Abstract The Vila Jussara Suite (VJS) is formed by Neoarchean (~ 2.75 Ga) granites that are located in the Sapucaia Domain of the Carajás Province (CP), Amazonian Craton. Four petrographic varieties were identified in the VJS: biotite-hornblende monzogranite (BHMzG); biotite-hornblende tonalite (BHTnl); biotite monzogranite (BMzG); and hornblende-biotite granodiorite (HBGd). In terms of magnetic signature, BHMzG has two subgroups: the first subgroup has low magnetic susceptibility (MS) values (0.16 × 10-3 to 0.81 × 10-3) and more commonly contains ilmenite with titanite rims; the second subgroup shows moderate to high MS (1.91 × 10-3 to 6.02 × 10-3) and magnetite dominant over ilmenite. BHTnl has moderate MS (0.85 × 10-3 to 1.36 × 10-3) and dominance of pyrite followed by magnetite. BMzG and HBGd have comparatively high MS (3.35 × 10-3 to 19.3 × 10-3 and 2.14 × 10-3 to 25.0 × 10-3, respectively), with magnetite dominant over pyrite. The granite varieties of the VJS were formed under different oxygen fugacity (fO2) conditions, varying from reducing (< fayalite-magnetite-quartz (FMQ)) to oxidizing conditions (nickel-nickel oxide (NNO) to NNO+1). In addition, biotite-hornblende syenogranite occurs subordinately and shows high MS values and extremely high FeOt/(FeOt + MgO) ratios, both in whole-rock and amphibole and biotite. The granites of the VJS are similar to other Neoarchean granites of the Carajás province. The reduced VJS granites are akin to the ferroan granites of Planalto suite, Estrela Complex and Vila União area and the magnesian granites of VJS approach the magnesian granites of Vila União area.

Abstract We present this manuscript as a methodological approach and general guidelines for geochemical mapping and background/baseline projects for environmental assessment in tropical areas. A case study was carried out in the Itacaiúnas River watershed (IRW), Eastern Amazon, to fill in a gap in knowledge on the distribution of chemical elements, particularly those potentially toxic, in the near-surface environment of the area. The high-impact results of this research project revealed the need for similar scientific investigation across the globe with the implementation of a systematic methodology. The study shows, for example, the importance of well-planned field activities, multi-medium sampling, analytical methods, laboratory procedures, database construction, and general aspects of data processing and statistical treatment. The importance of this contribution is that it can be used as a reference in support of geospatial analysis in research within the scope of geochemical mapping and background-baseline projects. The database is accessible through a web-based geographic information system front-end; a Geochemical Atlas of the IRW will be available as soon as possible.

Abstract The Pedra Branca suite (2.75 Ga) is located in the Canãa dos Carajás domain in the southeastern Amazonia Craton. It diverges from typical TTG in mineralogical and geochemical terms, by the presence of hornblende and clinopyroxene and because it has a high content of HFSE (Zr, Y, Ti, and Nb). It belongs to the low-K subalkaline series, which varies from metaluminous to peraluminous, and are mostly calc and ferroan granitoids. Amphibole is calcic and classified as ferroan-edenite, and hastingsite. Plagioclase is mainly oligoclase. The Fe/(Fe + Mg) ratios found in the amphiboles indicate that these granitoids were formed under high to moderate fO2 conditions. Geobarometric calculations suggest pressures between 9.3 and 71 Kbar for the origin and 4.8-53.4 Kbar for the emplacement. Geothermometric calculations suggest initial crystallization temperatures between 945 and 862°C, and the water content in the magma is estimated to be higher than 4 wt%. The magma source was defined as tholeiitic continental gabbro melted in an extensional setting (Carajás Rift) with geochemical features similar to diabase from Nova Canadá (PA). The Pedra Branca magma was originated by partial melting (~28%), leaving a residue with plagioclase (An40), hornblende, clinopyroxene, and may or may not have magnetite.

