The aim of this work was the study a trickling biofilter, where water was circulated throughout the bed. In the first steady state experiment, the packing materials used were 25mm Pall rings. The airflow rate was increased gradually and the concentration of styrene in the air stream was held constant. In the second experiment, 15mm Pall rings were used. In this case, the feed contained both styrene and a small amount of acetone. The concentration of acetone and the air flow rate were kept constant, but the styrene inlet concentration was increased. The concentrations were measured at the input, and also at an intermediate and the outlet position in the biotrickling filter to determine the concentration profile along the reactor. Using the values of coefficient of determination (R²) and the coefficient of variation of the fitted constant as criteria, a zero order model with diffusional limitation was chosen as the best representation of the data. Then a further, third, set of experiments were done at unsteady state, using step changes of the inlet concentration levels of both styrene and acetone at a steady air flow-rate . Inlet and outlet concentrations were measured as a function of time and the results were adequately described using a simple first order model.

The objective of this work was to evaluate toluene degradation in a trickle bed reactor when the loading was carried out by changing the air flow rate. The biofiltration system was inoculated with a mixed microbial population, adapted to degradation of hydrophobic compounds. Polypropylene high flow rings were used as a packing material. The system was operated for a period of 50 days at empty bed residence times ranging from 106s to 13s and with a constant inlet concentration of toluene of 100 mg.m-3. The reactor showed high removal efficiency at higher contact times and increasing elimination capacity with higher air-flow rates. The highest EC value reached was 9.8 gC.m-3.h-1 at EBRT = 13s. During the experiment, the consumption of NaOH solution was also measured. No significant variation of this value was found and an average value of 3.84 mmol of NaOH per gram of consumed carbon was recorded.

Este artigo propõe o uso de uma etapa preliminar de remoção de fenol para redução de picos de carga na entrada de sistemas convencionais de tratamento de efluentes. Um reator de leito fixo (RLF) foi usado, tendo como suportes inertes espuma de poliuretano, vidro poroso e também fibras de coco. Nos experimentos foram controladas a vazão e as concentrações de fenol de entrada e saída. Um simples modelo plug-flow é proposto para representar os resultados. Cinéticas de zero e primeira ordens, Monod e de inibição foram avaliadas. Foi verificado que o modelo de Monod foi o que melhor se ajustou aos dados experimentais, permitindo que gráficos lineares fossem traçados. A constante saturação de Monod, K, é de aproximadamente 50 g m-3 e ka em torno de 900 s-1.

This paper proposes the use of a preliminary, phenol removal step to reduce peak loads arriving at a conventional effluent plant. A packed bed reactor (PBR) using polyurethane foam, porous glass and also cocoa fibres as the inert support material was used. Experiments have been carried out where the flow-rates, plus inlet and outlet phenol concentrations were measured. A simple, plug-flow model is proposed to represent the results. Zero, first order, Monod and inhibited kinetics rate equations were evaluated. It was found that the Monod model gave the best fit to the experimental data and allowed linear graphs to be plotted. The Monod saturation constant, K, is approximately 50 g m-3, and ka is around 900 s-1.