The exploration of carbon steel corrosion inhibition in 0.5 mol L-1 H2SO4 using extracts from Hymenaea courbaril (HC) has resulted in significant findings. Extracts from the bark, leaves, fruit pulp, and fruit shell have all proven to be effective corrosion inhibitors, as demonstrated through surface studies and electrochemical methods. Infrared spectroscopy and high-performance liquid chromatography have identified the presence of phenolic compounds, which are known to have corrosion-inhibiting potential. UV-Vis spectroscopy has further revealed the adsorption of extract species on the steel surface. Electrochemical studies have confirmed the inhibition of corrosion, allowing to propose mechanisms of both chemisorption and physisorption. X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) have provided evidence of the formation of an inhibitory layer, further supporting the inhibition of corrosion. Langmuir isotherms have indicated favorable adsorption of the extracts, while reduced surface roughness suggests improved protection of the steel surface. Activation energy calculations have demonstrated an increase in energy barriers, resulting in slower corrosion rates. These findings suggest that extracts from Hymenaea courbaril show promise as eco-friendly corrosion inhibitors, with potential industrial applications. Further research is needed to optimize the extraction process and fully understand the inhibition mechanisms. 05 0 5 0. L1 L 1 L- HSO H SO H2SO HC (HC bark leaves pulp inhibitors methods highperformance high performance compounds corrosioninhibiting inhibiting UVVis UV Vis physisorption Xray X ray XPS (XPS energydispersive dispersive SEMEDS SEM EDS (SEM-EDS layer barriers rates ecofriendly eco friendly applications

ABSTRACT The estimation of evapotranspiration (ET) and crop water requirements are crucial for the proper management and allocation of water resources in terms of quantity, quality, and timeliness. Therefore, remote sensing estimation of ET using the SEBAL algorithm (Surface Energy Balance Algorithm for Land) can provide spatio-temporal, non-punctual data, unlike traditional calculations relying on the nearest meteorological station. This research analyzed ET using SEBAL, based on ten Landsat 8 satellite images processed with a program developed in the Model Builder of ArcGis® version 10.2. The analysis was conducted during the vegetative period of starchy corn from May to October 2016. Validation of the results happened with a drainage lysimeter installed in a monitoring plot. Additionally, the statistical indices - such as percentage relative error (PRE) (0,09), root mean square error (RMSE) (0,30), R2 (0,92), and Nash-Sutcliffe efficiency (NASH) (0,91) - indicated a good correlation of ET for starchy corn in the central highlands of Peru. The ET identified at ten monitoring points ranged from 1,05 to 7,79 mm d-1. (ET quantity quality timeliness Therefore Surface Land spatiotemporal, spatiotemporal spatio temporal, temporal spatio-temporal nonpunctual non punctual data station ArcGis 102 10 2 10.2 2016 plot Additionally PRE (PRE 0,09, 009 0,09 , 0 09 (0,09) RMSE (RMSE 0,30, 030 0,30 30 (0,30) R 0,92, 092 0,92 92 (0,92) NashSutcliffe Nash Sutcliffe NASH (NASH 0,91 091 91 (0,91 Peru 105 1 05 1,0 779 7 79 7,7 d1. d1 d 1. d-1 10. 201 00 0,0 (0,09 03 0,3 3 (0,30 0,9 9 (0,92 (0,9 1, 77 7, d- 20 0, (0,0 (0,3 (0, (0 (