ABSTRACT: The A-type Paleoproterozoic Bannach Granite belongs to the Jamon Suíte and cross-cut the Archean units of the Rio Maria Domain in the Carajás Province. It comprises eight facies with varied mafic content and texture: even-grained cumulate granite (CG), even coarse-grained biotite-amphibole monzogranite (cBAMz), even coarse-grained amphibole-biotite monzogranite (cABMz), porphyritic biotite monzogranite (pBMz), even coarse-grained leucomonzogranite (cLMz), early even medium-grained leucomonzogranite (EmLMz), late even medium-grained leucomonzogranite (LmLMz) and even fine-grained leucomonzogranite (fLMz). In the less evolved facies, the dominant amphibole is Fe-hornblende passing to Fe-edenite or hastingsite, with associated cummingtonite/grunerite originated from the destabilization of clinopyroxene. Biotite has ferroan composition and approaches annite in the late-emplaced leucomonzogranite. Plagioclase varies from andesine to oligoclase or from oligoclase to albite. Titanite, magnetite, and ilmenite are found in all granite facies showing magmatic origin. The near liquidus temperatures vary between 943ºC and 795ºC and the estimated emplacement pressure is 300 ± 50 MPa (~11.1 ± 1.9 km). Amphibole Fe/(Fe + Mg) ratios together with magmatic magnetite and titanite indicate that these granites crystallized at moderately oxidizing conditions, similar to those admitted for the Jamon granite and magnetite series granites of Laurentia. However, the composition of biotite suggests a more reduced character close to NNO to NNO -0.5. The late leucomonzogranite facies is an exception because it displays high Fe/(Fe + Mg) ratios in biotite and approaches to the reduced granites of Carajás, Laurentia and Fennoscandia in this regard. It derived from a more reduced source than the other facies of Bannach Granite.

Resumo: O topázio-álcali-feldspato-granito, fácies mais evoluída do plúton Água Boa, foi afetado por processos de alteração hidrotermal, que culminaram com a formação de greisens e veios de quartzo, principais hospedeiros de mineralizações de Sn e, subordinadamente, Zn. Os greisens foram classificados como quartzotopázio-siderofilita-greisen, topázio-siderofilita-quartzo-greisen e topázio-quartzo-greisen. São compostos por quartzo, siderofilita e topázio, acompanhados por quantidades variáveis de fluorita, zinnwaldita, esfalerita, cassiterita, zircão, anatásio e, localmente, Ce-monazita, galena, pirita, calcopirita e bismuto nativo. Estudos de química mineral em microssonda eletrônica permitiram identificar três tipos de micas: (1) siderofilita marrom, presente no topázio-granito; (2) siderofilita verde, encontrada nos greisens; (3) zinnwaldita, fracamente colorida, encontrada como coroas finas e descontínuas em torno da siderofilita verde dos greisens, e encontrada também em veios de quartzo. A composição da siderofilita do granito varia com a proximidade dos greisens, mostrando uma evolução de siderofilita → siderofilita litinífera, com aumento nos conteúdos de VIAl, Li e Si. A siderofilita do greisen foi, por sua vez, parcialmente substituída por zinnwaldita, também com aumento nos teores de VIAl, Li e Si. A cassiterita nos greisens forma cristais euédricos a subédricos em contato reto com siderofilita ou como agregados junto com topázio, quartzo e fluorita. Exibe cristais maclados, zonados e com forte pleocroísmo. As composições muito puras e baixos conteúdos de Nb e Ta, indicam formação em condições hidrotermais.

Abstract: The topaz-alkali-feldspar-granite, the most evolved facies of the Água Boa pluton, was affected by hydrothermal alteration, represented by greisens and quartz veins, the main host for Sn- and subordinated Zn mineralization. The greisens are classified as quartz-topaz-siderophyllite-greisen, topaz-siderophyllite-greisen and quartztopaz-quartz-greisen. They are composed essentially of quartz, topaz and siderophyllite, accompanied by variable amounts of fluorite, zinnwaldite, sphalerite, cassiterite, zircon and anatase and locally Ce-monazite, galena, pyrite, chalcopyrite and native bismuth. EMPA studies allowed identifying three types of micas: (1) brown siderophyllite from topaz-granite; (2) the green siderophyllite of greisens and (3) zinnwaldite, weakly colored, found as thin and discontinuous rims around green siderophyllite, and quartz vein. The siderophyllite composition of the granite towards greisens shows an evolution of siderophyllite to Li-siderophyllite with increase of VIAl, Li and Si contents. On the other hand, the siderophyllite of the greisen was partially replaced by zinnwaldite, with increase of VIAl, Li and Si contents. The cassiterite in the greisens forms euhedral to subeuhedral, twin and zoned crystals, with strong pleochroism. It occurs as aggregates together with topaz, quart and fluorite. The pure composition and the low content of the Nb and Ta of cassiterite indicate hydrothermal conditions