gradient (RDG) methods. The results showed that the coronene’s functionalization by a sulfur atom changes the coronene’s electronic structure. However, functionalization does not change the type of interactions between the monomers, as they remain predominantly van der Waals interactions. CO2 interaction with substituted coronene barely changed due to the presence of sulfur atoms. However, in dimers, the position of the heteroatom directly influences the interaction with CO2, although it is insufficient to change the interaction’s magnitude. For this reason, our results indicate that the sulfur heteroatom in asphaltenes should be addressed. However, new studies must be conducted by increasing the number of substituents, CO2 numbers, and the model size. aggregate CO emissions nosubstitute no substitute CAMB3LYPD3/6311Gd,p CAMB3LYPD36311Gdp CAMBLYPDGdp CAM B3LYP D3/6 311G d,p D3 6 d p B LYP D G CAM-B3LYP-D3/6-311G(d,p level HOMA, HOMA , (HOMA) QTAIM, QTAIM (QTAIM) RDG (RDG methods coronenes s structure However monomers dimers magnitude reason addressed substituents numbers size CAMB3LYPD3 6311Gd CAMB LYPD Gd Gdp BLYP D36 D3/ dp (HOMA (QTAIM CAMBLYPD CAMB3LYPD

The present study analyzed the chemical composition and phytotoxic activity of Artemisia lancea essential oil (EO). Gas chromatography-mass spectrometry (GC-MS) results showed the presence of 55 compounds, representing 82.36% of the entire EO, with eucalyptol (18.7%) being the most abundant constituent. Phytotoxic bioassay results indicated that the EO (concentration ranging from 0.25-5 mg mL−1) inhibited the growth of Amaranthus retroflexus and Setaria viridis. Root length of A. retroflexus and S. viridis were reduced with the increasing concentration of the EO, especially when the EO was applied at 1-5 mg mL−1. When treated with 1-5 mg mL−1 EO, shoot length of A. retroflexus and S. viridis were also significantly suppressed. The half maximal inhibitory concentration (IC50) values for inhibiting root and shoot growth of A. retroflexus by the EO were 0.284 and 0.246 mg mL−1; for S. viridis, the EO showed IC50 values of 0.44 and 0.262 mg mL−1 for root and shoot inhibition, respectively. The most promising findings were observed when A. lancea EO concentration reached 1 mg mL−1 and higher, which completely inhibited seed germination of A. retroflexus and S. viridis. These findings suggest A. lancea EO has potential as an eco-friendly bioherbicide for agricultural weed control. EO. . (EO) chromatographymass chromatography mass GCMS GC MS (GC-MS 5 compounds 8236 82 36 82.36 18.7% 187 18 7 (18.7% constituent 0.255 0255 0.25 0 25 0.25- mL1 mL A S 15 1- mL− suppressed IC (IC50 0284 284 0.28 0246 246 0.24 IC5 044 44 0.4 0262 262 0.26 inhibition respectively higher ecofriendly eco friendly control (EO 823 8 3 82.3 18.7 (18.7 255 025 0.2 2 (IC5 028 28 024 24 04 4 0. 026 26 82. 18. (18. 02 (IC (18 (1 (

ABSTRACT The purpose of this study was to analyze the influence of attention and skepticism in the evaluation of false market discourse with an environmental appeal (greenwashing). The theoretical support for the research was based on the study of the attention process (understood in terms of pre-attention and attention), as well as the practice of greenwashing and consumer skepticism. The methodological procedure adopted a hypothetical-deductive approach, carried out through two face-to-face experiments (n=129 and n=159) with a 2 factorial design (attention/pre-attention) x 2 (present/absent skepticism), with the measurement of four interest metrics (attribute evaluation, judgment about the practice of greenwashing, emotional reaction to the advertisement, and environmental purchase behavior), added to eye tracking. One-way ANOVA was used for one-dimensional analyzes and general linear model (GLM) ANOVA for multivariate analyses, with Tukey's post hoc test. As a result, it was possible to observe a better evaluation of the practice of greenwashing when pre-attentiveness and the absence of skepticism were combined, which sets up a potential scenario for the influence of this false marketing discourse on consumer behavior. greenwashing. . (greenwashing) understood preattention pre attention, , attention) hypotheticaldeductive hypothetical deductive approach facetoface face n=129 n129 n 129 (n=12 n=159 n159 159 attention/preattention attentionpreattention attention/pre (attention/pre-attention present/absent presentabsent present absent skepticism, skepticism) attribute advertisement behavior, behavior behavior) tracking Oneway One way onedimensional one dimensional GLM (GLM analyses Tukeys Tukey s test result preattentiveness attentiveness combined (greenwashing n=12 n12 12 (n=1 n=15 n15 15 attentionpre n=1 n1 1 (n= n= (n

RESUMO O trabalho teve como objetivo analisar a influência da atenção e do ceticismo na avaliação do falso discurso mercadológico com apelo ambiental (greenwashing). O suporte teórico da pesquisa assentou-se no estudo do processo da atenção (compreendido em termos de pré-atenção e atenção), assim como da prática de greenwashing e o ceticismo do consumidor. O procedimento metodológico adotou uma abordagem hipotético-dedutiva, realizada por meio de dois experimentos presenciais (n=129 e n=159) com desenho fatorial 2 (atenção/pré-atenção) x 2 (ceticismo presente/ausente), com a mensuração de quatro métricas de interesse (avaliação dos atributos, julgamento acerca da prática de greenwashing, reação emocional ao anúncio e comportamento ambiental de compra), somada ao monitoramento ocular (eyetracker). Foram empregadas a ANOVA one-way para as análises unidimensionais e a ANOVA pelo modelo linear geral (GLM) para as análises multivariadas, com o teste post hoc de Tukey. Como resultado, foi possível observar uma melhor avaliação da prática de greenwashing quando da junção da pré-atenção e da ausência do ceticismo, o que configura um cenário de potencialidade da capacidade de influência desse falso discurso mercadológico no comportamento do consumidor. greenwashing. . (greenwashing) assentouse assentou se compreendido préatenção pré atenção, , atenção) consumidor hipotéticodedutiva, hipotéticodedutiva hipotético dedutiva, dedutiva hipotético-dedutiva n=129 n129 n 129 (n=12 n=159 n159 159 atenção/préatenção atençãopréatenção atenção/pré (atenção/pré-atenção presente/ausente, presenteausente presente/ausente presente ausente presente/ausente) atributos compra, compra compra) eyetracker. eyetracker (eyetracker) oneway one way GLM (GLM multivariadas Tukey resultado (greenwashing n=12 n12 12 (n=1 n=15 n15 15 atençãopré (eyetracker n=1 n1 1 (n= n= (n