Bredemeyera Willd. is a genus of the Polygalaceae family, occurring in Brazil. This research aims to evaluate the phytochemical and antifungal potential, in vitro and in silico, of Bredemeyera brevifolia extracts. The identification of fatty acids by gas chromatography-mass spectrometry and their quantification by gas chromatography-flame ionization detector showed that palmitic (36.55 mg g−1), margaric (3.66 mg g−1), linolelaidic (108.82 mg g−1), oleic (7.86 mg g−1), stearic (41.11 mg g−1), dihomo-γ-linolenic (85.48 mg g−1), and arachidic (209.00 mg g−1) acids are present in the hexane extract. From the chloroform extract, 1-hydroxy-3,7-dimethoxyxanthone was isolated and identified. The minimum inhibitory concentration assay with methanolic extract demonstrated antifungal activity against species of the genus Candida, Sporothrix, and Trichophyton for up to 96 h, with values ranging from 64-1024 μg mL−1. The in silico study with the chemical compounds of this species showed fungal inhibition potential of sterol-14-α-demethylase, highlighting 1-hydroxy-3,7-dimethoxyxanthone, which presented an affinity energy of -8.8 kcal mol−1, greater than that observed for fluconazole (−8.3 kcal mol−1). The fatty acids interacted with the active site of the enzyme but presented energies ≥ −7.4 kcal mol−1. Compounds isolated from this species have pharmacokinetic potential for the development of pharmaceutical formulations. Willd family Brazil extracts chromatographymass chromatography mass chromatographyflame flame 36.55 3655 36 55 (36.5 g−1, g1 g g−1 , 1 3.66 366 3 66 (3.6 108.82 10882 108 82 (108.8 7.86 786 7 86 (7.8 41.11 4111 41 11 (41.1 dihomoγlinolenic dihomo γ linolenic 85.48 8548 85 48 (85.4 209.00 20900 209 00 (209.0 1hydroxy3,7dimethoxyxanthone 1hydroxy37dimethoxyxanthone hydroxydimethoxyxanthone hydroxy 3,7 dimethoxyxanthone identified Candida Sporothrix 9 h 641024 64 1024 64-102 mL1 mL mL−1 sterol14αdemethylase, sterol14αdemethylase sterolαdemethylase sterol 14 α demethylase, demethylase sterol-14-α-demethylase 1hydroxy3,7dimethoxyxanthone, dimethoxyxanthone, 8.8 88 8 -8. mol1 mol mol−1 −8.3 83 (−8. . mol−1) 74 4 −7. formulations 36.5 365 5 (36. g− 3.6 6 (3. 108.8 1088 10 (108. 7.8 78 (7. 41.1 411 (41. 85.4 854 (85. 209.0 2090 20 0 (209. 1hydroxy3 7dimethoxyxanthone 37 3, 64102 102 64-10 mL− αdemethylase 8. -8 mol− −8. (−8 −7 36. (36 3. (3 108. (108 7. (7 41. (41 85. (85 209. 2 (209 1hydroxy 6410 64-1 - −8 (− − ( (10 (4 (8 (20 641 64- (1 (2

The emergence of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) stands for being the most serious epidemic (so far) of the 21st century. However, only a few computational studies have investigated the molecular mechanisms underlying the neutralization of the spike protein by antibodies of different classes. Hence, bioinformatic methods were employed to unravel the factors contributing to the remarkable neutralization capacity exhibited by specific antibodies. Initially, crystallographic structures of IgA monomeric / dimeric, IgG, and IgM antibodies binding with the receptor-binding domain region of the SARS-CoV-2 spike protein were retrieved. Subsequently, rigid molecular docking and molecular dynamic simulations were performed over 100 ns with explicit water solvation. Lastly, an energy decomposition was conducted to estimate the binding affinity using the last frames from molecular dynamics. The results revealed a higher binding affinity for both monomeric and dimeric forms of IgA antibodies against the spike protein. Additionally, a greater number of hydrogen bonds were observed during their interaction with the spike protein, as well as greater structural instability along the time and especially a more thermodynamically favorable interaction affinity. In this way, the research contributes a small piece to the complex puzzle of understanding the humoral immune response induced by the SARS-CoV-2 virus. SARSCoV2 SARSCoV SARS CoV (SARS-CoV-2 so far st century However classes Hence Initially IgG receptorbinding receptor SARS-CoV- retrieved Subsequently 10 solvation Lastly dynamics Additionally way virus (SARS-CoV- SARS-CoV 1 (SARS-CoV

Silver film is commonly used to examine the structure and composition of molecules due to its surface-enhanced Raman scattering (SERS) effect. A simple method for preparing SERS silver films is proposed in this paper by electrodeposition in an amide-based liquid mixture (urea-acetamide-LiBr). The electrochemical behavior of silver in urea-acetamide-LiBr mixture was studied by cyclic voltammetry (CV) and chronoamperometry. It was found that the nucleation mechanism of silver shifts to instantaneous nucleation under diffusion control with increasing overpotential and temperature. The energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) investigations confirmed that the obtained deposits are pure silver. Scanning electron microscopy (SEM) analysis showed that the morphology of the silver deposits depends on the deposition potential and temperature. Rhodamine 6G was used as probe molecules for SERS experiments, showing that these new active substrates have high sensitivity to SERS response with high enhancement factors, of approximately 107, and enable Raman scattering even for diluted solutions. surfaceenhanced surface enhanced (SERS effect amidebased amide based ureaacetamideLiBr. ureaacetamideLiBr urea acetamide LiBr . (urea-acetamide-LiBr) CV (CV chronoamperometry temperature EDS (EDS Xray X ray XRD (XRD SEM (SEM G experiments factors 107 solutions (urea-acetamide-LiBr 10 1

