Resumo O objetivo deste trabalho foi avaliar a qualidade fisiológica e quantificar a eficácia do polímero na retenção de perdas por lixiviação do tratamento fitossanitário em sementes de soja com diferentes diâmetros e tratadas sob diferentes formas. Foram utilizados dois lotes de sementes com diferentes diâmetros e foram realizadas duas formas de aplicação do tratamento: polímero associados ao tratamento fitossanitário na mesma calda e aplicação do polímero em camada após o tratamento, sendo os tratamentos formados da seguinte maneira: Control= sem tratamento, Treat+pol= Tratamento fitossanitário + polímero aplicados na mesma calda, Treat/pol= Tratamento fitossanitário + polímero aplicados em camadas, Treat= Tratamento fitossanitário. Para avaliação da retenção do tratamento pelo polímero foi utilizado um extrator e realizada a quantificação do ingrediente ativo tiametoxam lixiviado. Para avaliação da qualidade fisiológica foram realizados os testes de germinação, primeira contagem, emergência, envelhecimento acelerado, comprimento de plântulas, massa seca de plântulas e grau de umidade. A aplicação de polímero associado ao tratamento fitossanitário de sementes foi eficiente na diminuição das perdas por lixiviação, reduzindo em 20% a perda de produtos. Não houve diferença na capacidade de retenção e na qualidade fisiológica entre as diferentes formas de aplicação do polímero. Sementes de maior tamanho apresentam maior vigor, porém a germinação não é afetada.

Abstract This study evaluated the physiological quality and quantified the efficiency of polymer in reducing the loss of phytosanitary products by leaching from soybean seeds of different diameters and in different treatments. Two lots of seed and two types of treatments were tested: polymers associated with seed treatment, and polymer application in layers after the seed treatment. For that, the following treatments were analyzed: Control= no seed treatment; Treat+pol= seed treatment + polymers in the mix; Treat/pol= seed treatment + polymers applied in layers; Treat= seed treatment. To evaluate seed treatment retention by the polymers, extraction equipment was employed and leaching of the active ingredient thiamethoxam was quantified. Evaluation of physical quality was conducted with tests of germination rate, first count, emergence rate, accelerated aging, seedling length, seedling dry mass and moisture content. Polymer application associated with seed treatment was efficient in reducing losses by leaching, reducing product loss by 20%. No significant differences in retention and physiological quality were found when different methods for polymer application were compared. Bigger seeds presented greater vigor, but the germination rate was unaffected.

A simple, fast and efficient method was developed for determination of six synthetic dyes (Tartrazine, Sunset Yellow, Amaranth, Ponceau 4R, Indigo Carmine and Brilliant Blue) in sports drinks using dispersive solid-phase extraction (d-SPE) with the polymeric sorbent Oasis® HLB. Sample preparation using d-SPE permitted to simplify the procedure and use less sorbent in comparison with SPE. The use of a syringe for the elution step make this easier and avoid the use of a manifold. High performance liquid chromatography with UV-Vis detection was employed for quantification. Recovery results, evaluated at 0.5; 1.0 and 1.5 mg L-1, were between 76 and 108% with relative standard deviation < 18%. The method limit of quantification was 0.5 mg L-1. The developed method was applied to the analysis of commercial sports drinks and the results indicated that all studied samples presented dye levels in conformity with the Brazilian legislation.

RESUMO O uso do tratamento químico de sementes é uma importante ferramenta na proteção de plântulas e tem contribuído com a elevação da produtividade de arroz (Oryza sativa L.). Objetivou-se avaliar a qualidade fisiológica e quantificar a retenção de produtos químicos em sementes de arroz tratadas com inseticida e fungicida recobertas com polímeros. Foram utilizados seis tratamentos de sementes: controle, tratamento fitossanitário e tratamento fitossanitário e recobrimento com os polímeros, Florite 1127®, Resina Sólida GV5®, Polyseed CF® e o VermDynaseed®. A qualidade fisiológica foi avaliada pelo teste de germinação e vigor pelos testes de primeira contagem, índice de velocidade de germinação, comprimento de parte aérea, comprimento de radícula, massa seca de plântulas e emergência em areia. Para determinar a retenção dos ingredientes ativos metalaxil-M e thiamethoxam, utilizou-se equipamento denominado extrator. O experimento foi organizado no delineamento inteiramente casualizado (DIC) e as médias foram separadas pelo Scott Knott (p≤0,05).O tratamento de sementes com o fungicida e inseticida, recobertos com os polímeros,Florite 1127®, ResinSolid GV5®, Polyseed CF® e o VermDynaseed®, não afetaram a qualidade fisiológica de sementes de arroz. Os polímeros ResinSolid GV5®, Polyseed CF® e o VermDynaseed® foram eficientes na retenção do thiamethoxam junto às sementes de arroz, impedindo que parte do ingrediente ativo do inseticida fosse lixiviado, através das colunas de areia, logo após a precipitação pluvial simulada.

ABSTRACT The use of chemical seed treatment is an important tool in the protection of seedlings and has contributed to the increase of rice yield (Oryza sativa L.). The objective of this study was to evaluate the physiological quality and quantify the retention of chemical products in rice seeds treated with insecticide and fungicide coated with polymers. Six seed treatments were used: control, phytosanitary treatment and phytosanitary treatment and coating with the polymers, Florite 1127®, GV5® Solid Resin, Polyseed CF® and VermDynaseed®. The physiological quality was evaluated by the test of germination and vigor by first count tests, germination speed index, shoot length, radicle length, seedling dry mass and sand emergence. To determine the retention of the active ingredients metalaxyl-M and thiamethoxam, an equipment called extractor was used. The experiment was organized in a completely randomized design (DIC) and the averages were separated by the Scott Knott test (p≤0.05). Seed treatment with the fungicide and insecticide, coated with the polymers, Florite 1127®, Solid Resin GV5®, Polyseed CF® and VermDynaseed®, did not affect the physiological quality of rice seeds. Solid Resin GV5®, Polyseed CF® and VermDynaseed® polymers were efficient at retaining thiamethoxam in the rice seeds, preventing some of the active ingredients of the insecticide from being leached through the sand columns immediately after the simulated pluvial precipitation.