RESUMO O objetivo da pesquisa foi avaliar a secagem da polpa de trapiá com a adição de aditivos de secagem, determinando a cinética de secagem e as propriedades termodinâmicas das amostras. Foram elaboradas formulações a partir da polpa e os aditivos monoglicerídeos, carboximetilcelulose - CMC e goma guar em diferentes combinações e concentrações (F1 - 0,5% de CMC e 0,5% de Monoglicerídeos; F2 - 0,5% de Goma Guar e 0,5% de Monoglicerídeos; e F3 - 0,25% de Goma Guar, 0,5% de CMC e 0,5% de Monoglicerídeos). A secagem foi realizada a 50, 60 e 70 ºC com camadas de 0,5 cm de espessura. A cinética de secagem foi determinada e diferentes modelos matemáticos foram ajustados aos dados. O modelo Midilli foi o que melhor representou a cinética de secagem, com coeficientes de determinação ≥ 0,9985. As difusividades efetivas aumentaram com o aumento da temperatura, com magnitudes da ordem de 10-10 m2 s-1. As variações de entalpia (ΔH) diminuíram com o aumento da temperatura e foram positivas. As variações de entropia (ΔS) foram negativas e inversamente proporcionais à temperatura. A variação da energia livre de Gibbs (ΔG) foi positiva e aumentou com o aumento da temperatura. amostras monoglicerídeos F1 F (F 05 0 5 Monoglicerídeos 025 25 0,25 Monoglicerídeos. . Monoglicerídeos) 50 6 7 0, espessura dados 09985 9985 0,9985 1010 10 10-1 m s1. s1 s 1. 1 s-1 ΔH (ΔH positivas ΔS (ΔS ΔG (ΔG 02 2 0,2 0998 998 0,998 101 10- s- 099 99 0,99 09 9 0,9

ABSTRACT The objective of the research was to study the drying of trapiá pulp with the addition of drying aids, determining the drying kinetics and thermodynamic properties of the samples. Formulations of the pulp was treated with the additives monoglycerides, carboxymethylcellulose - CMC and guar gum in different combinations and concentrations (F1 - 0.5% CMC and 0.5% Monoglycerides; F2 - 0.5% Guar Gum and 0.5% Monoglycerides; and F3 - 0.25% Guar Gum, 0.5% CMC and 0.5% Monoglycerides) trapiá. Drying was carried out at 50, 60 and 70 ºC with 0.5 cm thick layers. The drying kinetics were determined, and different mathematical models fitted to the data. The Midilli model best represented the drying kinetics, with determination coefficients ≥ 0.9985. The effective diffusivities increased with increase in temperature with magnitudes to the order of 10-10 m2 s-1. The enthalpy variations (ΔH) reduced with increase in temperature and were positive. The entropy variations (ΔS) were negative and inversely proportional to the temperature. The variation in Gibbs free energy (ΔG) was positive and increased with increase in temperature. aids samples monoglycerides F1 F (F 05 0 5 Monoglycerides 025 25 0.25 50 6 7 0. layers determined data 09985 9985 0.9985 1010 10 10-1 m s1. s1 s 1. 1 s-1 ΔH (ΔH ΔS (ΔS ΔG (ΔG 02 2 0.2 0998 998 0.998 101 10- s- 099 99 0.99 09 9 0.9

Abstract Introduction: The nursing area should perform a comprehensive assessment of adolescents and young people to be able to have an early intervention in the risk habits of this part of the population. Objective: Know how the consumption of energy drinks affects the mental health of adolescents and young adults. Methodology: Systematic review using selected reports for systematic reviews and PRISMA meta-analysis, searching Web Of Science, Medline, Scopus and Pubmed databases with descriptors such as energy drinks, mental health, young adult and adolescent. The inclusion criteria included articles published between 2017 and 2022, in Spanish, English or Portuguese, in the population aged 13 to 25, excluding secondary research, editorials, letters to the editor and expert opinions, not available in full text. Identifying 372 articles, leaving a sample of 10 for analysis and methodological evaluation using CASPe guidelines. Data used were duly referenced, respecting and identifying their authors. Results: The majority were studies using cross-sectional design. Frequent consumption of energy drinks increased levels of anxiety, depression, aggression and suicidal risk, with male adolescents being more affected. Conclusions: Although there was evidence of a relationship between energy drink consumption and mental health risks, most of the research used cross-sectional designs, so it was not possible to determine causality or direction of effect. In order to study the effect of energy drink consumption in depth, longitudinal studies and interventions are required since consumption is frequent and mental health problems are on the rise.

Abstrato Introdução: A área de enfermagem deve realizar uma avaliação abrangente dos adolescentes e jovens para poder intervir precocemente nos hábitos de risco dessa parcela da população. . Objetivo: Conhecer como o consumo de bebidas energéticas afeta a saúde mental de adolescentes e adultos jovens. Metodologia: Revisão sistemática usando relatórios selecionados para revisões sistemáticas e meta-análise PRISMA, pesquisando nos bancos de dados Web Of Science, Medline, Scopus e Pubmed com descritores como bebidas energéticas, saúde mental, adultos jovens e adolescentes. Os critérios de inclusão foram artigos publicados entre 2017 e 2022, em espanhol, inglês ou português, na população de 13 a 25 anos, excluindo pesquisas secundárias, editoriais, cartas ao editor ou opiniões de especialistas, não disponíveis em texto completo. Identificando 372 artigos, restando uma amostra de 10 para análise e avaliação metodológica utilizando as diretrizes do CASPe. Os dados utilizados foram devidamente referenciados, respeitando e identificando seus autores. Resultados: A maioria era de estudos com desenho transversal. O consumo frequente de bebidas energéticas aumentou os níveis de ansiedade, depressão, agressão e risco de suicídio, sendo os adolescentes do sexo masculino os mais afetados. Conclusões: Embora houvesse evidências de uma relação entre o consumo de bebidas energéticas e os riscos à saúde mental, a maioria das pesquisas utilizou desenhos transversais, de modo que não foi possível determinar a causalidade ou a direção do efeito. Para estudar o efeito do consumo de bebidas energéticas em profundidade, são necessários estudos longitudinais e intervenções, já que o consumo é frequente e os problemas de saúde mental estão aumentando.

Resumen Introducción: Enfermería debe realizar una valoración integral de adolescentes y jóvenes para poder intervenir en forma temprana sobre hábitos de riesgo. Objetivo: Conocer cómo afecta el consumo de bebidas energéticas en la salud mental de adolescentes y adultos jóvenes. Metodología: Revisión sistemática empleando informes preferidos para revisiones sistemáticas y metaanálisis PRISMA, realizando búsqueda en bases de datos Web Of Science, Medline, Scopus y Pubmed con descriptores bebidas energéticas, salud mental, adulto joven y adolescente, los criterios de inclusión fueron; artículos publicados entre 2017 y 2022, en idioma español, inglés o portugués, en población de 13 a 25 años, excluyendo investigaciones secundarias, editoriales, cartas al editor u opiniones de expertos, no disponibles en texto completo. Identificando 372 artículos, quedando una muestra de 10 para análisis y evaluación metodológica mediante pautas CASPe. Los datos utilizados fueron debidamente referenciados, respetando e identificando a sus autores. Resultados: La mayoría fueron estudios con diseño transversal, el ser consumidor frecuente de bebidas energéticas aumentó niveles de ansiedad, depresión, agresividad y riesgo suicida, siendo más afectados los adolescentes de género masculino. Conclusiones: Si bien se evidenció relación entre consumo de bebidas energéticas y riesgos para la salud mental, la mayoría de las investigaciones utilizaron diseños transversales, por lo cual no fue posible determinar causalidad o dirección del efecto. Se requieren estudios longitudinales e intervenciónes para estudiar con profundidad el consumo de bebidas energizantes, debido a que el consumo es frecuente y los problemas de salud mental van en aumento.

Abstract Cool materials have higher values of solar reflectance and lower values of thermal emittance, although still high when compared to conventional coatings, thus, their surfaces are less heated. In this regard, the goal was to identify the chemical elements present on cool surfaces that influence solar reflectance and thermal emittance. To this end, the spectral reflectance and the thermal emittance were measured with methods and equipment standardized by the Cool Roof Rating Council (CRRC) of 23 elastomeric cool coatings commercialized in the Brazilian market, and the chemical composition of the surfaces with EDS (Energy-dispersive X-ray detector) coupled to the field emission scanning electron microscope (FE-SEM) was analyzed. The presence of the metallic chemical element (titanium) in greater quantities on the surfaces was not decisive for lower thermal emittance values. The surfaces of materials with lower carbon and higher oxygen content have higher near infrared and solar reflectance. Therefore, surfaces with a matte finish have higher solar reflectance values because of the higher ratio of pigments in relation to resin than those with a glossy finish, which are mistakenly associated with higher reflectance due to its high surface gloss. thus heated regard end CRRC (CRRC 2 market Energydispersive Energy dispersive Xray X ray detector FESEM FE SEM (FE-SEM analyzed titanium (titanium Therefore gloss

Resumo Os materiais frios possuem maiores valores de refletância solar e menores, apesar de elevados, de emitância térmica comparados aos revestimentos convencionais, desta forma, aquecem menos suas superfícies. Assim, o objetivo foi identificar os elementos químicos presentes nas superfícies frias que influenciam na refletância solar e emitância térmica. Para isso, foram medidas a refletância espectral e a emitância térmica com métodos e equipamentos normatizados pelo Cool Roof Rating Council (CRRC) de 23 revestimentos frios elastoméricos do mercado brasileiro e analisada a composição química das superfícies com EDS (detector de energia dispersiva de raios-x) acoplado ao microscópio eletrônico de varredura por emissão de campo (SEM-FEG). A presença do elemento químico metálico (titânio) em maiores quantidades nas superfícies não foi determinante para menores valores de emitância térmica. As superfícies dos materiais com menor quantidade de carbono e maior em oxigênio possuem maior refletância no infravermelho próximo e solar. Portanto, superfícies com acabamento superficial fosco têm maiores valores de refletância solar por causa da maior proporção de pigmentos em relação à resina do que as de acabamento brilhante, que erroneamente são associadas com maior refletância por causa do alto brilho superficial. elevados convencionais forma Assim isso CRRC (CRRC 2 detector raiosx raios x raios-x SEMFEG. SEMFEG SEM FEG . (SEM-FEG) titânio (titânio Portanto brilhante (SEM-FEG

Abstract Introduction. Seedlings formation under controlled conditions is crucial for cultivating species like strawberry. With LED artificial lighting technology allowing greater control over light, variations in components such as wavelength and intensity can be manipulated to generate seedlings with different characteristics. However, there is a need to generate information for the development of precise and efficient light control practices. Objective. The evaluate strawberry seedling formation under different intensities of violet, blue, and red LED light. Material and methods. The study was conducted in 2020 at the Plant Genetics Laboratory of the Department of Agronomy at the Universidad de Guanajuato, Guanajuato, Mexico. Seeds from San Andreas variety fruits were collected, and seedlings were grown under violet, blue, and red LED light at high, medium, and low intensities. Color determinations of cotyledon area, Chroma saturation index, and Hue angle were performed. Additionally, physio-technical, chemical, and antioxidant activity variables were measured. Results. The most suitable treatments were high and medium intensity violet light, as well as high intensity blue light, with germination range exceeding 60 %. Seedlings did not elongate or thin out and exhibited the largest cotyledons areas and chlorophyll concentrations. Furthermore, these light treatments consumed, on average, 31.2 % less electrical energy. Conclusions. In addition to white light, the most suitable treatments for strawberry seedlings formation were high and medium intensity violet light, as well as high intensity blue light. It is suggested to evaluate violet and blue light treatments in other cultivars to confirm their positive effect on strawberry seedlings. Red light limited germination and showing higher antioxidant activity.

Resumen Introducción. La formación de plántulas en condiciones controladas es fundamental para cultivar especies como la fresa. Dado que la tecnología de iluminación artificial LED ha permitido un mayor control de la luz, la variación de componentes como la longitud de onda y la intensidad pueden ser manipulados para generar plántulas con diferentes características. Sin embargo, es necesario generar información para el desarrollo de prácticas precisas y eficientes en el control de la luz. Objetivo. Evaluar la formación de plántulas de fresa en diferentes intensidades de luz LED violeta, azul y roja. Materiales y métodos. El estudio se realizó durante 2020 en el Laboratorio de Genética Vegetal del Departamento de Agronomía de la Universidad de Guanajuato, Guanajuato, México. Se recuperaron semillas de frutos de la variedad San Andreas y se sembraron plántulas en luz LED violeta, azul y roja a intensidades alta, media y baja. Se realizaron determinaciones de color del área del cotiledón, índice de saturación de color y ángulo Hue. Además, se midieron variables fisiotécnicas, químicas y actividad antioxidante. Resultados. Los tratamientos más adecuados fueron luz violeta de intensidades altas y medias; así como luz azul de alta intensidad, debido a que el porcentaje de germinación superó el 60 %. Las plántulas no se alargaron ni adelgazaron, presentaron las mayores áreas de cotiledones y concentraciones de clorofila. Además, estos tratamientos de luz consumieron en promedio 31,2 % menos energía eléctrica. Conclusiones. Además de la luz blanca, los tratamientos más adecuados para la formación de plántulas de fresa fueron la luz violeta a alta y media intensidad, así como la luz azul a alta intensidad. Se sugiere evaluar los tratamientos de luz violeta y azul en otros cultivares para confirmar el efecto positivo en las plántulas de fresa. La luz roja limitó la germinación y mostró mayor actividad antioxidante.

Abstract: The aesthetic integration of solar systems with multi-family buildings remains rare in Latin American countries. This article considers sixty-five projects by architecture students in Lima (Peru) to establish compositional criteria using typological classifications of the solar system layout on the roofs, volumetric composition, and their relationship with façades and lower spaces. The results show a wide range of variables that must be resolved. However, there are limitations to understanding this integration when dealing with the inclination of roofs as well as the coherence and geometric arrangement in irregular configurations. More emphasis is required on understanding the interior organisation and its implications for solar systems when designing multi-family houses. Previous research on the quantification of solar incidence has already been published; however, more research for further aesthetic assessments in medium-density multi-family dwellings could be carried out in the future.

Resumen: La integración estética de sistemas solares en multifamiliares es un desafío todavía inédito en países latinoamericanos. Sesenta y cinco proyectos desarrollados por estudiantes de arquitectura en Lima (Perú) fueron considerados para establecer criterios de composición mediante clasificación tipológica a nivel de disposición de los sistemas fotovoltaicos, composición volumétrica, relación con las fachadas y los espacios inferiores. Los resultados demuestran múltiples posibilidades. Sin embargo, existen limitaciones para entender esta integración cuando se trata de la inclinación de los techos, así como la coherencia y la disposición geométrica en las configuraciones irregulares obtenidas. Tratándose de multifamiliares y debiendo lidiar con aspectos técnicos, se requiere mayor énfasis en la comprensión de la organización interior y sus implicancias con los sistemas solares. Una investigación previa relacionada a la cuantificación de la incidencia solar ha sido ya publicada, sin embargo, investigaciones para mayores evaluaciones estéticas en multifamiliares de media densidad podrían realizarse a futuro.

Abstract The present work focuses on a construction in Spanish, censured by grammarians, which combines the morphology of the analytical or periphrastic passive (ser ‘be’ + participle) with the multifunctional reflexive morpheme se and typically serves to generalize over processes affecting classes of things or groups of individuals (La energía incrementa cuando se es contenida ‘Energy increases when (it is) contained’). Our interest in the genesis of the construction leads us to locate its source in a regular structure of the language, known as the “impersonal reflexive with a passive clause”, wherein se marks the unspecified identity of the patient subject (cuando se es amado…‘when one is loved...’). Viewed from this angle, the “deviant” feature of the construction in study thus resides in the introduction of an explicit subject, which has the effect of erasing the impersonal character of the source and of altering the function of se in ways that will impose a reference to the so-called reflexive passive of Spanish. In the second part of our research, we seek to account for the productivity of the anomalous construction, discovered through our perusal in Google, by calling attention to the instrumental role played by the participle in allowing shifts of perspective between passive actions and resulting states. We discuss some examples to corroborate our hypothesis, highlight the expansion of the construction to non-generic contexts and, as our final task, take on the challenge of having to explain how the anomalous passive comes to be used with intransitive unaccusative verbs, as evidenced in the data of our corpus.

Resumen Este trabajo se centra en una construcción en español, censurada por los gramáticos, que combina la morfología de la pasiva perifrástica (ser + participio) con el multifuncional morfema reflexivo se y típicamente sirve para generalizar sobre procesos que afectan a clases de cosas o grupos de individuos (La energía incrementa cuando se es contenida). El interés por la formación de la construcción nos lleva a situar su origen en una estructura regular del idioma, conocida como “impersonal refleja con oración pasiva”, en la que se marca la indeterminación del sujeto paciente (cuando se es amado…). Desde este punto de vista, la “desviación” que manifiesta la construcción en estudio radica en la introducción de un sujeto explícito, con el efecto de que se borra el carácter impersonal del modelo original y se altera a la vez la función de se, que pasa a relacionarse con la llamada pasiva refleja del español. En la segunda parte de nuestra investigación, nos proponemos arrojar luz sobre la productividad de la construcción anómala, que desplegaron nuestras búsquedas en Google, apuntando al papel instrumental que juega el participio en propiciar cambios de perspectiva entre acciones pasivas y estados resultantes. Analizamos algunos ejemplos que ayudan a corroborar nuestra hipótesis, destacamos la expansión de la construcción a contextos no-genéricos y, finalmente, nos damos a la tarea de explicar cómo la pasiva anómala llega a utilizarse con verbos intransitivos inacusativos, según reflejan los datos recopilados para nuestro estudio.

Abstract Since 2010, there has been an approximate annual increase of 1% in CO2 emissions due to buildings. The reduction of energy consumption and consequently the mitigation of Greenhouse Gases are global goals due to the global issue of climate change. A key step in achieving these goals is to improve the energy performance of buildings, thereby reducing energy consumption and emissions generated by the built environment. In this regard, the present research focuses on identifying and estimating strategies to reduce energy consumption in buildings known as Community Police Units (UPCs) located in the city of Guayaquil, which corresponds to a very hot and humid climate zone. The study consists of statistical analysis of the historical energy performance of 43 buildings sharing the same architectural design. Additionally, the selection of a representative building was made for energy use monitoring and energy simulation. The results revealed a potential saving of 16 000 kWh per year by reducing the control temperature of the air conditioning system by 1°C and adjusting the on/off schedule. This is equivalent to 1 150 USD and 5 metric tons of CO2 emissions.

Resumen: Desde el 2010 existe un incremento aproximado del 1% anual respecto a las emisiones de CO2 a causa de los edificios. La disminución del consumo energético y consecuentemente la mitigación de los Gases de Efecto Invernadero son metas a nivel mundial debido a la problemática global del cambio climático. Un paso clave para alcanzar estas metas es mejorar el desempeño energético de las edificaciones y de esta manera reducir la energía consumida y las emisiones generadas por el parque edificado. En este sentido, la presente investigación se centra en identificación y estimación de estrategias para reducir el consumo de energía de los edificios llamados Unidades de Policía Comunitaria (UPC) localizadas en la ciudad de Guayaquil, y que corresponde a una zona climática húmeda muy calurosa. El estudio está compuesto por el análisis estadístico del rendimiento energético histórico de 43 edificios, que comparten el mismo diseño arquitectónico. Además, se realizó la selección de un edificio representativo para el monitoreo del uso de energía y simulación energética. Los resultados evidenciaron un potencial de ahorro de 16 000 kWh al año, al disminuir 1°C la temperatura de control del sistema de climatización y modificando el horario de encendido y apagado. Esto es equivalente a 1 150 USD y 5 toneladas equivalentes de CO2.

Abstract: Smart Grids have revolutionized the electricity industry by enabling more efficient control and monitoring of the electricity supply, with a key component being smart meters (SM). These collect information on demand, energy, and harmonic distortion, among others, which must be stored and managed efficiently in a metering data management system (MDMS). The MDMS must ensure that a complete set of data is obtained for use in algorithms to ensure the reliability and quality of the power supply. To address the challenge of management the big data generated by SM, short, medium, and long-term measurement forecasting techniques have been proposed, highlighting the use of artificial intelligence such as Artificial Neural Networks (ANN) and Deep Learning (DL) methods due to their ability to adapt to different input and output variables with various time horizons. In addition, the influence of the diversity of Information and Communication Technologies (ICT) on the update time and data storage in the MDMS is highlighted. In this sense, this work aims to identify which ANN or DL architecture(s) could be more suitable for enterprise, survey, or research applications, demonstrating favorable performance metrics in different scenarios of sampling frequency and typical data update times in Smart Grids. This is relevant due to the need for MDMS to perform multivariate and multi-pass predictions in the short term to complete the information until the information is available or updated.

Resumen: Las Redes Eléctricas Inteligentes de Distribución (REID) han revolucionado la industria eléctrica al permitir un control y monitoreo más eficiente del suministro eléctrico, con un componente clave siendo los medidores inteligentes (SM). Estos recopilan información sobre la demanda, energía, distorsión armónica, entre otros, que deben ser almacenados y gestionados eficientemente en un sistema de gestión de datos de medición (MDMS). El MDMS debe garantizar la obtención de un conjunto completo de datos para su uso en algoritmos que aseguren la confiabilidad y calidad del suministro eléctrico. Para abordar el desafío de gestionar la gran cantidad de datos generados por los SM, se han propuesto diferentes técnicas de predicción de mediciones a corto, mediano y largo plazo, destacando el uso de inteligencia artificial como las Redes Neuronales Artificiales (ANN) y métodos de Aprendizaje Profundo (DL) debido a su capacidad de adaptación a diferentes variables de entrada y salida con diversos horizontes temporales. Además, se destaca la influencia de la diversidad de Tecnologías de la Información y Comunicación (TIC) en el tiempo de actualización y almacenamiento de datos en un MDMS. En este sentido, este trabajo tiene como objetivo identificar qué arquitectura o arquitecturas de ANN o DL podrían ser más adecuadas para aplicaciones en empresas, estudios o investigaciones, demostrando métricas de rendimiento favorables en diferentes escenarios de frecuencia de muestreo y tiempos de actualización de datos típicos en un REID. Esto es relevante debido a la necesidad del MDMS de realizar predicciones multivariables y multipaso a corto plazo para completar la información, hasta que la misma esté disponible o se actualice.

Abstract: The objective of this research focuses on the numerical solution, simulation, and thermal behavior of the refrigerants R32 and R600a, the first being an industrial refrigerant and the other a hydrocarbon, the element to be studied is the internal temperature of a vehicle cabin, the air crosses the evaporator of the air conditioning system by analyzing the coil-type crossflow heat exchanger. Likewise, it is important to know the energy capacity that each refrigerant has to cool or heat the vehicle cabin to, after a mathematical analysis, contrast the information through numerical simulation of CFD fluids with specialized software in this case Fluent from ANSYS.

Resumen: El objetivo de esta investigación se centra la solución numérica, simulación y comportamiento térmico de los refrigerantes R32 y R600a, siendo el primero un refrigerante industrial y el otro un hidrocarburo, el elemento a estudiar es la temperatura interna de una cabina vehicular, el aire cruza el evaporador del sistema de aire acondicionado mediante el análisis del intercambiador de calor de flujo cruzado tipo serpentín. Asimismo, es importante conocer la transferencia de calor que tiene cada refrigerante para enfriar o calentar la cabina del vehículo, para en un análisis matemático posterior llevar un contraste de la información mediante la simulación numérica de fluidos CFD con un software especializado en este caso Fluent de ANSYS. Se encontró que el refrigerante R600a es una alternativa para los sistemas de aire acondicionado vehicular y el R32 no es tan aplicable para estos casos.

ABSTRACT Considering previous studies on the potential use of vinasse in the agricultural sector, this study seeks to design a feed for broilers in three presentations according to the stages of the animal’s feeding program (start 1-14, growth 15-30 and end 31-42 days) that includes vinasse in the formulation. To this end, soybeans were considered as a source of protein, a diet with metabolizable energy between 12,351.06 and 14,025.78 kJ∙kg-1. The granulometry was determined according to the broiler management manuals, and the feed manufacturing process was specified in a block diagram and a flow diagram; in the same way, a test protocol for the use of the feed formulated in a sample of broilers of the Cobb breed. This research suggests that using vinasse in feed formulations for broilers could provide significant benefits to the agricultural sector.

RESUMEN Considerando estudios previos sobre el potencial uso de la vinaza en el sector agropecuario, este estudio busca diseñar un alimento para pollos de engorde en tres presentaciones de acuerdo con las etapas del programa de alimentación del animal (inicio 1-14, crecimiento 15-30 y finalización 31-42 días) que incluya vinaza en la formulación. Para ello, se consideró el grano de soya como fuente de proteína, una dieta con energía metabolizable entre 12.351,06 a 14.025,78 kJ∙kg-1. Se determinó la granulometría de acuerdo con los manuales de manejo de pollos de engorde, y se especificó el proceso de fabricación del alimento en un diagrama de bloques y un diagrama de flujo; de igual forma se propone un protocolo de prueba para el uso del alimento formulado en una muestra de pollos de engorde de la raza Cobb. Esta investigación sugiere que el uso de la vinaza en las fórmulas de los beneficios para pollos de engorde podría aportar importantes beneficios al sector agrícola.